BR0317094A - Sal de alumìnio livre de zircÈnio, e, composição antiperspirante - Google Patents
Sal de alumìnio livre de zircÈnio, e, composição antiperspiranteInfo
- Publication number
- BR0317094A BR0317094A BR0317094-2A BR0317094A BR0317094A BR 0317094 A BR0317094 A BR 0317094A BR 0317094 A BR0317094 A BR 0317094A BR 0317094 A BR0317094 A BR 0317094A
- Authority
- BR
- Brazil
- Prior art keywords
- zirconium
- peak
- nitrogen
- range
- salt
- Prior art date
Links
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 title abstract 3
- 230000001166 anti-perspirative effect Effects 0.000 title abstract 2
- 239000003213 antiperspirant Substances 0.000 title abstract 2
- 239000000463 material Substances 0.000 abstract 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 2
- 230000003139 buffering effect Effects 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
- Catalysts (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
"SAL DE ALUMìNIO LIVRE DE ZIRCÈNIO, E, COMPOSIçãO ANTIPERSPIRANTE". Um sal de alumínio isento de zircónio, que: (a) tem uma relação molar de aluminio para cloreto na faixa de 0,5 a 2,5:1; (b) compreende um material de tamponamento contendo nitrogênio em uma quantidade tal que a relação do material contendo nitrogênio para alumínio situa-se na faixa de 0,05 a 0,26:1, e em que o material contendo nitrogênio é selecionado do grupo consistindo de um material de tamponamento contendo nitrogênio de fórmula (1), em que n é um número na faixa de 1 a 20, e cada um dentre R¬ 1¬, R¬ 2¬ e R¬3¬ é independentemente selecionado do grupo consistindo de hidrogênio, metila e etila; e (c) o sal tem um pH na faixa de 2 a 4 em uma concentração de 15%; em que o sal é livre de qualquer outro material removedor de haleto e tem um valor de pelo menos 0,50 para a relação calculada como: área do Pico 5/área total sob o Pico 2 + Pico 3 + Pico 4 + Pico 5.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/314,712 US20040109833A1 (en) | 2002-12-09 | 2002-12-09 | High efficacy, low irritation aluminum salts and related products |
| PCT/US2003/038486 WO2004052325A1 (en) | 2002-12-09 | 2003-12-04 | High efficacy, low irritation aluminum salts and antiperspirant products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0317094A true BR0317094A (pt) | 2005-10-25 |
Family
ID=32468544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0317094-2A BR0317094A (pt) | 2002-12-09 | 2003-12-04 | Sal de alumìnio livre de zircÈnio, e, composição antiperspirante |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US20040109833A1 (pt) |
| EP (1) | EP1572144A1 (pt) |
| AR (1) | AR042346A1 (pt) |
| AU (1) | AU2003293362A1 (pt) |
| BR (1) | BR0317094A (pt) |
| CA (1) | CA2511831A1 (pt) |
| CL (1) | CL2003002555A1 (pt) |
| GT (1) | GT200300272A (pt) |
| MX (1) | MXPA05006068A (pt) |
| PA (1) | PA8591301A1 (pt) |
| PL (1) | PL377343A1 (pt) |
| RU (1) | RU2005121556A (pt) |
| WO (1) | WO2004052325A1 (pt) |
| ZA (1) | ZA200504623B (pt) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2154722B1 (en) * | 2002-08-29 | 2017-10-11 | Seoul Semiconductor Co., Ltd. | Light-emitting device having light-emitting diodes |
| US20040241123A1 (en) * | 2003-05-30 | 2004-12-02 | Christine Popoff | Suspension free and elastomer free antiperspirant cream |
| US7204976B2 (en) * | 2003-05-30 | 2007-04-17 | Colgate-Palmolive Company | High efficacy gel with low glycol content |
| US7105691B2 (en) * | 2003-06-26 | 2006-09-12 | Colgate-Palmolive Company | Aluminum / zirconium / glycine antiperspirant actives stabilized with Betaine |
| GB0410616D0 (en) * | 2004-05-13 | 2004-06-16 | Unilever Plc | Antiperspirant or deodorant compositions |
| US8883129B2 (en) | 2005-01-13 | 2014-11-11 | The Procter & Gamble Company | Enhanced efficacy antiperspirant active |
| US7704531B2 (en) | 2005-02-18 | 2010-04-27 | Colgate-Palmolive Company | Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine |
