BRPI0815885A8 - Veículo para catalisador de óxido de olefina - Google Patents
Veículo para catalisador de óxido de olefinaInfo
- Publication number
- BRPI0815885A8 BRPI0815885A8 BRPI0815885A BRPI0815885A BRPI0815885A8 BR PI0815885 A8 BRPI0815885 A8 BR PI0815885A8 BR PI0815885 A BRPI0815885 A BR PI0815885A BR PI0815885 A BRPI0815885 A BR PI0815885A BR PI0815885 A8 BRPI0815885 A8 BR PI0815885A8
- Authority
- BR
- Brazil
- Prior art keywords
- vehicle
- olefin
- pores
- less
- olefin oxide
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
- B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/657—Pore diameter larger than 1000 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Epoxy Compounds (AREA)
Abstract
VEÍCULO PARA CATALISADOR DE ÓXIDO DE OLEFINA. Trata-se de um veículo para um catalisador útil para a epoxidação de uma olefina, que compreende um veículo sólido inerte e refratário. O veículo possui nenhum ou pouco volume absoluto de poros pequenos, de menos de 1 micrometro, e poros grandes, de mais de 5 micrometros. Entende-se por nenhum ou pouco volume absoluto de poros pequenos de menos de 1 mícron que o volume de poro de tais poros é menor do que 0,20 mL/g. Entende-se por nenhum ou pouco volume absoluto de poros grandes de mais de 5 micra que o volume de poro de tais poros é menor do que 0,20 mL/g. A invenção também propõe um catalisador útil para a epoxidação de uma olefina suportada em tal veículo e um processo para a oxidação de uma olefina, especialmente etileno, em um óxido de olefina, especialmente óxido de etileno.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/847,422 US7714152B2 (en) | 2007-08-30 | 2007-08-30 | Carrier for olefin oxide catalyst |
| PCT/US2008/072940 WO2009029414A1 (en) | 2007-08-30 | 2008-08-13 | Carrier for olefin oxide catalyst |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0815885A2 BRPI0815885A2 (pt) | 2015-02-18 |
| BRPI0815885A8 true BRPI0815885A8 (pt) | 2017-09-12 |
Family
ID=40387700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0815885A BRPI0815885A8 (pt) | 2007-08-30 | 2008-08-13 | Veículo para catalisador de óxido de olefina |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7714152B2 (pt) |
| EP (1) | EP2190575A4 (pt) |
| JP (1) | JP2010537807A (pt) |
| KR (1) | KR101502919B1 (pt) |
| CN (2) | CN101795762A (pt) |
| BR (1) | BRPI0815885A8 (pt) |
| CA (1) | CA2697771C (pt) |
| RU (1) | RU2464087C2 (pt) |
| TW (1) | TWI436827B (pt) |
| WO (1) | WO2009029414A1 (pt) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9115104B2 (en) | 2009-01-27 | 2015-08-25 | Scientific Design Company, Inc. | Ethylene oxide catalyst with optimized cesium content |
| CN102458651B (zh) | 2009-04-21 | 2015-06-10 | 陶氏技术投资有限公司 | 铼助催化的环氧化催化剂及其制造和使用方法 |
| EP2542340A4 (en) | 2010-03-01 | 2014-03-19 | Shell Oil Co | EPOXIDATION CATALYST, PROCESS FOR PREPARING THE CATALYST AND METHOD FOR PRODUCING AN OLEFIN OXIDE |
| US8883678B2 (en) * | 2010-06-04 | 2014-11-11 | Scientific Design Company, Inc. | Carrier for ethylene oxide catalysts |
| US8586769B2 (en) * | 2010-06-04 | 2013-11-19 | Scientific Design Company, Inc. | Carrier for ethylene oxide catalysts |
| US9018126B2 (en) | 2010-07-13 | 2015-04-28 | Shell Oil Company | Epoxidation catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide |
| KR101577613B1 (ko) | 2010-12-29 | 2015-12-15 | 생-고뱅 세라믹스 앤드 플라스틱스, 인코포레이티드 | 멀티 로브 다공성 세라믹 몸체 및 이를 제조하기 위한 방법 |
| CN107020094B (zh) | 2011-10-31 | 2019-10-11 | 陶氏技术投资有限责任公司 | 生产环氧化催化剂的方法和利用所述环氧化催化剂的环氧化方法 |
| WO2013077839A1 (en) * | 2011-11-21 | 2013-05-30 | Scientific Design Company, Inc. | Carrier for ethylene oxide catalysts |
