[go: up one dir, main page]

AU2002212771A1 - Prepolymerization method of alpha-olefin - Google Patents

Prepolymerization method of alpha-olefin

Info

Publication number
AU2002212771A1
AU2002212771A1 AU2002212771A AU1277102A AU2002212771A1 AU 2002212771 A1 AU2002212771 A1 AU 2002212771A1 AU 2002212771 A AU2002212771 A AU 2002212771A AU 1277102 A AU1277102 A AU 1277102A AU 2002212771 A1 AU2002212771 A1 AU 2002212771A1
Authority
AU
Australia
Prior art keywords
compound
olefin
alpha
halide
silicon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2002212771A
Inventor
Il-Seop Kim
Woo-Kyoung Kim
Kun Lo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanwha Impact Corp
Original Assignee
Samsung General Chemicals Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung General Chemicals Co Ltd filed Critical Samsung General Chemicals Co Ltd
Priority claimed from PCT/KR2001/001757 external-priority patent/WO2002038622A1/en
Publication of AU2002212771A1 publication Critical patent/AU2002212771A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/61Pretreating the metal or compound covered by group C08F4/60 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/612Pretreating with metals or metal-containing compounds
    • C08F4/616Pretreating with metals or metal-containing compounds with silicon or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A method of making an olefin polymerization catalyst is disclosed. The method involves contacting a magnesium halide compound with an alcohol, adding a mineral oil to the product, reacting this product with a hydroxylated ester and an alkoxy silane, then adding a titanium compound and a second silicon compound. The titanium compound is preferably an alkoxy halide, and the second silicon compound is preferably a silicon halide.
AU2002212771A 2000-11-09 2001-10-18 Prepolymerization method of alpha-olefin Abandoned AU2002212771A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR2000/0066410 2000-11-09
KR10-2000-0066411A KR100389475B1 (en) 2000-11-09 2000-11-09 Preparation method of catalyst for ethylene polymeration or copolymeration
PCT/KR2001/001757 WO2002038622A1 (en) 2000-11-09 2001-10-18 PREPOLYMERIZATION METHOD OF α-OLEFIN

Publications (1)

Publication Number Publication Date
AU2002212771A1 true AU2002212771A1 (en) 2002-05-21

Family

ID=19698065

Family Applications (2)

Application Number Title Priority Date Filing Date
AU2002212771A Abandoned AU2002212771A1 (en) 2000-11-09 2001-10-18 Prepolymerization method of alpha-olefin
AU2002215244A Abandoned AU2002215244A1 (en) 2000-11-09 2001-11-09 Method for producing a catalyst for homo- or co- polymerization of ethylene

Family Applications After (1)

Application Number Title Priority Date Filing Date
AU2002215244A Abandoned AU2002215244A1 (en) 2000-11-09 2001-11-09 Method for producing a catalyst for homo- or co- polymerization of ethylene

Country Status (9)

