BR0300500A - Combinações sinérgicas de absorvedores de uv para poliolefinas pigmentadas - Google Patents
Combinações sinérgicas de absorvedores de uv para poliolefinas pigmentadasInfo
- Publication number
- BR0300500A BR0300500A BR0300500-3A BR0300500A BR0300500A BR 0300500 A BR0300500 A BR 0300500A BR 0300500 A BR0300500 A BR 0300500A BR 0300500 A BR0300500 A BR 0300500A
- Authority
- BR
- Brazil
- Prior art keywords
- absorbers
- hydroxyphenyl
- pigmented
- synergistic combinations
- polyolefins
- Prior art date
Links
- 229920000098 polyolefin Polymers 0.000 title abstract 4
- 239000006096 absorbing agent Substances 0.000 title abstract 2
- 239000011885 synergistic combination Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 abstract 3
- 230000000087 stabilizing effect Effects 0.000 abstract 2
- HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical compound OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 abstract 1
- YHCGGLXPGFJNCO-UHFFFAOYSA-N 2-(2H-benzotriazol-4-yl)phenol Chemical compound OC1=CC=CC=C1C1=CC=CC2=C1N=NN2 YHCGGLXPGFJNCO-UHFFFAOYSA-N 0.000 abstract 1
- ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical compound OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 abstract 1
- NJCDRURWJZAMBM-UHFFFAOYSA-N 6-phenyl-1h-1,3,5-triazin-2-one Chemical compound OC1=NC=NC(C=2C=CC=CC=2)=N1 NJCDRURWJZAMBM-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000004611 light stabiliser Substances 0.000 abstract 1
- 239000012860 organic pigment Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0041—Optical brightening agents, organic pigments
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
"COMBINAçõES SINéRGICAS DE ABSORVEDORES DE UV PARA POLIOLEFINAS PIGMENTADAS". A presente invenção refere-se a uma composição de poliolefina que compreende d) pelo menos um pigmento orgânico e) pelo menos uma estabilizador à luz de amina estericamente elevado f) mistura absorvedora de UV de 2-hidroxifenil benzotriazol e um 2-hidroxifenil-s-triazina. Outros objetos da invenção são um método para estabilização de uma poliolefina pigmentada e o uso de misturadores absorvedores de UV de um hidroxifenil benzotriazol com um hidroxifenil-s-triazina para a estabilização das poliolefinas pigmentadas.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405162 | 2002-03-04 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0300500A true BR0300500A (pt) | 2004-08-10 |
| BR0300500B1 BR0300500B1 (pt) | 2013-03-05 |
Family
ID=27798954
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0300500-3A BR0300500B1 (pt) | 2002-03-04 | 2003-03-05 | composiÇço poliolefÍnica, processo para estabilizaÇço de uma poliolefina e uso de uma mistura. |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US6878761B2 (pt) |
| EP (1) | EP1342748B1 (pt) |
| JP (1) | JP2003261725A (pt) |
| KR (1) | KR100902337B1 (pt) |
| CN (1) | CN1294193C (pt) |
| AR (1) | AR038627A1 (pt) |
| AT (1) | ATE406406T1 (pt) |
| AU (1) | AU2003200799B2 (pt) |
| BR (1) | BR0300500B1 (pt) |
| CA (1) | CA2420549C (pt) |
| CO (1) | CO5310577A1 (pt) |
| DE (1) | DE60323174D1 (pt) |
| DK (1) | DK1342748T3 (pt) |
| ES (1) | ES2312743T3 (pt) |
