BR9908589A - Derivados de 2,4-diamino-1,3,5-triazina 6 substituìda com pelo menos dois átomos de carbono assimétricos substituìdos, sua preparação e seu emprego como herbicidas - Google Patents
Derivados de 2,4-diamino-1,3,5-triazina 6 substituìda com pelo menos dois átomos de carbono assimétricos substituìdos, sua preparação e seu emprego como herbicidasInfo
- Publication number
- BR9908589A BR9908589A BR9908589-5A BR9908589A BR9908589A BR 9908589 A BR9908589 A BR 9908589A BR 9908589 A BR9908589 A BR 9908589A BR 9908589 A BR9908589 A BR 9908589A
- Authority
- BR
- Brazil
- Prior art keywords
- alkyl
- halogen
- substituted
- optionally substituted
- carbon atoms
- Prior art date
Links
- 125000004432 carbon atom Chemical group C* 0.000 title abstract 3
- 239000004009 herbicide Substances 0.000 title abstract 3
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical group NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 title 1
- 229910052736 halogen Inorganic materials 0.000 abstract 6
- 150000002367 halogens Chemical class 0.000 abstract 6
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 125000003282 alkyl amino group Chemical group 0.000 abstract 2
- -1 amino, formylamino Chemical group 0.000 abstract 2
- 125000004663 dialkyl amino group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004466 alkoxycarbonylamino group Chemical group 0.000 abstract 1
- 125000005194 alkoxycarbonyloxy group Chemical group 0.000 abstract 1
- 125000005195 alkyl amino carbonyloxy group Chemical group 0.000 abstract 1
- 125000003806 alkyl carbonyl amino group Chemical group 0.000 abstract 1
- 125000005196 alkyl carbonyloxy group Chemical group 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000005202 dialkylaminocarbonyloxy group Chemical group 0.000 abstract 1
- 230000002363 herbicidal effect Effects 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 125000002950 monocyclic group Chemical group 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical class N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/14—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom
- C07D251/16—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom
- C07D251/18—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with hydrogen or carbon atoms directly attached to at least one ring carbon atom to only one ring carbon atom with nitrogen atoms directly attached to the two other ring carbon atoms, e.g. guanamines
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/12—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D251/00—Heterocyclic compounds containing 1,3,5-triazine rings
- C07D251/02—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings
- C07D251/12—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
- C07D251/26—Heterocyclic compounds containing 1,3,5-triazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members with only hetero atoms directly attached to ring carbon atoms
- C07D251/40—Nitrogen atoms
- C07D251/48—Two nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
- C07D307/78—Benzo [b] furans; Hydrogenated benzo [b] furans
- C07D307/79—Benzo [b] furans; Hydrogenated benzo [b] furans with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the hetero ring
- C07D307/81—Radicals substituted by nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/14—Radicals substituted by singly bound hetero atoms other than halogen
- C07D333/20—Radicals substituted by singly bound hetero atoms other than halogen by nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D333/28—Halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings linked by a chain containing hetero atoms as chain links
