BR8205931A - Processo para hidroxilar olefinas - Google Patents
Processo para hidroxilar olefinasInfo
- Publication number
- BR8205931A BR8205931A BR8205931A BR8205931A BR8205931A BR 8205931 A BR8205931 A BR 8205931A BR 8205931 A BR8205931 A BR 8205931A BR 8205931 A BR8205931 A BR 8205931A BR 8205931 A BR8205931 A BR 8205931A
- Authority
- BR
- Brazil
- Prior art keywords
- olefins
- hydroxyl
- catalyst
- oscl3
- hydroxylated
- Prior art date
Links
- -1 HYDROXYL OLEFINS Chemical class 0.000 title 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003426 co-catalyst Substances 0.000 abstract 1
- 230000033444 hydroxylation Effects 0.000 abstract 1
- 238000005805 hydroxylation reaction Methods 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000001590 oxidative effect Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
- UAIHPMFLFVHDIN-UHFFFAOYSA-K trichloroosmium Chemical compound Cl[Os](Cl)Cl UAIHPMFLFVHDIN-UHFFFAOYSA-K 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Saccharide Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31021781A | 1981-10-09 | 1981-10-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR8205931A true BR8205931A (pt) | 1983-09-13 |
Family
ID=23201487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR8205931A BR8205931A (pt) | 1981-10-09 | 1982-10-08 | Processo para hidroxilar olefinas |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0077202B1 (pt) |
| JP (1) | JPS5877832A (pt) |
| AT (1) | ATE19054T1 (pt) |
| AU (1) | AU8921782A (pt) |
| BR (1) | BR8205931A (pt) |
| DE (1) | DE3270461D1 (pt) |
| ES (1) | ES8401437A1 (pt) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4496778A (en) * | 1983-10-03 | 1985-01-29 | Exxon Research & Engineering Co. | Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper Co-catalyst, and an aromatic amine based promoter |
| US4496779A (en) * | 1984-04-26 | 1985-01-29 | Exxon Research & Engineering Co. | Process for the hydroxylation of olefins using molecular oxygen, an osmium containing catalyst, a copper co-catalyst, and a cycloaliphatic amine based promoter |
| US5516929A (en) * | 1988-01-11 | 1996-05-14 | Massachusetts Institute Of Technology | Method for catalytic asymmetric dihydroxylation of olefins using heterocyclic chiral ligands |
| US5126494A (en) * | 1988-01-11 | 1992-06-30 | Massachusetts Institute Of Technology | Methods for catalytic asymmetric dihydroxylation of olefins |
| US5260461A (en) * | 1988-01-11 | 1993-11-09 | Massachusetts Institute Of Technology | Ligands for ADH: cinchona alkaloids and moderately sized organic substituents linked through a planar aromatic spacer group |
| US5227543A (en) * | 1988-01-11 | 1993-07-13 | Massachusetts Institute Of Technology | Facilitation of turnover in the ADH by additives which catalyze the hydrolysis of the OS(VI) glycolate esters |
| DE3920917A1 (de) * | 1989-06-26 | 1991-01-03 | Hoechst Ag | Oxidische heterogenkatalysatoren des osmiums, verfahren zu ihrer herstellung und ihre verwendung fuer die ueberfuehrung von olefinischen verbindungen in glykole |
| US6765101B1 (en) * | 2001-05-01 | 2004-07-20 | Union Carbide Chemicals & Plastics Technology Corporation | Synthesis of lower alkylene oxides and lower alkylene glycols from lower alkanes and/or lower alkenes |
| DE10213981A1 (de) * | 2002-03-28 | 2003-10-16 | Bayer Ag | Verfahren zur Herstellung von vicinalen Diolen |
| CN108002977B (zh) * | 2018-01-15 | 2020-12-04 | 台州泰捷化工科技有限公司 | 一种联产化工产品二甲基苄醇和1,2-戊二醇的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3335174A (en) * | 1964-03-30 | 1967-08-08 | Marathon Oil Co | Preparation of diols and aliphatic carboxylic acid esters thereof from olefins |
| US3337635A (en) * | 1964-11-09 | 1967-08-22 | Marathon Oil Co | Method of producing ketols from hydrocarbons |
| US3488394A (en) * | 1966-05-11 | 1970-01-06 | Fmc Corp | Oxidation of olefinic compounds to glycols |
| GB1324763A (en) * | 1971-03-19 | 1973-07-25 | Continental Oil Co | Phase transfer catalysis of heterogeneous reactions by quaternary salts |
| US4280924A (en) * | 1978-12-26 | 1981-07-28 | Gulf Research & Development Company | Regenerating perosmate catalyst |
| US4393253A (en) * | 1980-11-24 | 1983-07-12 | Exxon Research & Engineering Co. | Hydroxylation of olefins |
-
1982
- 1982-10-08 AU AU89217/82A patent/AU8921782A/en not_active Abandoned
- 1982-10-08 DE DE8282305381T patent/DE3270461D1/de not_active Expired
- 1982-10-08 ES ES516355A patent/ES8401437A1/es not_active Expired
- 1982-10-08 BR BR8205931A patent/BR8205931A/pt unknown
- 1982-10-08 JP JP57178259A patent/JPS5877832A/ja active Pending
- 1982-10-08 EP EP82305381A patent/EP0077202B1/en not_active Expired
- 1982-10-08 AT AT82305381T patent/ATE19054T1/de not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| ATE19054T1 (de) | 1986-04-15 |
| EP0077202A2 (en) | 1983-04-20 |
| ES516355A0 (es) | 1983-12-01 |
| DE3270461D1 (en) | 1986-05-15 |
| JPS5877832A (ja) | 1983-05-11 |
| ES8401437A1 (es) | 1983-12-01 |
| EP0077202B1 (en) | 1986-04-09 |
| EP0077202A3 (en) | 1983-06-22 |
| AU8921782A (en) | 1983-04-14 |
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