BR9406932A - Composições polimeras microporosas à base de isocianato e método preparação - Google Patents
Composições polimeras microporosas à base de isocianato e método preparaçãoInfo
- Publication number
- BR9406932A BR9406932A BR9406932A BR9406932A BR9406932A BR 9406932 A BR9406932 A BR 9406932A BR 9406932 A BR9406932 A BR 9406932A BR 9406932 A BR9406932 A BR 9406932A BR 9406932 A BR9406932 A BR 9406932A
- Authority
- BR
- Brazil
- Prior art keywords
- isocyanate
- preparation
- polymer compositions
- compositions based
- microporous polymer
- Prior art date
Links
- 239000012948 isocyanate Substances 0.000 title 1
- 150000002513 isocyanates Chemical class 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 229920000642 polymer Polymers 0.000 title 1
- 238000002360 preparation method Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
- C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0091—Aerogels; Xerogels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/05—Elimination by evaporation or heat degradation of a liquid phase
- C08J2201/0502—Elimination by evaporation or heat degradation of a liquid phase the liquid phase being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/02—Foams characterised by their properties the finished foam itself being a gel or a gel being temporarily formed when processing the foamable composition
- C08J2205/028—Xerogel, i.e. an air dried gel
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
- C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8847393A | 1993-07-07 | 1993-07-07 | |
| PCT/US1994/007600 WO1995002009A1 (en) | 1993-07-07 | 1994-07-06 | Microporous isocyanate-based polymer compositions and method of preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9406932A true BR9406932A (pt) | 1996-09-10 |
Family
ID=22211588
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9406932A BR9406932A (pt) | 1993-07-07 | 1994-07-06 | Composições polimeras microporosas à base de isocianato e método preparação |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5478867A (pt) |
| EP (1) | EP0707612A1 (pt) |
| JP (1) | JPH08512349A (pt) |
| CN (1) | CN1129948A (pt) |
| AU (1) | AU7324294A (pt) |
| BR (1) | BR9406932A (pt) |
| WO (1) | WO1995002009A1 (pt) |
Families Citing this family (81)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5652278A (en) * | 1993-06-22 | 1997-07-29 | Imperial Chemical Industries Plc | Microvoid polyurethane materials |
| JPH09501455A (ja) * | 1993-07-22 | 1997-02-10 | インペリアル・ケミカル・インダストリーズ・ピーエルシー | エーロゲル |
| WO1996036654A1 (en) * | 1995-05-18 | 1996-11-21 | Imperial Chemical Industries Plc | Organic aerogels |
| EP0827521B1 (en) * | 1995-05-22 | 1999-02-10 | Imperial Chemical Industries Plc | Organic aerogels |
| US5877100A (en) * | 1996-09-27 | 1999-03-02 | Cabot Corporation | Compositions and insulation bodies having low thermal conductivity |
| ID22663A (id) * | 1997-04-01 | 1999-12-02 | Huntsman Ici Chem Llc | Aerogel berbasis poliisosianat |
| KR20010005842A (ko) * | 1997-04-01 | 2001-01-15 | 스윈넨 앤 마리 | 폴리이소시아네이트 기재 크세로겔 |
| WO1998044028A1 (en) * | 1997-04-01 | 1998-10-08 | Huntsman Ici Chemicals Llc | Polyisocyanate based aerogels |