| TW201442779A (zh) * | 2013-02-07 | 2014-11-16 | Scient Design Co | 用於銀基環氧乙烷觸媒之經改質載體 |
| US9714227B2 (en) * | 2013-12-09 | 2017-07-25 | Basf Se | Catalyst for the epoxidation of alkenes |
| WO2015136390A1 (en) * | 2014-03-14 | 2015-09-17 | Reliance Industries Limited | Stabilized inorganic oxide supports and adsorbents derived therefrom for carbon dioxide capture |
| TWI712577B (zh) | 2015-06-02 | 2020-12-11 | 美商科學設計有限公司 | 具有增強的孔結構的多孔體 |
| US10449520B2 (en) * | 2017-05-15 | 2019-10-22 | Scientific Design Company, Inc. | Porous bodies with enhanced crush strength |
| WO2019154863A1 (en) | 2018-02-07 | 2019-08-15 | Basf Se | Method for preparing a silver impregnation solution |
| TWI808125B (zh) | 2018-02-07 | 2023-07-11 | 德商巴斯夫歐洲公司 | 有效地將乙烯氧化轉化為環氧乙烷之催化劑 |
| EP3639924A1 (en) | 2018-10-15 | 2020-04-22 | Basf Se | Catalyst for producing ethylene oxide by gas-phase oxidation |
| EP3639923A1 (en) | 2018-10-15 | 2020-04-22 | Basf Se | Process for producing ethylene oxide by gas-phase oxidation of ethylene |
| EP3659703A1 (en) | 2018-11-28 | 2020-06-03 | Basf Se | Catalyst for producing ethylene oxide by gas-phase oxidation |
| CN112206798B (zh) * | 2020-10-29 | 2022-03-22 | 润和催化材料(浙江)有限公司 | 一种乙烯氧化制环氧乙烷的银催化剂及其制备方法和应用 |
| CN113617353B (zh) * | 2021-08-02 | 2023-09-22 | 常州大学 | 一种碳化硅基银纳米催化剂的制备方法及在环氧乙烷合成中的应用 |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1170663A (en) | 1967-03-22 | 1969-11-12 | Shell Int Research | Process for preparing Silver Catalysts |
| US3702259A (en) | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
| US3950507A (en) * | 1974-03-19 | 1976-04-13 | Boreskov Georgy Konstantinovic | Method for producing granulated porous corundum |
| US4212772A (en) * | 1976-05-19 | 1980-07-15 | Basf Aktiengesellschaft | Catalyst for the manufacture of ethylene oxide |
| GB1594362A (en) | 1977-05-23 | 1981-07-30 | Ici Ltd | Production of alkylene oxides and catalysts therefor |
| FR2412538A1 (fr) | 1977-12-22 | 1979-07-20 | Ugine Kuhlmann | Catalyseurs a base d'argent pour la production d'oxyde d'ethylene |
| US4301037A (en) * | 1980-04-01 | 1981-11-17 | W. R. Grace & Co. | Extruded alumina catalyst support having controlled distribution of pore sizes |
| US4379134A (en) * | 1981-02-13 | 1983-04-05 | Union Carbide Corporation | Process of preparing high purity alumina bodies |
| US4994589A (en) * | 1985-08-13 | 1991-02-19 | Union Carbide Chemicals And Plastics Company Inc. | Catalytic system for epoxidation of alkenes |
| US4994588A (en) * | 1985-08-13 | 1991-02-19 | Union Carbide Chemicals And Plastics Company Inc. | Fluorine-containing catalytic system for expoxidation of alkenes |
| US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| CN1009437B (zh) * | 1988-02-03 | 1990-09-05 | 中国石油化工总公司 | 乙烯氧化制环氧乙烷高效银催化剂 |
| DE68925767T2 (de) | 1988-08-30 | 1996-08-14 | Union Carbide Corp | Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5051395A (en) * | 1989-09-25 | 1991-09-24 | Union Carbide Chemicals And Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or efficiency |
| US5187140A (en) | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
| US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US5112795A (en) | 1990-10-12 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Supported silver catalyst, and processes for making and using same |
| DE4106508A1 (de) | 1991-03-01 | 1992-09-03 | Basf Ag | Silberkatalysator |
| US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
| US5266548A (en) | 1992-08-31 | 1993-11-30 | Norton Chemical Process Products Corp. | Catalyst carrier |
