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BR9606373A - Composto metaloceno, processo de preparação, e uso em catalizadores para a polimerização de olefinas - Google Patents

Composto metaloceno, processo de preparação, e uso em catalizadores para a polimerização de olefinas

Info

Publication number
BR9606373A
BR9606373A BR9606373-4A BR9606373A BR9606373A BR 9606373 A BR9606373 A BR 9606373A BR 9606373 A BR9606373 A BR 9606373A BR 9606373 A BR9606373 A BR 9606373A
Authority
BR
Brazil
Prior art keywords
preparation process
catalysts
olefin polymerization
metallocene compound
polymerization
Prior art date
Application number
BR9606373-4A
Other languages
English (en)
Inventor
Luigi Rescini
Fabrizio Piemontesi
Ilya Nifant Ev
Pavel V Ivchenko
Original Assignee
Montell Technology Company Bv
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=11370281&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR9606373(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Montell Technology Company Bv filed Critical Montell Technology Company Bv
Publication of BR9606373A publication Critical patent/BR9606373A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"COMPOSTO METALOCENO, PROCESSO DE PREPARAçãO, E USO EM CATALISADORES PARA A POLIMERIZAçãO DE OLEFINAS". é descrita uma classe de compostos metaloceno apresentando dois anéis ciclopentadienil ligados em ponte por um grupo alquilideno. estes compostos metaloceno estão aptos a serem utilizados como componentes de catalisador para a polimerização de olefinas. Em particular, pela polimerização de propileno na presença do catalisador baseados nestes compostos metaloceno, podem ser obtidos polímeros apresentando índices isostáticos muito altos, altos pesos moleculares e distribuição linear dos pesos moleculares.
BR9606373-4A 1995-01-23 1996-01-17 Composto metaloceno, processo de preparação, e uso em catalizadores para a polimerização de olefinas BR9606373A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITMI950099A IT1272923B (it) 1995-01-23 1995-01-23 Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
PCT/EP1996/000171 WO1996022995A1 (en) 1995-01-23 1996-01-17 Metallocene compounds, process for their prepration, and their use in catalysts for the polymerization of olefins

Publications (1)

Publication Number Publication Date
BR9606373A true BR9606373A (pt) 2004-06-29

Family

ID=11370281

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9606373-4A BR9606373A (pt) 1995-01-23 1996-01-17 Composto metaloceno, processo de preparação, e uso em catalizadores para a polimerização de olefinas

Country Status (24)

Country Link
US (3) US6051728A (pt)
EP (1) EP0751946B2 (pt)
JP (1) JP3838662B2 (pt)
KR (2) KR100418106B1 (pt)
CN (2) CN1075076C (pt)
AR (1) AR000776A1 (pt)
AU (1) AU700256B2 (pt)
BG (1) BG100904A (pt)
BR (1) BR9606373A (pt)
CA (1) CA2186232A1 (pt)
CZ (1) CZ309596A3 (pt)
DE (1) DE69617543T3 (pt)
ES (1) ES2167539T5 (pt)
FI (1) FI963759L (pt)
HU (1) HUP9602907A3 (pt)
IL (1) IL116853A (pt)
IT (1) IT1272923B (pt)
MX (1) MX9604229A (pt)
PL (1) PL185055B1 (pt)
RU (1) RU2177948C2 (pt)
TR (1) TR199600720T1 (pt)
TW (1) TW319777B (pt)
WO (1) WO1996022995A1 (pt)
ZA (1) ZA96485B (pt)

