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BR9814088A - Processo de sìntese de hidrocarboneto - Google Patents

Processo de sìntese de hidrocarboneto

Info

Publication number
BR9814088A
BR9814088A BR9814088-4A BR9814088A BR9814088A BR 9814088 A BR9814088 A BR 9814088A BR 9814088 A BR9814088 A BR 9814088A BR 9814088 A BR9814088 A BR 9814088A
Authority
BR
Brazil
Prior art keywords
gas
injectors
slurry
synthesis process
throat
Prior art date
Application number
BR9814088-4A
Other languages
English (en)
Other versions
BR9814088B1 (pt
Inventor
Min Chang
Constantine Anasta Coulaloglou
Edward Ching-Sheng Hsu
Larry Esteen Pedrick
Original Assignee
Exxon Research Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research Engineering Co filed Critical Exxon Research Engineering Co
Publication of BR9814088A publication Critical patent/BR9814088A/pt
Publication of BR9814088B1 publication Critical patent/BR9814088B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/342—Apparatus, reactors with moving solid catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/20—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium
    • B01J8/22—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with liquid as a fluidising medium gas being introduced into the liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
    • B01J8/44—Fluidisation grids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/06—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons
    • C07C1/063—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system
    • C07C1/066—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen in the presence of organic compounds, e.g. hydrocarbons the organic compound being the catalyst or a part of the catalyst system used for dissolving, suspending or transporting the catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO DE SìNTESE DE HIDROCARBONETO". Um processo de síntese de pasta fluida de hidrocarboneto com atrito de catalisador reduzido é obtida injetando-se um gás de síntese que compreende uma mistura de H~ 2~ e CO dentro da pasta fluida reativa com uma grade de distribuição de gás (106) que tenha injetores de gás (10) horizontalmente dispostos sobre a mesma e estendendo-se verticalmente de um lado a outro uma placa de outro modo impermeável a gás e a líquido (32). Os injetores (10) têm uma garganta (20) com um orifício redutor de pressão de gás (12) em uma extremidade, que é o fundo e a extremidade de entrada de gás e a outra extremidade aberta em um cone aberto (30) em que o gás que sobe entra em contato com a pasta fluida. Meios de desviar o fluxo nos injetores impedem a pasta fluida de entrar na garganta (20) e que seja submetida a atrito. Os injetores de gás não se projetam acima da superfície do topo da placa e o espaço plano é eliminado por meios tais como enchedores angulares (94), para impedir o acúmulo de sólidos no topo da bandeja.
BRPI9814088-4A 1997-10-21 1998-10-16 processo para sintetizar cataliticamente hidrocarbonetos lÍquidos enquanto se reduz o desgaste por fricÇço do catalisador. BR9814088B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/955,131 US5905094A (en) 1997-10-21 1997-10-21 Slurry hydrocarbon synthesis with reduced catalyst attrition and deactivation
PCT/US1998/021913 WO1999020583A1 (en) 1997-10-21 1998-10-16 Slurry hydrocarbon synthesis with reduced catalyst attrition and deactivation

Publications (2)

Publication Number Publication Date
BR9814088A true BR9814088A (pt) 2000-10-03
BR9814088B1 BR9814088B1 (pt) 2010-08-24

Family

ID=25496430

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9814088-4A BR9814088B1 (pt) 1997-10-21 1998-10-16 processo para sintetizar cataliticamente hidrocarbonetos lÍquidos enquanto se reduz o desgaste por fricÇço do catalisador.

Country Status (13)

