BR9808284A - Bar composition, and, process for preparing the same - Google Patents
Bar composition, and, process for preparing the sameInfo
- Publication number
- BR9808284A BR9808284A BR9808284-1A BR9808284A BR9808284A BR 9808284 A BR9808284 A BR 9808284A BR 9808284 A BR9808284 A BR 9808284A BR 9808284 A BR9808284 A BR 9808284A
- Authority
- BR
- Brazil
- Prior art keywords
- powder
- surfactant
- weight percent
- bar
- compositions
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 8
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000843 powder Substances 0.000 abstract 7
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 2
- 239000006057 Non-nutritive feed additive Substances 0.000 abstract 1
- 239000002671 adjuvant Substances 0.000 abstract 1
- 239000002280 amphoteric surfactant Substances 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- 229920006317 cationic polymer Polymers 0.000 abstract 1
- 239000003093 cationic surfactant Substances 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 229920001477 hydrophilic polymer Polymers 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 238000001694 spray drying Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/006—Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/24—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/40—Proteins
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Zoology (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Abstract
"COMPOSIçãO DE BARRA, E, PROCESSO PARA PREPARAR A MESMA". Composições coadjuvantes em pó, contendo um ou mais agentes de benefício, e as quais composições em pó são usadas em composições de detergente em barra, para aperfeiçoar a distribuição do agente de benefício. Os veículos usados para formar os coadjuvantes devem ter pontos de fusão mais altos bastante para suportarem o processos de secagem por aspersão. Especificamente, a invenção se refere a composições de barra compreendendo (A) cerca de 1 a 30% de pó compreendendo: (a) 1 a 70 por cento em peso do pó, agente de benefício; (b) 15 a 98 por cento em peso de veículo em pó, (c) 1 a 10 por cento em peso de umidade do pó, e (d) 0 a 30 por cento em peso de auxiliar de deposição/processamento de pó (por exemplo, tensoativo, polímero catiónico e/ou polímero hidrófilo); e (B) 99% a 70% de aparas, compreendendo 5% a 90% de um sistema tensoativo, em que o tensoativo é escolhido do grupo que consiste de sabão, tensoativo aniónico, tensoativo não iónico, tensoativo anfótero, tensoativo catiónico, e misturas deles. A presente invenção também fornece um processo para preparar barras em que (A) e (B) são preparados separadamente; em que (a), (b), (c) e opcionalmente (d) são misturados a de 40 a 80°C; em que a mistura de (a) e (b) é secada por aspersão a de 80 a 200°C, em uma pressão de 0,10 a 0,20 MPa; e em que (A) e (B) são misturados, transportados e extrudados em uma barra final."COMPOSITION OF BAR, AND, PROCESS TO PREPARE THE SAME". Supporting powder compositions, containing one or more benefiting agents, and which powder compositions are used in bar detergent compositions, to improve the distribution of the benefiting agent. The vehicles used to form the adjuvants must have melting points higher enough to withstand the spray drying process. Specifically, the invention relates to bar compositions comprising (A) about 1 to 30% of powder comprising: (a) 1 to 70 weight percent of the powder, beneficial agent; (b) 15 to 98 weight percent of vehicle powder, (c) 1 to 10 weight percent of powder moisture, and (d) 0 to 30 weight percent of powder deposition / processing aid ( for example, surfactant, cationic polymer and / or hydrophilic polymer); and (B) 99% to 70% of shavings, comprising 5% to 90% of a surfactant system, in which the surfactant is chosen from the group consisting of soap, anionic surfactant, non-ionic surfactant, amphoteric surfactant, cationic surfactant, and mixtures of them. The present invention also provides a process for preparing bars in which (A) and (B) are prepared separately; wherein (a), (b), (c) and optionally (d) are mixed at 40 to 80 ° C; wherein the mixture of (a) and (b) is spray-dried at 80 to 200 ° C, at a pressure of 0.10 to 0.20 MPa; and where (A) and (B) are mixed, transported and extruded in a final bar.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/821,502 US5955409A (en) | 1997-03-21 | 1997-03-21 | Bar compositions comprising adjuvant powders for delivering benefit agent |
| US08/821,501 US5770556A (en) | 1997-03-21 | 1997-03-21 | Process for making bar compositions having enhanced deposition of benefit agent comprising use of specific spray dryable adjuvant powders |
| PCT/EP1998/000528 WO1998042814A1 (en) | 1997-03-21 | 1998-01-23 | Detergent bars comprising adjuvant powders for delivering benefit agent and process for manufacture of said bars |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9808284A true BR9808284A (en) | 2000-05-16 |