Families Citing this family (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19533336A1 (de) * 1995-09-11 1997-03-13 Basf Ag Verfahren zur Herstellung von Propen/But-1-en-Copolymeren
DE19533337A1 (de) * 1995-09-11 1997-03-13 Basf Ag Propen/But-1-en-Copolymere
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
RU2194708C2 (ru) * 1996-11-15 2002-12-20 Монтелл Текнолоджи Компани Б.В. Металлоцен, лиганд, каталитическая система, способ полимеризации
US5900497A (en) * 1996-12-20 1999-05-04 Union Carbide Chemicals & Plsatics Technology Corporation Process for preparing metallocene procatalysts
WO1998043989A1 (en) 1997-03-29 1998-10-08 Montell Technology Company B.V. Metallocenes and catalysts for polymerization of olefins
AT405834B (de) 1997-10-09 1999-11-25 Borealis Ag Metallocene mit ferrocenyl-substituierten brücken und deren einsatz für die olefinpolymerisation
DE19748388A1 (de) * 1997-11-03 1999-05-06 Borealis Polymere Holding Gmbh Metallocene mit ferrocenyl-substituierten Brücken und deren Einsatz für die Olefinpolymerisation
JP2002505713A (ja) * 1998-04-21 2002-02-19 モンテル テクノロジー カンパニー ビーブイ α−オレフィンとのエチレンコポリマーの製造方法
HUP0100215A3 (en) * 1998-07-02 2001-12-28 Montell Technology Company Bv Process for the preparation of substantially amorphous alpha-ol
DE19922020A1 (de) * 1999-05-12 2000-11-16 Targor Gmbh Übergangsmetallverbindung, Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
AU783058B2 (en) 2000-02-24 2005-09-22 Basell Technology Company B.V. Organometallic compound useful as cocatalyst for polymerizing olefins
DE60104253T2 (de) 2000-03-22 2005-08-25 Basell Polyolefine Gmbh Herstellung thermoplastischer Zusammensetzungen aus Hoch- und minderisotaktischem Polypropylen
DE60108062T2 (de) 2000-05-24 2005-06-02 Basell Polyolefine Gmbh Propylenpolymere und verfahren zur ihrer herstellung
US6673869B2 (en) 2000-07-27 2004-01-06 Basell Poliolefine Italia S.P.A. Transparent elastomeric thermoplastic polyolefin compositions
JP2004516363A (ja) 2000-12-22 2004-06-03 バセル ポリオレフィン ジーエムビーエイチ オレフィンの重合用触媒成分
EP1355958A2 (en) 2000-12-22 2003-10-29 Basell Poliolefine Italia S.p.A. Process for the preparation of porous polymers and polymers obtainable thereof
WO2002102811A1 (en) 2001-05-21 2002-12-27 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefins
AU2002354949B2 (en) 2001-07-19 2005-06-23 Univation Technologies, Llc Low comonomer incorporating metallocene catalyst compounds
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
JP4020862B2 (ja) * 2001-07-19 2007-12-12 ユニベーション・テクノロジーズ・エルエルシー コモノマー少量組込み触媒とコモノマー多量組込み触媒を含有する混合メタロセン触媒系
JP4221363B2 (ja) 2001-07-19 2009-02-12 ユニベーション・テクノロジーズ・エルエルシー 物性が向上したポリエチレンフィルム
EP1448624A1 (en) 2001-11-27 2004-08-25 Basell Polyolefine GmbH Process for the treatment of polymer compositions
RU2214415C1 (ru) * 2002-05-13 2003-10-20 Общество с ограниченной ответственностью "Научно-исследовательская лаборатория "Синор" Способ получения галогенидов металлоценов (варианты)
US7572859B2 (en) 2002-06-26 2009-08-11 Basell Polyolefine Italia S.R.L. Impact-resistant polyolefin compositions
CA2487517A1 (en) * 2002-06-26 2004-01-08 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
US7449246B2 (en) * 2004-06-30 2008-11-11 General Electric Company Barrier coatings
AU2003273400A1 (en) * 2002-10-10 2004-05-04 Basell Polyolefine Gmbh Process for the copolymerization of ethylene
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CA2522917A1 (en) 2003-04-17 2004-10-28 Basell Poliolefine Italia S.R.L. Gas-phase olefin polymerization process
EP1648946B1 (en) 2003-07-04 2015-07-15 Basell Polyolefine GmbH Olefin polymerization process
EP1564226A1 (en) 2004-02-16 2005-08-17 Stichting Dutch Polymer Institute Titanocene-based catalyst system
WO2005095474A1 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Process for polymerizing 1-hexene or higher alpha-olefins
WO2005095468A2 (en) 2004-03-12 2005-10-13 Basell Polyolefine Gmbh Catalyst system for the polymerization of olefin
DE602005023844D1 (de) 2004-03-12 2010-11-11 Basell Polyolefine Gmbh Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen
EP1655314A1 (en) 2004-11-09 2006-05-10 Basell Polyolefine GmbH Process for the preparation of 1-butene/propylene copolymers
JP2008520793A (ja) 2004-11-22 2008-06-19 バーゼル・ポリオレフィン・ゲーエムベーハー プロピレンベースのターポリマー
US7300994B2 (en) * 2004-11-22 2007-11-27 Cornell Research Foundation, Inc. Isotactic polypropylene containing polymers
US20080160862A1 (en) * 2004-12-13 2008-07-03 Basell Poliolefine Italia S.R.L. Polyolefin Composition, Fibres and Nonwoven Fabrics
JP2008525651A (ja) * 2004-12-23 2008-07-17 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 弾性を有する繊維
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
WO2009077185A1 (en) 2007-12-18 2009-06-25 Basell Polyolefine Gmbh Gas-phase process for the polymerization of alpha-olefins
JP5578854B2 (ja) * 2008-01-11 2014-08-27 三井化学株式会社 変性プロピレン樹脂
EP2247424B1 (en) * 2008-02-29 2012-07-04 Basell Poliolefine Italia S.r.l. Polyolefin compositions
CN102216349A (zh) * 2008-11-18 2011-10-12 北欧化工公司 在茂金属催化剂存在下所生产的丙烯-丁烯无规共聚物
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
CN105358589B (zh) 2013-07-17 2018-07-03 埃克森美孚化学专利公司 金属茂和由其衍生的催化剂组合物
CN105377906A (zh) 2013-07-17 2016-03-02 埃克森美孚化学专利公司 取代的茂金属催化剂
EP3022235B1 (en) 2013-07-17 2020-04-08 ExxonMobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
US9938364B2 (en) 2013-07-17 2018-04-10 Exxonmobil Chemical Patents Inc. Substituted metallocene catalysts
EP3022236B1 (en) * 2013-07-17 2017-11-15 ExxonMobil Chemical Patents Inc. Process using substituted metallocene catalysts and products therefrom
WO2015009473A1 (en) * 2013-07-17 2015-01-22 Exxonmobil Chemical Patents Inc. Cyclopropyl substituted metallocene catalysts
KR101599978B1 (ko) * 2013-09-30 2016-03-04 주식회사 엘지화학 프로필렌-1-부텐 공중합체의 제조방법 및 이로부터 수득되는 프로필렌-1-부텐 공중합체
EP3173429B1 (en) * 2014-12-15 2019-03-20 LG Chem, Ltd. Metallocene compound, metallocene supported catalyst, and method for preparing polyolefin using same
KR101826253B1 (ko) 2015-07-15 2018-02-06 한화케미칼 주식회사 메탈로센 화합물 및 이의 제조방법
KR102212822B1 (ko) * 2016-12-05 2021-02-08 엑손모빌 케미칼 패턴츠 인코포레이티드 필름용의 브로드 오쏘고날 분포 메탈로센 폴리에틸렌
WO2019072695A1 (en) 2017-10-11 2019-04-18 Basell Polyolefine Gmbh CATALYST SUPPORTED SYSTEM

