BR0306850A - Processo para produzir uma membrana hidrofóbica integralmente assimétrica, membrana hidrofóbica integralmente assimétrica, e, uso da mesma - Google Patents
Processo para produzir uma membrana hidrofóbica integralmente assimétrica, membrana hidrofóbica integralmente assimétrica, e, uso da mesmaInfo
- Publication number
- BR0306850A BR0306850A BR0306850-1A BR0306850A BR0306850A BR 0306850 A BR0306850 A BR 0306850A BR 0306850 A BR0306850 A BR 0306850A BR 0306850 A BR0306850 A BR 0306850A
- Authority
- BR
- Brazil
- Prior art keywords
- membrane
- separation
- integrally asymmetric
- hydrophobic membrane
- producing
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title abstract 7
- 230000002209 hydrophobic effect Effects 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 238000000926 separation method Methods 0.000 abstract 4
- 229920000098 polyolefin Polymers 0.000 abstract 3
- 239000011148 porous material Substances 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 2
- 238000005191 phase separation Methods 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000008280 blood Substances 0.000 abstract 1
- 210000004369 blood Anatomy 0.000 abstract 1
- 239000002826 coolant Substances 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000006213 oxygenation reaction Methods 0.000 abstract 1
- 239000012071 phase Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0018—Thermally induced processes [TIPS]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/0025—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching
- B01D67/0027—Organic membrane manufacture by inducing porosity into non porous precursor membranes by mechanical treatment, e.g. pore-stretching by stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0023—Organic membrane manufacture by inducing porosity into non porous precursor membranes
- B01D67/003—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching
- B01D67/0031—Organic membrane manufacture by inducing porosity into non porous precursor membranes by selective elimination of components, e.g. by leaching by elimination of at least one of the blocks of a block copolymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
- B01D71/262—Polypropylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C67/00—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
- B29C67/20—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored
- B29C67/202—Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 for porous or cellular articles, e.g. of foam plastics, coarse-pored comprising elimination of a solid or a liquid ingredient
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/38—Graft polymerization
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/026—Sponge structure
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Dispersion Chemistry (AREA)
- Mechanical Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- External Artificial Organs (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
"PROCESSO PARA PRODUZIR UMA MEMBRANA HIDROFóBICA INTEGRALMENTE ASSIMéTRICA MEMBRANA HIDROFóBICA INTEGRALMENTE ASSIMéTRICA, E, USO DA MESMA". A invenção refere-se a um método para a produção de uma membrana poliolefinica hidrofóbica integralmente assimétrica com uma estrutura de suporte microporosa de poro aberto, esponjosa e uma camada de separação possuindo uma estrutura mais espessa por meio de um processo de separação de fases de líquido-líquido termalmente induzida. Uma solução de pelo menos uma poliolefina é extrusada para formar um corpo moldado. O solvente usado é tal que a temperatura de separação de uma solução a 25% em peso de poliolefina no citado solvente está entre 10<198>C e 70<198>C acima da temperatura de endurecimento. Após a desmoldagem, o corpo moldado é resfriado