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AR121734A1 - DIHYDROPYRROLOPYRAZINE TYPE MICROBICIDE DERIVATIVES OF QUINOLINE - Google Patents

DIHYDROPYRROLOPYRAZINE TYPE MICROBICIDE DERIVATIVES OF QUINOLINE

Info

Publication number
AR121734A1
AR121734A1 ARP210100842A ARP210100842A AR121734A1 AR 121734 A1 AR121734 A1 AR 121734A1 AR P210100842 A ARP210100842 A AR P210100842A AR P210100842 A ARP210100842 A AR P210100842A AR 121734 A1 AR121734 A1 AR 121734A1
Authority
AR
Argentina
Prior art keywords
cyano
alkoxy
alkyl
haloalkoxy
halogen
Prior art date
Application number
ARP210100842A
Other languages
Spanish (es)
Inventor
Simon Williams
Matthias Weiss
Original Assignee
Syngenta Crop Protection Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Crop Protection Ag filed Critical Syngenta Crop Protection Ag
Publication of AR121734A1 publication Critical patent/AR121734A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D487/00Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00
    • C07D487/02Heterocyclic compounds containing nitrogen atoms as the only ring hetero atoms in the condensed system, not provided for by groups C07D451/00 - C07D477/00 in which the condensed system contains two hetero rings
    • C07D487/04Ortho-condensed systems
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Compuestos de fórmula (1) en donde los sustituyentes son como se definen en la reivindicación 1, útiles como pesticidas, especialmente como fungicidas. Reivindicación 1: Un compuesto de fórmula (1) en donde: R¹ se selecciona independientemente entre halógeno y metilo; n es 0, 1 ó 2; R² y R³ se seleccionan independientemente entre hidrógeno, halógeno, metoxi, difluorometilo, trifluorometilo o metilo; R⁴ es ciano, alquilo C₁₋₅, alquenilo C₂₋₅, alquinilo C₂₋₅, alcoxi C₁₋₄, haloalcoxi C₁₋₄, alqueniloxi C₃₋₅, alquiniloxi C₃₋₅, alcoxi C₁₋₃-alquilo C₁₋₃, haloalcoxi C₁₋₄-alquilo C₁₋₅, haloalcoxi C₁₋₄-alcoxi C₁₋₄, haloalquenilo C₂₋₄, alcoxi C₁₋₄-alquenilo C₂₋₅, ciano-alquilo C₁₋₅, ciano-alcoxi C₁₋₄, ciano-alquenilo C₂₋₅, cicloalquilo C₃₋₆, fenilo, fenil-alquilo C₁₋₂, heteroarilo o heteroarilalquilo C₁₋₂, en donde el resto heteroarilo es un anillo aromático de 5 ó 6 miembros que comprende 1, 2, 3 ó 4 heteroátomos seleccionados individualmente entre N, O y S, y en donde los grupos cicloalquilo, fenilo o heteroarilo están sustituidos opcionalmente con 1, 2 ó 3 sustituyentes seleccionados independientemente entre halógeno, ciano, alquilo C₁₋₃, haloalquilo C₁₋₂, alcoxi C₁₋₄ y haloalcoxi C₁₋₄; y R⁵ es hidrógeno, alquilo C₁₋₅ o haloalquilo C₁₋₄; o R⁴ y R⁵ junto con el átomo de carbono conector forman un grupo carbocíclico de 3 a 6 miembros; R⁶ y R⁷ se seleccionan independientemente entre hidrógeno, flúor o metilo; R⁸ es hidrógeno, ciano, nitro, halógeno, alquilo C₁₋₅, cicloalquilo C₃₋₆, alcoxicarbonilo C₁₋₄, haloalquilo C₁₋₄, halocicloalquilo C₃₋₆, alquilsulfonilo C₁₋₄, haloalquilsulfonilo C₁₋₄, alcoxi C₁₋₄-alquilsulfonilo C₁₋₄, haloalcoxi C₁₋₄, alquilsulfonilo C₁₋₄, ciano-alquilsulfonilo C₁₋₄, cicloalquilsulfonilo C₃₋₆, fenilsulfonilo, bencilsulfonilo, fenilo y heteroarilo en donde el resto heteroarilo es un anillo aromático de 5 ó 6 miembros que comprende 1, 2, 3 ó 4 heteroátomos seleccionados individualmente entre N, O y S, y en donde el fenilo y heteroarilo están sustituidos opcionalmente con 1, 2 ó 3 sustituyentes seleccionados independientemente entre halógeno, alquilo C₁₋₃, alcoxi C₁₋₄, haloalcoxi C₁₋₄, ciano, haloalquilo C₁₋₂; y R⁹ es hidrógeno, halógeno, ciano o nitro; o una sal agronómicamente aceptable, un N-óxido o estereoisómero del mismo.Compounds of formula (1) in which the substituents are as defined in claim 1, useful as pesticides, especially as fungicides. Claim 1: A compound of formula (1) wherein: R¹ is independently selected from halogen and methyl; n is 0, 1 or 2; R² and R³ are independently selected from hydrogen, halogen, methoxy, difluoromethyl, trifluoromethyl, or methyl; R⁴ is cyano, C₁₋₅ alkyl, C₂₋₅ alkenyl, C₂₋₅ alkynyl, C₁₋₄ alkoxy, C₁₋₄ haloalkoxy, C₃₋₅ alkenyloxy, C₃₋₅ alkynyloxy, C₁₋₋alkoxy, C₁₋₋ haloalkoxy C₁₋₄-C₁₋₅-alkyl, C₁₋₄-haloalkoxy-C₁₋₄-alkoxy, C₂₋₄-haloalkenyl, C₁₋₄-alkoxy-C₂₋₅-alkenyl, C₁₋₅-cyano-alkyl, C₁₋-cyano-alkoxy C₂₋₅ alkenyl, C₃₋₆ cycloalkyl, phenyl, phenyl-C₁₋₂ alkyl, heteroaryl or C₁₋₂ heteroarylalkyl, wherein the heteroaryl moiety is a 5- or 6-membered aromatic ring comprising 1, 2, 3 or 4 heteroatoms individually selected from N, O and S, and wherein the cycloalkyl, phenyl or heteroaryl groups are optionally substituted with 1, 2 or 3 substituents independently selected from halogen, cyano, C₁₋₃ alkyl, C₁₋₂ haloalkyl, C₁₋₄ alkoxy and C₁₋₄ haloalkoxy; and R⁵ is hydrogen, C₁₋₅ alkyl or C₁₋₄ haloalkyl; or R⁴ and R⁵ together with the connecting carbon atom form a 3 to 6 membered carbocyclic group; R⁶ and R⁷ are independently selected from hydrogen, fluorine or methyl; R⁸ is hydrogen, cyano, nitro, halogen, C₁₋₅ alkyl, C₃₋₆ cycloalkyl, C₁₋₄ alkoxycarbonyl, C₁₋₄ haloalkyl, C₃₋₆ halocycloalkyl, C₁₋₄ alkylsulfonyl, C₁₋₄ haloalkylsulfonyl, C₋₋ alkoxy C₁₋₄ alkylsulfonyl, C₁₋₄ haloalkoxy, C₁₋₄ alkylsulfonyl, C₁₋₄ cyano-alkylsulfonyl, C₃₋₆ cycloalkylsulfonyl, phenylsulfonyl, benzylsulfonyl, phenyl, and heteroaryl wherein the heteroaryl moiety is a 5- or 6-membered aromatic ring comprising 1, 2, 3 or 4 heteroatoms individually selected from N, O and S, and wherein phenyl and heteroaryl are optionally substituted with 1, 2 or 3 substituents independently selected from halogen, C₁₋₃ alkyl, C₁₋₄ alkoxy, haloalkoxy C₁₋₄, cyano, C₁₋₂ haloalkyl; and R⁹ is hydrogen, halogen, cyano or nitro; or an agronomically acceptable salt, N-oxide or stereoisomer thereof.

