AR090076A1 - Metodos para producir compuestos sulfilimina - Google Patents
Metodos para producir compuestos sulfiliminaInfo
- Publication number
- AR090076A1 AR090076A1 ARP130100489A ARP130100489A AR090076A1 AR 090076 A1 AR090076 A1 AR 090076A1 AR P130100489 A ARP130100489 A AR P130100489A AR P130100489 A ARP130100489 A AR P130100489A AR 090076 A1 AR090076 A1 AR 090076A1
- Authority
- AR
- Argentina
- Prior art keywords
- compound
- alkyl
- group
- haloalkenyl
- haloalkyl
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title 1
- -1 sulfilimine compound Chemical class 0.000 abstract 11
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 6
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 6
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 6
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 abstract 4
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 4
- 125000004446 heteroarylalkyl group Chemical group 0.000 abstract 4
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 abstract 4
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 3
- 125000006656 (C2-C4) alkenyl group Chemical group 0.000 abstract 3
- 125000006650 (C2-C4) alkynyl group Chemical group 0.000 abstract 3
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000000304 alkynyl group Chemical group 0.000 abstract 3
- 125000004438 haloalkoxy group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 125000001072 heteroaryl group Chemical group 0.000 abstract 2
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/54—Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D213/57—Nitriles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
- C07D213/16—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom containing only one pyridine ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/32—Sulfur atoms
- C07D213/34—Sulfur atoms to which a second hetero atom is attached
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D237/00—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings
- C07D237/02—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings
- C07D237/06—Heterocyclic compounds containing 1,2-diazine or hydrogenated 1,2-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/02—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings
- C07D241/10—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having three double bonds between ring members or between ring members and non-ring members
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
- C07D263/02—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings
- C07D263/30—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D271/00—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms
- C07D271/02—Heterocyclic compounds containing five-membered rings having two nitrogen atoms and one oxygen atom as the only ring hetero atoms not condensed with other rings
- C07D271/06—1,2,4-Oxadiazoles; Hydrogenated 1,2,4-oxadiazoles
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D275/00—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings
- C07D275/02—Heterocyclic compounds containing 1,2-thiazole or hydrogenated 1,2-thiazole rings not condensed with other rings
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D277/00—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
- C07D277/02—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings
- C07D277/20—Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/08—1,2,4-Thiadiazoles; Hydrogenated 1,2,4-thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/12—1,3,4-Thiadiazoles; Hydrogenated 1,3,4-thiadiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Thiazole And Isothizaole Compounds (AREA)
Abstract
