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BRPI0418977B8 - processo para converter material carbonífero em gases energéticos e sistema para produzir um gás sintético - Google Patents

processo para converter material carbonífero em gases energéticos e sistema para produzir um gás sintético

Info

Publication number
BRPI0418977B8
BRPI0418977B8 BRPI0418977A BRPI0418977A BRPI0418977B8 BR PI0418977 B8 BRPI0418977 B8 BR PI0418977B8 BR PI0418977 A BRPI0418977 A BR PI0418977A BR PI0418977 A BRPI0418977 A BR PI0418977A BR PI0418977 B8 BRPI0418977 B8 BR PI0418977B8
Authority
BR
Brazil
Prior art keywords
hydrogen
steam
synthetic gas
liquid fuel
fed
Prior art date
Application number
BRPI0418977A
Other languages
English (en)
Inventor
Colin E Hackett
Joseph N Norbeck
Original Assignee
Univ Califórnia
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Califórnia filed Critical Univ Califórnia
Publication of BRPI0418977A publication Critical patent/BRPI0418977A/pt
Publication of BRPI0418977B1 publication Critical patent/BRPI0418977B1/pt
Publication of BRPI0418977B8 publication Critical patent/BRPI0418977B8/pt

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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
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    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
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    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
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    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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    • C10J3/58—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels combined with pre-distillation of the fuel
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    • C10J3/723—Controlling or regulating the gasification process
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D1/00—Heat-exchange apparatus having stationary conduit assemblies for one heat-exchange medium only, the media being in contact with different sides of the conduit wall, in which the other heat-exchange medium is a large body of fluid, e.g. domestic or motor car radiators
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    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
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    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Physics & Mathematics (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Treatment Of Sludge (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Liquid Carbonaceous Fuels (AREA)
  • Industrial Gases (AREA)

Abstract

processo para converter material carbonífero em gases energéticos, processos para a produção de gás sintético e de combustível líquido; aparelhos para produção de um gás sintético e de combustível líquido em um processo substancialmente auto-sustentável um processo e aparelho para produção de um gás sintético para uso como um combustível gasoso ou um alimento dentro de um reator fischer-tropsch para produzir um combustível líquido em um processo substancialmente auto-sustentável. em uma configuração, uma pasta fluida de partículas de material carbonífero na água, e hidrogênio de uma fonte interna, são alimentados dentro de um reator de hidro-gasificação sob condições por meio das quais gases produtos ricos em metano são gerados e alimentados dentro de um reformador pirolítico a vapor sob condições por meio das quais o gás sintético compreendendo hidrogênio e monóxido de carbono são gerados. uma porção do hidrogênio gerado pelo reformador pirolítico a vapor é alimentado através de um filtro de purificação de hidrogênio dentro do reator de hidro-gasificação, o hidrogênio distro constituindo o hidrogênio de uma fonte interna. o gás sintético remanescente gerado pelo reformador pirolitico a vapor é igualmente usado como combustível gasoso para um motor abastecido para produzir eletricidade e/ou transformador calor ou é alimentado dentro de um reator fischer-tropsch sob condições por meio das quais um combustível líquido é produzido. circuitos de sal fundido são usados para transferir calor do reator de hidro-gasificação, e o reator fischer-tropsch se o combustível liquido é produzido, para o gerador a vapor e o reformador pirolitico a vapor. em outra configuração da invenção, material carbonífero pode ser aquecido simultaneamente na presença de ambos hidrogênio e vapor para ser submetido a pirólise a vapor e hidro-gasificação em uma etapa única.
BRPI0418977A 2004-08-03 2004-08-04 processo para converter material carbonífero em gases energéticos e sistema para produzir um gás sintético BRPI0418977B8 (pt)

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US10/911,348 US7500997B2 (en) 2002-02-05 2004-08-03 Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials
US10/911.348 2004-08-03
PCT/US2004/025254 WO2006022687A2 (en) 2004-08-03 2004-08-04 Steam pyrolysis as a process to enhance the hydro-gasification of carbonaceous materials

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BRPI0418977B1 BRPI0418977B1 (pt) 2014-02-11
BRPI0418977B8 true BRPI0418977B8 (pt) 2016-05-24

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US (1) US7500997B2 (pt)
EP (1) EP1792134A2 (pt)
JP (1) JP2008525532A (pt)
KR (1) KR20070042571A (pt)
CN (1) CN101218018B (pt)
AU (1) AU2004322730B2 (pt)
BR (1) BRPI0418977B8 (pt)
CA (1) CA2575963C (pt)
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RU (1) RU2007108085A (pt)
WO (1) WO2006022687A2 (pt)

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