Country Link
US (2) US6897274B2 (en)
EP (1) EP1355952B1 (en)
JP (1) JP3950051B2 (en)
KR (1) KR100389475B1 (en)
CN (1) CN1213075C (en)
AT (1) ATE337342T1 (en)
AU (2) AU2002212771A1 (en)
DE (1) DE60122581T2 (en)
WO (1) WO2002038619A1 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100546499B1 (en) * 1999-05-27 2006-01-26 삼성토탈 주식회사 Catalysts for Ethylene Polymerization and Copolymerization
KR100389475B1 (en) * 2000-11-09 2003-06-27 삼성종합화학주식회사 Preparation method of catalyst for ethylene polymeration or copolymeration
KR100389476B1 (en) 2000-11-09 2003-06-27 삼성종합화학주식회사 A method for producing ethylene homo- and co-polymer
KR100389962B1 (en) 2000-11-10 2003-07-02 삼성종합화학주식회사 Preparation method of catalyst for ethylene polymeration or copolymeration
KR100421551B1 (en) 2000-12-16 2004-03-09 삼성아토피나주식회사 Catalyst obtained by prepolymerization of polyolefin and olefin polymerization method using the same
WO2002052059A1 (en) 2000-12-22 2002-07-04 Samsung General Chemicals Co., Ltd. Flame retardant polypropylene resin composition
WO2002051882A1 (en) 2000-12-22 2002-07-04 Samsung General Chemicals Co., Ltd. Chelate catalyst for olefin polymerization and olefin polymerization method using the same
KR100530795B1 (en) * 2001-12-26 2005-11-23 삼성토탈 주식회사 A method for ethylene homo- and copolymerization
KR100989997B1 (en) * 2002-05-24 2010-10-26 이데미쓰 고산 가부시키가이샤 Magnesium Compounds, Solid Catalyst Components for Olefin Polymerization, Catalysts for Olefin Polymerization and Polyolefin Production Process
TWI253451B (en) * 2002-08-29 2006-04-21 Toho Catalyst Co Ltd Solid catalyst component, catalyst for polymerization of olefins, and polymerizing method of olefins
US7153803B2 (en) 2004-06-28 2006-12-26 Engelhard Corporation High activity and good hydrogen response Ziegler-Natta polyethylene catalyst
US20120157295A1 (en) 2010-12-21 2012-06-21 Linfeng Chen Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product
US8536290B2 (en) * 2010-12-21 2013-09-17 Dow Global Technologies Llc Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same
US9382343B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same
US9382342B2 (en) 2010-12-21 2016-07-05 W. R. Grace & Co.-Conn. Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same
US9874214B2 (en) 2014-01-28 2018-01-23 4Front Engineered Solutions, Inc. Fan with fan blade mounting structure
CN105440174B (en) * 2014-08-15 2017-12-19 中国石油化工股份有限公司 Catalytic component for olefinic polymerization and preparation method thereof and the catalyst for olefinic polymerization and application
US9726192B2 (en) 2015-03-31 2017-08-08 Assa Abloy Entrance Systems Ab Fan blades and associated blade tips
CN106632765B (en) * 2015-10-29 2019-06-28 中国石油化工股份有限公司 A kind of preparation method of the polyethylene powder for 3D printing
DE102017210582A1 (en) 2017-06-23 2018-12-27 Bayerische Motoren Werke Aktiengesellschaft Internal combustion engine
DE102018207829A1 (en) 2018-05-18 2019-12-05 Bayerische Motoren Werke Aktiengesellschaft Internal combustion engine
JP7023322B2 (en) * 2020-05-27 2022-02-21 東邦チタニウム株式会社 Method for producing catalyst for olefin polymerization