ARP210100842A 2020-04-08 2021-04-05 DIHYDROPYRROLOPYRAZINE TYPE MICROBICIDE DERIVATIVES OF QUINOLINE AR121734A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP20168756 2020-04-08

Publications (1)

Publication Number Publication Date
AR121734A1 true AR121734A1 (en) 2022-07-06

Family

ID=70277211

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP210100842A AR121734A1 (en) 2020-04-08 2021-04-05 DIHYDROPYRROLOPYRAZINE TYPE MICROBICIDE DERIVATIVES OF QUINOLINE

Country Status (4)

Country Link
AR (1) AR121734A1 (en)
TW (1) TW202200587A (en)
UY (1) UY39162A (en)
WO (1) WO2021204855A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2025008226A1 (en) * 2023-07-05 2025-01-09 Basf Se Substituted quinolyl/quinoxalyl dihydropyrrolotriazine compounds for combatting phyto-pathogenic fungi
WO2025008227A1 (en) * 2023-07-05 2025-01-09 Basf Se Substituted pyridyl/pyrazinyl dihydropyrrolotriazine compounds for combatting phytopath-ogenic fungi

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Also Published As

Publication number Publication date
UY39162A (en) 2021-11-30
TW202200587A (en) 2022-01-01
WO2021204855A1 (en) 2021-10-14

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