BR9911208A - Processo de epoxidação para aril alil éteres. - Google Patents
Processo de epoxidação para aril alil éteres.Info
- Publication number
- BR9911208A BR9911208A BR9911208-6A BR9911208A BR9911208A BR 9911208 A BR9911208 A BR 9911208A BR 9911208 A BR9911208 A BR 9911208A BR 9911208 A BR9911208 A BR 9911208A
- Authority
- BR
- Brazil
- Prior art keywords
- percent
- transition metal
- ethers
- allyl ethers
- epoxidation
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 238000006735 epoxidation reaction Methods 0.000 title abstract 3
- -1 aryl allyl ethers Chemical class 0.000 title abstract 2
- 229910052723 transition metal Inorganic materials 0.000 abstract 3
- 150000003624 transition metals Chemical class 0.000 abstract 3
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 abstract 2
- 239000004593 Epoxy Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 abstract 1
- 150000002170 ethers Chemical class 0.000 abstract 1
- 150000002432 hydroperoxides Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/19—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/02—Polycondensates containing more than one epoxy group per molecule
- C08G59/027—Polycondensates containing more than one epoxy group per molecule obtained by epoxidation of unsaturated precursor, e.g. polymer or monomer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Epoxy Compounds (AREA)
- Epoxy Resins (AREA)
Abstract
"PROCESSO DE EPOXIDAçãO PARA ARIL ALIL éTERES". Um processo para produzir um composto epóxi de glicidil éter aromático contatando um alil éter produzido a partir de uma parcela hidroxi de um composto aromático contendo hidroxi com um oxidante de hidroperóxido inorgânico ou orgânico na presença de um catalisador de complexo de metal de transição, sendo que pelo menos (a) o alil éter está conformacionalmente restrito ou (b) o catalisador de complexo de metal de transição contém pelo menos um ou mais ligantes estáveis ligados ao metal de transição. O processo da presente invenção provê epóxidar aril alil éteres com alto rendimento de epoxidação (por exemplo, maior que 70 por cento a 90 por cento) e alta seletividade a hidroperóxido (por exemplo, maior que 70 por cento a 90 por cento).
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8716998P | 1998-05-29 | 1998-05-29 | |
| PCT/US1999/011427 WO1999062894A2 (en) | 1998-05-29 | 1999-05-24 | Process for epoxidation of aryl allyl ethers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9911208A true BR9911208A (pt) | 2001-02-13 |
Family
ID=22203520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9911208-6A BR9911208A (pt) | 1998-05-29 | 1999-05-24 | Processo de epoxidação para aril alil éteres. |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP1080084B1 (pt) |
| JP (1) | JP2002517387A (pt) |
| KR (1) | KR20010043904A (pt) |
| CN (1) | CN1303382A (pt) |
| AU (1) | AU4096399A (pt) |
| BR (1) | BR9911208A (pt) |
| DE (1) | DE69917018T2 (pt) |
| TW (1) | TW448164B (pt) |
| WO (1) | WO1999062894A2 (pt) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6534621B2 (en) | 2000-05-18 | 2003-03-18 | Dow Global Technologies Inc. | Process for manufacturing a hydroxyester derivative intermediate and epoxy resins prepared therefrom |
| KR100342659B1 (en) * | 2000-12-15 | 2002-07-04 | Rstech Co Ltd | Chiral polymer salene catalyst and process for preparing chiral compounds from racemic epoxide using the same |
| EP1398080A1 (en) * | 2002-07-18 | 2004-03-17 | Nippon Shokubai Co., Ltd. | Liquid phase oxygenation reaction using tungsten species |