Family Cites Families (177)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332927A (en) * 1966-02-14 1967-07-25 Cabot Corp Process for polymerization
US3632620A (en) * 1968-06-26 1972-01-04 Olin Mathieson Preparation of isocyanates from carbodiimides
CA920299A (en) * 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
US3642772A (en) * 1968-09-04 1972-02-15 Boehringer Mannheim Gmbh Process for preparing s-adenosyl homocysteine
NL163522B (en) * 1970-07-20 1980-04-15 Montedison Spa PROCESS FOR PREPARING A CATALYST FOR THE POLYMERIZATION OF OLEFINS-1.
NL7114641A (en) 1970-10-29 1972-05-03
US4226963A (en) * 1971-06-25 1980-10-07 Montedison S.P.A. Process for the stereoregular polymerization of alpha-olephins
US4107413A (en) * 1971-06-25 1978-08-15 Montedison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4107414A (en) * 1971-06-25 1978-08-15 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4187196A (en) * 1971-06-25 1980-02-05 Montedison S.P.A. Process for the stereoregular polymerization of alpha-olefins
US4156063A (en) * 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
NL160286C (en) * 1971-06-25
BE785673A (en) * 1971-06-30 1973-01-02 Naphtachimie Sa POLYMERIZATION CATALYZERS OF OLEFINS PREPARED FROM DECOMPOSED ORGANOMAGNESIANS
US4013823A (en) * 1972-06-09 1977-03-22 The B. F. Goodrich Company Process for preparing elastomeric copolymers of ethylene and higher alpha-olefins
US3953414A (en) * 1972-09-13 1976-04-27 Montecatini Edison S.P.A., Catalysts for the polymerization of olefins to spherically shaped polymers
US4071674A (en) * 1972-09-14 1978-01-31 Mitsui Petrochemical Industries Ltd. Process for polymerization or copolymerization of olefin and catalyst compositions used therefor
US4107415A (en) * 1972-09-26 1978-08-15 Montecatini Edison S.P.A. Process for the stereospecific polymerization of alpha-olefins
US4071672A (en) * 1972-11-10 1978-01-31 Mitsui Petrochemical Industries Ltd. Process for polymerizing or copolymerizing olefins
US3899477A (en) * 1973-02-16 1975-08-12 Monsanto Co Polymerization of ethylene
GB1492618A (en) 1974-02-01 1977-11-23 Mitsui Petrochemical Ind Process for preparing highly stereoregular polyolefins and catalyst used therefor
US4157435A (en) * 1974-08-10 1979-06-05 Mitsui Petrochemical Industries, Ltd. Process for preparing highly stereoregular polyolefins and catalyst used therefor
US4076924A (en) * 1974-09-03 1978-02-28 Mitsui Petrochemical Industries Ltd. Process for polymerization or copolymerizing olefins containing at least 3 carbon atoms
US4614727A (en) * 1975-01-23 1986-09-30 Montecatini Edison S.P.A. Polymerization catalyst
JPS565404B2 (en) * 1975-02-14 1981-02-04
JPS5328269Y2 (en) 1975-03-20 1978-07-17
IT1042667B (en) * 1975-09-18 1980-01-30 Montedison Spa CATALYSTS FOR THE POLYMERIZATION OF SEROIDAL POLYMER OLEFINS
US4069169A (en) * 1975-11-24 1978-01-17 Mitsui Petrochemical Industries Ltd. Process for preparation of catalyst component supported on high performance carrier
DE2553104A1 (en) 1975-11-26 1977-06-08 Mitsui Petrochemical Ind Supported catalyst prodn. - by contacting titanium cpd. with solid magnesium compone
DE2605992B2 (en) 1976-02-14 1980-02-28 Flamuco Gmbh Vereinigte Farben- Und Lackfabriken, 8000 Muenchen Quick-drying, solvent-based paints with an increased flash point
JPS5517360Y2 (en) 1976-02-19 1980-04-22
IT1062072B (en) * 1976-06-03 1983-06-25 Montedison Spa CATALYSTS FOR THE POLYMERIZATION OF ETHYLENE
US4158642A (en) * 1977-04-25 1979-06-19 Exxon Research & Engineering Co. Trialkyl aluminum cocatalyst
JPS53131826A (en) 1977-04-22 1978-11-17 Canon Inc Photographing system for photograph data of camera
US4148756A (en) * 1977-04-25 1979-04-10 Exxon Research & Engineering Co. Novel trialkyl aluminum cocatalyst
GB1603724A (en) * 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
IT1114822B (en) * 1977-07-04 1986-01-27 Montedison Spa COMPONENTS OF CATALYSTS FOR THE POLYMERIZATION OF ALPHA-OLEFINS
IT1113129B (en) * 1978-04-12 1986-01-20 Montedison Spa CATALYSTS AND COMPONENTS OF CATALYSTS FOR THE POLYMERIZATION OF OLEFINS
JPS5919566B2 (en) * 1978-07-28 1984-05-07 東亜燃料工業株式会社 Method for producing catalyst component for α-olefin polymerization
IT1098272B (en) * 1978-08-22 1985-09-07 Montedison Spa COMPONENTS, CATALYSTS AND CATALYSTS FOR THE POLYMERIZATION OF ALPHA-OLEFINS