por um meio de resfriamento líquido que não dissolve o polímero em temperaturas de até a temperatura de ferramenta, até a separação de fases e o endurecimento da fase rica em polímero. A membrana integralmente assimétrica assim produzida possui uma porosidade que é maior do que 30% em volume - 75% em volume, uma estrutura de suporte microporosa de poro aberto, esponjosa destituída de macrovazios e possui poros isotrópicos em seu centro e pelo menos uma camada de separação possuindo um número máximo de poros > 100 arranjados sobre pelo menos uma sua superfície. A membrana e preferivelmente usada para processos de separação gasosa ou de transferência gasosa e especialmente para a oxigenação de sangue.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10202594 | 2002-01-24 | ||
| PCT/EP2003/000084 WO2003061812A2 (de) | 2002-01-24 | 2003-01-08 | Polyolefinmembran mit integral asymmetrischer struktur und verfahren zu ihrer herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0306850A true BR0306850A (pt) | 2004-11-03 |
| BR0306850B1 BR0306850B1 (pt) | 2011-12-13 |
Family
ID=27588019
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0306850-1A BR0306850B1 (pt) | 2002-01-24 | 2003-01-08 | processo para produzir uma membrana hidrofóbica integralmente assimétrica. |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7429343B2 (pt) |
| EP (1) | EP1469935B1 (pt) |
| JP (1) | JP4217627B2 (pt) |
| CN (1) | CN1301149C (pt) |
| AT (1) | ATE337080T1 (pt) |
| BR (1) | BR0306850B1 (pt) |
| CA (1) | CA2477190C (pt) |
| DE (1) | DE50304738D1 (pt) |
| WO (1) | WO2003061812A2 (pt) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5076320B2 (ja) | 2006-01-11 | 2012-11-21 | 東洋紡績株式会社 | ポリフッ化ビニリデン系中空糸型微多孔膜の製造方法 |
| WO2010081077A2 (en) * | 2009-01-09 | 2010-07-15 | Massachusetts Institute Of Technology | Liquid filtration using pressure difference across a hydrophobic membrane |
| CN102416300B (zh) * | 2010-09-28 | 2014-03-12 | 中国石油化工股份有限公司 | 一种聚丙烯平板分离膜的制备方法 |
| CN102755840B (zh) * | 2011-04-25 | 2014-08-06 | 中国石油化工股份有限公司 | 一种平板聚丙烯分离膜的制备方法 |
| AT511431B1 (de) * | 2011-06-01 | 2012-12-15 | Univ Wien Tech | Herstellung asymmetrischer membranen |
| US20130068222A1 (en) * | 2011-06-20 | 2013-03-21 | Klaus Michael SCHMIDT | Anesthetic circuit and a method for using the anesthetic circuit |
| US10076620B2 (en) | 2012-12-22 | 2018-09-18 | Dmf Medical Incorporated | Anesthetic circuit having a hollow fiber membrane |
| CN107073411B (zh) * | 2014-11-03 | 2021-05-07 | 3M创新有限公司 | 微孔聚偏二氟乙烯平膜 |
| WO2016136294A1 (ja) * | 2015-02-27 | 2016-09-01 | 富士フイルム株式会社 | ガス分離膜、ガス分離モジュール、ガス分離装置、ガス分離方法、及びガス分離非対称膜の製造方法 |
| JP6366813B2 (ja) * | 2015-02-27 | 2018-08-01 | 富士フイルム株式会社 | ガス分離非対称膜、ガス分離モジュール、ガス分離装置、及びガス分離方法 |
| JP6323847B2 (ja) * | 2015-02-27 | 2018-05-16 | 富士フイルム株式会社 | ガス分離膜、ガス分離モジュール、ガス分離装置、及びガス分離方法 |
| EP3235558A1 (en) * | 2016-04-21 | 2017-10-25 | 3M Innovative Properties Company of 3M Center | Hollow fiber membrane for use in an anesthetic circuit |
| CN106823806B (zh) * | 2017-03-23 | 2020-04-28 | 南京膜材料产业技术研究院有限公司 | 一种规则四层结构的纳滤膜、制备方法及在高浓度盐分离过程中的应用 |
| CN108099185B (zh) * | 2017-12-07 | 2020-11-13 | 浙江海洋大学 | 一种基于3d打印快速在基体上制备超疏水表面方法 |
| CN108211809B (zh) * | 2017-12-13 | 2020-12-08 | 浙江长兴求是膜技术有限公司 | 一种永久亲水的聚偏氟乙烯膜及其制造方法 |
| CN108211808B (zh) * | 2017-12-13 | 2020-12-08 | 浙江长兴求是膜技术有限公司 | 一种食品级聚偏氟乙烯膜及其制造方法 |
| US20200139309A1 (en) | 2018-11-01 | 2020-05-07 | Entegris, Inc. | Porous polyethylene filter membrane with asymmetric pore structure, and related filters and methods |
| CN110538582A (zh) * | 2019-09-09 | 2019-12-06 | 杭州科百特过滤器材有限公司 | 一种非对称聚烯烃膜的制备方法 |
| KR20220074956A (ko) * | 2019-10-10 | 2022-06-03 | 엔테그리스, 아이엔씨. | 다공성 중합체 막 및 관련 필터 및 방법 |
| CN111888946B (zh) * | 2020-08-17 | 2022-08-30 | 杭州科百特科技有限公司 | 一种用于血液氧合的非对称疏水性聚烯烃中空纤维膜及其制备方法与用途 |