| BR9808110A (pt) * | 1997-04-01 | 2000-03-08 | Huntsman Ici Chem Llc | Processo para preparar um xerogel baseado em poliisocianato, dito xerogel, e, uso do mesmo |
| US6666935B1 (en) * | 1997-09-09 | 2003-12-23 | The Regents Of The University Of California | Sol-gel manufactured energetic materials |
| US6090861A (en) * | 1998-12-28 | 2000-07-18 | General Ideas, Inc. | Process for high temperature production of organic aerogels |
| EP1047845A1 (en) * | 1998-01-19 | 2000-11-02 | Huntsman Ici Chemicals Llc | Evacuated insulation panel |
| KR100356540B1 (ko) * | 1998-06-05 | 2003-04-03 | 삼성전자 주식회사 | 진공단열판넬 |
| KR100329475B1 (ko) * | 1998-06-05 | 2002-11-22 | 삼성전자 주식회사 | 진공단열판넬 |
| AU5862099A (en) * | 1998-10-22 | 2000-05-15 | Huntsman Ici Chemicals Llc | Insulated bodies |
| EP1141060A1 (en) * | 1998-11-30 | 2001-10-10 | Huntsman International Llc | Polyisocyanate based aerogels |
| AU3844599A (en) * | 1999-05-07 | 2000-11-21 | Salviac Limited | Biostable polyether polyurethane product |
| EP1176993B1 (en) * | 1999-05-07 | 2003-06-04 | Salviac Limited | Biostable polyurethane products |
| JP2001329037A (ja) * | 2000-05-24 | 2001-11-27 | Matsushita Refrig Co Ltd | 有機多孔体断熱材とその製造方法、および、断熱箱体 |
| EP1288770B1 (en) | 2000-06-06 | 2009-03-04 | Panasonic Corporation | Portable information appliance |
| RU2004126237A (ru) * | 2002-01-29 | 2005-05-27 | Кабот Корпорейшн (US) | Термостойкий аэрогельный изолирующий композиционный материал и способ его получения: аэрогельная связующая композиция и способ ее получения |
| EP1787716A1 (en) * | 2002-01-29 | 2007-05-23 | Cabot Corporation | Heat resistant aerogel insulation composite and method for its preparation;aerogel binder composition and method for its preparation |
| DE10259237B4 (de) | 2002-12-17 | 2006-02-09 | Geze Gmbh | Antrieb für einen Flügel einer Tür oder eines Fensters |
| DE10308581A1 (de) * | 2003-02-27 | 2004-09-16 | Wacker-Chemie Gmbh | Wärmedämmung für Unterwasser-Bauteile für die Öl- und Gasförderung |
| JP2004359950A (ja) * | 2003-05-15 | 2004-12-24 | Nisshinbo Ind Inc | 薬剤耐性を付与した水膨潤性ポリウレタンフォームとその製造方法及びそれを用いたバイオリアクター用担体 |
| US7575979B2 (en) * | 2004-06-22 | 2009-08-18 | Hewlett-Packard Development Company, L.P. | Method to form a film |
| WO2007044027A2 (en) * | 2004-11-26 | 2007-04-19 | Aspen Aerogels, Inc. | Polyolefin-based aerogels |
| US20060211840A1 (en) * | 2005-03-20 | 2006-09-21 | Aspen Aerogels Inc. | Polyurea aerogels |
| US8383238B2 (en) * | 2005-03-22 | 2013-02-26 | G. Stuart Burchill, Jr. | Highly porous coated fine particles, composition, and method of production |
| US9469739B2 (en) | 2005-04-07 | 2016-10-18 | Aspen Aerogels, Inc. | Microporous polyolefin-based aerogels |
| US8461223B2 (en) * | 2005-04-07 | 2013-06-11 | Aspen Aerogels, Inc. | Microporous polycyclopentadiene-based aerogels |
| DE102005025970A1 (de) * | 2005-06-03 | 2006-12-07 | Basf Ag | Poröse Polyisocyanat-Polyadditionsprodukte |
| TWI482748B (zh) * | 2005-06-24 | 2015-05-01 | Honeywell Int Inc | 含有經氟取代之烯烴之組合物 |
| TWI341218B (en) * | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
| WO2007140293A2 (en) | 2006-05-25 | 2007-12-06 | Aspen Aerogels, Inc. | Aerogel compositions with enhanced performance |
