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MX2015014630A - Metodo para la preparacion de un silicato de metal del grupo 4 y su uso. - Google Patents

Metodo para la preparacion de un silicato de metal del grupo 4 y su uso.

Info

Publication number
MX2015014630A
MX2015014630A MX2015014630A MX2015014630A MX2015014630A MX 2015014630 A MX2015014630 A MX 2015014630A MX 2015014630 A MX2015014630 A MX 2015014630A MX 2015014630 A MX2015014630 A MX 2015014630A MX 2015014630 A MX2015014630 A MX 2015014630A
Authority
MX
Mexico
Prior art keywords
preparation
group
metal silicate
silicate
pore
Prior art date
Application number
MX2015014630A
Other languages
English (en)
Inventor
Jim Aloysius Maria Brandts
Lorianne Wagemaker
Original Assignee
Basf Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Corp filed Critical Basf Corp
Publication of MX2015014630A publication Critical patent/MX2015014630A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/80—Catalysts, in general, characterised by their form or physical properties characterised by their amorphous structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30—Ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/28—Treatment of water, waste water, or sewage by sorption
    • C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • C11C3/10—Ester interchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/006—Radioactive compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Nanotechnology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

La invención provee un método para la preparación de un silicato amorfo de por lo menos un metal del Grupo 4 de la Tabla Periódica de Elementos con un volumen de poro total de por lo menos 0.3 ml/g. El método de preparación involucra el uso de condiciones de formación de poros, que pueden ser el uso de un formador de poros y opcionalmente un aumento de la temperatura de precipitación, por ejemplo por lo menos 60°C. El silicato de la invención es especialmente adecuado en reacciones catalíticas tales como esterificaciones, adiciones de Michael, transesterificaciones, (ep) oxidaciones, hidroxilaciones, o en adsorbencia de moléculas inorgánicas y orgánicas pequeñas, por ejemplo CO2 o compuestos aromáticos.
MX2015014630A 2013-04-17 2014-04-16 Metodo para la preparacion de un silicato de metal del grupo 4 y su uso. MX2015014630A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13164165 2013-04-17
PCT/IB2014/060755 WO2014170835A1 (en) 2013-04-17 2014-04-16 Method for preparation of a group 4 metal silicate and use thereof

Publications (1)

Publication Number Publication Date
MX2015014630A true MX2015014630A (es) 2016-03-01

Family

ID=48142651

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2015014630A MX2015014630A (es) 2013-04-17 2014-04-16 Metodo para la preparacion de un silicato de metal del grupo 4 y su uso.

Country Status (12)

Country Link
US (2) US9764315B2 (es)
EP (1) EP2986558B1 (es)
JP (1) JP6218925B2 (es)
CN (1) CN105377760B (es)
AR (1) AR095886A1 (es)
BR (1) BR112015026346B1 (es)
CA (1) CA2909781C (es)
MX (1) MX2015014630A (es)
MY (1) MY194934A (es)
RU (1) RU2015149207A (es)
TW (1) TWI647178B (es)
WO (1) WO2014170835A1 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112015016324A2 (pt) * 2013-01-09 2017-07-11 Basf Corp método de remoção de radionuclídeos divalentes e/ou trivalentes de um fluxo de água
US20160365578A1 (en) * 2015-06-12 2016-12-15 Sharp Kabushiki Kaisha Sodium transition metal silicate and method of forming same
EP4071115A1 (en) * 2017-01-18 2022-10-12 Massachusetts Institute Of Technology Potassium-releasing material
EA039758B1 (ru) * 2017-06-16 2022-03-10 Массачусетс Инститьют Оф Текнолоджи Материал, высвобождающий калий
US11964266B2 (en) * 2019-07-09 2024-04-23 Uop Llc Process for removing cobalt, lead, cadmium and chromium ions from bodily fluids using metallate ion exchange compositions
CN112871206B (zh) * 2021-01-19 2022-04-08 中国科学院大连化学物理研究所 一种低成本高活性苯酚羟基化钛硅分子筛催化剂的制备方法
US20230356180A1 (en) * 2022-05-03 2023-11-09 Graver Technologies Llc Sorbent for removal of ions from liquid streams and method of making the same
CN115255347B (zh) * 2022-06-30 2024-08-09 南昌大学 一种钨硅酸化微米零价铁材料及其制备方法和应用

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6046915A (ja) 1983-08-24 1985-03-14 Taki Chem Co Ltd 合成無定形ジルコニウム結合珪酸塩及びその製造方法
US5053139A (en) * 1990-12-04 1991-10-01 Engelhard Corporation Removal of heavy metals, especially lead, from aqueous systems containing competing ions utilizing amorphous tin and titanium silicates
IT1244478B (it) 1990-12-21 1994-07-15 Eniricerche Spa Gel cataliticamente attivo e procedimento per la sua preparazione
US5508457A (en) 1993-05-04 1996-04-16 Engelhard De Meern B.V. Esterification process
JP3577681B2 (ja) * 1995-08-29 2004-10-13 日本化学工業株式会社 メソポーラスメタロシリケートの製造方法
JPH11140025A (ja) * 1997-11-06 1999-05-25 Mitsubishi Chemical Corp カルボン酸エステルの製造方法
US6482380B1 (en) * 2000-11-22 2002-11-19 The United States Of America As Represented By The Department Of Energy Silicotitanate molecular sieve and condensed phases
JP4034958B2 (ja) 2001-11-13 2008-01-16 触媒化成工業株式会社 歯科材料用無機粒子およびその製造方法
JP4831663B2 (ja) * 2004-10-27 2011-12-07 独立行政法人産業技術総合研究所 薄板状多孔質シリカ金属複合体粒子とその製造方法
CN101757929B (zh) * 2008-12-24 2012-01-25 中国石油化工股份有限公司 一种加氢裂化催化剂及其制备方法
WO2010101991A1 (en) * 2009-03-04 2010-09-10 Basf Se Method of removing heavy metal from an aqueous solution

Also Published As

Publication number Publication date
TWI647178B (zh) 2019-01-11
US20180015447A1 (en) 2018-01-18
CA2909781C (en) 2019-01-15
EP2986558B1 (en) 2020-01-08
RU2015149207A (ru) 2017-05-22
CA2909781A1 (en) 2014-10-23
AR095886A1 (es) 2015-11-18
US20160067693A1 (en) 2016-03-10
CN105377760A (zh) 2016-03-02
US9764315B2 (en) 2017-09-19
JP6218925B2 (ja) 2017-10-25
US10286390B2 (en) 2019-05-14
CN105377760B (zh) 2018-02-06
MY194934A (en) 2022-12-25
BR112015026346B1 (pt) 2021-08-10
EP2986558A1 (en) 2016-02-24
WO2014170835A1 (en) 2014-10-23
BR112015026346A2 (pt) 2017-07-25
TW201504146A (zh) 2015-02-01
JP2016517840A (ja) 2016-06-20

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