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4668773A (en) * 1985-03-25 1987-05-26 Northwestern University Organolanthanide catalysts
DE3751694T2 (de) * 1987-04-03 1996-08-01 Fina Technology Metallocen-katalysatorsysteme für die Polymersation von Olefinen, mit einer Silizium-Hydrocarbyl-Brücke.
US4892851A (en) * 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
DE68928696T2 (de) * 1988-12-26 1998-12-03 Mitsui Chemicals, Inc., Tokio/Tokyo Olefin-kopolymer und verfahren zur herstellung
DE3929693A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Verfahren zur herstellung eines polyolefinwachses
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
IT1249008B (it) * 1990-06-27 1995-02-11 Himont Inc Copolimeri cristallini sindiotattici del propilene
DE59104869D1 (de) * 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
ES2090209T3 (es) * 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
WO1992012184A1 (en) * 1990-12-28 1992-07-23 Exxon Chemical Patents Inc. Syndiotactic polypropylene
ES2087339T3 (es) * 1991-05-27 1996-07-16 Hoechst Ag Procedimiento para la preparacion de poliolefinas con amplia distribucion de masas moleculares.
JPH04351638A (ja) * 1991-05-29 1992-12-07 Toray Dow Corning Silicone Co Ltd ヘキセニル基含有シリコーンレジンおよびその製造方法
TW300901B (pt) * 1991-08-26 1997-03-21 Hoechst Ag
US5330948A (en) * 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
ATE177436T1 (de) * 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
TW272985B (pt) * 1992-09-11 1996-03-21 Hoechst Ag
EP0588208A3 (en) * 1992-09-12 1994-07-06 Hoechst Ag Polyolefin moulding composition with broad melt range, process and use therefore
JP3307704B2 (ja) * 1993-02-19 2002-07-24 三菱化学株式会社 α‐オレフィン重合体の製造法
EP0812854B2 (en) 1993-06-07 2011-04-20 Mitsui Chemicals, Inc. Novel transition metal compound, olefin polymerization catalyst comprising said compound, process for olefin polymerization using said catalyst and propylene homo- and copolymer
EP0629631B1 (en) * 1993-06-07 2002-08-28 Mitsui Chemicals, Inc. Novel transition metal compound, and polymerization catalyst containing it
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5504223A (en) * 1994-01-25 1996-04-02 The Dow Chemical Company Synthesis of cyclopentadienyl metal coordination complexes from metal hydrocarbyloxides

