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BR9809222A - Método para preparação de ácido formilfosfÈnico - Google Patents

Método para preparação de ácido formilfosfÈnico

Info

Publication number
BR9809222A
BR9809222A BR9809222-7A BR9809222A BR9809222A BR 9809222 A BR9809222 A BR 9809222A BR 9809222 A BR9809222 A BR 9809222A BR 9809222 A BR9809222 A BR 9809222A
Authority
BR
Brazil
Prior art keywords
formylphosphonic acid
preparing
reaction
formylphosphonic
reagent
Prior art date
Application number
BR9809222-7A
Other languages
English (en)
Inventor
Thaddeus S Franczyk
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of BR9809222A publication Critical patent/BR9809222A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3886—Acids containing the structure -C(=X)-P(=X)(XH)2 or NC-P(=X)(XH)2, (X = O, S, Se)
    • C07F9/3891—Acids containing the structure -C(=X)-P(=X)(XH)2, (X = O, S, Se)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3817—Acids containing the structure (RX)2P(=X)-alk-N...P (X = O, S, Se)

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Patente de Invenção: <B>"MéTODO PARA PREPARAçãO DE áCIDO FORMILFOSFÈNICO"<D>. Esta invenção descreve um processo aperfeiçoado para a produção de derivados de ácido formilfosfónico. Um substrato de ácido amino-metilfosfónico é contactado com um reagente selecionado do grupo que consiste em água, um álcool, um composto de fenol, e misturas dos mesmos, e um gás oxidante, na presença de um catalisador, para formar uma mistura de produtos de reação que contém um derivado de ácido formilfosfónico, e as condições sob as quais o contato é realizado são controladas de modo que não mais de 50% do derivado de ácido formilfosfónico formado na mistura de produtos de reação sejam consumidos através de reação com o reagente.
BR9809222-7A 1997-05-05 1998-05-04 Método para preparação de ácido formilfosfÈnico BR9809222A (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4582597P 1997-05-05 1997-05-05
US09/071,265 US6054608A (en) 1997-05-05 1998-05-01 Method for preparing formylphosphonic acid
PCT/US1998/008814 WO1998050391A1 (en) 1997-05-05 1998-05-04 Method for preparing formylphosphonic acid

Publications (1)

Publication Number Publication Date
BR9809222A true BR9809222A (pt) 2000-07-04

Family

ID=26723245

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9809222-7A BR9809222A (pt) 1997-05-05 1998-05-04 Método para preparação de ácido formilfosfÈnico

Country Status (13)

Country Link
US (6) US6054608A (pt)
EP (1) EP0986566A1 (pt)
KR (1) KR20010012122A (pt)
CN (1) CN1255137A (pt)
AU (1) AU747331B2 (pt)
BR (1) BR9809222A (pt)
CA (1) CA2287248A1 (pt)
HU (1) HUP0004619A3 (pt)
ID (1) ID22832A (pt)
IL (1) IL132729A0 (pt)
NO (1) NO995388L (pt)
NZ (1) NZ500178A (pt)
WO (1) WO1998050391A1 (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
WO2000009519A1 (en) * 1998-08-12 2000-02-24 Monsanto Company Preparation of formylphosphonic acid from (phosphonomethyl)amine n-oxides
US6274760B1 (en) * 2000-03-14 2001-08-14 Monsanto Co. Preparation of formylphosphonic acid from tertiary aminomethylphosphonic acid N-oxides
US6441223B1 (en) * 2000-11-30 2002-08-27 Monsanto Technology Llc Method of making phosphorus-containing compounds and products thereof
US7908486B2 (en) * 2003-03-10 2011-03-15 Igt Dynamic configuration of a gaming system
EP2750712A2 (en) 2011-08-31 2014-07-09 Mallinckrodt LLC Nanoparticle peg modification with h-phosphonates
CN102786547B (zh) * 2012-08-29 2015-05-20 常州储能材料与器件研究院 一种合成增甘膦的方法

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3784590A (en) * 1969-01-02 1974-01-08 Merck & Co Inc Hydroxy and imino containing phosphonic acid diesters
US3738937A (en) * 1970-05-08 1973-06-12 Textilana Corp Polyalkylene polyamino polykis methylene phosphonic acids and salts thereof and methods for producing same
US3969398A (en) * 1974-05-01 1976-07-13 Monsanto Company Process for producing N-phosphonomethyl glycine
US3907652A (en) * 1974-10-30 1975-09-23 Monsanto Co Electrooxidation of phosphonomethyl amines
US4072706A (en) * 1976-01-02 1978-02-07 Monsanto Company Oxidation of phosphonomethylamines
US4264776A (en) * 1976-01-02 1981-04-28 Monsanto Company Production of secondary amines
DE3039998A1 (de) * 1980-10-23 1982-06-03 Bayer Ag, 5090 Leverkusen Phosphonoformaldehyd, ein verfahren zu seiner herstellung und seine verwendung als zwischenprodukt fuer die herstellung von arzneimittel
US4439474A (en) * 1981-10-30 1984-03-27 The Procter & Gamble Company Disposable floor mat with improved wet soil absorptivity
US4439373A (en) * 1982-12-27 1984-03-27 Stauffer Chemical Company Process for preparing phosphonomethylated amino acids
US4624937A (en) * 1984-05-10 1986-11-25 Monsanto Company Process for removing surface oxides from activated carbon catalyst
US4650613A (en) * 1984-12-28 1987-03-17 Monsanto Company Process for preparing N-phosphonomethylglycine and derivatives
US4568432A (en) * 1984-12-28 1986-02-04 Monsanto Company Process for preparing glyphosate and glyphosate derivatives
US4657705A (en) 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
IE883838L (en) * 1988-12-22 1990-06-22 Barclay Intellectual Propertie N-phosphonomethylglycine
DE69012218T3 (de) * 1989-06-15 2001-03-29 Finchimica S.P.A., Manerbio Verfahren zur Herstellung von N-Phosphonomethylglycin.
US5312972A (en) * 1992-10-29 1994-05-17 Hampshire Chemical Corp. Conversion of hydroxymethyl-iminodiacetic acid to phosphonomethyl-iminodiacetic acid
US6054608A (en) * 1997-05-05 2000-04-25 Monsanto Company Method for preparing formylphosphonic acid
US6232494B1 (en) 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine

Also Published As

Publication number Publication date
CN1255137A (zh) 2000-05-31
CA2287248A1 (en) 1998-11-12
HUP0004619A3 (en) 2003-02-28
AU747331B2 (en) 2002-05-16
KR20010012122A (ko) 2001-02-15
NO995388D0 (no) 1999-11-04
EP0986566A1 (en) 2000-03-22
AU7273498A (en) 1998-11-27
HUP0004619A2 (hu) 2001-06-28
US6218570B1 (en) 2001-04-17
US20040225147A1 (en) 2004-11-11
US6762317B2 (en) 2004-07-13
NO995388L (no) 1999-11-04
WO1998050391A1 (en) 1998-11-12
IL132729A0 (en) 2001-03-19
US20010031889A1 (en) 2001-10-18
US6054608A (en) 2000-04-25
US7091376B2 (en) 2006-08-15
US7294733B2 (en) 2007-11-13
US20060211881A1 (en) 2006-09-21
ID22832A (id) 1999-12-09
NZ500178A (en) 2001-10-26
US20030114706A1 (en) 2003-06-19

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Legal Events

Date Code Title Description
B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1891 DE 03/04/2007.