| JP3669360B2 (ja) * | 2002-11-29 | 2005-07-06 | 昭和高分子株式会社 | エポキシフルオレン化合物およびその製造方法 |
| US7030255B2 (en) * | 2004-03-09 | 2006-04-18 | Lyondell Chemical Technology, L.P. | Oxidation process with in-situ H202 generation and polymer-encapsulated catalysts therefor |
| JP2008505940A (ja) | 2004-07-14 | 2008-02-28 | スリーエム イーエスピーイー アーゲー | 不飽和ハロゲン化アリールアルキルエーテル成分を含む歯科用組成物 |
| CN101018536A (zh) * | 2004-07-14 | 2007-08-15 | 3M埃斯佩股份公司 | 含环氧官能可聚合化合物的牙科组合物 |
| JP4998261B2 (ja) * | 2005-06-06 | 2012-08-15 | 三菱瓦斯化学株式会社 | レジスト用化合物およびレジスト組成物 |
| JP2007197518A (ja) * | 2006-01-24 | 2007-08-09 | Fujifilm Corp | エポキシ樹脂化合物、熱硬化性樹脂組成物、及び感光性組成物 |
| JPWO2007094173A1 (ja) | 2006-02-17 | 2009-07-02 | 出光興産株式会社 | アダマンタン誘導体、それを含有する組成物及びその組成物を用いた光学電子部材 |
| JPWO2011019061A1 (ja) * | 2009-08-13 | 2013-01-17 | 昭和電工株式会社 | ポリグリシジルエーテル化合物の製造方法 |
| CN102666519B (zh) * | 2009-12-24 | 2016-01-13 | 昭和电工株式会社 | 环氧化合物的制造方法 |
| KR101415113B1 (ko) * | 2009-12-24 | 2014-07-04 | 도꾸리쯔교세이호진 상교기쥬쯔 소고겡뀨죠 | 글리시딜에테르 화합물의 제조 방법 및 모노알릴모노글리시딜에테르 화합물 |
| EP2357180A1 (en) * | 2010-02-02 | 2011-08-17 | Momentive Specialty Chemicals Research Belgium S.A. | Manufacture of epoxyethyl ethers or glycidyl ethers |
| TWI426090B (zh) * | 2011-05-31 | 2014-02-11 | Tsrc Corp | 製造環氧化聚合物的方法 |
| KR101252063B1 (ko) | 2011-08-25 | 2013-04-12 | 한국생산기술연구원 | 알콕시실릴기를 갖는 에폭시 화합물, 이의 제조 방법, 이를 포함하는 조성물과 경화물 및 이의 용도 |
| US9534075B2 (en) | 2011-11-01 | 2017-01-03 | Korea Institute Of Industrial Technology | Isocyanurate epoxy compound having alkoxysilyl group, method of preparing same, composition including same, cured product of the composition, and use of the composition |
| US9902803B2 (en) | 2012-03-14 | 2018-02-27 | Korea Institute Of Industrial Technology | Epoxy compound having alkoxy silyl group, composition comprising same, cured product, use thereof and method for preparing epoxy compound having alkoxy silyl group |
| KR101898526B1 (ko) | 2012-04-02 | 2018-09-14 | 한국생산기술연구원 | 알콕시실릴기를 갖는 에폭시 화합물, 이를 포함하는 조성물, 경화물, 이의 용도 및 알콕시실릴기를 갖는 에폭시 화합물의 제조방법 |
| KR101863111B1 (ko) | 2012-07-06 | 2018-06-01 | 한국생산기술연구원 | 노볼락계 에폭시 화합물, 이의 제조 방법, 이를 포함하는 조성물, 경화물 및 이의 용도 |
| US9127127B2 (en) | 2012-10-03 | 2015-09-08 | Sabic Global Technologies B.V. | Polyetherimide compositions, methods of manufacture, and articles formed therefrom |
| JPWO2014123051A1 (ja) * | 2013-02-05 | 2017-02-02 | 日本化薬株式会社 | アリルエーテル樹脂及びエポキシ樹脂 |
| MX2015013672A (es) | 2013-03-28 | 2016-02-16 | Procter & Gamble | Composiciones de limpieza que contiene una polieteramina, un polimero para el desprendimiento de la suciedad y una carboximetilcelulosa. |
| US10676571B2 (en) | 2013-12-02 | 2020-06-09 | Sabic Global Technologies B.V. | Polyetherimides with improved melt stability |
| WO2015148361A1 (en) | 2014-03-27 | 2015-10-01 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| EP3122849B1 (en) | 2014-03-27 | 2021-07-21 | The Procter & Gamble Company | Cleaning compositions containing a polyetheramine |
| WO2015187757A1 (en) | 2014-06-06 | 2015-12-10 | The Procter & Gamble Company | Detergent composition comprising polyalkyleneimine polymers |
| WO2016032991A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
| WO2016032992A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Detergent composition comprising a cationic polymer |
| CA2956121A1 (en) | 2014-08-27 | 2016-03-03 | The Procter & Gamble Company | Method of treating a fabric |
| US9951297B2 (en) | 2014-08-27 | 2018-04-24 | The Procter & Gamble Company | Detergent composition compromising a cationic polymer containing a vinyl formamide nonionic structural unit |
