[go: up one dir, main page]

BR0016112A - Método para inibir a polimerização prematura de monÈmeros etilenicamente insaturados e composição - Google Patents

Método para inibir a polimerização prematura de monÈmeros etilenicamente insaturados e composição

Info

Publication number
BR0016112A
BR0016112A BR0016112-8A BR0016112A BR0016112A BR 0016112 A BR0016112 A BR 0016112A BR 0016112 A BR0016112 A BR 0016112A BR 0016112 A BR0016112 A BR 0016112A
Authority
BR
Brazil
Prior art keywords
alkyl
group
ethylenically unsaturated
unsaturated monomers
premature polymerization
Prior art date
Application number
BR0016112-8A
Other languages
English (en)
Inventor
Brigitte Benage
Brendan J Geelan
Gerald J Abruscato
Leo Bonnell
Original Assignee
Crompton Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Crompton Corp filed Critical Crompton Corp
Publication of BR0016112A publication Critical patent/BR0016112A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B63/00—Purification; Separation; Stabilisation; Use of additives
    • C07B63/04—Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

"MéTODO PARA INIBIR A POLIMERIZAçãO PREMATURA DE MONÈMEROS ETILENICAMENTE INSATURADOS E COMPOSIçãO". é revelado aqui um método para inibir a polimerização prematura de monómeros etilenicamente insaturados caracterizado por compreender a adição aos monómeros de uma quantidade efetiva de uma mistura compreendendo: A) pelo menos um composto de nitroxila retardado estável tendo a fórmula estrutural: em que R~ 1~ e R~ 4~ são selecionados independentemente do grupo consistindo em hidrogênio, alquil, e alquil de heteroátomo-substituído e R~ 2~ e R~ 3~ são selecionados independentemente a partir do grupo consistindo em alquil e alquil de heteroátomo-substituído; e X~ 1~ e X~ 2~ (1) são selecionados independentemente do grupo consistindo em halogênio, ciano, COOR~ 7~, -S-COR~ 7~, -OCOR~ 7~, em que R~ 7~ é alquil ou aril, amido, -S-C~ 6~H~ 5~, carbonil, alquenil, ou alquil de 1 a 15 átomos de carbono, ou (2) considerado em conjunto, formam uma estrutura de anel com o nitrogênio; e B) pelo menos um inibidor selecionado do grupo consistindo em orto-quinona, orto-hidroquinona, para-quinona, para-hidroquinona, e derivados dos anteriormente mencionados.
BR0016112-8A 1999-12-02 2000-11-06 Método para inibir a polimerização prematura de monÈmeros etilenicamente insaturados e composição BR0016112A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US45297299A 1999-12-02 1999-12-02
PCT/US2000/030552 WO2001040149A2 (en) 1999-12-02 2000-11-06 Inhibition of polymerization of unsaturated monomers

Publications (1)

Publication Number Publication Date
BR0016112A true BR0016112A (pt) 2002-11-26

Family

ID=23798714

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0016112-8A BR0016112A (pt) 1999-12-02 2000-11-06 Método para inibir a polimerização prematura de monÈmeros etilenicamente insaturados e composição

Country Status (13)

Country Link
US (1) US6653414B2 (pt)
EP (1) EP1233937B1 (pt)
JP (1) JP3854149B2 (pt)
KR (1) KR100715592B1 (pt)
CN (1) CN1238312C (pt)
AR (2) AR029773A1 (pt)
AT (1) ATE307789T1 (pt)
BR (1) BR0016112A (pt)
CA (1) CA2392055C (pt)
DE (1) DE60023542T2 (pt)
MX (1) MXPA02005423A (pt)
TW (1) TW593214B (pt)
WO (1) WO2001040149A2 (pt)