| US20090029147A1 (en) * | 2006-06-12 | 2009-01-29 | Aspen Aerogels, Inc. | Aerogel-foam composites |
| CA2683529A1 (en) * | 2007-05-16 | 2008-11-20 | Basf Se | Xerogels made from aromatic polyureas |
| WO2009027310A1 (de) | 2007-08-28 | 2009-03-05 | Basf Se | Xerogele auf basis von polyharnstoff |
| JP5655281B2 (ja) * | 2008-06-10 | 2015-01-21 | 東ソー株式会社 | 塩素化ポリエーテル及びそれよりなるポリウレタン |
| CN102356107B (zh) * | 2009-03-16 | 2013-07-10 | 巴斯夫欧洲公司 | 制备干凝胶复合材料的方法 |
| KR101832504B1 (ko) | 2009-06-29 | 2018-02-26 | 바스프 에스이 | 방향족 폴리우레아에 기초한 다공성 겔 |
| RU2541536C2 (ru) | 2009-08-13 | 2015-02-20 | Басф Се | Пористые гели на основе ароматических и циклоалифатических аминов |
| PT2510026E (pt) * | 2009-12-11 | 2014-04-02 | Basf Se | Materiais porosos melhorados, à base de aminas aromáticas |
| US9260580B2 (en) * | 2010-06-28 | 2016-02-16 | Basf Se | Process for producing porous materials based on polyurea |
| EP2399945A1 (de) | 2010-06-28 | 2011-12-28 | Basf Se | Verfahren zur Herstellung von Porösen materialien auf basis von Polyharnstoff |
| WO2012000184A1 (en) * | 2010-06-30 | 2012-01-05 | Dow Global Technologies Llc | Inorganic nanoporous particles with water dispersible polyurethane binder |
| BR112013010740A2 (pt) * | 2010-11-04 | 2016-08-09 | Basf Se | processo para produzir um aerogel ou xerogel, material poroso, e, uso de materiais porosos |
| US8741976B2 (en) | 2010-11-04 | 2014-06-03 | Basf Se | Process for producing aerogels or xerogels |
| US8697766B2 (en) | 2011-02-24 | 2014-04-15 | Basf Se | Process for producing pulverulent porous materials |
| US20120235070A1 (en) * | 2011-03-18 | 2012-09-20 | Basf Se | Process for producing flame-retardant porous materials based on polyurea |
| DE102011083017A1 (de) * | 2011-09-20 | 2013-03-21 | Evonik Industries Ag | Verbundwerkstoffe umfassend eine offenzellige Polymermatrix und darin eingebettete Granulate |
| EP2900715B1 (de) * | 2012-09-27 | 2020-11-25 | Basf Se | Verfahren zur herstellung von porösen materialien auf basis von isocyanat |
| US9676915B2 (en) | 2012-12-17 | 2017-06-13 | Basf Se | Porous branched/highly branched polyimides |
| US9133973B2 (en) | 2013-01-14 | 2015-09-15 | Nanopore, Inc. | Method of using thermal insulation products with non-planar objects |
| US9726438B2 (en) | 2013-01-14 | 2017-08-08 | Nanopore Incorporated | Production of thermal insulation products |
| US9598857B2 (en) | 2013-01-14 | 2017-03-21 | Nanopore, Inc. | Thermal insulation products for insulating buildings and other enclosed environments |
| US9849405B2 (en) * | 2013-01-14 | 2017-12-26 | Nanopore, Inc. | Thermal insulation products and production of thermal insulation products |
| BR112015029428A2 (pt) | 2013-05-24 | 2017-07-25 | Basf Se | processo para produção de materiais porosos, material poroso e uso deste |
| US10106717B2 (en) * | 2014-01-13 | 2018-10-23 | Honeywell International Inc. | Composite phase change material (PCM), method for manufacturing a composite PCM, and article of clothing including a composite PCM |
| WO2015144698A1 (en) * | 2014-03-24 | 2015-10-01 | Basf Se | Process for producing porous materials |
| KR102461563B1 (ko) | 2014-07-18 | 2022-11-01 | 에어로젤-잇 게엠베하 | 다공성 재료의 제조 방법 |