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Patente de Invenção: <B>"DERIVADOS DE 2,4-DIAMINO-1,3,5-TRIAZINA 6 SUBSTITUìDA COM PELO MENOS DOIS áTOMOS DE CARBONO ASSIMéTRICOS SUBSTITUìDOS, SUA PREPARAçãO E SEU EMPREGO COMO HERBICIDAS"<D>. A invenção refere-se a aminotriazinas substituídas óticamente ativas contendo pelo menos dois átomos de carbono assimétricos substituídos de fórmula (I), na qual A representa uma ligação simples ou cada alcanodiila ou oxaalcanodiila de cadeia reta ou ramificada; R¹ representa amino, formilamino, ou cada alquilamino, dialquilamino, alquil carbonil amino, N-alquil-N-alquil carbonilamino, alcoxicarbonil amino, N-alquil-N-alcoxicarbonil-amino, alquil-aminoalquilida amino ou dialquilamino alquilida amino que são opcionalmente substituídos por ciano, halogênio ou C~ 1~-C~ 4~-alcóxi; R², R³, representam hidrogênio, halogênio ou alquila que é opcionalmente substituída por ciano, halogênio ou C~1~-C~ 4~-alcóxi, ou R³ juntamente com R² representa alcanodiila que é opcionalmente substituída por ciano, halogênio ou C~ 1~-C~ 4~-alquila; R^ 4^ representa alquila ou cicloalquila; Y representa hidrogênio, hidróxi, mercapto, amino, ciano, halogênio ou cada alquila, alcóxi, alquilcarbonilóxi, alcoxicarbonilóxi, alquilamino carbonilóxi, dialquilamino carbonilóxi, alquiltio, alquilamino ou dialquilamino que são opcionalmente substituídos por ciano, halogênio ou C~ 1~-C~ 4~-alcóxi, e; Z representa um radical monocíclico ou bicíclico ou radicais heterocíclicos que são opcionalmente substituídos. Os substituintes são fornecidos com a condição de que R², R³ e Y são diferentes um do outro em cada caso individual, e que os substituintes estão ligados em ambos os átomos de carbono, no qual R² e R³ ou R^ 4^, R,R ou R,S ou S, R ou S,S ou R, rac ou S, rac são configurados [a primeira afirmação refere-se aos substituintes de triazina -CR²R³Y, e a segunda afirmação refere-se aos substituintes amino -CHR^ 4^(A-Z)]. A invenção também refere-se a um processo para a preparação dos compostos de fórmula (I) e à utilização do mesmo como herbicida.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19810394A DE19810394A1 (de) | 1998-03-11 | 1998-03-11 | Substituierte Aminotriazine mit mindestens zwei asymmetrisch substituierten Kohlenstoffatomen |
| PCT/EP1999/001234 WO1999046249A1 (de) | 1998-03-11 | 1999-02-26 | 6-substituierte 2,4-diamino-1,3,5-triazin derivate mit mindestens zwei asymmetrisch substituierten kohlenstoffatomen, deren herstellung und deren verwendung als herbizide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9908589A true BR9908589A (pt) | 2000-11-14 |
Family
ID=7860431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9908589-5A BR9908589A (pt) | 1998-03-11 | 1999-02-26 | Derivados de 2,4-diamino-1,3,5-triazina 6 substituìda com pelo menos dois átomos de carbono assimétricos substituìdos, sua preparação e seu emprego como herbicidas |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6358886B1 (pt) |
| EP (1) | EP1071672A1 (pt) |
| JP (1) | JP2002506062A (pt) |
| KR (1) | KR20010041351A (pt) |
| CN (1) | CN1299352A (pt) |
| AU (1) | AU752788B2 (pt) |
| BR (1) | BR9908589A (pt) |
| CA (1) | CA2322417A1 (pt) |
| DE (1) | DE19810394A1 (pt) |
| WO (1) | WO1999046249A1 (pt) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19846516A1 (de) * | 1998-10-09 | 2000-04-20 | Bayer Ag | Substituierte Formylaminotriazine |
| DE19933937A1 (de) * | 1999-07-20 | 2001-01-25 | Bayer Ag | Optisch aktive Thienylalkylamino-1,3,5-triazine |
| DE19960683A1 (de) * | 1999-12-15 | 2001-08-23 | Aventis Cropscience Gmbh | Substituierte 2,4-Diamino-1,3,5-triazine, Verfahren zur Herstellung und Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| DE102006059941A1 (de) * | 2006-12-19 | 2008-06-26 | Bayer Cropscience Ag | Substituierte 2,4-Diamino-1,3,5-triazine, Verfahren zu deren Herstellung und deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| EP2912024B1 (en) * | 2012-10-24 | 2016-07-20 | Basf Se | Herbicidal azines |
| CN111018748A (zh) * | 2019-12-27 | 2020-04-17 | 广东省生物医药技术研究所 | 化合物(s)-1-(1-萘基)乙基双胍及其制备方法和应用 |
| CN117466831A (zh) * | 2022-07-29 | 2024-01-30 | 江西天宇化工有限公司 | 一种α-取代苄基-三嗪类化合物及其制备方法和应用、一种除草剂 |