| IL (1) | IL154706A (pt) |
| MX (1) | MX238184B (pt) |
| SA (1) | SA03230548B1 (pt) |
| TW (1) | TWI293973B (pt) |
| ZA (1) | ZA200301683B (pt) |
Families Citing this family (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030225191A1 (en) * | 2002-04-12 | 2003-12-04 | Francois Gugumus | Stabilizer mixtures |
| US20040031225A1 (en) * | 2002-08-14 | 2004-02-19 | Gregory Fowler | Water resistant tongue and groove flooring |
| WO2004077935A1 (en) * | 2003-03-06 | 2004-09-16 | North-West University | Plant protective cover |
| MY149850A (en) * | 2003-09-29 | 2013-10-31 | Ciba Holding Inc | Stabilization of photochromic systems |
| JP2007511656A (ja) * | 2003-11-21 | 2007-05-10 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | 耐候性の、顔料着色されたポリスチレン |
| US20060083940A1 (en) * | 2004-04-30 | 2006-04-20 | Solomon Bekele | Ultraviolet light absorbing composition |
| JP4666957B2 (ja) | 2004-06-16 | 2011-04-06 | 株式会社Adeka | 耐候性の改善されたポリエステル樹脂製容器 |
| US20060122293A1 (en) * | 2004-12-03 | 2006-06-08 | Rick Wilk | Ultraviolet light absorber stabilizer combination |
| GB0426742D0 (en) * | 2004-12-06 | 2005-01-12 | Ykk Europ Ltd | A slide fastener |
| US7541398B2 (en) * | 2005-01-03 | 2009-06-02 | Board Of Regents, The University Of Texas System | Method for transformation of conventional and commercially important polymers into durable and rechargeable antimicrobial polymeric materials |
| EA015480B1 (ru) | 2005-01-03 | 2011-08-30 | Борд Оф Риджентс, Зе Юниверсити Оф Техас Систем | Противомикробная полимерная добавка и способы преобразования обычных и коммерчески важных полимеров в регенерируемые противомикробные полимерные материалы |
| JP2008531777A (ja) * | 2005-02-25 | 2008-08-14 | チバ ホールディング インコーポレーテッド | フッ素化された化合物 |
| US20070062884A1 (en) | 2005-08-11 | 2007-03-22 | Board Of Regents, The University Of Texas System | N-halamines compounds as multifunctional additives |
| US7416766B2 (en) * | 2005-08-16 | 2008-08-26 | S.C. Johnson & Son, Inc. | Bottles made from metallocene polypropylene for delivery of fragrances |
| DE102005061954A1 (de) * | 2005-12-23 | 2007-07-05 | Basf Ag | Verfahren zur Wiedergewinnung von Ruthenium aus gebrauchten Rutheniumoxid-haltigen Katalysatoren |
| WO2007082842A1 (de) * | 2006-01-13 | 2007-07-26 | Basf Aktiengesellschaft | Stabilisatormischung |
| CA2636831C (en) * | 2006-02-01 | 2014-08-12 | Ciba Holding Inc. | Stabilizer composition for polymers |
| US8486428B2 (en) * | 2006-03-27 | 2013-07-16 | Board Of Regents, The University Of Texas System | Compositions and methods for making and using acyclic N-halamine-based biocidal polymeric materials and articles |
| EP2004742B1 (de) * | 2006-03-31 | 2011-07-27 | Basf Se | Zusammensetzung, enthaltend polymere, farbmittel und stabilisatoren |
| ES2670436T3 (es) * | 2007-01-15 | 2018-05-30 | Basf Se | Recubrimientos transparentes teñidos estabilizados para UV con 2-hidroxifenil triazina |
| US8211361B2 (en) * | 2007-03-26 | 2012-07-03 | Board Of Regents, The University Of Texas System | N-halamine-based rechargeable biofilm-controlling tubular devices, method of making and using |
| US7789957B2 (en) * | 2007-06-06 | 2010-09-07 | Ciba Corporation | Low-dust additive and pigment blends with improved color |