| CA2959431C (en) | 2014-09-25 | 2019-10-22 | The Procter & Gamble Company | Fabric care compositions containing a polyetheramine |
| FR3030514A1 (fr) * | 2014-12-18 | 2016-06-24 | Centre De Coop Int En Rech Agronomique Pour Le Dev (Cirad) | Dimeres polyaromatiques |
| CN104557532B (zh) * | 2015-01-13 | 2017-03-01 | 西安力邦制药有限公司 | 二联苯衍生物及其应用 |
| WO2019171167A1 (en) * | 2018-03-09 | 2019-09-12 | Chevron U.S.A. Inc. | Synthesis of *mre framework type molecular sieves |
| CN109985659B (zh) * | 2019-04-22 | 2022-03-01 | 南京工程学院 | 一种co2定向转化制备芳烃的催化剂及其制备方法 |
| KR102232340B1 (ko) | 2019-11-15 | 2021-03-26 | 한국생산기술연구원 | 알콕시실릴기를 갖는 에폭시 수지의 조성물 및 이의 복합체 |
| CN112920223B (zh) * | 2021-02-08 | 2022-09-20 | 兰州大学 | 一种用于醛与三甲基氰硅烷的硅腈化反应的催化剂及制备方法 |
| EP4386035A4 (en) | 2021-08-10 | 2025-07-30 | Nippon Catalytic Chem Ind | POLYALKYLENE OXIDE-CONTAINING COMPOUND |
| CN114920652B (zh) * | 2022-05-30 | 2024-04-19 | 宁波工程学院 | 光催化合成1-烷基苯乙烯衍生物的方法 |
| CN115960335B (zh) * | 2022-12-21 | 2025-08-26 | 江苏兴盛化工有限公司 | 一种超高分子量甲基溴化环氧树脂及其制备方法和应用 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4507492A (en) * | 1983-05-06 | 1985-03-26 | The Dow Chemical Company | Preparation of aromatic derivatives |
| JPS59227872A (ja) * | 1983-06-08 | 1984-12-21 | Sumitomo Chem Co Ltd | エポキシ化合物の製造方法 |
| JPS6056975A (ja) * | 1983-09-07 | 1985-04-02 | Sumitomo Chem Co Ltd | グリシジルエ−テルの製造方法 |
| CA1240942A (en) * | 1984-05-28 | 1988-08-23 | Keizo Furuhashi | Process for the preparation of epoxides by means of microorganisms |
| US4740330A (en) * | 1986-09-03 | 1988-04-26 | The Dow Chemical Company | Method for allylating aromatic hydroxyl-containing compounds |
| US5118822A (en) * | 1991-09-30 | 1992-06-02 | Arco Chemical Technology, L.P. | Olefin epoxidation using a perrhenate catalyst and an organic hydroperoxide |
| US5319114A (en) * | 1993-09-23 | 1994-06-07 | Arco Chemical Technology, L. P. | Olefin epoxidation using a carbon molecular sieve impregnated with a transition metal |
| US5578740A (en) * | 1994-12-23 | 1996-11-26 | The Dow Chemical Company | Process for preparation of epoxy compounds essentially free of organic halides |
| GB2309655A (en) * | 1996-02-03 | 1997-08-06 | Univ Delft Tech | Heterogeneous Catalysts |
| US5633391A (en) * | 1996-04-12 | 1997-05-27 | National Starch And Chemical Investment Holding Corporation | Methyltrioxorhenium-bis(trimethylsilyl)peroxide epoxidation of olefins |
-
1999
- 1999-05-24 EP EP99924475A patent/EP1080084B1/en not_active Expired - Lifetime
- 1999-05-24 CN CN99806813A patent/CN1303382A/zh active Pending
- 1999-05-24 KR KR1020007013419A patent/KR20010043904A/ko not_active Abandoned
- 1999-05-24 BR BR9911208-6A patent/BR9911208A/pt not_active Application Discontinuation
- 1999-05-24 DE DE69917018T patent/DE69917018T2/de not_active Expired - Fee Related
- 1999-05-24 WO PCT/US1999/011427 patent/WO1999062894A2/en not_active Ceased
- 1999-05-24 JP JP2000552106A patent/JP2002517387A/ja active Pending
- 1999-05-24 AU AU40963/99A patent/AU4096399A/en not_active Abandoned
- 1999-05-28 TW TW088108850A patent/TW448164B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP1080084A2 (en) | 2001-03-07 |
| DE69917018T2 (de) | 2005-03-24 |
| WO1999062894A3 (en) | 2000-04-06 |
| JP2002517387A (ja) | 2002-06-18 |
| KR20010043904A (ko) | 2001-05-25 |
| AU4096399A (en) | 1999-12-20 |
| TW448164B (en) | 2001-08-01 |
| WO1999062894A2 (en) | 1999-12-09 |
| CN1303382A (zh) | 2001-07-11 |
| DE69917018D1 (de) | 2004-06-09 |
| EP1080084B1 (en) | 2004-05-06 |
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