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BRPI0417185A - material de superte contendo zircÈnia para catalizadores - Google Patents

material de superte contendo zircÈnia para catalizadores

Info

Publication number
BRPI0417185A
BRPI0417185A BRPI0417185-3A BRPI0417185A BRPI0417185A BR PI0417185 A BRPI0417185 A BR PI0417185A BR PI0417185 A BRPI0417185 A BR PI0417185A BR PI0417185 A BRPI0417185 A BR PI0417185A
Authority
BR
Brazil
Prior art keywords
catalyst
palladium
support material
relates
gold
Prior art date
Application number
BRPI0417185-3A
Other languages
English (en)
Inventor
Tao Wang
Leslie E Wade
Victor Wong
David M Lowe
Jun Han
Valery Sokolovskii
Alfred Hagemeyer
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of BRPI0417185A publication Critical patent/BRPI0417185A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/398—Egg yolk like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/399—Distribution of the active metal ingredient homogeneously throughout the support particle
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"MATERIAL DE SUPORTE CONTENDO ZIRCÈNIA PARA CATALISADORES". A presente invenção refere-se a pelo menos quatro diferentes aspectos relacionados com estrutura de catalisadores, métodos de fabricação destes catalisadores e métodos de utilização daqueles catalisadores para fabricar alcanoatos de alquenila. Separadamente ou juntos, os diversos aspectos da invenção referem-se a aperfeiçoar a produção de alcanoatos de alquenila e VA em especial, incluindo a redução de subprodutos e eficiência de produção melhorada. Um primeiro aspecto da presente invenção refere-se a um catalisador único de paládio/ouro ou pré-catalisador (opcionalmente calcinado) que inclui ródio ou outro metal. Um segundo aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador que é baseado em um material de suporte em camadas onde uma camada do material de suporte é substancialmente isenta de componentes cataliticos. Um terceiro aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador sobre um material de suporte que contém zircónia. Um quarto aspecto refere-se a um catalisador de paládio/ouro ou pré-catalisador que é produzido a partir de componentes catalíticos substancialmente isentos de cloro.
BRPI0417185-3A 2003-12-19 2004-11-19 material de superte contendo zircÈnia para catalizadores BRPI0417185A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53148603P 2003-12-19 2003-12-19
PCT/US2004/039039 WO2005061107A1 (en) 2003-12-19 2004-11-19 Zirconia containing support material for catalysts

Publications (1)

Publication Number Publication Date
BRPI0417185A true BRPI0417185A (pt) 2007-03-06

Family

ID=34710229

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0417185-3A BRPI0417185A (pt) 2003-12-19 2004-11-19 material de superte contendo zircÈnia para catalizadores

Country Status (14)

