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AR094723A1 - Compuestos de malononitrilo para controlar plagas de animales - Google Patents

Compuestos de malononitrilo para controlar plagas de animales

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Publication number
AR094723A1
AR094723A1 ARP130103877A ARP130103877A AR094723A1 AR 094723 A1 AR094723 A1 AR 094723A1 AR P130103877 A ARP130103877 A AR P130103877A AR P130103877 A ARP130103877 A AR P130103877A AR 094723 A1 AR094723 A1 AR 094723A1
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AR
Argentina
Prior art keywords
substituted
alkyl
cycloalkyl
alkenyl
carbon atoms
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Application number
ARP130103877A
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English (en)
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Basf Se
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Publication of AR094723A1 publication Critical patent/AR094723A1/es

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    • A—HUMAN NECESSITIES
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    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
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    • A61P33/02—Antiprotozoals, e.g. for leishmaniasis, trichomoniasis, toxoplasmosis
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    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/35—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms, or by nitro or nitroso groups
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    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/37—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by etherified hydroxy groups
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    • C07C255/41—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by carboxyl groups, other than cyano groups
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    • C07D317/48—Methylenedioxybenzenes or hydrogenated methylenedioxybenzenes, unsubstituted on the hetero ring
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    • C07D319/16—1,4-Dioxanes; Hydrogenated 1,4-dioxanes condensed with carbocyclic rings or ring systems condensed with one six-membered ring
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Environmental Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Veterinary Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Public Health (AREA)
  • Medicinal Chemistry (AREA)
  • Animal Behavior & Ethology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
  • Pyrrole Compounds (AREA)
  • Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
  • Quinoline Compounds (AREA)