EP0008307A1 (en) 1978-08-24 1980-03-05 Basf Wyandotte Corporation Polyurethane foams prepared from condensation products of amines, epihalohydrins and alkylene oxides
FR2436794A1 (en) * 1978-09-22 1980-04-18 Naphtachimie Sa PROCESS FOR THE POLYMERIZATION OF ETHYLENE AND PRODUCTS THEREOF
JPS6037804B2 (en) * 1979-04-11 1985-08-28 三井化学株式会社 Method for manufacturing carrier for olefin polymerization catalyst
US4235747A (en) * 1979-04-19 1980-11-25 Standard Oil Company (Indiana) Process for improving polymerization performance of brown solid titanium trichloride catalyst component
JPS56811A (en) * 1979-06-18 1981-01-07 Mitsui Petrochem Ind Ltd Preparation of olefin polymer or copolymer
US4482687A (en) * 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
US4277372A (en) * 1980-01-09 1981-07-07 Hercules Incorporated Solid catalyst component for olefin polymerization
JPS6023764B2 (en) * 1980-02-27 1985-06-10 チッソ株式会社 Method for producing α-olefin polymer
US4384983A (en) * 1981-05-26 1983-05-24 Standard Oil Company (Indiana) Catalyst and process for production of polyolefins of improved morphology
JPS5842639A (en) * 1981-09-07 1983-03-12 Toa Nenryo Kogyo Kk Polyolefin composition
JPS5883006A (en) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd Olefin polymerization method
JPS58138720A (en) * 1982-02-12 1983-08-17 Mitsui Petrochem Ind Ltd Preparation of propylene random copolymer
FR2529207A1 (en) * 1982-06-24 1983-12-30 Bp Chimie Sa PROCESS FOR THE PREPARATION OF CATALYST SUPPORTS FOR THE POLYMERIZATION OF ALPHA-OLEFINS AND SUPPORTS OBTAINED
FR2532649B1 (en) * 1982-09-07 1986-08-29 Bp Chimie Sa COPOLYMERIZATION OF ETHYLENE AND HEXENE-1 IN A FLUIDIZED BED
IT1195953B (en) * 1982-09-10 1988-11-03 Montedison Spa COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINE
US4518706A (en) * 1982-09-30 1985-05-21 E. I. Du Pont De Nemours And Company Hydrocarbon soluble catalyst supports and resultant polymerization catalysts
US4434282A (en) * 1982-10-04 1984-02-28 The Dow Chemical Company Process for polymerizing olefins
JPS5964602U (en) 1982-10-23 1984-04-28 ダン機工株式会社 Paddy puddling device
JPS59117508A (en) * 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd Olefin polymerization
JPS59145206U (en) 1983-03-14 1984-09-28 日新電機株式会社 closed switchboard
US4477639A (en) * 1983-05-27 1984-10-16 Shell Oil Company Olefin polymerization catalyst component and composition and method of preparation
JPS601241A (en) * 1983-06-17 1985-01-07 Kyowa Chem Ind Co Ltd Flame-retardant resin composition
JPS60501762A (en) 1983-07-01 1985-10-17 ユニオン カ−バイド コ−ポレ−シヨン Olefin polymerization catalyst adapted to gas phase process
JPS60110738A (en) * 1983-11-22 1985-06-17 Asahi Glass Co Ltd Flame-retarding polyolefin composition
FR2560200B1 (en) * 1984-02-23 1986-06-27 Bp Chimie Sa PROCESS FOR THE PREPARATION OF SUPPORTED CATALYSTS BASED ON VANADIUM COMPOUNDS FOR THE POLYMERIZATION AND COPOLYMERIZATION OF ETHYLENE
US5013702A (en) * 1984-03-23 1991-05-07 Amoco Corporation Olefin polymerization catalyst
US4988656A (en) * 1984-03-23 1991-01-29 Amoco Corporation Olefin polymerization catalyst
US4866022A (en) * 1984-03-23 1989-09-12 Amoco Corporation Olefin polymerization catalyst
US4548915A (en) * 1984-04-10 1985-10-22 Shell Oil Company Olefin polymerization catalyst composition
JPS60228504A (en) * 1984-04-26 1985-11-13 Sumitomo Chem Co Ltd Production of olefin polymer
JPS61268704A (en) 1985-05-23 1986-11-28 Mitsubishi Petrochem Co Ltd Olefin polymerization catalyst
GB2176443B (en) * 1985-06-10 1990-11-14 Canon Kk Liquid jet recording head and recording system incorporating the same
JPS6281405U (en) 1985-11-08 1987-05-25
JPH06104693B2 (en) * 1986-01-06 1994-12-21 東邦チタニウム株式会社 Catalyst for olefin polymerization
DE3777339D1 (en) * 1986-05-06 1992-04-16 Toho Titanium Co Ltd CATALYST FOR THE POLYMERIZATION OF OLEFINS.
JPS62267305A (en) * 1986-05-15 1987-11-20 Sumitomo Chem Co Ltd Production of olefinic polymer
JPS63308003A (en) 1986-10-06 1988-12-15 Toho Titanium Co Ltd Catalyst for polymerizing olefins
JPH0832737B2 (en) * 1986-10-08 1996-03-29 東邦チタニウム株式会社 Solid catalyst component for olefin polymerization
DE3636060C3 (en) 1986-10-23 1994-04-07 Behringwerke Ag Bioaffine porous solid phase, process for their preparation and their use