| CN117466832A (zh) * | 2022-07-29 | 2024-01-30 | 江西天宇化工有限公司 | 一种取代苯乙胺-三嗪类化合物及其制备方法和应用、一种除草剂 |
| CN118515558A (zh) * | 2024-04-25 | 2024-08-20 | 福建永晶科技股份有限公司 | 一种用二乙胺基三氟化硫制备具有光学活性的氟代丙酸甲酯的方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3753986A (en) * | 1970-04-02 | 1973-08-21 | Exxon Research Engineering Co | Triazine herbicides |
| US3816419A (en) | 1972-10-27 | 1974-06-11 | American Cyanamid Co | Substituted s-triazines |
| US3932167A (en) | 1972-10-27 | 1976-01-13 | American Cyanamid Company | Substituted s-triazines as herbicidal agents |
| JPS61189277A (ja) | 1985-02-15 | 1986-08-22 | Idemitsu Kosan Co Ltd | トリアジン誘導体，その製造方法およびそれを有効成分とする除草剤 |
| US4844731A (en) | 1986-12-27 | 1989-07-04 | Idemitsu Company Co., Ltd. | Triazine derivatives |
| JPS63222166A (ja) * | 1987-03-10 | 1988-09-16 | Idemitsu Kosan Co Ltd | トリアジン誘導体，その製造方法およびそれを含有する除草剤 |
| CA2027562C (en) * | 1989-02-20 | 1994-05-10 | Masahiro Nishii | Triazine derivative and a herbicide comprising the same as an effective ingredient |
| JP3029545B2 (ja) | 1995-02-17 | 2000-04-04 | 出光興産株式会社 | トリアジン誘導体 |
| DE19522137A1 (de) | 1995-06-19 | 1997-01-02 | Hoechst Schering Agrevo Gmbh | 2-Amino-1,3,5-triazine, Verfahren zu deren Herstellung und deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| DE19531084A1 (de) * | 1995-08-24 | 1997-02-27 | Hoechst Schering Agrevo Gmbh | 2,4-Diamino-1,3,5-triazine, Verfahren zu deren Herstellung und deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| DE19604191A1 (de) * | 1996-02-06 | 1997-08-07 | Hoechst Schering Agrevo Gmbh | 2,4-Diamino-1,3,5-triazine, Verfahren zu deren Herstellung und deren Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| EP0888714A1 (en) * | 1996-03-22 | 1999-01-07 | Idemitsu Kosan Company Limited | Herbicidal composition |
| DE19641692A1 (de) | 1996-10-10 | 1998-04-23 | Bayer Ag | Substituierte 2,4-Diamino-1,3,5-triazine |
| DE19641691A1 (de) * | 1996-10-10 | 1998-04-16 | Bayer Ag | Substituierte 2-Amino-4-alkylamino-1,3,5-triazine |
| DE19641694A1 (de) * | 1996-10-10 | 1998-04-16 | Bayer Ag | Substituierte 2,4-Diamino-1,3,5-triazine |
| DE19641693A1 (de) * | 1996-10-10 | 1998-04-16 | Bayer Ag | Substituierte 2-Amino-4-alkylamino-1,3,5-triazine |
| DE19704922A1 (de) | 1997-02-10 | 1998-08-13 | Hoechst Schering Agrevo Gmbh | 2,4-Diamino-1,3,5-triazine, ihre Herstellung und Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| DE19711825A1 (de) * | 1997-03-21 | 1998-09-24 | Bayer Ag | Substituierte 2,4-Diamino-1,3,5-triazine |
| DE19744232A1 (de) * | 1997-10-07 | 1999-04-08 | Bayer Ag | Substituierte 2,4-Diamino-1,3,5-triazine |
-
1998
- 1998-03-11 DE DE19810394A patent/DE19810394A1/de not_active Withdrawn
-
1999
- 1999-02-26 CA CA002322417A patent/CA2322417A1/en not_active Abandoned
- 1999-02-26 WO PCT/EP1999/001234 patent/WO1999046249A1/de not_active Ceased
- 1999-02-26 JP JP2000535630A patent/JP2002506062A/ja active Pending
- 1999-02-26 KR KR1020007009465A patent/KR20010041351A/ko not_active Withdrawn
- 1999-02-26 US US09/623,612 patent/US6358886B1/en not_active Expired - Fee Related
- 1999-02-26 BR BR9908589-5A patent/BR9908589A/pt not_active IP Right Cessation
- 1999-02-26 AU AU31418/99A patent/AU752788B2/en not_active Ceased
- 1999-02-26 EP EP99913191A patent/EP1071672A1/de not_active Withdrawn
- 1999-02-26 CN CN99805776A patent/CN1299352A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2002506062A (ja) | 2002-02-26 |
| CA2322417A1 (en) | 1999-09-16 |
| CN1299352A (zh) | 2001-06-13 |
| DE19810394A1 (de) | 1999-09-16 |
| EP1071672A1 (de) | 2001-01-31 |
| WO1999046249A1 (de) | 1999-09-16 |
| US6358886B1 (en) | 2002-03-19 |
| AU752788B2 (en) | 2002-10-03 |
| KR20010041351A (ko) | 2001-05-15 |
| AU3141899A (en) | 1999-09-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTA A 6O, 7O E 8O ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1911 DE 21/08/2007. |