BR9902633A - Preparação direta de pirrolo[3-4-c]pirróis - Google Patents
Preparação direta de pirrolo[3-4-c]pirróisInfo
- Publication number
- BR9902633A BR9902633A BR9902633-3A BR9902633A BR9902633A BR 9902633 A BR9902633 A BR 9902633A BR 9902633 A BR9902633 A BR 9902633A BR 9902633 A BR9902633 A BR 9902633A
- Authority
- BR
- Brazil
- Prior art keywords
- formula
- pigment
- pyrroles
- diketopyrrolo
- iii
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/006—Preparation of organic pigments
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D487/00—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
- C07D487/02—Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
- C07D487/04—Ortho-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/004—Diketopyrrolopyrrole dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Plural Heterocyclic Compounds (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Patente de Invenção:<B>"PREPARAçãO DIRETA DE PIRROLO[3,4-C]PIRRóIS"<D>. é descrito um processo para a preparação direta de 1,4-dicetopirrolo-[3-4-c]pirróis pigmentares da fórmula (I) onde cada um de R~ 1~ e R~ 2~, independentemente do outro, é um radical aromático isocíclico ou heterocíclico, processo este que compreende o aquecimento de uma razão molar apropriada de um dissuccinato com uma nitrila da fórmula (II) R~ 1~-CN (II) ou da fórmula (III) R~ 2~-CN (III) ou com misturas das ditas nitrilas, em um solvente orgânico, e na presença de uma base forte e uma quantidade efetiva de um inibidor do crescimento da partícula selecionado de fórmulas (IV)-(X), e então a obtenção do composto de fórmula (I) a partir do produto de reação por protólise. O processo produz 1,4-dicetopirrolo-[3-4-c]pirróis pigmentares diretamente, isto é, sem a necessidade de tratamentos subseq³entes adicionais para a redução do tamanho da partícula. Também descrita é uma composição compreendendo um 1,4-dicetopirrolo-[3-4-c]pirrol pigmentar e o inibidor do crescimento da partícula. Estas composições de pigmentos são úteis para pigmentar materiais orgânicos de alto peso molecular.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8777398P | 1998-06-02 | 1998-06-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9902633A true BR9902633A (pt) | 2000-04-11 |
Family
ID=22207165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9902633-3A BR9902633A (pt) | 1998-06-02 | 1999-05-31 | Preparação direta de pirrolo[3-4-c]pirróis |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US6057449A (pt) |
| EP (1) | EP0962499B2 (pt) |
| JP (2) | JP2000007677A (pt) |
| KR (1) | KR100562696B1 (pt) |
| CN (1) | CN1315831C (pt) |
| BR (1) | BR9902633A (pt) |
| CA (1) | CA2273392A1 (pt) |
| CZ (1) | CZ299533B6 (pt) |
| DE (1) | DE69905652T3 (pt) |
| TW (1) | TWI232862B (pt) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6375732B1 (en) * | 1999-04-08 | 2002-04-23 | Clariant Finance (Bvi) Limited | Pigments, the process of their manufacturing and their use |
| DE19958181A1 (de) * | 1999-12-02 | 2001-06-07 | Clariant Gmbh | Pigmentdispergatoren auf Basis von Diketopyrrolopyrrolverbindungen und Pigmentzubereitungen |
| DE10028104A1 (de) * | 2000-06-07 | 2001-12-13 | Clariant Gmbh | Verfahren zur Herstellung von Diketopyrrologyrrol-Pigmenten |
