BR9904775A - Sìntese de zeólitos e zeótipos de poros grandes, zeólitos e zeóticos obtidos e uso destes. - Google Patents
Sìntese de zeólitos e zeótipos de poros grandes, zeólitos e zeóticos obtidos e uso destes.Info
- Publication number
- BR9904775A BR9904775A BR9904775-6A BR9904775A BR9904775A BR 9904775 A BR9904775 A BR 9904775A BR 9904775 A BR9904775 A BR 9904775A BR 9904775 A BR9904775 A BR 9904775A
- Authority
- BR
- Brazil
- Prior art keywords
- zeolites
- large pores
- zeotypes
- materials
- source
- Prior art date
Links
- 239000010457 zeolite Substances 0.000 title abstract 7
- 239000011148 porous material Substances 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- 238000000034 method Methods 0.000 abstract 4
- 229910021536 Zeolite Inorganic materials 0.000 abstract 3
- 150000001450 anions Chemical class 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- 229910020175 SiOH Inorganic materials 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 238000001354 calcination Methods 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 238000005341 cation exchange Methods 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002892 organic cations Chemical group 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7007—Zeolite Beta
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
- B01J29/035—Microporous crystalline materials not having base exchange properties, such as silica polymorphs, e.g. silicalites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
"SìNTESE DE ZEóLITOS E ZEóTIPOS DE POROS GRANDES, ZEóLITOS E ZEóTIPOS OBTIDOS E USO DESTES", sendo os materiais de zeólito de poros grandes relacionados estruturalmente com o zeólito Beta a caracaterizados pelo fato de apresentarem o meio de síntese com pH relativamente baixo e o uso de âninons F^ -^ como mineralizadores, dita invenção referindo-se também aos materiais assim obtidos, caracaterizados pela sua estabilidade térmica muito elevada, baixa concentração de defeitos SiO^ -^ ou SiOH, ampla faixa de composição química, poros grandes e pelo fato de a sua calcinação permitir a obtenção da forma ácida sem o uso do processo de troca catiónica. Apesar de os referidos materais estarem relacionados com o zeólitos Beta, eles apresentam, ocasionalmente, diferenças substanciais com relação ao zeólito Beta. Também reinvindicado é o uso do meterial obtido no processo catalítico de transformação de hidrocarbonetos e em processo de oxidação. O Método compreende aquecer a 363-473K uma mistura de reação contendo uma fonte de pelo menos um elemento tetravalente T(IV), opcionalmente uma fonte de uma elemento T(III), opcionalmente H~ 2~O~ 2~, um cátion orgânico diretor de estrutura, uma fonte de ânios F^ -^ e água, não sendo necessária a presença de cátions alcalinos.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES9800269A ES2152143B1 (es) | 1998-02-06 | 1998-02-06 | Sintesis de zeolitas y zeotipos de poro grande. |
| PCT/ES1999/000032 WO1999040026A1 (es) | 1998-02-06 | 1999-02-04 | Sintesis de zeolitas y zeotipos de poro grande |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9904775A true BR9904775A (pt) | 2000-03-08 |
Family
ID=8302711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9904775-6A BR9904775A (pt) | 1998-02-06 | 1999-02-04 | Sìntese de zeólitos e zeótipos de poros grandes, zeólitos e zeóticos obtidos e uso destes. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP0997434A1 (pt) |
| BR (1) | BR9904775A (pt) |
| CA (1) | CA2286010A1 (pt) |
| ES (1) | ES2152143B1 (pt) |
| WO (1) | WO1999040026A1 (pt) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2155797B1 (es) * | 1999-07-29 | 2001-12-01 | Univ Valencia Politecnica | Zeolita itq-10 |
| ES2200624B1 (es) * | 2001-02-09 | 2005-05-01 | Universidad Politecnica De Valencia | Sintesis en medio alcalino de la zeolita itq.-16. |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2652347B1 (fr) * | 1989-09-22 | 1992-01-10 | Inst Francais Du Petrole | Zeolithe de type beta et son procede de preparation invention de philippe caullet, jean-louis guth, anne-catherine faust, francis raatz, jean-francois joly et jean-marie deves. |
| US5268161A (en) * | 1992-10-09 | 1993-12-07 | Chevron Research And Technology Company | Process for preparing molecular sieves using a 1,3,3,8,8-pentamethyl-3-azoniabicyclo [3.2.1] octane template |
| ES2133042B1 (es) * | 1996-03-14 | 2000-05-16 | Univ Valencia Politecnica | Sintesis de zeolita y zeotipos isomorfos a la zeolita beta. |
-
1998
- 1998-02-06 ES ES9800269A patent/ES2152143B1/es not_active Expired - Fee Related
-
1999
- 1999-02-04 EP EP99901606A patent/EP0997434A1/en not_active Withdrawn
- 1999-02-04 BR BR9904775-6A patent/BR9904775A/pt not_active Application Discontinuation
- 1999-02-04 WO PCT/ES1999/000032 patent/WO1999040026A1/es not_active Ceased
- 1999-02-04 CA CA002286010A patent/CA2286010A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999040026A1 (es) | 1999-08-12 |
| ES2152143A1 (es) | 2001-01-16 |
| EP0997434A1 (en) | 2000-05-03 |
| ES2152143B1 (es) | 2001-08-16 |
| CA2286010A1 (en) | 1999-08-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA10 | Dismissal: dismissal - article 33 of industrial property law | ||
| B11Y | Definitive dismissal acc. article 33 of ipl - extension of time limit for request of examination expired |