BR0012441A - System and method for water extraction, in a process and dry cleaning, involving a siloxane solvent - Google Patents
System and method for water extraction, in a process and dry cleaning, involving a siloxane solventInfo
- Publication number
- BR0012441A BR0012441A BR0012441-9A BR0012441A BR0012441A BR 0012441 A BR0012441 A BR 0012441A BR 0012441 A BR0012441 A BR 0012441A BR 0012441 A BR0012441 A BR 0012441A
- Authority
- BR
- Brazil
- Prior art keywords
- dry cleaning
- water
- involving
- cleaning fluid
- water extraction
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/82—Compounds containing silicon
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
- D06F43/007—Dry cleaning methods
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
- D06F43/08—Associated apparatus for handling and recovering the solvents
- D06F43/081—Reclaiming or recovering the solvent from a mixture of solvent and contaminants, e.g. by distilling
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
- D06F43/00—Dry-cleaning apparatus or methods using volatile solvents
- D06F43/08—Associated apparatus for handling and recovering the solvents
- D06F43/081—Reclaiming or recovering the solvent from a mixture of solvent and contaminants, e.g. by distilling
- D06F43/085—Filtering arrangements; Filter cleaning; Filter-aid powder dispensers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
- D06L1/08—Multi-step processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S210/00—Liquid purification or separation
- Y10S210/05—Coalescer
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Cleaning By Liquid Or Steam (AREA)
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
- Extraction Or Liquid Replacement (AREA)
- Detergent Compositions (AREA)
Abstract
"SISTEMA E MéTODO PARA EXTRAçãO DE áGUA EM UM PROCESSO E DE LIMPEZA A SECO, ENVOLVENDO UM SOLVENTE DE SILOXANO". Sistema e processo para a separação de água de um solvente durante a limpeza a seco. é incluída uma entrada ( 52 ) capaz de receber uma mistura de fluido de limpeza a seco e água originária de um cesto de um aparelho de limpeza a seco. O fluido de limpeza a seco inclui uma composição de siloxano. Também é provido um controlador de fluxo ( 60 ) para impelir o fluxo da mistura recebida a partir da saída. Acoplado ao controlador de fluxo ( 60 ) está um meio coalescente ( 64 ) que recebe a mistura impelida pelo controlador de fluxo ( 60 ). Uma câmara ( 68 ) é acoplada ao meio coalescente ( 64 ) para receber a mistura do meio coalescente ( 64 ) para separar a água e o fluido de limpeza a seco. Também acoplada à câmara ( 68 ) está uma saída ( 69 ) para remover o fluido de limpeza a seco da câmara ( 68 ) na ausência de água."SYSTEM AND METHOD FOR WATER EXTRACTION IN A PROCESS AND DRY CLEANING, INVOLVING A SILOXAN SOLVENT". System and process for separating water from a solvent during dry cleaning. An inlet 52 capable of receiving a mixture of dry cleaning fluid and water from a basket of a dry cleaning apparatus is included. The dry cleaning fluid includes a siloxane composition. A flow controller (60) is also provided to drive the flow of the received mix from the outlet. Coupled to the flow controller (60) is a coalescing medium (64) which receives the mixture impelled by the flow controller (60). A chamber (68) is coupled to the coalescing medium (64) to receive the coalescing medium mixture (64) to separate the water and the dry cleaning fluid. Also coupled to chamber (68) is an outlet (69) for removing dry cleaning fluid from chamber (68) in the absence of water.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/353,212 US6086635A (en) | 1997-08-22 | 1999-07-14 | System and method for extracting water in a dry cleaning process involving a siloxane solvent |
| PCT/US2000/019228 WO2001027380A1 (en) | 1999-07-14 | 2000-07-13 | System and method for extracting water in a dry cleaning process involving a siloxane solvent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0012441A true BR0012441A (en) | 2002-05-28 |