Families Citing this family (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1230492C (zh) * 1999-12-03 2005-12-07 尤尼罗亚尔化学公司 用于抑制聚合和聚合物增长的组合物和方法
US7696290B2 (en) * 2004-12-03 2010-04-13 Crompton Corporation Aromatic sulfonic acids, amines, and nitrophenols in combination with nitroxyl radical-containing compounds or C-nitrosanilines as polymerization inhibitors
ES2441429T3 (es) 2005-02-04 2014-02-04 Addivant Switzerland Gmbh Medios para controlar la reacción exotérmica de monómeros estirénicos con ácidos sulfónicos
US7731794B2 (en) 2005-06-09 2010-06-08 United States Gypsum Company High starch light weight gypsum wallboard
USRE44070E1 (en) 2005-06-09 2013-03-12 United States Gypsum Company Composite light weight gypsum wallboard
US7931823B2 (en) * 2005-09-12 2011-04-26 Fujifilm Electronic Materials U.S.A., Inc. Additives to prevent degradation of cyclic alkene derivatives
WO2007033075A2 (en) * 2005-09-12 2007-03-22 Fujifilm Electronic Materials U.S.A., Inc. Additives to prevent degradation of cyclic alkene derivatives
US7985826B2 (en) 2006-12-22 2011-07-26 Reichhold, Inc. Molding resins using renewable resource component
CN101274875B (zh) * 2007-03-30 2011-04-20 中国石油天然气股份有限公司 一种丁二烯提纯及精制过程中的复合型阻聚剂的应用
WO2009070693A2 (en) * 2007-11-28 2009-06-04 Sirion Therapeutics, Inc Modulators of ocular oxidative stress
US8440099B2 (en) * 2007-12-19 2013-05-14 Air Products And Chemicals, Inc. Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor
US7968001B2 (en) * 2007-12-19 2011-06-28 Air Products And Chemicals, Inc. Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor
EP2072485B1 (en) * 2007-12-19 2012-06-20 Air Products and Chemicals, Inc. Stabilizers for the stabilization of unsaturated hydrocarbon-based precursor
CN101240169B (zh) * 2008-03-10 2011-12-21 上海华谊丙烯酸有限公司 一种酚焦油废渣的再利用方法
US8173213B2 (en) * 2008-05-28 2012-05-08 Air Products And Chemicals, Inc. Process stability of NBDE using substituted phenol stabilizers
JP5792617B2 (ja) 2008-07-08 2015-10-14 フジフィルム・エレクトロニック・マテリアルズ・ユーエスエイ・インコーポレイテッドＦｕｊｉＦｉｌｍ Ｅｌｅｃｔｒｏｎｉｃ Ｍａｔｅｒｉａｌｓ ＵＳＡ， Ｉｎｃ． 環状アルケン誘導体を含む組成物及びそれを使用する方法
GB0903005D0 (en) 2009-02-23 2009-04-08 Nufarm Ltd Composition for controlling polymerisation
DE102009027115A1 (de) 2009-06-23 2010-12-30 Wacker Chemie Ag Verfahren zur Herstellung von Vinylacetat
EP2319821A1 (en) * 2009-11-06 2011-05-11 L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude Stabilization of bicycloheptadiene
US20110207950A1 (en) 2010-02-24 2011-08-25 Hildeberto Nava Vinyl-containing compounds and processes for making the same
GB201011594D0 (en) 2010-07-09 2010-08-25 Nufarm Uk Ltd Retarder composition
US8323785B2 (en) 2011-02-25 2012-12-04 United States Gypsum Company Lightweight, reduced density fire rated gypsum panels
US9611336B2 (en) * 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
US10544299B2 (en) 2012-12-18 2020-01-28 Reichhold Llc 2 Vinyl-containing compounds with high heat distortion
US9068045B2 (en) 2013-04-05 2015-06-30 Reichhold, Inc. Curing of liquid thermosetting resins
DE102013225114A1 (de) 2013-12-06 2015-06-11 Wacker Chemie Ag Verfahren zur Herstellung von Vinylacetat mit inhibierter Nebenproduktbildung
US10000602B2 (en) 2014-10-02 2018-06-19 Reichhold Llc 2 Curable compositions
US10155705B2 (en) * 2015-04-20 2018-12-18 Ecolab Usa Inc. Sterically hindered hydroquinones as antifoulants for unsaturated monomers
US11180578B2 (en) 2018-07-13 2021-11-23 Ecolab Usa Inc. Polymerization inhibitor and retarder compositions with amine stabilizer
EP3820836A1 (en) 2018-07-13 2021-05-19 Ecolab USA, Inc. Compositions of oxygenated amines and quinone methides as antifoulants for vinylic monomers
EP3856792A1 (en) * 2018-09-28 2021-08-04 Ecolab USA, Inc. Amino-quinone antipolymerants and methods of using
EP3898566B1 (en) * 2018-12-20 2024-12-11 Ecolab USA, Inc. Hydroxylated quinone antipolymerants and methods of using
US11518834B2 (en) 2019-01-02 2022-12-06 Polynt Composites USA, Inc. Radically polymerizable compositions
KR20240141744A (ko) 2022-01-26 2024-09-27 바스프 에스이 에틸렌계 불포화 화합물의 저장 및/또는 수송
WO2025051570A1 (de) * 2023-09-05 2025-03-13 Basf Se Polymerisationsinhibitoren
TW202530173A (zh) * 2023-09-14 2025-08-01 美商藝康美國公司 具有苯醌或萘醌及氧化胺基苯酚的抗聚合劑組成物及其使用方法