Country Link
US (1) US5905094A (pt)
EP (1) EP1027311B1 (pt)
JP (1) JP4362223B2 (pt)
KR (1) KR20010031287A (pt)
AR (1) AR015975A1 (pt)
AU (1) AU740412B2 (pt)
BR (1) BR9814088B1 (pt)
CA (1) CA2304955C (pt)
DE (1) DE69805092T2 (pt)
MY (1) MY121016A (pt)
NO (1) NO20002009L (pt)
WO (1) WO1999020583A1 (pt)
ZA (1) ZA989108B (pt)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6076810A (en) * 1997-10-21 2000-06-20 Exxon Research And Engineering Co. Throat and cone gas injector and gas distribution grid for slurry reactor
US6486217B2 (en) * 1997-10-21 2002-11-26 Exxonmobil Research And Engineering Company Throat and cone gas injector and gas distribution grid for slurry reactor (CJB-0004)
DE19825589A1 (de) * 1998-06-09 1999-12-16 Elenac Gmbh Gasphasenwirbelschichtreaktor
US6732370B1 (en) * 1998-11-30 2004-05-04 Diva Systems Corporation Service provider side interactive program guide encoder
US6262132B1 (en) * 1999-05-21 2001-07-17 Energy International Corporation Reducing fischer-tropsch catalyst attrition losses in high agitation reaction systems
US6169120B1 (en) 1999-09-17 2001-01-02 Syntroleum Corporation Extended catalyst life two stage hydrocarbon synthesis process
US6239184B1 (en) 1999-09-22 2001-05-29 Syntroleum Corporation Extended catalyst life Fischer-Tropsch process
US6695965B1 (en) * 2000-04-04 2004-02-24 Exxonmobil Research And Engineering Company Process for adjusting the hardness of Fischer-Tropsch wax by blending
US6776898B1 (en) * 2000-04-04 2004-08-17 Exxonmobil Research And Engineering Company Process for softening fischer-tropsch wax with mild hydrotreating
EA006222B1 (ru) * 2001-05-25 2005-10-27 Бп Эксплорейшн Оперейтинг Компани Лимитед Способ проведения реакции синтеза фишера-тропша
US20080260631A1 (en) 2007-04-18 2008-10-23 H2Gen Innovations, Inc. Hydrogen production process
CN101396647B (zh) * 2007-09-29 2011-03-16 中科合成油技术有限公司 用于费-托合成的气-液-固三相悬浮床反应器及其应用
KR101272083B1 (ko) * 2010-08-10 2013-06-07 한국에너지기술연구원 재분산수단을 적용한 트레이 기포탑 반응기
US8143464B2 (en) 2011-03-24 2012-03-27 Cool Planet Biofuels, Inc. Method for making renewable fuels
US8951476B2 (en) 2011-03-24 2015-02-10 Cool Planet Energy Systems, Inc. System for making renewable fuels
KR101399403B1 (ko) * 2011-10-27 2014-05-27 한국에너지기술연구원 동적 기체분배기 및 그를 적용한 기포탑 반응기
WO2013062226A1 (ko) * 2011-10-27 2013-05-02 한국에너지기술연구원 동적 기체분배기 및 그를 적용한 기포탑 반응기
EP2888339A4 (en) * 2012-08-21 2016-07-20 Cool Planet Energy Systems Inc MANUFACTURING RENEWABLE FUELS INCLUDING GASOLINE, DIESEL AND NOZZLE FUEL
US10518238B2 (en) * 2013-03-15 2019-12-31 Synthesis Energy Systems, Inc. Apparatus using multiple jets for gas delivery and methods of fluidizing
JP6372086B2 (ja) * 2014-01-28 2018-08-15 三菱ケミカル株式会社 流動床反応器及びそれを用いたニトリル化合物の製造方法
CN112823870A (zh) * 2019-11-20 2021-05-21 中国石油化工股份有限公司 一种气体分布板、流化装置和反应方法
EP4426811A4 (en) * 2021-11-03 2025-10-01 Lanzatech Inc REACTOR EQUIPPED WITH DYNAMIC DIFFUSER

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB728543A (en) * 1952-03-05 1955-04-20 Koppers Gmbh Heinrich Process for the synthesis of hydrocarbons
US3283413A (en) * 1963-07-22 1966-11-08 Exxon Research Engineering Co Reaction vessel with a grid
US3974091A (en) * 1974-08-29 1976-08-10 Shell Oil Company Fluidized bed regeneration of carbon-contaminated catalysts using gas discharge nozzles of specific dimensions
US4257171A (en) * 1979-07-16 1981-03-24 Stone & Webster Engineering Corp. Fluidized bed gas distributor system
US4251926A (en) * 1979-12-06 1981-02-24 Monsanto Company Gas distributor apparatus for fluidized bed reactor
DE4041976C2 (de) * 1990-12-21 1994-10-06 Ruhr Oel Gmbh Verfahren zum Koksabbrand von Katalysatoren im rezirkulierenden Wirbelbett und Vorrichtung zur Durchführung des Verfahrens
GB9203959D0 (en) * 1992-02-25 1992-04-08 Norske Stats Oljeselskap Method of conducting catalytic converter multi-phase reaction
US5382748A (en) * 1992-12-18 1995-01-17 Exxon Research & Engineering Co. Hydrocarbon synthesis reactor employing vertical downcomer with gas disengaging means
US5527473A (en) * 1993-07-15 1996-06-18 Ackerman; Carl D. Process for performing reactions in a liquid-solid catalyst slurry
US5980782A (en) * 1997-04-25 1999-11-09 Exxon Research And Engineering Co. Face-mixing fluid bed process and apparatus for producing synthesis gas

Also Published As

Publication number Publication date
WO1999020583A1 (en) 1999-04-29
US5905094A (en) 1999-05-18
JP4362223B2 (ja) 2009-11-11
CA2304955A1 (en) 1999-04-29
BR9814088B1 (pt) 2010-08-24
NO20002009D0 (no) 2000-04-17
DE69805092D1 (de) 2002-05-29
MY121016A (en) 2005-12-30
AR015975A1 (es) 2001-05-30
ZA989108B (en) 1999-04-12
JP2001520279A (ja) 2001-10-30
KR20010031287A (ko) 2001-04-16
CA2304955C (en) 2006-01-10
DE69805092T2 (de) 2002-08-22
AU9806498A (en) 1999-05-10
EP1027311A1 (en) 2000-08-16
AU740412B2 (en) 2001-11-01
EP1027311B1 (en) 2002-04-24
NO20002009L (no) 2000-06-14

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 24/08/2010, OBSERVADAS AS CONDICOES LEGAIS.

B24H Lapse because of non-payment of annual fees (definitively: art 78 iv lpi)
B24F Patent annual fee: publication cancelled

Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2259 DE 22/04/2014 POR TER SIDO INDEVIDA.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE AS 14A, 15A, 16A, 17A, 18A, 19A, 20A, 21A E 22A ANUIDADES.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.