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RU2000124488A - METHOD FOR COLLABORATING 1-ETHYL-2-ALKYLIDENALUMUMICYCLOPENTANES AND 1-ETHYL-2-METHYLENE-3-ALKYLUMENUCYCLOPENTANES - Google Patents

METHOD FOR COLLABORATING 1-ETHYL-2-ALKYLIDENALUMUMICYCLOPENTANES AND 1-ETHYL-2-METHYLENE-3-ALKYLUMENUCYCLOPENTANES

Info

Publication number
RU2000124488A
RU2000124488A RU2000124488/04A RU2000124488A RU2000124488A RU 2000124488 A RU2000124488 A RU 2000124488A RU 2000124488/04 A RU2000124488/04 A RU 2000124488/04A RU 2000124488 A RU2000124488 A RU 2000124488A RU 2000124488 A RU2000124488 A RU 2000124488A
Authority
RU
Russia
Prior art keywords
ethyl
methylene
alkylumenucyclopentanes
alkylidenalumumicyclopentanes
collaborating
Prior art date
Application number
RU2000124488/04A
Other languages
Russian (ru)
Other versions
RU2183637C2 (en
Inventor
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Лейла Османовна Хафизова
Гузель Нурисламовна Гильфанова
Наталья Анатольевна Прохорова
Рифкат Мухатьярович Султанов
Original Assignee
Институт нефтехимии и катализа АН РБ и УНЦ РАН
Filing date
Publication date
Application filed by Институт нефтехимии и катализа АН РБ и УНЦ РАН filed Critical Институт нефтехимии и катализа АН РБ и УНЦ РАН
Priority to RU2000124488A priority Critical patent/RU2183637C2/en
Priority claimed from RU2000124488A external-priority patent/RU2183637C2/en
Application granted granted Critical
Publication of RU2183637C2 publication Critical patent/RU2183637C2/en
Publication of RU2000124488A publication Critical patent/RU2000124488A/en

Links

Claims (1)

Способ совместного получения 1-этил-2-алкилиденалюма-циклопентанов и 1-этил-2-метилен-3-алкилалюмациклопентанов, отличающийся тем, что алкилаллены общей формулы R-=•=, где R = н-С6Н13, н-C8H17, взаимодействуют с триэтилалюминием Et3Al в мольном соотношении R-=•=: Et3Al = 10:(10÷14) соответственно в присутствии катализатора цирконацендихлорида (Cp2ZrCl2) в количестве 2-6% по отношению к алкилаллену, и реакцию проводят в среде гексана в атмосфере аргона, при нормальных условиях, в течение 8-12 ч.A method for the joint production of 1-ethyl-2-alkylidenealumene cyclopentanes and 1-ethyl-2-methylene-3-alkylaluminacyclopentanes, characterized in that the alkyl allens of the general formula R- = • =, where R = n — C 6 H 13 , n- C 8 H 17 interact with triethylaluminum Et 3 Al in a molar ratio R- = • =: Et 3 Al = 10: (10 ÷ 14), respectively, in the presence of a catalyst of zirconacene dichloride (Cp 2 ZrCl 2 ) in an amount of 2-6% in relation to alkylallylene, and the reaction is carried out in hexane in an argon atmosphere, under normal conditions, for 8-12 hours
RU2000124488A 2000-09-25 2000-09-25 Method of combined synthesis of 1-ethyl-2- alkylidenealumacyclopentanes and 1-ethyl-2- methylene-3- alkylalumacyclopentanes RU2183637C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2000124488A RU2183637C2 (en) 2000-09-25 2000-09-25 Method of combined synthesis of 1-ethyl-2- alkylidenealumacyclopentanes and 1-ethyl-2- methylene-3- alkylalumacyclopentanes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2000124488A RU2183637C2 (en) 2000-09-25 2000-09-25 Method of combined synthesis of 1-ethyl-2- alkylidenealumacyclopentanes and 1-ethyl-2- methylene-3- alkylalumacyclopentanes