| US6388093B1 (en) * | 2001-01-05 | 2002-05-14 | Sun Chemical Corporation | Syntheses for preparing 1,4-diketopyrrolo [3,4-c]pyrroles |
| EP1412431B1 (en) * | 2001-04-24 | 2014-05-14 | Basf Se | Pigment compositions and pigmented water-based coating materials |
| CA2444912A1 (en) * | 2001-05-14 | 2002-11-21 | Shivakumar Basalingapp Hendi | New crystal modification of diketopyrrolpyrrole solid solution pigment |
| AU2002342633A1 (en) * | 2001-09-11 | 2003-03-24 | Ciba Specialty Chemicals Holding Inc. | Process for the preparation of diketopyrrolopyrroles |
| WO2004076457A1 (en) | 2003-02-27 | 2004-09-10 | Mca Technologies Gmbh | Solvent-free process for the preparation of pyrrolo (3,4c) pyrrole compounds |
| EP1611207B1 (en) | 2003-04-10 | 2016-02-03 | Basf Se | Fluorescent diketopyrrolopyrroles |
| US7390901B2 (en) * | 2003-08-08 | 2008-06-24 | Sipix Imaging, Inc. | Fluorinated dyes or colorants and their uses |
| DE102006007622A1 (de) * | 2006-02-18 | 2007-08-23 | Clariant International Limited | Hochechte Diketopyrrolopyrrol-Pigmente |
| DE102007008140A1 (de) * | 2007-02-19 | 2008-08-21 | Clariant International Ltd. | Diketopyrrolopyrrol-Mischkristalle mit hoher Transparenz |
| DE102007011068A1 (de) * | 2007-03-07 | 2008-09-11 | Clariant International Ltd. | Verfahren zur direkten Herstellung feinteiliger Diketopyrrolopyrrolpigmente |
| JP5464789B2 (ja) * | 2007-03-27 | 2014-04-09 | キヤノン株式会社 | 粒子化合物分散体の製造方法 |
| DE102007049682A1 (de) | 2007-10-17 | 2009-04-23 | Clariant International Ltd. | Diketopyrrolopyrrol-Pigmentzusammensetzung zur Verwendung in Colorfiltern |
| DE102008032091A1 (de) | 2008-07-08 | 2010-01-14 | Clariant International Ltd. | Diketopyrrolopyrrol-Mischpigmentzubereitung zur Verwendung in Colorfiltern |
| TWI431071B (zh) * | 2007-10-17 | 2014-03-21 | Clariant Finance Bvi Ltd | 用於彩色濾光片中的二酮基吡咯并吡咯顏料組成物 |
| DE102007049883A1 (de) | 2007-10-18 | 2009-04-23 | Clariant International Ltd. | Diketopyrrolopyrrol-Mischkristalle |
| WO2009144115A1 (en) | 2008-05-28 | 2009-12-03 | Basf Se | Improved, red colour filter composition |
| JP2010083982A (ja) | 2008-09-30 | 2010-04-15 | Fujifilm Corp | 有機顔料微粒子の製造方法、それにより得られる有機顔料微粒子、その分散液、及びその組成物 |
| WO2011002927A2 (en) | 2009-06-30 | 2011-01-06 | Plextronics, Inc. | Novel compositions, methods and polymers |
| JP2011063786A (ja) * | 2009-08-18 | 2011-03-31 | Fujifilm Corp | 顔料微粒子分散体、これを用いたカラーフィルタ、及び顔料微粒子分散体の製造方法 |
| KR101639701B1 (ko) * | 2009-08-27 | 2016-07-14 | 후지필름 가부시키가이샤 | 디클로로디케토피롤로피롤 안료, 이것을 함유하는 색재 분산물 및 그 제조방법 |
| WO2011028827A2 (en) | 2009-09-04 | 2011-03-10 | Plextronics, Inc. | Organic electronic devices and polymers, including photovoltaic cells and diketone-based polymers |
| JP5620115B2 (ja) * | 2010-02-02 | 2014-11-05 | 富士フイルム株式会社 | 顔料微粒子分散体、これを用いた光硬化性組成物及びカラーフィルタ、これに用いられる新規化合物 |
| CN101831197A (zh) * | 2010-05-17 | 2010-09-15 | 南通市争妍颜料化工有限公司 | 颜料红254的高遮盖力品种hl的生产工艺 |
| JP5224008B2 (ja) * | 2011-02-24 | 2013-07-03 | Dic株式会社 | インクジェット記録用水性インクの調製のための水性顔料分散体及びインクジェット記録用水性インク |
| CN103012409B (zh) * | 2012-12-07 | 2015-05-27 | 辽宁鸿港化工有限公司 | 制备吡咯并吡咯-1,4-二酮衍生物的改进方法 |
Family Cites Families (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1986852A (en) * | 1933-04-06 | 1935-01-08 | Philip A Petter | Water meter |