Reivindicación 1: Un método para producir un compuesto sulfilimina, que comprende: combinar un compuesto sulfido, cianamida, un compuesto de hipoclorito y una base; y oxidizar el compuesto sulfido para formar un compuesto sulfilimina. Reivindicación 2: El método de la reivindicación 1, que comprende adicionalmente un amortiguador al compuesto sulfido, cianamida, compuesto de hipoclorito y base. Reivindicación 3: El método de la reivindicación 1, en donde la combinación de un compuesto sulfido, cianamida, un compuesto de hipoclorito y una base comprende combinar cianamida, compuesto de hipoclorito y base con un compuesto sulfido que tiene la estructura química de fórmula (1) en donde Het es una parte seleccionada del grupo de fórmulas (2); X es una parte seleccionada del grupo que consiste en un halógeno, un alquilo C₁₋₄, un haloalquilo C₁₋₄, un alquenilo C₂₋₄, un alquinilo C₂₋₄, un haloalquenilo C₂₋₄, un alcoxi C₁₋₄, un haloalcoxi C₁₋₄, CN, NO₂, SOₘR⁶ donde m es un número entero de 0 - 2, COOR⁴ y CONR⁴R⁵; Y es una parte seleccionada del grupo que consiste en hidrógeno, un halógeno, un alquilo C₁₋₄, un haloalquilo C₁₋₄, un alquenilo C₂₋₄, un alquinilo C₂₋₄, un haloalquenilo C₂₋₄, un alcoxi C₁₋₄, un haloalcoxi C₁₋₄, CN, NO₂, SOₘR¹ donde m es un número entero de 0 - 2, COOR⁴, CONR⁴R⁵, arilo y heteroarilo; n es un número entero de 0 - 3; L es ya sea un enlace simple, -CH(CH₂)ₚ- donde R¹, S y L tomados juntos son un anillo de 4, 5 ó 6 miembros y p es un número entero de 1 - 3, -CH(CH₂OCH₂)- donde R¹, S y L tomados juntos son un anillo de 6 miembros, o -CH- donde L, R² y el carbono común al cual se conectan tomados juntos son un anillo de 4, 5 ó 6 miembros con hasta 1 heteroátomo, pero no más; R¹ es una parte seleccionada del grupo que consiste en un alquilo C₁₋₄, un haloalquilo C₁₋₄, un alquenilo C₃₋₆, un alquinilo C₃₋₆, un haloalquenilo C₃₋₆, un arilalquilo, un heteroarialquilo, o -CH₂-, en casos donde R¹, S y L tomados juntos son un anillo de 4, 5 ó 6 miembros; cada R² y R³ es seleccionado independientemente del grupo que consiste en hidrógeno, halógeno, alquilo C₁₋₄, un haloalquilo C₁₋₄, un alquenilo C₂₋₄, un alquinilo C₂₋₄, un haloalquenilo C₂₋₄, un alcoxi C₁₋₄, un haloalcoxi C₁₋₄, CN, SOₘR⁶ donde m es un número entero de 0 - 2, COOR⁴, CONR⁴R⁵, un arilalquilo, un heteroarilalquilo, o R² y R³ y el carbono común al cual se conectan forman un anillo de 3 a 6 miembros; cada R⁴ y R⁵ es seleccionado independientemente del grupo que consiste en hidrógeno, un alquilo C₁₋₄, un haloalquilo C₁₋₄, un alquenilo C₃₋₆, un alquinilo C₃₋₆, un haloalquenilo C₃₋₆, un arilo, un heteroarilo, un arilalquilo o un heteroarilalquilo; y R⁶ es una parte seleccionada del grupo que consiste en un alquilo C₁₋₄, un haloalquilo C₁₋₄, un alquenilo C₃₋₆, un alquinilo C₃₋₆, un haloalquenilo C₃₋₆, un arilalquilo y un heteroarilalquilo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261599489P | 2012-02-16 | 2012-02-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR090076A1 true AR090076A1 (es) | 2014-10-15 |
Family
ID=48982761
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP130100489A AR090076A1 (es) | 2012-02-16 | 2013-02-15 | Metodos para producir compuestos sulfilimina |
Country Status (19)
| Country | Link |
|---|---|
| US (2) | US9227936B2 (es) |
| EP (1) | EP2814812B1 (es) |
| JP (1) | JP6138834B2 (es) |
| KR (1) | KR102064827B1 (es) |
| CN (1) | CN104271555B (es) |
| AR (1) | AR090076A1 (es) |
| AU (1) | AU2013221420B2 (es) |
| BR (1) | BR102013003576B8 (es) |
| CA (1) | CA2863994C (es) |
| CO (1) | CO7081159A2 (es) |
| ES (1) | ES2625106T3 (es) |
| IL (1) | IL233956B (es) |
| IN (1) | IN2014DN07442A (es) |
| MX (1) | MX368125B (es) |
| PL (1) | PL2814812T3 (es) |
| RU (1) | RU2634718C2 (es) |
| UA (1) | UA116628C2 (es) |
| WO (1) | WO2013123349A1 (es) |
| ZA (1) | ZA201406494B (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AR093901A1 (es) * | 2012-12-11 | 2015-06-24 | Dow Agrosciences Llc | Proceso mejorado para la preparacion de determinadas sulfiliminas sustituidas |
| CA2942386A1 (en) | 2014-03-13 | 2015-09-17 | Proteostasis Therapeutics, Inc. | Compounds, compositions, and methods for increasing cftr activity |
| CA2942387A1 (en) | 2014-03-13 | 2015-09-17 | Proteostasis Therapeutics, Inc. | Compounds, compositions and methods of increasing cftr actvity |
| WO2015196071A1 (en) | 2014-06-19 | 2015-12-23 | Proteostasis Therapeutics, Inc. | Compounds, compositions and methods of increasing cftr activity |
| US10392378B2 (en) | 2014-12-23 | 2019-08-27 | Proteostasis Therapeutics, Inc. | Derivatives of 5-phenyl- or 5-heteroarylathiazol-2-carboxylic amide useful for the treatment of inter alia cystic fibrosis |