| BR0012441B1 BR0012441B1 (en) | 2009-08-11 |
Family
ID=23388195
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0012441-9A BR0012441B1 (en) | 1999-07-14 | 2000-07-13 | dry cleaning system containing a siloxane solvent and dry cleaning process of an article. |
Country Status (23)
| Country | Link |
|---|---|
| US (1) | US6086635A (en) |
| EP (1) | EP1194630A4 (en) |
| JP (1) | JP2003511579A (en) |
| KR (1) | KR20020033456A (en) |
| CN (1) | CN1174138C (en) |
| AR (1) | AR024759A1 (en) |
| AU (1) | AU772554B2 (en) |
| BR (1) | BR0012441B1 (en) |
| CA (1) | CA2378835C (en) |
| CU (1) | CU23217A3 (en) |
| CZ (1) | CZ200297A3 (en) |
| EE (1) | EE200200019A (en) |
| HK (1) | HK1046938A1 (en) |
| HU (1) | HUP0202357A3 (en) |
| IL (1) | IL147536A0 (en) |
| MX (1) | MXPA02000357A (en) |
| NO (1) | NO20020198L (en) |
| NZ (1) | NZ516607A (en) |
| PL (1) | PL352858A1 (en) |
| RU (1) | RU2276212C2 (en) |
| TW (1) | TW518247B (en) |
| WO (1) | WO2001027380A1 (en) |
| ZA (1) | ZA200200171B (en) |
Families Citing this family (62)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6045588A (en) | 1997-04-29 | 2000-04-04 | Whirlpool Corporation | Non-aqueous washing apparatus and method |
| US7534304B2 (en) | 1997-04-29 | 2009-05-19 | Whirlpool Corporation | Non-aqueous washing machine and methods |
| US6086635A (en) * | 1997-08-22 | 2000-07-11 | Greenearth Cleaning, Llc | System and method for extracting water in a dry cleaning process involving a siloxane solvent |
| DE19926313A1 (en) * | 1999-06-09 | 2000-12-14 | Satec Gmbh | Method and device for separating multiphase solvent mixtures with low density differences |
| HUP0202336A2 (en) * | 1999-07-14 | 2002-11-28 | Greenearth Cleaning, Llc | Method for extracting water in a dry cleaning process involving a silicone-based solvent |
| US7390778B1 (en) | 1999-08-24 | 2008-06-24 | The Procter & Gamble Company | Cleaning compositions that reduce shrinkage of fabrics |
| AU1613601A (en) * | 1999-11-16 | 2001-05-30 | Procter & Gamble Company, The | Cleaning process which uses ultrasonic waves |
| US6258130B1 (en) | 1999-11-30 | 2001-07-10 | Unilever Home & Personal Care, A Division Of Conopco, Inc. | Dry-cleaning solvent and method for using the same |
| US6706076B2 (en) | 2000-06-05 | 2004-03-16 | Procter & Gamble Company | Process for separating lipophilic fluid containing emulsions with electric coalescence |
| US6706677B2 (en) | 2000-06-05 | 2004-03-16 | Procter & Gamble Company | Bleaching in conjunction with a lipophilic fluid cleaning regimen |
| US6939837B2 (en) * | 2000-06-05 | 2005-09-06 | Procter & Gamble Company | Non-immersive method for treating or cleaning fabrics using a siloxane lipophilic fluid |
| US6670317B2 (en) | 2000-06-05 | 2003-12-30 | Procter & Gamble Company | Fabric care compositions and systems for delivering clean, fresh scent in a lipophilic fluid treatment process |
| US6855173B2 (en) | 2000-06-05 | 2005-02-15 | Procter & Gamble Company | Use of absorbent materials to separate water from lipophilic fluid |
| US6840069B2 (en) | 2000-06-05 | 2005-01-11 | Procter & Gamble Company | Systems for controlling a drying cycle in a drying apparatus |
| US6840963B2 (en) | 2000-06-05 | 2005-01-11 | Procter & Gamble | Home laundry method |
| US20030069159A1 (en) * | 2001-09-10 | 2003-04-10 | The Procter & Gamble Company | Down the drain cleaning system |
| US6673764B2 (en) | 2000-06-05 | 2004-01-06 | The Procter & Gamble Company | Visual properties for a wash process using a lipophilic fluid based composition containing a colorant |
| US6691536B2 (en) * | 2000-06-05 | 2004-02-17 | The Procter & Gamble Company | Washing apparatus |
| US6828292B2 (en) * | 2000-06-05 | 2004-12-07 | Procter & Gamble Company | Domestic fabric article refreshment in integrated cleaning and treatment processes |
| US6930079B2 (en) * | 2000-06-05 | 2005-08-16 | Procter & Gamble Company | Process for treating a lipophilic fluid |
| US6564591B2 (en) | 2000-07-21 | 2003-05-20 | Procter & Gamble Company | Methods and apparatus for particulate removal from fabrics |