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB968891A (en) 1961-07-04 1964-09-02 British Petroleum Co Improvements relating to the conversion of hydrocarbons
US3163677A (en) 1961-08-07 1964-12-29 American Cyanamid Co Process for preparing n, n, o-trisubstituted hydroxyl amines and n, n-disubstituted nitroxides and products
GB983134A (en) 1962-06-13 1965-02-10 American Cyanamid Co Cyclic nitroxides and process for preparing same
US3502692A (en) 1962-06-13 1970-03-24 American Cyanamid Co Cyclic nitroxides and process for preparing same
US3422144A (en) 1965-04-27 1969-01-14 American Cyanamid Co Stable free radical nitroxides
US3372182A (en) 1965-04-27 1968-03-05 American Cyanamid Co Process for preparation of stable, free radical nitroxides
GB1127127A (en) 1966-04-26 1968-09-11 Bp Chem Int Ltd Stabilization of acrylic acid
FR1501769A (fr) 1966-07-04 1967-11-18 Commissariat Energie Atomique Radicaux libres du type nitroxyde
DE1936410A1 (de) 1969-07-17 1971-02-11 Hoechst Ag O-Acyl-lysergole und Verfahren zu ihrer Herstellung
SU334845A1 (ru) 1970-07-22 1984-01-30 Филиал Института Химической Физики Ан Ссср Способ ингибировани радикальной полимеризации олигоэфиракрилатов
US3873564A (en) 1971-03-03 1975-03-25 Synvar Ass 2-Imidazolinyl-3-oxide-1-oxypropionic acid
CH579118A5 (pt) 1973-06-22 1976-08-31 Ciba Geigy Ag
SU478838A1 (ru) 1973-09-17 1975-07-30 Отделение ордена Ленина института химической физики АН СССР Способ ингибировани радикальной полимеризации олигоэфиракрилатов
US4182658A (en) 1977-11-23 1980-01-08 Cosden Technology, Inc. Emergency polymerization inhibitor system for vinyl aromatic compounds
US4665185A (en) 1984-03-22 1987-05-12 Ciba-Geigy Corporation Process for preparing nitroxyls of sterically hindered amines
ATE49588T1 (de) 1984-10-10 1990-02-15 Amoco Corp Verfahren zur reinigung von methacrylsaeure.
US5290888A (en) 1990-07-20 1994-03-01 Ciba-Geigy Corporation Process for stabilizing ethylenically unsaturated compounds and stabilized monomer compositions
US5254760A (en) 1992-07-29 1993-10-19 Ciba-Geigy Corporation Inhibiting polymerization of vinyl aromatic monomers
JP2725593B2 (ja) * 1993-04-15 1998-03-11 株式会社日本触媒 （メタ）アクリル酸およびそのエステルの重合防止方法
US5728872A (en) * 1994-06-27 1998-03-17 Lutz Riemenschneider Stabilized acrylic acid compositions
US5545786C1 (en) 1994-11-28 2001-10-16 Ciba Geigy Corp Method for inhibiting premature polymerization of vinyl aromatic monomers
US5616774A (en) * 1995-04-14 1997-04-01 Ciba-Geigy Corporation Inhibition of unsaturated monomers with 7-aryl quinone methides
DE59704135D1 (de) 1996-06-05 2001-09-13 Basf Ag Mischungen, enthaltend monomere und stabilisatoren
WO1998002403A1 (en) 1996-07-15 1998-01-22 Betzdearborn Inc. Method for inhibiting vinyl aromatic monomer polymerization in condenser and compression systems
WO1998014416A1 (en) 1996-10-04 1998-04-09 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
DE19651307A1 (de) 1996-12-10 1998-06-18 Basf Ag Stoffmischungen, enthaltend vinylgruppenhaltige Verbindungen und Stabilisatoren
ID20069A (id) 1997-03-20 1998-09-24 Ciba Sc Holding Ag Proses inhibitor polimerisasi
FR2761680B1 (fr) 1997-04-07 1999-05-28 Rhodia Chimie Sa Composition inhibitrice de la polymerisation radicalaire de monomeres insatures ethyleniquement ainsi que procede d'inhibition de la polymerisation radicalaire desdits monomeres
US5877344A (en) 1997-06-13 1999-03-02 Ciba Specialty Chemicals Corporation Polymerization inhibition of acrylates using blends of nitroxides
ATE230714T1 (de) * 1998-09-09 2003-01-15 Baker Hughes Inc Inhibierung der polymerisation von styrolmonomeren mit substituierten dihydroxyarenen und stickoxiden
EP1065197B1 (en) * 1999-06-28 2002-11-06 Rohm And Haas Company Process for preparing (meth)acrylic acid