US4777639A (en) * 1986-12-15 1988-10-11 Prc Corporation Laser optical element mounting arrangement and method
JP2657261B2 (en) 1987-02-03 1997-09-24 住友化学工業株式会社 Aromatic vinyl compound polymerization catalyst and method for producing aromatic vinyl compound polymer using the same
IT1203330B (en) * 1987-02-06 1989-02-15 Enichem Base Spa Catalyst and catalyst component for the polymerization of ethylene or the co-polymerization of ethylene with alpha-Olefin
JPS63191811U (en) 1987-05-26 1988-12-09
JPS63199703U (en) 1987-06-15 1988-12-22
JP2502624B2 (en) * 1987-09-22 1996-05-29 東燃株式会社 Catalyst component for olefin polymerization
JPH0717709B2 (en) * 1987-11-13 1995-03-01 日本石油株式会社 Method for producing ultra high molecular weight polyethylene
FR2623812B1 (en) * 1987-11-30 1992-02-21 Bp Chimie Sa CATALYST FOR POLYMERIZATION OF ZIEGLER NATTA-TYPE OLEFINS AND PROCESS FOR THE PREPARATION THEREOF FROM MAGNESIUM DIALCOXIDE
DE3888145T2 (en) * 1987-12-26 1994-06-01 Toho Titanium Co Ltd Solid catalyst for olefin polymerization and olefin polymerization catalyst.
US4912074A (en) * 1988-01-15 1990-03-27 Mobil Oil Corporation Catalyst composition for preparing high density or medium density olefin polymers
DE68913375T3 (en) * 1988-06-17 2002-05-02 Mitsui Chemicals, Inc. Olefin polymerization process and applicable polymerization catalyst.
KR920002488B1 (en) * 1988-06-17 1992-03-26 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 Process for polymerizing olefins and polymerization catalyst therefor
US5134104A (en) * 1988-06-28 1992-07-28 Sumitomo Chemical Company, Limited Liquid catalyst component, catalyst system containing said component and process for producing ethylene-α-olefin copolymer using said catalyst system
US5064798A (en) * 1988-08-19 1991-11-12 Exxon Chemical Patents Inc. Catalyst for olefin polymerization
IT1227259B (en) * 1988-09-30 1991-03-28 Himont Inc CATALYSTS FOR THE POLYMERIZATION OF OLEFINE.
CA2011188C (en) 1989-03-02 2000-01-18 Naoshi Ishimaru Process for polymerizing olefins and catalyst for polymerizing olefins
CA2013657C (en) 1989-04-04 1996-12-03 Shinichi Akitaya Flame retardant polypropylene resin composition
JP2757206B2 (en) 1989-05-15 1998-05-25 東ソー株式会社 Method for producing polyolefin
JP2893743B2 (en) * 1989-08-10 1999-05-24 三菱化学株式会社 Production of α-olefin polymer
FR2651001B1 (en) 1989-08-17 1993-03-12 Bp Chemicals Sa PROCESS FOR THE PREPARATION OF A ZIEGLER-NATTA CATALYST BASED ON VANADIUM AND TITANIUM
US4946816A (en) * 1989-08-21 1990-08-07 Amoco Corporation Morphology-controlled olefin polymerization catalyst
FR2656314B1 (en) * 1989-12-22 1992-04-17 Bp Chemicals Snc ZIRCONIUM CATALYST SUPPORTED ON MAGNESIUM CHLORIDE, PROCESS FOR THE PREPARATION AND USE OF THE CATALYST IN OLEFIN POLYMERIZATION.
IT1241062B (en) * 1990-01-10 1993-12-29 Himont Inc COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINE
US5021382A (en) * 1990-02-28 1991-06-04 Exxon Chemical Patents Inc. Diene activated ziegler transition metal catalyst components for ethylene polymerization
JP3049569B2 (en) * 1990-03-23 2000-06-05 東ソー株式会社 Method for producing polyolefin
US5726262A (en) 1990-04-13 1998-03-10 Mitsui Petrochemical Industries, Ltd. Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
US5244996A (en) * 1990-04-18 1993-09-14 Mitsui Petrochemical Industries, Ltd. Hot-melt adhesive
JP2958923B2 (en) * 1990-04-27 1999-10-06 東邦チタニウム株式会社 Solid catalyst components and catalysts for olefin polymerization
US5081090A (en) * 1990-07-23 1992-01-14 Amoco Corporation Dry olefin polymerization catalyst
US5124297A (en) * 1990-12-07 1992-06-23 Amoco Corporation Olefin polymerization and copolymerization catalyst
US5218052A (en) * 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
DE69219206T2 (en) * 1991-05-31 1997-08-28 Mitsui Petrochemical Ind Solid catalyst component, catalyst and process for olefin polymerization
US5182245A (en) * 1991-06-26 1993-01-26 Amoco Corporation Olefin polymerization and copolymerization catalyst
US5387567A (en) * 1991-06-27 1995-02-07 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
US5175332A (en) * 1991-12-16 1992-12-29 Dow Corning Corporation Cycloalkoxysilanes
IT1262934B (en) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl COMPONENTS AND CATALYSTS FOR THE POLYMERIZATION OF OLEFINE