| US20060263311A1 (en) * | 2005-05-19 | 2006-11-23 | Scavone Timothy A | Consumer noticeable improvement in wetness protection using solid antiperspirant compositions |
| US8632755B2 (en) * | 2005-05-19 | 2014-01-21 | The Procter & Gamble Company | Consumer noticeable improvement in wetness protection |
| US8147808B2 (en) * | 2005-05-19 | 2012-04-03 | The Procter & Gamble Company | Consumer noticeable improvement in wetness protection using solid antiperspirant compositions |
| US20060292098A1 (en) * | 2005-05-19 | 2006-12-28 | Scavone Timothy A | Consumer noticeable improvement in wetness protection |
| US20070020211A1 (en) * | 2005-07-22 | 2007-01-25 | Reheis, Inc. | Betaine with Calcium and/or Strontium Antiperspirants |
| CL2006003116A1 (es) * | 2005-11-16 | 2008-02-29 | Colgate Palmolive Co | Composicion antitranspirante que comprende al menos una sal elegida de aluminio, aluminio zirconio, una sal compleja de aluminio o una sal compleja de aluminio-zirconio, un hidroxiacido y un compuesto acido de amonio cuaternario; proceso para prepara |
| US20070196303A1 (en) * | 2006-02-17 | 2007-08-23 | Reheis, Inc. | Stable buffered aluminum compositions having high hplc bands iii and iv containing calcium/strontium |
| US9789038B2 (en) | 2007-02-02 | 2017-10-17 | Colgate-Palmolive Company | Antiperspirant/deodorant compositions |
| US7976828B2 (en) | 2007-02-02 | 2011-07-12 | Colgate-Palmolive Company | Antiperspirant/deodorant composition |
| US10149910B2 (en) * | 2007-03-01 | 2018-12-11 | The Procter & Gamble Plaza | Compositions and/or articles comprising cyclodextrin complexing material |
| US11090250B2 (en) | 2007-03-01 | 2021-08-17 | The Procter & Gamble Company | Compositions and/or articles comprising cyclodextrin complexing material |
| MX344017B (es) | 2009-09-30 | 2016-12-02 | Colgate-Palmolive Company * | Composicion antitranspirante/desodorante. |
| AU2009353312B2 (en) * | 2009-09-30 | 2013-04-04 | Colgate-Palmolive Company | Antiperspirant/deodorant composition |
| AR078677A1 (es) | 2009-10-20 | 2011-11-23 | Colgate Palmolive Co | Composicion antitranspirante que reduce o elimina la decoloracion amarilla en las prendas de vestir |
| WO2011079001A2 (en) | 2009-12-23 | 2011-06-30 | Colgate-Palmolive Company | Anhydrous liquid antiperspirant/deodorant composition |
| AU2010357196B2 (en) | 2010-07-06 | 2014-07-17 | Colgate-Palmolive Company | Personal care product and manufacture thereof |
| US8895041B2 (en) | 2012-03-23 | 2014-11-25 | The Procter & Gamble Company | Compositions for delivering perfume to the skin |
| US9707171B2 (en) | 2012-12-11 | 2017-07-18 | Colgate-Palmolive Company | Antiperspirant/deodorant with alkylated polyvinylpyrrolidone |
| JP2016512565A (ja) | 2013-03-15 | 2016-04-28 | ザ プロクター アンド ギャンブル カンパニー | パーソナルケア組成物 |
| WO2014171948A1 (en) | 2013-04-19 | 2014-10-23 | Colgate-Palmolive Company | Aerosol antiperspirants |
| CA2951239A1 (en) | 2014-07-21 | 2016-01-28 | Colgate-Palmolive Company | Antiperspirant compositions containing ethylenediamine disuccinate |
| MX379903B (es) | 2016-09-06 | 2025-03-11 | Procter & Gamble | Composiciones en aerosol |
| BR112019004271B8 (pt) | 2016-09-06 | 2022-09-20 | Procter & Gamble | Composições desodorantes e antitranspirantes |
| CN110114052A (zh) | 2016-12-27 | 2019-08-09 | 高露洁-棕榄公司 | 具有改善的功效的挤出止汗剂组合物 |
| RU2747954C1 (ru) | 2017-12-14 | 2021-05-17 | Колгейт-Палмолив Компани | Композиции антиперспиранта/дезодоранта, содержащие биоразлагаемые аминокарбоксилаты, и способы их получения |
| MX2022005497A (es) | 2019-11-14 | 2022-06-02 | Colgate Palmolive Co | Composiciones para el cuidado personal para el tratamiento de bacterias que provocan olor y metodos del mismo. |
Family Cites Families (49)