| US7513132B2 (en) | 2003-10-31 | 2009-04-07 | Whirlpool Corporation | Non-aqueous washing machine with modular construction |
| WO2002027608A1 (en) * | 2000-09-28 | 2002-04-04 | The Procter & Gamble Company | Method for treating permeable surface items according to item owner's instructions |
| US6814875B2 (en) * | 2000-10-06 | 2004-11-09 | Yamaha Corporation | Method and device for treating waste liquid, solvent separator, and cleaning device using thereof |
| US6914040B2 (en) * | 2001-05-04 | 2005-07-05 | Procter & Gamble Company | Process for treating a lipophilic fluid in the form of a siloxane emulsion |
| US20030226214A1 (en) * | 2002-05-02 | 2003-12-11 | The Procter & Gamble Company | Cleaning system containing a solvent filtration device and method for using the same |
| US7276162B2 (en) | 2001-09-10 | 2007-10-02 | The Procter & Gamble Co. | Removal of contaminants from a lipophilic fluid |
| EP1434640A2 (en) * | 2001-09-10 | 2004-07-07 | The Procter & Gamble Company | Multifunctional filter |
| KR100637014B1 (en) * | 2001-09-10 | 2006-10-23 | 더 프록터 앤드 갬블 캄파니 | Treatment method of lipophilic fluid |
| EP1425078A1 (en) * | 2001-09-10 | 2004-06-09 | The Procter & Gamble Company | Method for processing a lipophilic fluid |
| AR036777A1 (en) * | 2001-09-10 | 2004-10-06 | Procter & Gamble | FILTER TO REMOVE WATER AND / OR SURFACTANTS FROM A LIPOFILO FLUID |
| US20030088432A1 (en) * | 2001-10-25 | 2003-05-08 | Berndt Wolf-Dieter R. | Dry cleaning business model algorithm |
| US20040045096A1 (en) * | 2002-04-22 | 2004-03-11 | General Electric Company | Chemical-specific sensor for monitoring amounts of volatile solvent during a drying cycle of a dry cleaning process |
| US7308808B2 (en) * | 2002-04-22 | 2007-12-18 | General Electric Company | Apparatus and method for article cleaning |
| US20040117920A1 (en) * | 2002-04-22 | 2004-06-24 | General Electric Company | Detector for monitoring contaminants in solvent used for dry cleaning articles |
| US7210182B2 (en) * | 2002-04-22 | 2007-05-01 | General Electric Company | System and method for solvent recovery and purification in a low water or waterless wash |
| US7018966B2 (en) * | 2002-06-13 | 2006-03-28 | General Electric Company | Compositions and methods for preventing gel formation comprising a siloxane and an alkylamine |
| JP4121822B2 (en) * | 2002-10-04 | 2008-07-23 | 三洋電機株式会社 | Dry cleaning device |
| US20040148708A1 (en) * | 2003-01-30 | 2004-08-05 | Steven Stoessel | Methods and compositions for cleaning articles |
| US7300593B2 (en) | 2003-06-27 | 2007-11-27 | The Procter & Gamble Company | Process for purifying a lipophilic fluid |
| US7300594B2 (en) * | 2003-06-27 | 2007-11-27 | The Procter & Gamble Company | Process for purifying a lipophilic fluid by modifying the contaminants |
| US7345016B2 (en) * | 2003-06-27 | 2008-03-18 | The Procter & Gamble Company | Photo bleach lipophilic fluid cleaning compositions |
| US7365043B2 (en) * | 2003-06-27 | 2008-04-29 | The Procter & Gamble Co. | Lipophilic fluid cleaning compositions capable of delivering scent |
| US7297277B2 (en) * | 2003-06-27 | 2007-11-20 | The Procter & Gamble Company | Method for purifying a dry cleaning solvent |
| US20050011543A1 (en) * | 2003-06-27 | 2005-01-20 | Haught John Christian | Process for recovering a dry cleaning solvent from a mixture by modifying the mixture |
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| US7356865B2 (en) * | 2003-07-29 | 2008-04-15 | General Electric Company | Apparatus and method for removing contaminants from dry cleaning solvent |
| US7926311B2 (en) * | 2003-10-01 | 2011-04-19 | General Electric Company | Integral laundry cleaning and drying system and method |
| US7695524B2 (en) | 2003-10-31 | 2010-04-13 | Whirlpool Corporation | Non-aqueous washing machine and methods |
| US7513004B2 (en) * | 2003-10-31 | 2009-04-07 | Whirlpool Corporation | Method for fluid recovery in a semi-aqueous wash process |
| US7300468B2 (en) | 2003-10-31 | 2007-11-27 | Whirlpool Patents Company | Multifunctioning method utilizing a two phase non-aqueous extraction process |