| US4362704A (en) * | 1979-11-29 | 1982-12-07 | Taylor Patrick R | Cobalt leaching process |
| DE3366011D1 (en) * | 1982-05-17 | 1986-10-16 | Ciba Geigy Ag | Preparation of pyrrolo-(3,4-c) pyrroles |
| EP0181290B1 (de) * | 1984-11-07 | 1991-09-18 | Ciba-Geigy Ag | Pigmentmischungen |
| US4659775A (en) * | 1984-11-07 | 1987-04-21 | Ciba-Geigy Corporation | Process for the preparation of pyrrolo[3,4-c]pyrroles, and novel pyrrolo[3,4-c]pyrroles |
| US4791204A (en) * | 1985-11-26 | 1988-12-13 | Ciba-Geigy Corporation | 1,4-diketopyrrolo[3,4-c]pyrrole pigments |
| EP0243304B1 (en) † | 1986-04-08 | 1993-06-02 | Ciba-Geigy Ag | Surface modified pigment compositions |
| JPS63207858A (ja) * | 1987-02-24 | 1988-08-29 | Sumitomo Chem Co Ltd | 銅フタロシアニン顔料の製造方法 |
| DE3851346D1 (de) * | 1987-02-02 | 1994-10-13 | Ciba Geigy Ag | Feste Lösungen von Pyrrolo-[3,4-c]-pyrrolen mit Chinacridonen. |
| US4810304A (en) * | 1987-02-02 | 1989-03-07 | Ciba-Geigy Corporation | Solid solutions of pyrrolo-(3,4-C)-pyrroles with quinacridones |
| US4931566A (en) * | 1987-07-31 | 1990-06-05 | Ciba-Geigy Corporation | Process for the preparation of pyrrolo[3,4-c]pyrroles |
| DE3838814A1 (de) † | 1987-12-22 | 1989-07-06 | Hoechst Ag | Neue pigmente und ihre verwendung |
| JPH083049B2 (ja) * | 1988-02-25 | 1996-01-17 | 東洋インキ製造株式会社 | 顔料組成物,分散方法および塗料 |
| US4992101A (en) * | 1988-04-15 | 1991-02-12 | Ciba-Geigy Corporation | Process for the preparation of opaque diketopyrrolo-pyrrole pigments |
| JPH01271077A (ja) † | 1988-04-22 | 1989-10-30 | Suzuki Motor Co Ltd | リモート溶接装置および溶接電流の制御回路 |
| DE58907880D1 (de) * | 1988-07-20 | 1994-07-21 | Ciba Geigy | Verfahren zur Herstellung aminierter Diketodi(het)aryl-pyrrolopyrrole und Verwendung derselben als photoleitfähige Substanzen. |
| JPH0819345B2 (ja) * | 1989-06-07 | 1996-02-28 | 東洋インキ製造株式会社 | 顔料組成物および顔料の分散方法 |
| JP2584515B2 (ja) † | 1989-06-23 | 1997-02-26 | 東洋インキ製造株式会社 | 顔料分散剤および顔料組成物 |
| KR0143777B1 (ko) * | 1989-11-28 | 1998-07-01 | 월터 클리웨인, 한스-피터 위트린 | 디케토피롤로피롤을 기재로 하는 물질의 조성물 |
| EP0430875A3 (en) † | 1989-11-28 | 1992-08-05 | Ciba-Geigy Ag | Water-based coating materials containing specific modified organic pigments |
| ES2071280T3 (es) * | 1990-11-08 | 1995-06-16 | Ciba Geigy Ag | Derivados de pigmento conteniendo pirazol. |
| US5145524A (en) † | 1991-02-20 | 1992-09-08 | Ciba-Geigy Corporation | Surface modified pigment compositions |
| DE59206887D1 (de) * | 1991-04-26 | 1996-09-19 | Ciba Geigy Ag | Neue Diketopyrrolopyrrolverbindungen |
| US5286863A (en) * | 1991-08-22 | 1994-02-15 | Ciba-Geigy Corporation | Oxidation process for preparing quinacridone pigments |
| JP2885329B2 (ja) * | 1991-09-13 | 1999-04-19 | 大日精化工業株式会社 | 画像記録用着色組成物及び熱転写画像記録材 |
| EP0538784B2 (de) * | 1991-10-23 | 2000-12-27 | Clariant GmbH | Pigmentzubereitungen |
| JPH06212088A (ja) † | 1993-01-20 | 1994-08-02 | Dainippon Ink & Chem Inc | 顔料組成物及び塗料 |
| GB2275477B (en) † | 1993-02-26 | 1997-04-02 | Toyo Ink Mfg Co | Water-based pigment dispersion |
| TW372244B (en) * | 1993-07-29 | 1999-10-21 | Ciba Sc Holding Ag | Process for producing novel finely divided highly transparent diketopyrrolopyrrole pigments |
| EP0640604B2 (de) * | 1993-07-29 | 2004-06-30 | Ciba SC Holding AG | Neue feinteilige cyansubstituierte Diketopyrrolopyrrolpigmente und Verwendung derselben |