Also Published As

Publication number Publication date
EP0751946A1 (en) 1997-01-08
US6518386B1 (en) 2003-02-11
JP3838662B2 (ja) 2006-10-25
CN1196721C (zh) 2005-04-13
TR199600720T1 (tr) 1997-03-21
RU2177948C2 (ru) 2002-01-10
TW319777B (pt) 1997-11-11
US20030120015A1 (en) 2003-06-26
HUP9602907A3 (en) 1997-12-29
KR100418106B1 (ko) 2004-04-30
CN1075076C (zh) 2001-11-21
IL116853A (en) 2000-09-28
CA2186232A1 (en) 1996-08-01
FI963759A7 (fi) 1996-09-20
FI963759A0 (fi) 1996-09-20
PL316387A1 (en) 1997-01-06
BG100904A (bg) 1997-07-31
ZA96485B (en) 1996-08-13
KR100414759B1 (ko) 2004-01-13
JPH09510994A (ja) 1997-11-04
ES2167539T5 (es) 2007-04-01
EP0751946B1 (en) 2001-12-05
CZ309596A3 (en) 1997-04-16
ITMI950099A1 (it) 1996-07-23
CN1355256A (zh) 2002-06-26
HUP9602907A2 (en) 1997-05-28
DE69617543D1 (de) 2002-01-17
MX9604229A (es) 1997-12-31
PL185055B1 (pl) 2003-02-28
CN1150430A (zh) 1997-05-21
ITMI950099A0 (it) 1995-01-23
EP0751946B2 (en) 2006-08-09
FI963759L (fi) 1996-09-20
AU700256B2 (en) 1998-12-24
WO1996022995A1 (en) 1996-08-01
US6051728A (en) 2000-04-18
AU4536696A (en) 1996-08-14
DE69617543T3 (de) 2007-01-18
DE69617543T2 (de) 2002-08-01
IT1272923B (it) 1997-07-01
ES2167539T3 (es) 2002-05-16
KR970701723A (ko) 1997-04-12
AR000776A1 (es) 1997-08-06
IL116853A0 (en) 1996-07-23

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