| CA2971835A1 (en) | 2014-12-23 | 2016-06-30 | Proteostasis Therapeutics, Inc. | Derivatives of 3-heteroarylisoxazol-5-carboxylic amide useful for the treatment of inter alia cystic fibrosis |
| MA41253A (fr) | 2014-12-23 | 2017-10-31 | Proteostasis Therapeutics Inc | Composés, compositions et procédés pour augmenter l'activité du cftr |
| US10738011B2 (en) | 2014-12-23 | 2020-08-11 | Proteostasis Therapeutics, Inc. | Derivatives of 5-(hetero)arylpyrazol-3-carboxylic amide or 1-(hetero)aryltriazol-4-carboxylic amide useful for the treatment of inter alia cystic fibrosis |
| WO2017019589A1 (en) | 2015-07-24 | 2017-02-02 | Proteostasis Therapeutics, Inc. | Compounds, compositions and methods of increasing cftr activity |
| SG11201802798WA (en) | 2015-10-06 | 2018-05-30 | Proteostasis Therapeutics Inc | Compounds, compositions, and methods for modulating cftr |
| US10662207B2 (en) | 2016-04-07 | 2020-05-26 | Proteostasis Therapeutics, Inc. | Compounds, compositions, and methods for modulating CFTR |
| TWI735573B (zh) * | 2016-06-21 | 2021-08-11 | 美商陶氏農業科學公司 | 生產某些經取代硫亞胺之方法 |
| ES2954658T3 (es) | 2016-06-21 | 2023-11-23 | Proteostasis Therapeutics Inc | Compuestos, composiciones y procedimientos para aumentar la actividad de CFTR |
| GB201905721D0 (en) | 2019-04-24 | 2019-06-05 | Univ Dundee | Compounds |
| WO2025017547A1 (en) | 2023-07-18 | 2025-01-23 | Adama Makhteshim Ltd. | Method for preparing an n-cyano sulfilimine compound |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2573733A (en) * | 1950-01-03 | 1951-11-06 | Celanese Corp | Production of anthraquinone dyestuffs |
| US4085093A (en) | 1976-07-23 | 1978-04-18 | The Goodyear Tire & Rubber Company | Sulfilimines as premature vulcanization inhibitors |
| FR2723370B1 (fr) * | 1994-08-02 | 1996-09-13 | Roussel Uclaf | Nouveaux derives de l'imidazole, leur procede de preparation, les nouveaux intermediaires obtenus, leur application a titre de medicaments et les compositions pharmaceutiques les renfermant |
| AR015104A1 (es) * | 1996-11-13 | 2001-04-18 | Dowelanco | Compuestos de n-arilsulfilimina sustituidos, utiles como catalizadores en la preparacion de compuestos de n-arilarilsulfonamida; proceso para preparar dichos compuestos y su uso para catalizar dicha preparacion. |
| MXPA06011589A (es) * | 2004-04-08 | 2006-12-20 | Dow Agrosciences Llc | Sulfoximinas n-sustituidas insecticidas. |
| TWI387585B (zh) | 2006-09-01 | 2013-03-01 | Dow Agrosciences Llc | 殺蟲性之ｎ-取代（雜芳基）烷基烴基硫亞胺 |
| TWI383970B (zh) * | 2006-11-08 | 2013-02-01 | Dow Agrosciences Llc | 多取代的吡啶基磺醯亞胺及其作為殺蟲劑之用途 |
| DK2114886T3 (da) * | 2007-02-26 | 2014-06-30 | Dow Agrosciences Llc | Fremgangsmåde til fremstilling af visse substituerede sulfiliminer |
| WO2009134224A1 (en) * | 2008-05-01 | 2009-11-05 | Dow Agrosciences Llc | Synergistic pesticidal mixtures |
| KR101512528B1 (ko) * | 2007-07-20 | 2015-04-15 | 다우 아그로사이언시즈 엘엘씨 | 식물 생장력의 증가 |
| KR20120050492A (ko) * | 2009-08-26 | 2012-05-18 | 노파르티스 아게 | 테트라-치환된 헤테로아릴 화합물 및 ｍｄｍ2 및/또는 ｍｄｍ4 조절제로서의 그의 용도 |
| AR093901A1 (es) * | 2012-12-11 | 2015-06-24 | Dow Agrosciences Llc | Proceso mejorado para la preparacion de determinadas sulfiliminas sustituidas |
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2013
- 2013-02-15 UA UAA201410166A patent/UA116628C2/uk unknown
- 2013-02-15 ES ES13748778.1T patent/ES2625106T3/es active Active
- 2013-02-15 CA CA2863994A patent/CA2863994C/en active Active
- 2013-02-15 RU RU2014137257A patent/RU2634718C2/ru active
- 2013-02-15 KR KR1020147025686A patent/KR102064827B1/ko active Active
- 2013-02-15 AR ARP130100489A patent/AR090076A1/es active IP Right Grant
- 2013-02-15 MX MX2014009922A patent/MX368125B/es active IP Right Grant
- 2013-02-15 CN CN201380019956.XA patent/CN104271555B/zh active Active
- 2013-02-15 EP EP13748778.1A patent/EP2814812B1/en active Active
- 2013-02-15 JP JP2014557818A patent/JP6138834B2/ja active Active
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- 2013-02-15 WO PCT/US2013/026377 patent/WO2013123349A1/en not_active Ceased
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2014
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2015
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