Publications (2)

Publication Number Publication Date
RU2183637C2 RU2183637C2 (en) 2002-06-20
RU2000124488A true RU2000124488A (en) 2002-08-10

Family

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RU2000124488A RU2183637C2 (en) 2000-09-25 2000-09-25 Method of combined synthesis of 1-ethyl-2- alkylidenealumacyclopentanes and 1-ethyl-2- methylene-3- alkylalumacyclopentanes

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RU (1) RU2183637C2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
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RU2404177C2 (en) * 2008-11-20 2010-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Российской Академии Наук METHOD FOR SYNTHESIS OF endo-, exo-TETRACYCLO[4.5.1.02,6.08,11]DODEC-3(4)-ENE-9-SPIRO-1'-(3'-SELENIUM)CYCLOPENTANES

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RU2283315C1 (en) * 2005-03-30 2006-09-10 Институт нефтехимии и катализа РАН Method for preparing 1-chloro-2,3,4,5-tetraalkylaluminacyclopenta-2,4-dienes
RU2295528C1 (en) * 2005-10-05 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 1-chloro-3,4-dialkyl-2,5-bis-(trimethylsilyl)-aluminacyclopenta-2,4-dienes
RU2295531C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 15-chloro-1,12,13,14-tetraalkyl-15-aluminatetracyclo[10.2.1.02,11.04,9]pentadeca-4(9),5,7,13-tetraene-3,10-diones
RU2295530C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 11-chloro-1,8,9,10-tetraalkyl-11-aluminatricyclo[6.2.1.02,7]undec-9-ene-3,6-diones
RU2295529C1 (en) * 2005-10-17 2007-03-20 Институт нефтехимии и катализа РАН Method for preparing 10-chloro-1,7,8,9-tetraalkyl-4-methyl-4-aza-10-aluminatricyclo[5.2.1.02,6]dec-8-ene-3,5-diones
RU2315054C1 (en) * 2006-05-06 2008-01-20 Институт нефтехимии и катализа РАН Method for combined preparing 3-ethyl-3-aluminadicyclo[01,5]-nonane, 3,4-di-(5-hexenyl)-1-ethylaluminacyclopentane and 3,12-diethyl-3,12-dialuminatricyclo[01,5.010,14]octadecane
RU2309958C1 (en) * 2006-05-06 2007-11-10 Институт нефтехимии и катализа РАН Method for combined preparing 3,4-di-(3-butenyl)-1-ethylaluminacyclopentane, 3,4-diethyl-3,10-dialuminatricyclo-[01,5.08,12]tetradecane and 3,10,17-triethyl-3,10,17-trialuminatetracyclo[01,5.08,12.015,19]geneicosane
RU2313531C1 (en) * 2006-05-06 2007-12-27 Институт нефтехимии и катализа РАН Method for preparing 1-ethyl-3,4-di-(7-octenyl)-aluminacyclopentane
RU2440358C2 (en) * 2008-11-13 2012-01-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method of producing 1-diethylaluminium-2-ethylalkanes
RU2423370C2 (en) * 2009-07-02 2011-07-10 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Ран Method for combined synthesis of 1-ethyl-2-alkylidenealuminacyclopentanes and 1-ethyl-2-methylene-3-alkylaluminacyclopentanes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3817090A1 (en) * 1988-05-19 1989-11-30 Merck Patent Gmbh CYCLIC METAL ORGANIC COMPOUNDS
RU2145327C1 (en) * 1997-09-17 2000-02-10 Институт нефтехимии и катализа с опытным заводом АН РБ Method of preparing 1-(alkoxy)-2(2'-diphenylethylene)-3- phenylalumacyclopropanes

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2404177C2 (en) * 2008-11-20 2010-11-20 Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Российской Академии Наук METHOD FOR SYNTHESIS OF endo-, exo-TETRACYCLO[4.5.1.02,6.08,11]DODEC-3(4)-ENE-9-SPIRO-1'-(3'-SELENIUM)CYCLOPENTANES

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