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| US1025615A (en) * | 1911-10-19 | 1912-05-07 | Hoffmann La Roche Chemical Works | Process of separating meta- and para-cresols. |
| US4025615A (en) | 1975-02-25 | 1977-05-24 | Armour Pharmaceutical Company | Antiperspirant complexes formed with alkali metal and ammonium zirconyl carbonates |
| FR2303536A1 (fr) | 1975-03-11 | 1976-10-08 | Rhone Poulenc Ind | Nouveaux sels d'aluminium, leur preparation et les compositions qui les contiennent |
| US4359456A (en) | 1976-01-14 | 1982-11-16 | Lever Brothers Company | Antiperspirant activity of basic aluminum compounds |
| FR2407713A1 (fr) * | 1977-11-03 | 1979-06-01 | Warner Lambert Co | Compositions anti-perspirantes et leur preparation |
| CA1140470A (en) | 1980-05-27 | 1983-02-01 | Leonard Mackles | Aluminum chloride and aluminum zirconium hydroxychloride as antiperspirant |
| US4435382A (en) | 1980-07-14 | 1984-03-06 | Bristol-Myers Company | Anhydrous alcoholic antiperspirant suspension composition containing certain aluminum or aluminum/zirconium salt glycine complexes |
| US4331609A (en) | 1980-09-08 | 1982-05-25 | The Procter & Gamble Company | Antiperspirant composition |
| US4675177A (en) * | 1980-10-09 | 1987-06-23 | American Cyanamid Company | Antiperspirant compositions |
| CA1153313A (en) | 1980-12-15 | 1983-09-06 | Chung T. Shin | Antiperspirant composition containing aluminum chlorohydrate, aluminum chloride and an aluminum zirconium polychlorohydrate complex and method of use |
| US4606915A (en) * | 1981-04-23 | 1986-08-19 | Bristol-Myers Company | Antiperspirant combination containing an aluminum halohydrate and a stannic halide |
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| GB8410403D0 (en) * | 1984-04-24 | 1984-05-31 | Unilever Plc | Antiperspirant product |
| US5234677A (en) * | 1984-11-21 | 1993-08-10 | Reheis Inc. | Enhanced efficacy aluminum chlorhydrate antiperspirant and method of making same |
| US4871525A (en) * | 1986-10-24 | 1989-10-03 | Westwood Chemical Corporation | Antiperspirant composition and method of preparation |
| US5356612A (en) * | 1988-04-14 | 1994-10-18 | The Gillette Company | Antiperspirant and method of making same |
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| US5516511A (en) | 1994-05-06 | 1996-05-14 | The Procter & Gamble Company | Antiperspirant gel compositions comprising chelators |
| US5643558A (en) | 1994-11-02 | 1997-07-01 | The Gillette Company | Method of making polyhydric alcohol solutions of enhanced efficacy antiperspirant actives |
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| US5997850C1 (en) * | 1997-10-29 | 2001-11-27 | Colgate Palmolive Co | Antiperspirant actives and formulations made therefrom |
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| ES2190204T3 (es) | 1998-04-03 | 2003-07-16 | Colgate Palmolive Co | Composicion cosmetica baja en residuos. |
| US6042816A (en) | 1998-08-19 | 2000-03-28 | The Gillette Company | Enhanced antiperspirant salts stabilized with calcium and concentrated aqueous solutions of such salts |
| DE19855935A1 (de) | 1998-12-04 | 2000-06-08 | Beiersdorf Ag | Verwendung von funktional substituierten Betainen als Antitranspirantien |
| DE19855934A1 (de) | 1998-12-04 | 2000-06-08 | Beiersdorf Ag | Verwendung von Betainen als Antitranspirantien |
| US6024945A (en) * | 1999-07-29 | 2000-02-15 | Reheis, Inc. | Antiperspirant compositions for aerosol formulations |
| US6126928A (en) * | 1999-08-24 | 2000-10-03 | The Procter & Gamble Company | Compositions containing solubilized, acid-enhanced antiperspirant active |
| US6265364B1 (en) | 1999-12-28 | 2001-07-24 | Colgate-Palmolive Company | Solid cleansing composition comprising a choline salt |
| AR031108A1 (es) | 2000-06-19 | 2003-09-10 | Colgate Palmolive Co | Un metodo para mejorar la actividad de una sal de aluminio o de aluminio/circonio que contiene especies de aluminio pequenas y grandes, las sales asi obtenidas y los productos antitranspirantes y/o desodorantes preparados con dichas sales mejoradas |