| CN112535956B (zh) * | 2020-11-17 | 2022-09-23 | 上海翊科聚合物科技有限公司 | 一种用于氧合膜的超疏水聚烯烃中空纤维膜及其制备方法 |
| CN114733361B (zh) * | 2021-01-07 | 2024-06-14 | 杭州费尔新材料有限公司 | 一种聚烯烃中空纤维膜的制备方法 |
| WO2022230923A1 (ja) | 2021-04-28 | 2022-11-03 | 東レ株式会社 | 分離膜及びその製造方法 |
| CN120897793A (zh) | 2023-04-05 | 2025-11-04 | 东丽株式会社 | 分离膜、其制造方法、作为脱气用和注气用的至少一者的膜组件、以及作为脱气用和注气用的至少一者的装置 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4247498A (en) * | 1976-08-30 | 1981-01-27 | Akzona Incorporated | Methods for making microporous products |
| DK171108B1 (da) | 1976-08-30 | 1996-06-10 | Akzo Nv | Mikroporøst polymerlegeme samt dettes fremstilling og anvendelse |
| DE2833493C2 (de) | 1978-07-31 | 1989-10-12 | Akzo Gmbh, 5600 Wuppertal | Hohlfäden |
| US4564488A (en) * | 1978-07-31 | 1986-01-14 | Akzo Nv | Methods for the preparation of porous fibers and membranes |
| DE3205289C2 (de) * | 1982-02-15 | 1984-10-31 | Akzo Gmbh, 5600 Wuppertal | Verfahren zur Herstellung von porösen Körpern mit einstellbarem Gesamtporenvolumen, einstellbarer Porengröße und einstellbarer Porenwandung |
| US4490431A (en) * | 1982-11-03 | 1984-12-25 | Akzona Incorporated | 0.1 Micron rated polypropylene membrane and method for its preparation |
| JPS59196706A (ja) * | 1983-04-22 | 1984-11-08 | Dainippon Ink & Chem Inc | 不均質膜およびその製造方法 |
| EP0133882B1 (de) * | 1983-07-30 | 1990-04-04 | Akzo Patente GmbH | Poren aufweisende Formkörper |
| DE3803693A1 (de) * | 1987-03-10 | 1988-09-22 | Akzo Gmbh | Mehrlagiger hohlfadenwickelkoerper |
| EP0299381B2 (en) | 1987-07-11 | 1999-06-30 | Dainippon Ink And Chemicals, Inc. | Membrane-type artificial lung and method of using it |
| US5238618A (en) * | 1987-09-14 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Method for preparing oriented microporous film |
| US4957943A (en) * | 1988-10-14 | 1990-09-18 | Minnesota Mining And Manufacturing Company | Particle-filled microporous materials |
| US5238623A (en) * | 1989-11-20 | 1993-08-24 | Minnesota Mining And Manufacturing Company | Method for preparing microporous polyolefin shaped articles |
| KR100567153B1 (ko) | 1997-07-23 | 2006-04-04 | 멤브라나 게엠베하 | 가스 운반용 일체형 비대칭성 폴리올레핀 멤브레인 및 이의 제조방법 |
| EP1144096B1 (de) | 1999-01-21 | 2003-10-01 | Membrana GmbH | Integral asymmetrische polyolefinmembran |
| CN1136035C (zh) * | 1999-01-22 | 2004-01-28 | 制膜有限公司 | 整体不对称聚烯烃膜的生产方法 |
-
2003
- 2003-01-08 US US10/502,346 patent/US7429343B2/en not_active Expired - Fee Related
- 2003-01-08 AT AT03731665T patent/ATE337080T1/de not_active IP Right Cessation
- 2003-01-08 CA CA2477190A patent/CA2477190C/en not_active Expired - Lifetime
- 2003-01-08 DE DE50304738T patent/DE50304738D1/de not_active Expired - Lifetime
- 2003-01-08 EP EP03731665A patent/EP1469935B1/de not_active Expired - Lifetime
- 2003-01-08 BR BRPI0306850-1A patent/BR0306850B1/pt active IP Right Grant
- 2003-01-08 CN CNB038027437A patent/CN1301149C/zh not_active Expired - Lifetime
- 2003-01-08 JP JP2003561748A patent/JP4217627B2/ja not_active Expired - Lifetime
- 2003-01-08 WO PCT/EP2003/000084 patent/WO2003061812A2/de not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20050145107A1 (en) | 2005-07-07 |
| WO2003061812A3 (de) | 2004-02-05 |
| JP4217627B2 (ja) | 2009-02-04 |
| CN1301149C (zh) | 2007-02-21 |
| WO2003061812A2 (de) | 2003-07-31 |
| DE50304738D1 (de) | 2006-10-05 |
| EP1469935B1 (de) | 2006-08-23 |
| JP2005515061A (ja) | 2005-05-26 |
| CN1622850A (zh) | 2005-06-01 |
| US7429343B2 (en) | 2008-09-30 |
| EP1469935A2 (de) | 2004-10-27 |
| CA2477190A1 (en) | 2003-07-31 |
| ATE337080T1 (de) | 2006-09-15 |
| CA2477190C (en) | 2011-07-26 |
| BR0306850B1 (pt) | 2011-12-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 08/01/2003, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B25A | Requested transfer of rights approved |