| EP3229977A4 (en) * | 2014-12-08 | 2019-02-27 | University of Virginia Patent Foundation, D/B/A University of Virginia | COMPOSITIONS AND METHODS FOR BONDING ADHESIVES, FABRICS AND COATINGS ON SURFACES |
| EP3274401A1 (en) | 2015-03-24 | 2018-01-31 | Basf Se | Process for producing porous materials comprising a catalyst system |
| WO2016173903A1 (en) | 2015-04-27 | 2016-11-03 | Huntsman International Llc | Functionalized isocyanate based porous materials |
| RU2708692C2 (ru) * | 2015-08-06 | 2019-12-11 | ХАНТСМЭН ИНТЕРНЭШНЛ ЭлЭлСи | Органические ксерогели с пониженной плотностью на основе изоцианатов |
| CN105037672B (zh) * | 2015-08-27 | 2017-08-25 | 厦门大学 | 一种异氰酸酯微孔聚合物材料及其制备方法与应用 |
| EP3362497B1 (en) | 2015-10-16 | 2019-09-04 | Basf Se | Process for producing isocyanate-based xerogels and aerogels with mineral acids |
| BR112018009846B1 (pt) * | 2015-11-16 | 2022-04-19 | Huntsman International Llc | Aerogel/xerogel/criogel orgânico à base de isocianato hidrofóbico, processo para produção do aerogel/xerogel/criogel orgânico à base de isocianato hidrofóbico, e, uso dos xerogéis/aerogéis/criogéis hidrofóbicos |
| WO2017125414A1 (en) | 2016-01-18 | 2017-07-27 | Basf Se | Process for producing porous materials |
| WO2017125415A1 (en) | 2016-01-18 | 2017-07-27 | Basf Se | Process for producing porous materials |
| JP2019167388A (ja) * | 2016-08-12 | 2019-10-03 | Agc株式会社 | 多孔質体および遮音材 |
| EP3315529B1 (en) * | 2016-10-28 | 2019-12-04 | Henkel AG & Co. KGaA | Copolymer hybrid aerogels based on isocyanate - cyclic ether - clay networks |
| WO2019012127A1 (en) | 2017-07-13 | 2019-01-17 | Basf Se | POROUS MATERIALS HAVING SUPERIOR REVERSIBLE WATER ABSORPTION |
| EP3655455A1 (en) | 2017-07-17 | 2020-05-27 | Basf Se | Process for producing porous materials |
| CN108285520B (zh) * | 2018-01-29 | 2021-04-06 | 爱彼爱和新材料有限公司 | 一种聚氨酯-聚脲结构互穿气凝胶及其制备方法 |
| CN112313004A (zh) * | 2018-04-26 | 2021-02-02 | 蓝移材料有限公司 | 无溶剂交换制备的聚合物气凝胶 |
| US11319138B2 (en) * | 2018-11-20 | 2022-05-03 | Simple Container Solutions, Inc. | Pop-up liner |
| KR20210116570A (ko) | 2019-01-17 | 2021-09-27 | 바스프 에스이 | 다공성 물질의 제조 방법 |
| JP2022529347A (ja) | 2019-04-15 | 2022-06-21 | ビーエーエスエフ ソシエタス・ヨーロピア | モノリシック有機エアロゲルをベースとした成型品 |
| WO2021185716A1 (en) | 2020-03-17 | 2021-09-23 | Basf Se | Thin and flexible thermal insulation material based on a monolithic organic aerogel |
| JP6925554B1 (ja) * | 2020-06-30 | 2021-08-25 | 株式会社イノアック技術研究所 | ポリウレア発泡体 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3715326A (en) * | 1967-01-10 | 1973-02-06 | Bayer Ag | Using monoisocyanates to prepare microporous polyurethanes |
| DE1694152C3 (de) * | 1967-05-12 | 1979-09-13 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von mikroporösen Flächengebilden |
| US3574150A (en) * | 1969-05-28 | 1971-04-06 | Atomic Energy Commission | Open-pore polyurethane product |
| DE2034538C3 (de) * | 1970-07-11 | 1980-09-11 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von mikroporösen Flächengebilden |
| US4359541A (en) * | 1981-01-19 | 1982-11-16 | Basf Wyandotte Corporation | Process for the preparation of polyisocyanurate dispersions and compositions prepared therefrom |