| US5424429A (en) * | 1993-09-15 | 1995-06-13 | Ciba-Geigy Corporation | Preparation of pigmentary 2,9-dichloroquinacridone |
| US5457203A (en) * | 1993-09-15 | 1995-10-10 | Ciba-Geigy Corporation | Pigmentary synthesis of quinacridone solid solutions |
| US5492564A (en) * | 1994-03-16 | 1996-02-20 | Ciba-Geigy Corporation | Diketopyrrolopyrrole pigment with high chroma |
| TW434296B (en) * | 1994-10-12 | 2001-05-16 | Ciba Sc Holding Ag | Process for the preparation of diaryldiketopyrrolopyrrole pigments |
| EP0748851B1 (de) * | 1995-06-15 | 2001-05-09 | Ciba SC Holding AG | Pigmentzusammensetzungen aus Diketopyrrolopyrrolen |
| DE69708721T2 (de) † | 1996-02-13 | 2002-08-22 | Ciba Speciality Chemicals Holding Inc., Basel | Pigmentzusammensetzungen |
| EP0811625B1 (en) * | 1996-06-05 | 2002-04-17 | Ciba SC Holding AG | Process for preparing diketopyrrolopyrrole derivatives |
| ES2184929T3 (es) * | 1996-07-18 | 2003-04-16 | Degussa | Mezclas de organo-polisulfanos y procedimiento para la preparacion de mezclas de caucho que los contienen. |
| DE59703652D1 (de) * | 1996-08-22 | 2001-07-05 | Ciba Sc Holding Ag | Kristallmodifikation eines Diketopyrrolopyrrolpigments |
| US5786487A (en) * | 1996-09-26 | 1998-07-28 | Ciba Specialty Chemicals Corporation | 1,4-diketo-3,6-diarylpyrolo 3,4-C!pyrrole pigment derivatives |
| US5785750A (en) * | 1996-09-26 | 1998-07-28 | Ciba Specialty Chemicals Corporation | 1,4-diketo-3,6-diarylpyrolo 3,4-c! pyrrole |
-
1999
- 1999-05-13 US US09/311,094 patent/US6057449A/en not_active Expired - Lifetime
- 1999-05-25 EP EP99810452A patent/EP0962499B2/en not_active Expired - Lifetime
- 1999-05-25 DE DE69905652T patent/DE69905652T3/de not_active Expired - Lifetime
- 1999-05-29 TW TW088108936A patent/TWI232862B/zh not_active IP Right Cessation
- 1999-05-31 CZ CZ0192399A patent/CZ299533B6/cs not_active IP Right Cessation
- 1999-05-31 JP JP11150817A patent/JP2000007677A/ja active Pending
- 1999-05-31 CA CA002273392A patent/CA2273392A1/en not_active Abandoned
- 1999-05-31 BR BR9902633-3A patent/BR9902633A/pt not_active IP Right Cessation
- 1999-06-01 CN CNB991069315A patent/CN1315831C/zh not_active Expired - Lifetime
- 1999-06-02 KR KR1019990020194A patent/KR100562696B1/ko not_active Expired - Fee Related
-
2000
- 2000-02-14 US US09/503,266 patent/US6361594B1/en not_active Expired - Lifetime
-
2010
- 2010-07-22 JP JP2010164776A patent/JP2011038096A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CZ192399A3 (cs) | 2000-03-15 |
| KR100562696B1 (ko) | 2006-03-23 |
| DE69905652D1 (de) | 2003-04-10 |
| JP2011038096A (ja) | 2011-02-24 |
| EP0962499A3 (en) | 2000-02-23 |
| CA2273392A1 (en) | 1999-12-02 |
| EP0962499B1 (en) | 2003-03-05 |
| TWI232862B (en) | 2005-05-21 |
| KR20000005832A (ko) | 2000-01-25 |
| US6057449A (en) | 2000-05-02 |
| CN1240211A (zh) | 2000-01-05 |
| JP2000007677A (ja) | 2000-01-11 |
| US6361594B1 (en) | 2002-03-26 |
| DE69905652T2 (de) | 2003-09-25 |
| CN1315831C (zh) | 2007-05-16 |
| EP0962499B2 (en) | 2008-03-05 |
| CZ299533B6 (cs) | 2008-08-27 |
| DE69905652T3 (de) | 2008-10-30 |
| EP0962499A2 (en) | 1999-12-08 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A, 6A, 7A E 8A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1910 DE 14/08/2007. |