US5968862A (en) 1992-06-10 1999-10-19 Chevron Chemical Company Transition metal-magnesium catalyst precursors for the polymerization of olefins
JP3280477B2 (en) 1992-08-31 2002-05-13 三井化学株式会社 Method for preparing solid titanium catalyst component for olefin polymerization
US5587436A (en) * 1992-11-12 1996-12-24 Quantum Chemical Corporation Process for controlling the polymerization of propylene and ethylene and copolymer products
TW300235B (en) 1992-12-04 1997-03-11 Mitsui Petroleum Chemicals Ind
EP0602922B1 (en) 1992-12-14 1998-01-14 Dow Corning Corporation Method for producing dicycloalkylsubstituted silanes
FI95387C (en) * 1992-12-29 1996-01-25 Borealis As Process for polymerizing olefins and prepolymerized catalyst composition and process for its preparation
JPH06199946A (en) * 1993-01-05 1994-07-19 Showa Denko Kk Polymerization of alpha-olefin
EP0606125B1 (en) 1993-01-08 1997-05-21 Shell Internationale Researchmaatschappij B.V. Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds
US5346872A (en) * 1993-01-29 1994-09-13 Quantum Chemical Corporation Cocatalyst for vanadium/titanium containing polymerization catalyst
KR0119267B1 (en) * 1993-05-06 1998-07-01 황선두 Highly Active Ethylene Polymerization Catalyst
US5459116A (en) * 1993-05-07 1995-10-17 Samsung General Chemicals Co., Ltd. Highly active catalyst for the polymerization of olefins and method for the preparation of the same
JPH06340711A (en) 1993-05-31 1994-12-13 Idemitsu Kosan Co Ltd Olefin polymerization catalyst and method for producing polyolefin using the catalyst
US5419116A (en) * 1993-07-02 1995-05-30 The United States Of America As Represented By The Secretary Of The Navy Miniscale ballistic motor testing method for rocket propellants
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
DE4332786A1 (en) * 1993-09-27 1995-03-30 Hoechst Ag Process for the production of ultra high molecular weight polyethylene with high bulk density
JPH07292029A (en) * 1994-04-28 1995-11-07 Toho Titanium Co Ltd Catalyst and method for polymerizing olefin
JP3472935B2 (en) 1994-02-18 2003-12-02 三井化学株式会社 Ethylene polymer and method for producing the same, solid titanium catalyst component for ethylene polymerization, and catalyst for ethylene polymerization
US5869418A (en) 1994-05-31 1999-02-09 Borealis Holding A/S Stereospecific catalyst system for polymerization of olefins
JP3547794B2 (en) 1994-06-07 2004-07-28 株式会社海洋バイオテクノロジー研究所 Harimesin A derivative
RU2064836C1 (en) 1994-06-20 1996-08-10 Институт катализа им. Г.К.Борескова СО РАН Method to produce applied catalyst for ethylene polymerization and copolymerization of ethylene with alfa-olefins
TW369547B (en) 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
DE69520332T2 (en) 1994-11-25 2001-08-09 Japan Polyolefins Co. Ltd., Tokio/Tokyo Catalyst for polymerizing olefins and process for producing polyolefins using the same
US5502128A (en) * 1994-12-12 1996-03-26 University Of Massachusetts Group 4 metal amidinate catalysts and addition polymerization process using same
ATE203756T1 (en) 1995-02-13 2001-08-15 Toho Titanium Co Ltd SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION AND CATALYST
US6218331B1 (en) 1995-03-29 2001-04-17 Equistar Chemicals, L.P. Polymer-supported catalyst for olefin polymerization
RU2153932C2 (en) 1995-05-18 2000-08-10 Митсуи Кемикалс, Инк. Method of preparing solid titanium catalytic component, olefin- polymerization catalyst containing thereof, and olefin polymerization process
US5817591A (en) 1995-06-07 1998-10-06 Fina Technology, Inc. Polyolefin catalyst from metal alkoxides or dialkyls, production and use
DE69600988T2 (en) 1995-10-02 1999-07-08 Borealis Ag, Schwechat-Mannswoerth Supported catalyst for olefin polymerization
JP3746337B2 (en) 1995-10-11 2006-02-15 三井化学株式会社 Method for preparing solid titanium catalyst component for olefin polymerization and method for producing polyolefin
JPH09165414A (en) 1995-10-11 1997-06-24 Mitsui Petrochem Ind Ltd Solid Titanium Catalyst Component and Its Application to Olefin Polymerization Catalyst
JP2759780B2 (en) 1995-12-19 1998-05-28 三星綜合化学株式会社 Method for producing supported catalyst for polymerization of ethylene and copolymerization of ethylene and α-olefin