Also Published As

Publication number Publication date
CN1238312C (zh) 2006-01-25
TW593214B (en) 2004-06-21
CA2392055C (en) 2010-06-22
AR029773A1 (es) 2003-07-16
WO2001040149A2 (en) 2001-06-07
JP3854149B2 (ja) 2006-12-06
AR076896A2 (es) 2011-07-13
KR100715592B1 (ko) 2007-05-10
WO2001040149A3 (en) 2002-01-24
KR20020070302A (ko) 2002-09-05
US6653414B2 (en) 2003-11-25
ATE307789T1 (de) 2005-11-15
EP1233937A2 (en) 2002-08-28
DE60023542D1 (de) 2005-12-01
CA2392055A1 (en) 2001-06-07
CN1402697A (zh) 2003-03-12
DE60023542T2 (de) 2006-07-20
JP2003515575A (ja) 2003-05-07
US20020037958A1 (en) 2002-03-28
EP1233937B1 (en) 2005-10-26
MXPA02005423A (es) 2002-11-29

Similar Documents

Publication Publication Date Title
BR0016112A (pt) Método para inibir a polimerização prematura de monÈmeros etilenicamente insaturados e composição
BR0016984A (pt) Método para inibir polimerização prematura de monÈmeros etilenicamente insaturados
BR0016071A (pt) Método para inibir polimerização prematura de monÈmeros etilenicamente insaturados e composição
PT703228E (pt) Compostos de naftilo intermediarios processos composicoes que os envolvem
EP1103552A4 (en) BENZOTHIEPINE DERIVATIVES, METHOD FOR THEIR PRODUCTION AND THEIR USE
HU9400473D0 (en) Alcohol or aldehyde derivatives and pharmaceutical compositions containing them
NO965160D0 (no) Nye farnesyl-transferase-inhibitorer, deres fremstilling samt farmasöytiske preparater inneholdende forbindelsene
BR0206738A (pt) Derivados tricìclicos de lactama e de sultama e uso dos mesmos como inibidores de histona desacetilase
ATE218141T1 (de) Erythromycin-derivate, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel
EA200200898A1 (ru) Способ получения циталопрама
BR0013346A (pt) Método para inibir polimerização prematura de monÈmero etilenicamente insaturado e composição
BRPI0506719A (pt) composto, composição farmacêutica, e, uso de um composto
BR9806141A (pt) Componente catalisador sólido e catalisador para a polimerização de olefinas ch2=chr.
MY123083A (en) Acyclic nucleoside derivatives
BR0116406A (pt) Composição para revestimento e substrato revestido com boa estabilidade ao calor de cor
BG107050A (en) Method for the preparation of citalopram
DE69329084D1 (de) Benzoxazepin-Derivate als Cholinesterase-Inhibitoren
ES2188481T3 (es) Derivados de polinalbufina.
ATE50773T1 (de) Alkylresorcinolphosphite.
KR920701120A (ko) 치환된 비시클로헵탄디온 유도체
EA200200523A1 (ru) Новые разветвленные замещенные аминопроизводные 3-амино-1-фенил-1h[1,2,4]триазола, способы их получения и содержащие их фармацевтические композиции
BR0109268A (pt) Método de preparação de citalopram, composto e citaplopram
KR900016178A (ko) 2-치환 n,n'-디트리메톡시벤조일 피페라진, 그의 제조 방법 및 그를 함유하는 치료 조성물
GB1528790A (en) Benzisoquinoline derivatives
HRP20000027B1 (en) Process for the preparation of alkoxyfuranoneamine derivatives, compounds obtained by this process, and the use of these compounds

Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL.