BR0211290A - Compostos de catalisador de metaloceno de baixa incorporação de comonÈmero - Google Patents
Compostos de catalisador de metaloceno de baixa incorporação de comonÈmeroInfo
- Publication number
- BR0211290A BR0211290A BR0211290-6A BR0211290A BR0211290A BR 0211290 A BR0211290 A BR 0211290A BR 0211290 A BR0211290 A BR 0211290A BR 0211290 A BR0211290 A BR 0211290A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst compounds
- metallocene
- compounds
- catalyst
- metallocene catalyst
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title 1
- 238000010348 incorporation Methods 0.000 title 1
- 239000012968 metallocene catalyst Substances 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
"COMPOSTOS DE CATALISADOR DE METALOCENO DE BAIXA INCORPORAçãO DE COMONÈMERO". A presente invenção provê compostos de catalisador de polimerização, sistemas de catalisador incluindo esses compostos de catalisador e ao seu uso na polimerização de etileno e pelo menos um comonómero. Em particular, a invenção refere-se à identificação do comportamento de incorporação do comonómero de compostos de catalisador de polimerização de metaloceno. Mais particularmente, a invenção refere-se à identificação de compostos de catalisador de metaloceno que incorporam comonómero pobremente. De preferência, tais compostos de catalisador de metaloceno contêm pelo menos um ligante à base de ciclopentadienila de anel fundido substituído ou não-substituído. A invenção refere-se também ao uso desses compostos de catalisador de metaloceno de baixa incorporação de metaloceno em sistemas de catalisador para produzir polímeros que são fáceis de processar em uma variedade de artigos, especialmente película à base de polietileno, tendo propriedades acentuadas.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US30650301P | 2001-07-19 | 2001-07-19 | |
| US10/199,147 US7060765B2 (en) | 2001-07-19 | 2002-07-19 | Low comonomer incorporating metallocene catalyst compounds |
| PCT/US2002/022942 WO2003008465A2 (en) | 2001-07-19 | 2002-07-19 | Low comonomer incorporating metallocene catalyst compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0211290A true BR0211290A (pt) | 2004-09-14 |
Family
ID=26894511
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0211290-6A BR0211290A (pt) | 2001-07-19 | 2002-07-19 | Compostos de catalisador de metaloceno de baixa incorporação de comonÈmero |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7060765B2 (pt) |
| EP (1) | EP1412394A2 (pt) |
| JP (1) | JP2004536183A (pt) |
| CN (1) | CN1545523A (pt) |
| AU (1) | AU2002354949B2 (pt) |
| BR (1) | BR0211290A (pt) |
| CA (1) | CA2454060A1 (pt) |
| WO (1) | WO2003008465A2 (pt) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6936675B2 (en) * | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| JP4221363B2 (ja) * | 2001-07-19 | 2009-02-12 | ユニベーション・テクノロジーズ・エルエルシー | 物性が向上したポリエチレンフィルム |
| US6911508B2 (en) | 2003-06-05 | 2005-06-28 | Univation Technologies, Llc | Class of metallocenes and method of producing polyethylene |
| JP5493238B2 (ja) * | 2005-09-30 | 2014-05-14 | 住友化学株式会社 | エチレン−α−オレフィン共重合体および成形体 |
| WO2008136621A1 (en) * | 2007-05-02 | 2008-11-13 | Lg Chem, Ltd. | Polyolefin and preparation method thereof |
| US20120172548A1 (en) | 2007-05-02 | 2012-07-05 | Lg Chem, Ltd. | Polyolefin and preparation method thereof |
| US7544825B1 (en) | 2008-06-12 | 2009-06-09 | Basell Polyolefine Gmbh | Preparation of siloxy-bridged metallocenes |
| US20160362510A1 (en) * | 2014-02-11 | 2016-12-15 | Univation Technologies, Llc | Method to prepare ethylene copolymers |
| US10934376B2 (en) | 2017-11-28 | 2021-03-02 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions and films made therefrom |
| WO2019108315A1 (en) | 2017-11-28 | 2019-06-06 | Exxonmobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
| KR20210019522A (ko) * | 2018-06-13 | 2021-02-22 | 바스프 에스이 | 금속 또는 반금속-함유 필름의 제조 방법 |
| CN112745415B (zh) * | 2019-10-30 | 2022-09-09 | 中国石油化工股份有限公司 | 一种制备高粘度指数聚α-烯烃的方法 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6411508A (en) * | 1987-07-02 | 1989-01-17 | Makiko Sawa | Toothbrush for infant |
| DE3808268A1 (de) | 1988-03-12 | 1989-09-21 | Hoechst Ag | Verfahren zur herstellung eines 1-olefinpolymers |
| US5382631A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distributions |
| US5382630A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
| DE3836059A1 (de) * | 1988-10-22 | 1990-05-03 | Hoechst Ag | Verfahren zur herstellung eines ethylen-propylen-copolymers |
| TW218884B (pt) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
| US5359015A (en) | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
| TW309523B (pt) | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
| NL9201970A (nl) | 1992-11-11 | 1994-06-01 | Dsm Nv | Indenylverbindingen en katalysatorcomponenten voor de polymerisatie van olefinen. |