Family
ID=27124549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9808284-1A BR9808284A (en) | 1997-03-21 | 1998-01-23 | Bar composition, and, process for preparing the same |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0973858B1 (en) |
| JP (1) | JP2001518100A (en) |
| KR (1) | KR100498944B1 (en) |
| CN (1) | CN1137981C (en) |
| AR (1) | AR012088A1 (en) |
| AU (1) | AU736652B2 (en) |
| BR (1) | BR9808284A (en) |
| CA (1) | CA2282336C (en) |
| CZ (1) | CZ296195B6 (en) |
| DE (1) | DE69816058T2 (en) |
| ES (1) | ES2202811T3 (en) |
| ID (1) | ID23412A (en) |
| IN (1) | IN189608B (en) |
| PL (1) | PL188422B1 (en) |
| RU (1) | RU2188854C2 (en) |
| WO (1) | WO1998042814A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002509163A (en) | 1998-01-20 | 2002-03-26 | グレイン・プロセッシング・コーポレーシヨン | Reduced malto-oligosaccharide |
| US6919446B1 (en) | 1998-01-20 | 2005-07-19 | Grain Processing Corp. | Reduced malto-oligosaccharides |
| US6380379B1 (en) | 1999-08-20 | 2002-04-30 | Grain Processing Corporation | Derivatized reduced malto-oligosaccharides |
| JP2003512508A (en) | 1999-10-20 | 2003-04-02 | グレイン・プロセッシング・コーポレーシヨン | Reduced maltooligosaccharide cleansing composition |
| BR0007201A (en) | 1999-10-20 | 2001-10-30 | Grain Processing Corp | Compositions including reduced demalto-oligosaccharide preserving agents, and methods for preserving a material |
| US7226899B2 (en) | 2003-12-23 | 2007-06-05 | Kimberly - Clark Worldwide, Inc. | Fibrous matrix of synthetic detergents |
| JP5276770B2 (en) * | 2005-09-01 | 2013-08-28 | ポーラ化成工業株式会社 | Cosmetics for wrinkle removal massage |
| BR112018010527A2 (en) * | 2015-12-04 | 2018-11-13 | Colgate Palmolive Co | taurine cleaning bars |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NZ184181A (en) * | 1976-06-04 | 1979-10-25 | Colgate Palmolive Co | Preparing toilet soap bars comprising poly-(ehtyene oxide) of high molecular weight |
| US5096608A (en) * | 1985-05-13 | 1992-03-17 | The Procter & Gamble Company | Ultra mild skin cleansing composition |
| US4808322A (en) * | 1988-03-10 | 1989-02-28 | Mclaughlin James H | Skin cleansing-cream conditioning bar |
| US5154849A (en) * | 1990-11-16 | 1992-10-13 | The Procter & Gamble Company | Mild skin cleansing toilet bar with silicone skin mildness/moisturizing aid |
| ES2158939T3 (en) * | 1994-03-30 | 2001-09-16 | Procter & Gamble | COMPOSITION IN PADS FOR CLEANING AND HYDRATION OF THE SKIN. |
| US5520840A (en) * | 1995-03-22 | 1996-05-28 | Lever Brothers Company | Detergent bars comprising water soluble starches |
-
1997
- 1997-03-10 IN IN128BO1997 patent/IN189608B/en unknown
-
1998
- 1998-01-23 JP JP54478198A patent/JP2001518100A/en not_active Ceased
- 1998-01-23 AU AU62148/98A patent/AU736652B2/en not_active Ceased
- 1998-01-23 WO PCT/EP1998/000528 patent/WO1998042814A1/en not_active Ceased
- 1998-01-23 CA CA002282336A patent/CA2282336C/en not_active Expired - Fee Related
- 1998-01-23 DE DE69816058T patent/DE69816058T2/en not_active Expired - Fee Related
- 1998-01-23 KR KR10-1999-7008551A patent/KR100498944B1/en not_active Expired - Fee Related
- 1998-01-23 CN CNB988051079A patent/CN1137981C/en not_active Expired - Fee Related
- 1998-01-23 ID IDW991050A patent/ID23412A/en unknown
- 1998-01-23 EP EP98904167A patent/EP0973858B1/en not_active Expired - Lifetime
- 1998-01-23 RU RU99122352/13A patent/RU2188854C2/en not_active IP Right Cessation
- 1998-01-23 PL PL98335807A patent/PL188422B1/en not_active IP Right Cessation
- 1998-01-23 BR BR9808284-1A patent/BR9808284A/en not_active IP Right Cessation
- 1998-01-23 ES ES98904167T patent/ES2202811T3/en not_active Expired - Lifetime
- 1998-01-23 CZ CZ0335199A patent/CZ296195B6/en not_active IP Right Cessation
- 1998-03-17 AR ARP980101193A patent/AR012088A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU6214898A (en) | 1998-10-20 |
| KR20010005494A (en) | 2001-01-15 |
| DE69816058D1 (en) | 2003-08-07 |
| CZ296195B6 (en) | 2006-02-15 |
| KR100498944B1 (en) | 2005-07-04 |
| IN189608B (en) | 2003-03-29 |
| WO1998042814A1 (en) | 1998-10-01 |
| DE69816058T2 (en) | 2003-12-24 |
| ES2202811T3 (en) | 2004-04-01 |
| CZ9903351A3 (en) | 2000-12-13 |
| CN1137981C (en) | 2004-02-11 |
| JP2001518100A (en) | 2001-10-09 |
| ID23412A (en) | 2000-04-20 |
| AR012088A1 (en) | 2000-09-27 |
| EP0973858B1 (en) | 2003-07-02 |
| PL335807A1 (en) | 2000-05-22 |
| HK1025119A1 (en) | 2000-11-03 |
| CN1255942A (en) | 2000-06-07 |
| RU2188854C2 (en) | 2002-09-10 |
| CA2282336C (en) | 2007-05-22 |
| AU736652B2 (en) | 2001-08-02 |
| EP0973858A1 (en) | 2000-01-26 |
| CA2282336A1 (en) | 1998-10-01 |
| PL188422B1 (en) | 2005-01-31 |
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