Country Link
EP (1) EP1694436A1 (pt)
JP (1) JP4772695B2 (pt)
KR (1) KR100886048B1 (pt)
CN (1) CN100457257C (pt)
AU (1) AU2004305515C1 (pt)
BR (1) BRPI0417185A (pt)
CA (1) CA2547187C (pt)
NO (1) NO20062531L (pt)
NZ (1) NZ547072A (pt)
PL (1) PL215127B1 (pt)
RU (2) RU2006119185A (pt)
UA (1) UA96563C2 (pt)
WO (1) WO2005061107A1 (pt)
ZA (1) ZA200604362B (pt)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8168562B2 (en) 2006-02-02 2012-05-01 Lyondell Chemical Technology, L.P. Preparation of palladium-gold catalysts
DE102007025356A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025444A1 (de) * 2007-05-31 2008-12-11 Süd-Chemie AG VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025358A1 (de) * 2007-05-31 2009-01-08 Süd-Chemie AG Verfahren zur Herstellung eines mit Pd und/oder Au beladenen Schalenkatalysators
DE102007025223A1 (de) * 2007-05-31 2008-12-04 Süd-Chemie AG Zirkoniumoxid-dotierter VAM-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025442B4 (de) 2007-05-31 2023-03-02 Clariant International Ltd. Verwendung einer Vorrichtung zur Herstellung eines Schalenkatalysators und Schalenkatalysator
DE102007025362A1 (de) 2007-05-31 2008-12-11 Süd-Chemie AG Dotierter Pd/Au-Schalenkatalysator, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007025443A1 (de) 2007-05-31 2008-12-04 Süd-Chemie AG Pd/Au-Schalenkatalysator enthaltend HfO2, Verfahren zu dessen Herstellung sowie dessen Verwendung
DE102007043446B4 (de) 2007-09-12 2013-08-22 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter Wärmeleitfähigkeit
DE102007043447B4 (de) 2007-09-12 2014-02-13 Süd-Chemie Ip Gmbh & Co. Kg Katalysatorträger mit erhöhter thermischer Leitfähigkeit
DE102008058971A1 (de) * 2008-11-25 2010-07-15 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
DE202008017277U1 (de) * 2008-11-30 2009-04-30 Süd-Chemie AG Katalysatorträger
DE102008059340A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Katalysatorträger, Verfahren zu seiner Herstellung sowie dessen Verwendung
DE102008059342A1 (de) 2008-11-30 2010-06-10 Süd-Chemie AG Schalenkatalysator, Verfahren zu seiner Herstellung sowie Verwendung
DE102010026462A1 (de) * 2010-07-08 2012-01-12 Süd-Chemie AG Verfahren zur Herstellung eines Schalenkatalysators und Schalenkatalysator
CN102153189A (zh) * 2010-12-16 2011-08-17 哈尔滨工业大学 浮石催化臭氧化去除水中有机物的方法
DE102012008714A1 (de) * 2012-05-03 2013-11-07 Clariant Produkte (Deutschland) Gmbh Vorimprägnierung von Schalenkatalysatoren mit einem Acetat
CN106215561B (zh) * 2016-08-31 2018-04-20 苏州贝捷环保设备有限公司 一种燃煤烟气处理方法
CN107096532B (zh) * 2017-05-16 2019-12-10 嘉兴学院 一种Au-ZrO2催化剂及其应用

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19501891C1 (de) * 1995-01-23 1996-09-26 Degussa Verfahren zur Herstellung eines Trägerkatalysators und seine Verwendung für die Produktion von Vinylacetat
US6072078A (en) * 1997-12-12 2000-06-06 Celanese International Corporation Vinyl acetate production using a catalyst comprising palladium, gold, copper and any of certain fourth metals
US6015769A (en) * 1998-06-02 2000-01-18 Celanese International Corporation Vinyl acetate catalyst comprising metallic palladium, gold and copper supported on a carrier and prepared with potassium aurate
DE19843693A1 (de) * 1998-09-24 2000-03-30 Degussa Trägerkatalysator für die Produktion von Vinylacetatmonomer
US6358882B1 (en) * 1998-12-08 2002-03-19 The Standard Oil Company Fluid bed vinyl acetate catalyst
DE10030039A1 (de) * 2000-06-17 2002-01-10 Celanese Chem Europe Gmbh Katalysator zur Herstellung von Vinylacetat und Verfahren zur Herstellung des Katalysators

Also Published As

Publication number Publication date
KR100886048B1 (ko) 2009-02-26
KR20060103514A (ko) 2006-10-02
AU2004305515A1 (en) 2005-07-07
CA2547187A1 (en) 2005-07-07
WO2005061107A1 (en) 2005-07-07
PL215127B1 (pl) 2013-10-31
JP2007514543A (ja) 2007-06-07
CN1894035A (zh) 2007-01-10
CA2547187C (en) 2010-11-02
EP1694436A1 (en) 2006-08-30
PL380021A1 (pl) 2006-12-11
AU2004305515C1 (en) 2009-06-25
ZA200604362B (en) 2007-11-28
UA96563C2 (ru) 2011-11-25
NO20062531L (no) 2006-07-03
AU2004305515B2 (en) 2008-08-28
CN100457257C (zh) 2009-02-04
NZ547072A (en) 2010-05-28
JP4772695B2 (ja) 2011-09-14
RU2006119185A (ru) 2007-12-20
RU2011131292A (ru) 2013-02-10

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Legal Events

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B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O E 13 DA LPI.

B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.