| EP0664301A1 (en) | 1994-01-24 | 1995-07-26 | Dainichiseika Color & Chemicals Mfg. Co. Ltd. | Chitosan derivatives, preparation process thereof and cosmetic compositions containing same |
| DE4425414C2 (de) * | 1994-07-19 | 1999-02-11 | Gerhard Muendler | Vorrichtung zum Pflegen von Hartplätzen oder Aschenbahnen mit einem Fahrzeug |
| US5594081A (en) * | 1994-07-22 | 1997-01-14 | Mitsubishi Chemical Corporation | Catalyst component for the polymerization of α-olefins and a process for preparing α-olefin polymers with use of same |
| JPH08113604A (ja) | 1994-10-17 | 1996-05-07 | Showa Denko Kk | 新規担体、その製造方法および重合触媒 |
| IT1272923B (it) | 1995-01-23 | 1997-07-01 | Spherilene Srl | Composti metallocenici,procedimento per la loro preparazione,e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| DE69600892T2 (de) * | 1995-02-21 | 1999-04-01 | Mitsubishi Chemical Corp., Tokio/Tokyo | Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren |
| IT1275856B1 (it) | 1995-03-03 | 1997-10-24 | Spherilene Srl | Composti metallocenici bis-fluorenilici, procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione |
| IT1275408B (it) | 1995-05-30 | 1997-08-05 | Spherilene Spa | Composti metallocenici bis-indenilici pontanti procedimento per la loro preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine |
| JP3491855B2 (ja) | 1995-06-29 | 2004-01-26 | 三井化学株式会社 | 結晶性ポリオレフィン樹脂組成物 |
| IT1275777B1 (it) * | 1995-07-06 | 1997-10-17 | Enichem Spa | Catalizzatore metallocenico per la (co)polimerizzazione delle olefine |
| EA000702B1 (ru) | 1995-08-15 | 2000-02-28 | Филлипс Петролеум Компани | Пленки, содержащие полиэтилен, катализированный металлоценом |
| CN1067689C (zh) | 1995-10-20 | 2001-06-27 | 中国科学院化学研究所 | 一种用于合成高分子量聚乙烯的金属茂催化剂及其制备方法 |
| IT1283630B1 (it) | 1996-05-09 | 1998-04-23 | Enichem Spa | Procedimento per la preparazione di copolimeri elastomerici ep(d)m |
| JPH1036423A (ja) | 1996-07-30 | 1998-02-10 | Idemitsu Kosan Co Ltd | オレフィン系重合用触媒及びそれを用いたオレフィン系重合体の製造方法 |
| US6180736B1 (en) | 1996-12-20 | 2001-01-30 | Exxon Chemical Patents Inc | High activity metallocene polymerization process |
| JPH10193379A (ja) | 1997-01-08 | 1998-07-28 | Mitsui Chem Inc | ポリエチレン製射出成形体 |
| US5886202A (en) | 1997-01-08 | 1999-03-23 | Jung; Michael | Bridged fluorenyl/indenyl metallocenes and the use thereof |
| US6111019A (en) | 1997-03-31 | 2000-08-29 | Exxon Chemical Patents, Inc. | LLDPE blends with an ethylene-norbornene copolymer for resins of improved toughness and processibility for film production |
| JPH111508A (ja) * | 1997-06-13 | 1999-01-06 | Mitsubishi Chem Corp | α−オレフィン重合用触媒成分、触媒およびα−オレフィン重合体の製造法 |
| US6166152A (en) | 1998-02-26 | 2000-12-26 | Phillips Petroleum Company | Process to produce low density polymer in a loop reactor |
| ES2188047T3 (es) * | 1998-03-09 | 2003-06-16 | Basell Polyolefine Gmbh | Compuestos de circonoceno puenteados, procedimiento para su preparacion y su empleo como componentes catalizadores en la polimerizacion de olefinas. |
| IT1298616B1 (it) | 1998-03-10 | 2000-01-12 | Enichem Spa | Complesso metallocenico pontato per la (co) polimerizzazione delle olefine |
| HUP0101144A2 (hu) | 1998-11-20 | 2001-07-30 | Montell Technology Company B.V. | Hidas szerkezetű metallocének, előállításuk és alkalmazásuk katalitikus rendszerekben |
| IT1304181B1 (it) * | 1998-12-17 | 2001-03-08 | Enichem Spa | Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine. |
| US6087290A (en) * | 1999-01-19 | 2000-07-11 | Hughes Electronics Corporation | Si-N-Si-bridged metallocenes, their production and use |
| US6399722B1 (en) * | 1999-12-01 | 2002-06-04 | Univation Technologies, Llc | Solution feed of multiple catalysts |
| US6274684B1 (en) * | 1999-10-22 | 2001-08-14 | Univation Technologies, Llc | Catalyst composition, method of polymerization, and polymer therefrom |
-
2002
- 2002-07-19 AU AU2002354949A patent/AU2002354949B2/en not_active Expired - Fee Related
- 2002-07-19 JP JP2003514021A patent/JP2004536183A/ja not_active Abandoned
- 2002-07-19 CN CNA028163664A patent/CN1545523A/zh active Pending
- 2002-07-19 EP EP02752457A patent/EP1412394A2/en not_active Ceased
- 2002-07-19 WO PCT/US2002/022942 patent/WO2003008465A2/en not_active Ceased
- 2002-07-19 CA CA002454060A patent/CA2454060A1/en not_active Abandoned
- 2002-07-19 US US10/199,147 patent/US7060765B2/en not_active Expired - Lifetime
- 2002-07-19 BR BR0211290-6A patent/BR0211290A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US7060765B2 (en) | 2006-06-13 |
| WO2003008465A2 (en) | 2003-01-30 |
| EP1412394A2 (en) | 2004-04-28 |
| AU2002354949B2 (en) | 2005-06-23 |
| US20040077785A1 (en) | 2004-04-22 |
| CN1545523A (zh) | 2004-11-10 |
| JP2004536183A (ja) | 2004-12-02 |
| CA2454060A1 (en) | 2003-01-30 |
| WO2003008465A3 (en) | 2003-08-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application fees: application dismissed [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A,6A E 7A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 DA RPI 2029 DE 24/11/2009. |