| CN101386694B (zh) * | 2007-09-14 | 2011-11-09 | 株式会社藤仓 | 耐放射线性树脂组合物及耐放射线性电线、电缆 |
| WO2009039180A2 (en) * | 2007-09-19 | 2009-03-26 | Board Of Regents, The University Of Texas System | Colorants based n-halamines compositions and method of making and using |
| KR101618890B1 (ko) * | 2008-03-12 | 2016-05-09 | 바스프 에스이 | 플랫 패널 디스플레이용 광학 필름 |
| WO2010048436A2 (en) * | 2008-10-22 | 2010-04-29 | Microban Products Company | Antimicrobial polymer with anti-yellowing property |
| US20100190878A1 (en) * | 2008-12-24 | 2010-07-29 | Sumitomo Chemical Company, Limited | Polyolefin resin composition and foam molded article |
| ES2505492T3 (es) | 2009-08-11 | 2014-10-10 | Basf Se | Alcoxiaminas bi- o tricíclicas estéricamente impedidas y procedimientos para su preparación |
| KR20120104164A (ko) * | 2009-08-18 | 2012-09-20 | 바스프 에스이 | Uv-안정화된 광전 모듈 |
| JP2012036270A (ja) * | 2010-08-05 | 2012-02-23 | Mitsui Chemicals Inc | 4−メチル−1−ペンテン系重合体組成物 |
| KR101798693B1 (ko) * | 2010-09-30 | 2017-11-16 | 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 엘엘씨 | 전압 안정화된 내부층을 갖는 코팅된 도체 |
| US9855682B2 (en) | 2011-06-10 | 2018-01-02 | Columbia Insurance Company | Methods of recycling synthetic turf, methods of using reclaimed synthetic turf, and products comprising same |
| JP5734826B2 (ja) * | 2011-12-20 | 2015-06-17 | 株式会社Adeka | オレフィン樹脂組成物の製造方法 |
| US9034271B2 (en) | 2012-08-28 | 2015-05-19 | Sensor Electronics Technology, Inc. | Storage device including ultraviolet illumination |
| WO2014036083A1 (en) | 2012-08-28 | 2014-03-06 | Sensor Electronic Technology, Inc. | Utraviolet system for disinfection |
| US9919068B2 (en) | 2012-08-28 | 2018-03-20 | Sensor Electronic Technology, Inc. | Storage device including ultraviolet illumination |
| US10646603B2 (en) | 2012-08-28 | 2020-05-12 | Sensor Electronic Technology, Inc. | Multi wave sterilization system |
| US9981051B2 (en) | 2012-08-28 | 2018-05-29 | Sensor Electronic Technology, Inc. | Ultraviolet gradient sterilization, disinfection, and storage system |
| US10383964B2 (en) | 2012-08-28 | 2019-08-20 | Sensor Electronic Technology, Inc. | Storage device including ultraviolet illumination |
| US10688210B2 (en) | 2012-08-28 | 2020-06-23 | Sensor Electronic Technology, Inc. | Storage device including ultraviolet illumination |
| CN104853625A (zh) | 2012-08-28 | 2015-08-19 | 传感器电子技术股份有限公司 | 多波灭菌系统 |
| US9724441B2 (en) | 2012-08-28 | 2017-08-08 | Sensor Electronic Technology, Inc. | Storage device including target UV illumination ranges |
| US9707307B2 (en) | 2012-08-28 | 2017-07-18 | Sensor Electronic Technology, Inc. | Ultraviolet system for disinfection |
| US10441670B2 (en) | 2012-08-28 | 2019-10-15 | Sensor Electronic Technology, Inc. | Storage device including ultraviolet illumination |
| US9878061B2 (en) | 2012-08-28 | 2018-01-30 | Sensor Electronic Technology, Inc. | Ultraviolet system for disinfection |
| KR101742845B1 (ko) * | 2013-09-30 | 2017-06-01 | 주식회사 엘지화학 | 자외선 차단 기능이 우수한 광학 필름 및 이를 포함하는 편광판 |
| EP2818504B1 (en) * | 2013-06-28 | 2020-06-03 | Borealis AG | Use of an extrusion processing aid for the production of coloured polyethylene pipes |