| US7739891B2 (en) | 2003-10-31 | 2010-06-22 | Whirlpool Corporation | Fabric laundering apparatus adapted for using a select rinse fluid |
| US20050108831A1 (en) * | 2003-11-25 | 2005-05-26 | Berndt Wolf-Dieter R. | Dry cleaning business model algorithm |
| US20050183208A1 (en) * | 2004-02-20 | 2005-08-25 | The Procter & Gamble Company | Dual mode laundry apparatus and method using the same |
| WO2005106105A1 (en) | 2004-04-29 | 2005-11-10 | Unilever N.V. | Dry cleaning method |
| EP1985743A2 (en) * | 2005-02-16 | 2008-10-29 | Sanyo Electric Co., Ltd. | Dry-cleaning-machine |
| JP4619158B2 (en) * | 2005-03-15 | 2011-01-26 | 三洋電機株式会社 | Dry cleaning device |
| US7966684B2 (en) | 2005-05-23 | 2011-06-28 | Whirlpool Corporation | Methods and apparatus to accelerate the drying of aqueous working fluids |
| JP5059755B2 (en) | 2005-06-20 | 2012-10-31 | グリーンアース クリーニング,リミティド ライアビリティ カンパニー | System and method for article dry cleaning |
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| DE102009028484B3 (en) * | 2009-08-12 | 2011-01-05 | BSH Bosch und Siemens Hausgeräte GmbH | Water-bearing household appliance with a pump |
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-
1999
- 1999-07-14 US US09/353,212 patent/US6086635A/en not_active Expired - Lifetime
-
2000
- 2000-07-13 CA CA002378835A patent/CA2378835C/en not_active Expired - Lifetime
- 2000-07-13 KR KR1020027000352A patent/KR20020033456A/en not_active Ceased
- 2000-07-13 AU AU59341/00A patent/AU772554B2/en not_active Expired
- 2000-07-13 WO PCT/US2000/019228 patent/WO2001027380A1/en not_active Ceased
- 2000-07-13 EP EP00945390A patent/EP1194630A4/en not_active Withdrawn
- 2000-07-13 CZ CZ200297A patent/CZ200297A3/en unknown
- 2000-07-13 CN CNB008128057A patent/CN1174138C/en not_active Expired - Fee Related
- 2000-07-13 HK HK02107405.2A patent/HK1046938A1/en unknown
- 2000-07-13 EE EEP200200019A patent/EE200200019A/en unknown
- 2000-07-13 IL IL14753600A patent/IL147536A0/en active IP Right Grant
- 2000-07-13 HU HU0202357A patent/HUP0202357A3/en unknown
- 2000-07-13 NZ NZ516607A patent/NZ516607A/en not_active IP Right Cessation
- 2000-07-13 BR BRPI0012441-9A patent/BR0012441B1/en not_active IP Right Cessation
- 2000-07-13 PL PL00352858A patent/PL352858A1/en unknown
- 2000-07-13 JP JP2001529504A patent/JP2003511579A/en active Pending
- 2000-07-13 MX MXPA02000357A patent/MXPA02000357A/en unknown
- 2000-07-13 RU RU2002103594/04A patent/RU2276212C2/en active
- 2000-07-17 AR ARP000103643A patent/AR024759A1/en unknown
- 2000-08-24 TW TW089113942A patent/TW518247B/en active
-
2002
- 2002-01-08 CU CU20020005A patent/CU23217A3/en unknown
- 2002-01-09 ZA ZA200200171A patent/ZA200200171B/en unknown
- 2002-01-14 NO NO20020198A patent/NO20020198L/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU772554B2 (en) | 2004-04-29 |
| IL147536A0 (en) | 2002-08-14 |
| CA2378835C (en) | 2007-11-13 |
| US6086635A (en) | 2000-07-11 |
| CA2378835A1 (en) | 2001-04-19 |
| TW518247B (en) | 2003-01-21 |
| WO2001027380A1 (en) | 2001-04-19 |
| HUP0202357A3 (en) | 2004-03-01 |
| CN1174138C (en) | 2004-11-03 |
| EP1194630A4 (en) | 2002-11-20 |
| AU5934100A (en) | 2001-04-23 |
| ZA200200171B (en) | 2002-10-30 |
| AR024759A1 (en) | 2002-10-23 |
| RU2276212C2 (en) | 2006-05-10 |
| NZ516607A (en) | 2003-08-29 |
| EE200200019A (en) | 2003-04-15 |
| WO2001027380A8 (en) | 2002-06-20 |
| CN1373822A (en) | 2002-10-09 |
| MXPA02000357A (en) | 2002-07-02 |
| CU23217A3 (en) | 2007-07-20 |
| BR0012441B1 (en) | 2009-08-11 |
| EP1194630A1 (en) | 2002-04-10 |
| HK1046938A1 (en) | 2003-01-30 |
| NO20020198D0 (en) | 2002-01-14 |
| JP2003511579A (en) | 2003-03-25 |
| HUP0202357A2 (en) | 2002-11-28 |
| KR20020033456A (en) | 2002-05-06 |
| PL352858A1 (en) | 2003-09-08 |
| CZ200297A3 (en) | 2002-06-12 |
| NO20020198L (en) | 2002-03-14 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 13/07/2000, OBSERVADAS AS CONDICOES LEGAIS. |
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Free format text: PATENTE EXTINTA EM 13.07.2020 |