JPH09328513A (en) 1996-04-09 1997-12-22 Mitsui Petrochem Ind Ltd Method for preparing solid titanium catalyst component, olefin polymerization catalyst and olefin polymerization method
KR100223105B1 (en) 1996-10-09 1999-10-15 유현식 Olefin polymerization catalyst and olefin polymerization using the same
US5849655A (en) 1996-12-20 1998-12-15 Fina Technology, Inc. Polyolefin catalyst for polymerization of propylene and a method of making and using thereof
BR9804806A (en) 1997-03-29 1999-08-17 Montell Technology Company Bv Processed alcohol-magnesium dichloride adducts for their preparation and components of catalysts obtained from them
KR100334167B1 (en) 1997-05-08 2002-11-22 삼성종합화학주식회사 Process for polymerizing alpha-olefin
GB2325004B (en) 1997-05-09 1999-09-01 Samsung General Chemicals Co A catalyst for polymerization and copolymerization of olefins
KR100361086B1 (en) * 1997-07-14 2003-02-11 삼성종합화학주식회사 Manufacturing method of catalyst for ethylene polymerization
TW539690B (en) 1997-08-11 2003-07-01 Mitsui Chemicals Inc Process for preparing solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
KR100240519B1 (en) 1997-09-11 2000-01-15 유현식 New chelating catalyst for olefin polymerization and olefin polymerization method using the same
KR100334164B1 (en) 1998-04-17 2002-09-25 삼성종합화학주식회사 A PRODUCTION METHOD OF A SUPPORTED T i / V CATALYST FOR ETHYLENE POLYMERIZATION AND ETHYLENE/ α-OLEFIN COPOLYMERIZATION
KR100334165B1 (en) 1998-04-17 2002-11-27 삼성종합화학주식회사 A PRODUCTION METHOD OF A SUPPORTED CATALYST FOR ETHYLENE POLYMERIZATION AND ETHYLENE/α-OLEFIN COPOLYMERIZATION
JP3570264B2 (en) 1998-12-28 2004-09-29 セルヴィシオス コンデュメクス ソシエダッド アノニマ デ・エ セ・ヴェ Fire-resistant, low-smoke-free, halogen-free polyolefin compound for insulation protection of automotive cables
KR100705475B1 (en) 1998-12-30 2007-12-20 삼성토탈 주식회사 Catalysts for Olefin Polymerization and Copolymerization
KR100546499B1 (en) 1999-05-27 2006-01-26 삼성토탈 주식회사 Catalysts for Ethylene Polymerization and Copolymerization
CA2388704C (en) 1999-10-23 2005-05-17 Samsung General Chemicals Co., Ltd. An improved catalyst for homo- and co-polymerization of olefin
KR100361224B1 (en) * 1999-12-01 2002-11-29 삼성종합화학주식회사 Method for preparing catalyst for ethylene homo- and co-polymerization
KR100345190B1 (en) 2000-02-26 2002-07-24 박경렬 Simultaneous absorption method of odor and volatile organic compounds which is used petroleum fuel as a solvent
EP1187602A4 (en) 2000-04-18 2004-09-15 Peptron Inc Injectable sustained release pharmaceutical composition and processes for preparing the same
KR100351386B1 (en) 2000-04-24 2002-09-05 삼성종합화학주식회사 Catalyst for preparation of ultra high molecular weight polyethylene and preparation method of ultra high molecular weight polyethylene using the same
KR100353960B1 (en) 2000-05-31 2002-09-27 삼성종합화학주식회사 A method for producing ethylene homo- and co-polymer
KR100389476B1 (en) 2000-11-09 2003-06-27 삼성종합화학주식회사 A method for producing ethylene homo- and co-polymer
KR100389477B1 (en) 2000-11-09 2003-06-27 삼성종합화학주식회사 A method for producing ethylene homo- and co-polymer
KR100389961B1 (en) 2000-11-09 2003-07-02 삼성종합화학주식회사 α-olefin prepolymerization method
KR100389475B1 (en) * 2000-11-09 2003-06-27 삼성종합화학주식회사 Preparation method of catalyst for ethylene polymeration or copolymeration
KR100389962B1 (en) 2000-11-10 2003-07-02 삼성종합화학주식회사 Preparation method of catalyst for ethylene polymeration or copolymeration
KR100421551B1 (en) 2000-12-16 2004-03-09 삼성아토피나주식회사 Catalyst obtained by prepolymerization of polyolefin and olefin polymerization method using the same
WO2002052059A1 (en) 2000-12-22 2002-07-04 Samsung General Chemicals Co., Ltd. Flame retardant polypropylene resin composition
JP2004516379A (en) 2000-12-22 2004-06-03 サムソン ジェネラル ケミカルズ カンパニー リミテッド Polypropylene resin composition with improved surface hardness and scratch resistance
ATE305490T1 (en) 2000-12-22 2005-10-15 Samsung General Chemicals Co POLYOLEFIN RESIN COMPOSITION
WO2002051882A1 (en) 2000-12-22 2002-07-04 Samsung General Chemicals Co., Ltd. Chelate catalyst for olefin polymerization and olefin polymerization method using the same
KR100421553B1 (en) 2000-12-27 2004-03-09 삼성아토피나주식회사 A polymerization method of alpha-olefins
KR20020096590A (en) 2001-06-21 2002-12-31 삼성종합화학주식회사 Catalyst for polymerization and copolymerization of ethylene