| BR112016004083B1 (pt) | 2013-09-13 | 2021-04-27 | Dow Global Technologies Llc | Composições reticuláveis de peróxido e processos para preparar uma pelota reticulável com peróxido |
| MX385675B (es) * | 2013-09-27 | 2025-03-18 | Basf Se | Composiciones de poliolefina para materiales de construccion. |
| CN103804952A (zh) * | 2014-01-23 | 2014-05-21 | 上海百艳实业有限公司 | 吡咯并吡咯二酮类颜料组合物 |
| CN106589514B (zh) * | 2015-10-20 | 2020-03-24 | 天罡新材料(廊坊)股份有限公司 | 一种光稳定剂组合物母粒及其制备方法和应用 |
| KR101993033B1 (ko) * | 2016-08-02 | 2019-06-26 | (주)비피케미칼 | 고분자용 유동성 첨가제 및 이의 제조방법 |
| CN107793634A (zh) * | 2016-08-29 | 2018-03-13 | 合肥杰事杰新材料股份有限公司 | 一种具有高遮光性能的浅色pp合金及其制备方法 |
| CN111801306A (zh) * | 2017-12-27 | 2020-10-20 | 巴斯夫欧洲公司 | 含亚甲基丙二酸酯单体和聚合物的组合物、其制备及其在地板应用中的用途 |
| EP3536742A1 (en) * | 2018-03-09 | 2019-09-11 | Polytex Sportbeläge Produktions-GmbH | Artificial turf fiber with uv protection substances |
| WO2019244986A1 (ja) * | 2018-06-21 | 2019-12-26 | 凸版印刷株式会社 | 保護フィルムおよびシート |
| PL3841166T5 (pl) * | 2018-08-22 | 2025-08-18 | Basf Se | Stabilizowana poliolefina wytwarzana w procesie formowania rotacyjnego |
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| CN111004428A (zh) * | 2019-12-23 | 2020-04-14 | 海南联塑科技实业有限公司 | 一种聚乙烯给水管材专用色母粒及其制备方法和应用 |
| US11692085B2 (en) * | 2020-03-18 | 2023-07-04 | University Of South Florida | Geomembranes and methods for making and using the same |
| US12043008B2 (en) * | 2020-10-13 | 2024-07-23 | The Goodyear Tire & Rubber Company | Method for repairing self-sealing tires |
| CN112430393B (zh) * | 2020-11-20 | 2022-11-18 | 广州辰东新材料有限公司 | 一种用于激光焊接的耐紫外热塑性聚酰胺复合材料及其制备方法 |
| CN112300546B (zh) * | 2020-11-20 | 2022-10-25 | 广州辰东新材料有限公司 | 一种用于激光焊接的耐紫外热塑性聚酯复合材料及其制备方法 |
| AU2022250860A1 (en) * | 2021-04-01 | 2023-10-12 | Basf Se | Stabilizer mixture |
| WO2023041512A1 (en) * | 2021-09-14 | 2023-03-23 | Ineos Styrolution Group Gmbh | High clarity and low haze uv stabilized styrene and methyl methacrylate copolymers |
| AU2022346816A1 (en) * | 2021-09-16 | 2024-03-28 | Basf Se | Stabilizer formulation |
| CN114213749B (zh) * | 2021-11-23 | 2024-11-26 | 金发科技股份有限公司 | 一种阻燃聚丙烯材料及其制备方法与应用 |
| CN114316471A (zh) * | 2021-12-31 | 2022-04-12 | 天津利安隆新材料股份有限公司 | 适用于硬质聚氯乙烯材料的复合光稳定剂、硬质聚氯乙烯材料及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8720365D0 (en) | 1987-08-28 | 1987-10-07 | Sandoz Ltd | Organic compounds |
| DE59107052D1 (de) | 1990-03-30 | 1996-01-25 | Ciba Geigy Ag | Lackzusammensetzungen |
| GB2278115B (en) * | 1993-05-17 | 1997-08-06 | Ciba Geigy Ag | 2-(2-Hydroxyphenyl)-1,3-pyrimidine derivatives and their use as stabilizers for coating compositions |
| US5556973A (en) * | 1994-07-27 | 1996-09-17 | Ciba-Geigy Corporation | Red-shifted tris-aryl-s-triazines and compositions stabilized therewith |
| EP0704560B1 (en) | 1994-09-30 | 1999-01-13 | Ciba SC Holding AG | Stabilization of pigmented fiber with a synergistic mixture of hindered amine and UV absorber |
| DE4441651A1 (de) * | 1994-11-23 | 1996-04-25 | Basf Ag | Verfahren zur oberflächlichen Beschichtung von Substraten |
| CH691970A5 (de) * | 1996-03-04 | 2001-12-14 | Ciba Sc Holding Ag | Alkylphenylbisacylphosphinoxide und Photoinitiatormischungen. |