| IL109236A (en) * | 1993-04-13 | 1998-01-04 | Sumitomo Chemical Co | A-alumina powder and its production |
| US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5418202A (en) | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
| DE19533486A1 (de) * | 1995-09-12 | 1997-03-13 | Basf Ag | Monomodale und polymodale Katalysatorträger und Katalysatoren mit engen Porengrößenverteilungen und deren Herstellverfahren |
| JP4206404B2 (ja) * | 1995-09-25 | 2009-01-14 | 三菱化学株式会社 | 酸化エチレン製造用触媒 |
| WO1997046317A1 (en) | 1996-06-05 | 1997-12-11 | Shell Internationale Research Maatschappij B.V. | Epoxidation catalyst and process |
| US6831037B2 (en) | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
| CN100553763C (zh) * | 2002-02-25 | 2009-10-28 | 国际壳牌研究有限公司 | 负载的银催化剂和使用该催化剂的环氧化方法 |
| JP4537848B2 (ja) * | 2002-06-28 | 2010-09-08 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の選択性を改善する方法及びオレフィンのエポキシ化方法 |
| WO2004039790A1 (en) | 2002-10-28 | 2004-05-13 | Shell Internationale Research Maatschappij B.V. | Olefin oxide catalysts |
| CN1297345C (zh) * | 2004-01-13 | 2007-01-31 | 厦门大学 | 一种固体催化剂在苯乙烯环氧化制环氧苯乙烷中的应用 |
| US7507844B2 (en) | 2005-05-09 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Nanometer scale restructuring of alumina carrier surface and catalysts for the production of alkene oxides |
| BRPI0611676B1 (pt) * | 2005-06-07 | 2015-08-11 | Shell Int Research | Catalisador, processo para a preparação do catalisador, e processo para a produção de um óxido de olefina, um 1,2- diol, e um 1,2-diol éter e uma alcanolamina |
| TW200744749A (en) * | 2005-12-22 | 2007-12-16 | Shell Int Research | A process for the preparation of a chemical derivable from an olefin oxide, and a reactor suitable for such a process |
| JP4267015B2 (ja) | 2006-09-29 | 2009-05-27 | 株式会社日本触媒 | エチレンオキシド製造用触媒およびエチレンオキシドの製造方法 |
| EP3677334B1 (en) * | 2006-11-01 | 2024-06-19 | Dow Global Technologies Llc | Alpha-alumina carrier for epoxidation catalyst and epoxidation method |
-
2007
- 2007-08-30 US US11/847,422 patent/US7714152B2/en not_active Expired - Fee Related
-
2008
- 2008-08-13 CN CN200880105020A patent/CN101795762A/zh active Pending
- 2008-08-13 EP EP08797731.0A patent/EP2190575A4/en not_active Withdrawn
- 2008-08-13 WO PCT/US2008/072940 patent/WO2009029414A1/en not_active Ceased
- 2008-08-13 JP JP2010523023A patent/JP2010537807A/ja active Pending
- 2008-08-13 CN CN201510543875.0A patent/CN105126795A/zh active Pending
- 2008-08-13 CA CA2697771A patent/CA2697771C/en active Active
- 2008-08-13 RU RU2010111905/04A patent/RU2464087C2/ru active
- 2008-08-13 KR KR1020107006476A patent/KR101502919B1/ko active Active
- 2008-08-13 BR BRPI0815885A patent/BRPI0815885A8/pt not_active Application Discontinuation
- 2008-08-27 TW TW097132757A patent/TWI436827B/zh active
-
2010
- 2010-03-26 US US12/732,664 patent/US20100179336A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0815885A2 (pt) | 2015-02-18 |
| RU2464087C2 (ru) | 2012-10-20 |
| RU2010111905A (ru) | 2011-10-10 |
| US20100179336A1 (en) | 2010-07-15 |
| EP2190575A4 (en) | 2014-05-21 |
| US7714152B2 (en) | 2010-05-11 |
| KR101502919B1 (ko) | 2015-03-16 |
| US20090062556A1 (en) | 2009-03-05 |
| CN101795762A (zh) | 2010-08-04 |
| WO2009029414A1 (en) | 2009-03-05 |
| JP2010537807A (ja) | 2010-12-09 |
| CA2697771C (en) | 2018-09-04 |
| TWI436827B (zh) | 2014-05-11 |
| KR20100061698A (ko) | 2010-06-08 |
| EP2190575A1 (en) | 2010-06-02 |
| CN105126795A (zh) | 2015-12-09 |
| TW200927286A (en) | 2009-07-01 |
| CA2697771A1 (en) | 2009-03-05 |
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