Also Published As

Publication number Publication date
US6916759B2 (en) 2005-07-12
US6897274B2 (en) 2005-05-24
KR20020036287A (en) 2002-05-16
EP1355952A4 (en) 2005-01-12
KR100389475B1 (en) 2003-06-27
EP1355952B1 (en) 2006-08-23
DE60122581T2 (en) 2006-12-14
JP3950051B2 (en) 2007-07-25
US20040116278A1 (en) 2004-06-17
DE60122581D1 (en) 2006-10-05
CN1503810A (en) 2004-06-09
WO2002038619A1 (en) 2002-05-16
EP1355952A1 (en) 2003-10-29
US20040063571A1 (en) 2004-04-01
JP2004513989A (en) 2004-05-13
CN1213075C (en) 2005-08-03
AU2002215244A1 (en) 2002-05-21
ATE337342T1 (en) 2006-09-15

Similar Documents

Publication Publication Date Title
AU2002212771A1 (en) Prepolymerization method of alpha-olefin
AU2002224155A1 (en) Method for producing a catalyst for homo- or co-polymerization of ethylene
WO2004024309A3 (en) System and method for the mitigation of paraffin wax deposition from crude oil by using ultrasonic waves
EA200400255A1 (en) METHOD OF OBTAINING GROWTH PRODUCTS CHAIN
ZA200108415B (en) Organometallic compound useful as cocatalyst for polymerizing olefins.
AU2930700A (en) Pyridine-imine polymerisation catalyst
EP2174964A3 (en) Metallocene catalysts for olefin polymerization and method of polymerizing olefins using the metallocene catalysts
EP1498433A4 (en) Process for producing (meth)acrylic polymer terminated by crosslinkable silyl group
AU2002226622A1 (en) Production of hydrocarbon products
WO2002046243A3 (en) Polymerization process
MXPA03003650A (en) Method of induction sealing liners to cartons.
AU2001272433A1 (en) Method for producing transition metal compounds and their use for the polymerization of olefins
AU2002227186A1 (en) Fluorinated zwitterionic cocatalyst activators for olefin polymerization
AU2001259516A1 (en) Preparation of secondary aminoisobutylalkoxysilanes
CA2429936A1 (en) Polymerization process
RU2000124488A (en) METHOD FOR COLLABORATING 1-ETHYL-2-ALKYLIDENALUMUMICYCLOPENTANES AND 1-ETHYL-2-METHYLENE-3-ALKYLUMENUCYCLOPENTANES
NZ512207A (en) Process for producing quinolinecarbaldehyde
WO2003071118A3 (en) Process for producing c19 minus fischer-tropsch products having high olefinicity
EP1505084A4 (en) SOLID CATALYST COMPONENT FOR OLEFIN POLYMERIZATION, CATALYST FOR OLEFIN POLYMERIZATION AND METHOD FOR PRODUCING OLEFINE POLYMER
WO2002032908A8 (en) Non-metallocene compounds, method for the production thereof and use of the same for the polymerisation of olefins
AU2002212291A1 (en) Method for producing highly branched ethylene polymers
FI990283A0 (en) A Polymerization Catalyst System for Alpha-Olefin and Its Use in Polymerization of Alpha-Olefins
AU2001284099A1 (en) Ligands with at least a fluorosilicone substituent useful for preparing metallocenes
EP1241175A3 (en) Transition metal compound, catalyst for polymerization of olefin, and process for polymerization of olefin using the catalyst
WO2002040550A3 (en) A method for preparing a catalyst composition and its use in a polymerization process