| KR100517489B1 (ko) * | 1996-04-02 | 2006-05-03 | 시바 스페셜티 케미칼스 홀딩 인크. | 광안정화제로서의 아미노-및 하이드록시 치환된 트리페닐-s-트리아진 |
| GB9606970D0 (en) | 1996-04-02 | 1996-06-05 | Ciba Geigy Ag | Compounds |
| TW467931B (en) * | 1996-08-22 | 2001-12-11 | Ciba Sc Holding Ag | Stabilizer mixtures |
| BE1012529A3 (fr) | 1996-09-13 | 2000-12-05 | Ciba Sc Holding Ag | Melange de triaryltriazines et son utilisation pour la stabilisation de materiaux organiques. |
| GB2332678B (en) | 1997-12-23 | 2000-09-27 | Ciba Sc Holding Ag | Stabilizer mixtures containing a sterically hindered amine |
| GB2361005B (en) | 2000-04-04 | 2002-08-14 | Ciba Sc Holding Ag | Synergistic mixtures of uv-absorbers in polyolefins |
-
2003
- 2003-01-01 ZA ZA200301683A patent/ZA200301683B/xx unknown
- 2003-02-05 US US10/358,823 patent/US6878761B2/en not_active Expired - Fee Related
- 2003-02-20 CO CO03014529A patent/CO5310577A1/es not_active Application Discontinuation
- 2003-02-24 SA SA3230548A patent/SA03230548B1/ar unknown
- 2003-02-25 DE DE60323174T patent/DE60323174D1/de not_active Expired - Lifetime
- 2003-02-25 DK DK03405121T patent/DK1342748T3/da active
- 2003-02-25 ES ES03405121T patent/ES2312743T3/es not_active Expired - Lifetime
- 2003-02-25 AT AT03405121T patent/ATE406406T1/de active
- 2003-02-25 EP EP03405121A patent/EP1342748B1/en not_active Expired - Lifetime
- 2003-02-28 AR ARP030100666A patent/AR038627A1/es not_active Application Discontinuation
- 2003-02-28 CA CA2420549A patent/CA2420549C/en not_active Expired - Fee Related
- 2003-03-02 IL IL154706A patent/IL154706A/en not_active IP Right Cessation
- 2003-03-03 TW TW092104375A patent/TWI293973B/zh not_active IP Right Cessation
- 2003-03-03 KR KR1020030012956A patent/KR100902337B1/ko not_active Expired - Fee Related
- 2003-03-03 AU AU2003200799A patent/AU2003200799B2/en not_active Ceased
- 2003-03-04 MX MXPA03001899 patent/MX238184B/es active IP Right Grant
- 2003-03-04 JP JP2003057447A patent/JP2003261725A/ja active Pending
- 2003-03-04 CN CNB031198368A patent/CN1294193C/zh not_active Expired - Fee Related
- 2003-03-05 BR BRPI0300500-3A patent/BR0300500B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| MXPA03001899A (es) | 2003-09-11 |
| CN1442446A (zh) | 2003-09-17 |
| ES2312743T3 (es) | 2009-03-01 |
| CA2420549A1 (en) | 2003-09-04 |
| DK1342748T3 (da) | 2008-11-24 |
| CO5310577A1 (es) | 2003-08-29 |
| IL154706A0 (en) | 2003-10-31 |
| ATE406406T1 (de) | 2008-09-15 |
| CA2420549C (en) | 2011-07-12 |
| IL154706A (en) | 2006-12-10 |
| KR100902337B1 (ko) | 2009-06-12 |
| EP1342748B1 (en) | 2008-08-27 |
| KR20030072231A (ko) | 2003-09-13 |
| US6878761B2 (en) | 2005-04-12 |
| ZA200301683B (en) | 2004-09-06 |
| TW200408668A (en) | 2004-06-01 |
| JP2003261725A (ja) | 2003-09-19 |
| AU2003200799B2 (en) | 2008-04-24 |
| US20040030009A1 (en) | 2004-02-12 |
| BR0300500B1 (pt) | 2013-03-05 |
| AR038627A1 (es) | 2005-01-19 |
| CN1294193C (zh) | 2007-01-10 |
| MX238184B (es) | 2006-06-28 |
| SA03230548B1 (ar) | 2006-11-11 |
| DE60323174D1 (de) | 2008-10-09 |
| TWI293973B (en) | 2008-03-01 |
| EP1342748A1 (en) | 2003-09-10 |
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