| US6375937B1 (en) * | 2000-10-20 | 2002-04-23 | Colgate-Palmolive Company | Antiperspirant salts for enhanced cosmetic products |
| US6436381B1 (en) | 2000-10-25 | 2002-08-20 | The Gillette Company | Aluminum-zirconium antiperspirant salts with high peak 5 al content |
| US6726901B2 (en) | 2002-05-09 | 2004-04-27 | The Gillette Company | Stabilized antiperspirant compositions containing aluminum-zirconium salts with low M:Cl ratio |
| US20040091436A1 (en) | 2002-11-12 | 2004-05-13 | Zijun Li | Antiperspirant compositions of enhanced efficacy containing strontium |
| US6911195B2 (en) | 2002-12-16 | 2005-06-28 | The Gillette Company | Gel antiperspirant composition containing volatile linear silicone and calcium enhanced antiperspirant salt |
| US20040198998A1 (en) | 2003-04-04 | 2004-10-07 | Marian Holerca | Glycine-free antiperspirant salts with betaine for enhanced cosmetic products |
| US7105691B2 (en) | 2003-06-26 | 2006-09-12 | Colgate-Palmolive Company | Aluminum / zirconium / glycine antiperspirant actives stabilized with Betaine |
| US6902724B1 (en) | 2004-03-24 | 2005-06-07 | Reheis, Inc. | Enhanced efficacy basic aluminum halides, antiperspirant active compositions and methods for making |
| US7014843B2 (en) | 2004-03-24 | 2006-03-21 | Reheis, Inc. | Enhanced efficacy basic aluminum halides/metal cation salt, antiperspirants actives and compositions containing such materials and methods for making |
| US7704531B2 (en) | 2005-02-18 | 2010-04-27 | Colgate-Palmolive Company | Enhanced efficacy aluminum or aluminum-zirconium antiperspirant salt compositions containing calcium salt(s) and betaine |
| CL2006003116A1 (es) | 2005-11-16 | 2008-02-29 | Colgate Palmolive Co | Composicion antitranspirante que comprende al menos una sal elegida de aluminio, aluminio zirconio, una sal compleja de aluminio o una sal compleja de aluminio-zirconio, un hidroxiacido y un compuesto acido de amonio cuaternario; proceso para prepara |
-
2002
- 2002-12-09 US US10/314,712 patent/US20040109833A1/en not_active Abandoned
-
2003
- 2003-12-04 PL PL377343A patent/PL377343A1/pl not_active Application Discontinuation
- 2003-12-04 BR BR0317094-2A patent/BR0317094A/pt not_active IP Right Cessation
- 2003-12-04 MX MXPA05006068A patent/MXPA05006068A/es not_active Application Discontinuation
- 2003-12-04 WO PCT/US2003/038486 patent/WO2004052325A1/en not_active Ceased
- 2003-12-04 CA CA002511831A patent/CA2511831A1/en not_active Abandoned
- 2003-12-04 AU AU2003293362A patent/AU2003293362A1/en not_active Abandoned
- 2003-12-04 RU RU2005121556/15A patent/RU2005121556A/ru not_active Application Discontinuation
- 2003-12-04 EP EP03790308A patent/EP1572144A1/en not_active Withdrawn
- 2003-12-08 GT GT200300272A patent/GT200300272A/es unknown
- 2003-12-09 AR ARP030104531A patent/AR042346A1/es not_active Application Discontinuation
- 2003-12-09 PA PA20038591301A patent/PA8591301A1/es unknown
- 2003-12-09 CL CL200302555A patent/CL2003002555A1/es unknown
-
2005
- 2005-03-15 US US11/080,913 patent/US7311898B2/en not_active Expired - Fee Related
- 2005-06-06 ZA ZA200504623A patent/ZA200504623B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PL377343A1 (pl) | 2006-01-23 |
| CL2003002555A1 (es) | 2005-02-04 |
| PA8591301A1 (es) | 2004-12-16 |
| WO2004052325A1 (en) | 2004-06-24 |
| AR042346A1 (es) | 2005-06-15 |
| ZA200504623B (en) | 2006-08-30 |
| RU2005121556A (ru) | 2006-01-20 |
| US7311898B2 (en) | 2007-12-25 |
| US20050158261A1 (en) | 2005-07-21 |
| GT200300272A (es) | 2004-08-18 |
| CA2511831A1 (en) | 2004-06-24 |
| US20040109833A1 (en) | 2004-06-10 |
| AU2003293362A1 (en) | 2004-06-30 |
| MXPA05006068A (es) | 2005-08-16 |
| EP1572144A1 (en) | 2005-09-14 |
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