| US4745015A (en) * | 1981-09-30 | 1988-05-17 | The Dow Chemical Company | Thermal insulating panel |
| US4444821A (en) * | 1982-11-01 | 1984-04-24 | General Electric Company | Vacuum thermal insulation panel |
| US4607064A (en) * | 1983-05-16 | 1986-08-19 | The Dow Chemical Company | Polyurethane and urethane-modified isocyanurate foams and a polyol composition useful in their preparation |
| DE3418637A1 (de) * | 1984-05-18 | 1985-11-21 | Wacker-Chemie GmbH, 8000 München | Waermedaemmformkoerper mit umhuellung |
| US4661529A (en) * | 1984-08-09 | 1987-04-28 | The Dow Chemical Company | Polyurethane and urethane-modified isocyanurate foams and a polyol composition useful in their preparation |
| DE3429671A1 (de) * | 1984-08-11 | 1986-02-20 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von aerogelen |
| US4668555A (en) * | 1984-12-27 | 1987-05-26 | Matsushita Refrigeration Co. | Heat insulating body |
| US4636415A (en) * | 1985-02-08 | 1987-01-13 | General Electric Company | Precipitated silica insulation |
| US4726974A (en) * | 1986-10-08 | 1988-02-23 | Union Carbide Corporation | Vacuum insulation panel |
| GB8712363D0 (en) * | 1987-05-26 | 1987-07-01 | Ici Plc | Polyisocyanurate rigid foams |
| US4997804A (en) * | 1988-05-26 | 1991-03-05 | The United States Of America As Represented By The United States Department Of Energy | Low density, resorcinol-formaldehyde aerogels |
| DE3914850A1 (de) * | 1989-05-05 | 1990-11-08 | Basf Ag | Thermisches isoliermaterial auf der basis von pigmenthaltigen kieselsaeureaerogelen |
| US4966919A (en) * | 1989-06-20 | 1990-10-30 | The United States Of America As Represented By The United States Department Of Energy | Composite foams |
| US5091233A (en) * | 1989-12-18 | 1992-02-25 | Whirlpool Corporation | Getter structure for vacuum insulation panels |
| US5018328A (en) * | 1989-12-18 | 1991-05-28 | Whirlpool Corporation | Multi-compartment vacuum insulation panels |
| US5084320A (en) * | 1990-01-22 | 1992-01-28 | Barito Robert W | Evacuated thermal insulation |
| US5086085A (en) * | 1991-04-11 | 1992-02-04 | The United States Of America As Represented By The Department Of Energy | Melamine-formaldehyde aerogels |
| GB9312869D0 (en) * | 1993-06-22 | 1993-08-04 | Ici Plc | Evacuated insulation panels |
| GB9312868D0 (en) * | 1993-06-22 | 1993-08-04 | Ici Plc | Microvoid polyurethane materials |
-
1994
- 1994-06-29 US US08/268,059 patent/US5478867A/en not_active Expired - Fee Related
- 1994-07-06 WO PCT/US1994/007600 patent/WO1995002009A1/en not_active Ceased
- 1994-07-06 AU AU73242/94A patent/AU7324294A/en not_active Abandoned
- 1994-07-06 CN CN94193209A patent/CN1129948A/zh active Pending
- 1994-07-06 JP JP7504147A patent/JPH08512349A/ja active Pending
- 1994-07-06 BR BR9406932A patent/BR9406932A/pt not_active Application Discontinuation
- 1994-07-06 EP EP94923350A patent/EP0707612A1/en not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| US5478867A (en) | 1995-12-26 |
| WO1995002009A1 (en) | 1995-01-19 |
| AU7324294A (en) | 1995-02-06 |
| EP0707612A1 (en) | 1996-04-24 |
| CN1129948A (zh) | 1996-08-28 |
| JPH08512349A (ja) | 1996-12-24 |
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