Abstract

Reivindicación 1: El uso de un compuesto de la fórmula (1) o una de sus sales para combatir plagas animales, en donde Y es fenilo no sustituido o sustituido con 1, 2, 3, 4 ó 5 sustituyentes R⁵; o naftilo no sustituido o sustituido con 1, 2, 3, 4, 5, 6 ó 7 sustituyentes R⁵; Q es fenilo no sustituido o sustituido con 1, 2, 3, 4 ó 5 sustituyentes R⁶; cicloalquilo C₃₋₈ no sustituido o sustituido con uno o varios sustituyentes R⁶; o cicloalquenilo C₃₋₈ no sustituido o sustituido con uno o varios sustituyentes R⁶; R¹ es hidrógeno, halógeno, ciano, hidroxi, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, cicloalquenilo C₃₋₈, alcoxi C₁₋₆, alquenil C₂₋₆-oxi, alquil C₁₋₆-tio, (alcoxi C₁₋₆)carbonilo, en donde los átomos de carbono de los radicales alifáticos o cicloalifáticos antes mencionados no están sustituidos o están sustituidos con 1, 2 ó 3 sustituyentes R⁷; R² es hidrógeno o halógeno; o R¹ y R² forman, junto con el átomo de carbono al que están unidos, un grupo metileno o un grupo ciclopropilo; R³ es hidrógeno, halógeno, ciano, hidroxi, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, cicloalquenilo C₃₋₈, alcoxi C₁₋₆, alquenil C₂₋₆-oxi, alquil C₁₋₆-tio, (alcoxi C₁₋₆)carbonilo, en donde los átomos de carbono de los radicales alifáticos o cicloalifáticos antes mencionados no están sustituidos o están sustituidos con 1, 2 ó 3 sustituyentes R⁷; R⁴ es hidrógeno o halógeno; o R³ y R⁴ forman, junto con el átomo de carbono al que están unidos, un grupo metileno o un grupo ciclopropilo; cada R⁵, R⁶ es, de modo independiente, halógeno, ciano, azido, nitro, -SCN, SF₅, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, en donde los átomos de carbono de los radicales alifáticos antes mencionados no están sustituidos o están sustituidos con uno o varios Rᵃ; cicloalquilo C₃₋₈ o cicloalquenilo C₃₋₈, en donde los átomos de carbono de los radicales cicloalifáticos antes mencionados no están sustituidos o están sustituidos con uno o varios Rᵇ; fenilo no sustituido o sustituido con hasta 5 Rᶜ; un anillo heterocíclico saturado, parcialmente insaturado o aromático de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos heteroatómicos seleccionados de N, O, S, NO, SO, SO₂, en donde el anillo antes mencionado no está sustituido o está sustituido con hasta 5 Rᵈ; Si(Rᵉ)₃, ORᶠ, SRᶠ, OS(O)ˣRʰ, S(O)ˣRʰ, N(Rⁱ)₂, N(Rⁱ)C(=O)Rᵐ, OC(=O)Rᵐ, C(=O)Rᵐ, C(=O)ORᶠ, C(=NRⁱ)Rᵐ, C(S)Rᵐ; o dos R⁵ en dos átomos de carbono adyacentes presentes en un anillo fenilo son juntos un puente seleccionado de CH₂CH₂CH₂CH₂, N=CH-CH=CH, CH=N-CH=CH, N=CH-N=CH, N=CH-CH=N, OCH₂CH₂CH₂, OCH=CHCH₂, CH₂OCH₂CH₂, OCH₂CH₂O, OCH₂OCH₂, CH₂CH₂CH₂, CH=CHCH₂, CH₂CH₂O, CH=CHO, CH₂OCH₂, CH₂C(=O)O, C(=O)OCH₂, O(CH₂)O, SCH₂CH₂CH₂, SCH=CHCH₂, CH₂SCH₂CH₂, SCH₂CH₂S, SCH₂SCH₂, CH₂CH₂S, CH=CHS, CH₂SCH₂, CH₂C(=S)S, C(=S)SCH₂, S(CH₂)S, CH₂CH₂NRK, CH₂CH=N, CH=CHNRK, OCH=N, SCH=N y forman, junto con los átomos de carbono a los que están unidos dos R⁵, un anillo carbocíclico o heterocíclico parcialmente insaturado o aromático de 5 ó 6 miembros, en donde el anillo no está sustituido o está sustituido con 1 ó 2 sustituyentes seleccionados de =O, OH, CH₃, OCH₃, halógeno, halometilo y halometoxi; cada R⁷ es, de modo independiente, halógeno, ciano, hidroxi, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, cicloalquenilo C₃₋₈, alcoxi C₁₋₆, alquenil C₂₋₆-oxi, alquil C₁₋₆-tio, (alcoxi C₁₋₆)carbonilo, OSi(Rᵉ)₃, en donde los átomos de carbono de los radicales alifáticos o cicloalifáticos antes mencionados no están sustituidos, están parcial o completamente halogenados y/u oxigenados; cada Rᵃ es, de modo independiente, halógeno, ciano, azido, nitro, -SCN, SF₅, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquil C₁₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, haloalquil C₁₋₆-tio, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆, alquil C₁₋₆-cicloalquilo C₃₋₈, Si(Rᵉ)₃, ORA, SRA, OSO₂RB, S(O)ˣRB, S(O)ˣN(RD)₂, N(RD)₂, C(=O)N(RD)₂, C(=S)N(RD)₂, C(=O)ORA, fenilo no sustituido o sustituido con hasta 5 RE; un anillo heterocíclico saturado, parcialmente insaturado o aromático de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos heteroatómicos seleccionados de N, O, S, NO, SO, SO₂, en donde el anillo antes mencionado no está sustituido o está sustituido con hasta 5 RE, o dos Rᵃ presentes en un átomo de carbono son juntos =O, =C(RF)₂, =NRD, =NORA, =NNRD, o dos Rᵃ forman un anillo carbocíclico o heterocíclico saturado o parcialmente insaturado de 3, 4, 5, 6, 7 u 8 miembros junto con los átomos de carbono a los que dos Rᵃ están unidos; cada Rᵇ es, de modo independiente, halógeno, ciano, azido, nitro, -SCN, SF₅, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxi C₁₋₆, haloalcoxi C₁₋₆, alquil C₁₋₆-tio, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, haloalquil C₁₋₆-tio, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆, alquil C₁₋₆-cicloalquilo C₃₋₈, Si(RG)₃, ORH, SRH, OSO₂RJ, S(O)ˣRJ, -S(O)ˣN(RK)₂, N(RK)₂, C(=O)N(RK)₂, C(=S)N(RK)₂, C(=O)ORH, o dos Rᵇ presentes en un átomo de carbono son juntos =O, =C(RL)₂, =NRK, =NORH, =NNRK, o dos Rᵇ forman un anillo carbocíclico o heterocíclico saturado o parcialmente insaturado de 3, 4, 5, 6, 7 u 8 miembros junto con los átomos de carbono a los que dos Rᵇ están unidos; cada Rᶜ es, de modo independiente, halógeno, ciano, azido, nitro, -SCN, SF₅, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, en donde los átomos de carbono de los radicales alifáticos o cicloalifáticos antes mencionados no están sustituidos o están sustituidos con uno o varios RM; Si(RG)₃, ORH, SRH, OS(O)ˣRJ, S(O)ˣRJ, -S(O)ˣN(RK)₂, N(RK)₂, C(=O)RN, C(=O)ORH, C(=NRK)RN, C(=O)N(RK)₂, C(=S)N(RK)₂; cada Rᵈ es, de modo independiente, halógeno, ciano, azido, nitro, -SCN, SF₅, alquilo C₁₋₆, alquenilo C₂₋₆, alquinilo C₂₋₆, cicloalquilo C₃₋₈, en donde los átomos de carbono de los radicales alifáticos o cicloalifáticos antes mencionados no están sustituidos o están sustituidos con uno o varios RM; Si(RG)₃, ORH, SRH, OS(O)ˣRJ, S(O)ˣRJ, S(O)ˣN(RK)₂, N(RK)₂, C(=O)RN, C(=O)ORH, C(=NRK)RN, C(=O)N(RK)₂, C(=S)N(RK)₂, o dos Rᵈ presentes en un átomo de un anillo heterocíclico saturado o parcialmente insaturado son juntos =O, =C(RL)₂, =NRK, =NORH o =NNRK; cada Rᵉ es, de modo independiente, halógeno, alquilo C₁₋₆, haloalquilo C₁₋₆, alcoxialquilo C₁₋₆, alquenilo C₂₋₆, haloalquenilo C₂₋₆, alquinilo C₂₋₆, haloalquinilo C₂₋₆, cicloalquilo C₃₋₈, halocicloalquilo C₃₋₈, haloalcoxialquilo C₁₋₆, fenilo, un anillo heterocíclico saturado, parcialmente insaturado o aromático de 3, 4, 5, 6 ó 7 miembros que contiene 1, 2 ó 3 heteroátomos o grupos heteroatómicos seleccionados de N, O, S, NO, SO, SO₂; cada Rᶠ es, de modo independiente, hidrógeno, ciano, alquilo C₁₋₆, alquil C₁₋₆-sulfinilo, alquil C₁₋₆-sulfonilo, cicloalquilo C₃₋₈, alquenilo C₂₋₆, alquinilo C₂₋₆, en donde los átomos de carbono de los radicales alifáticos o cicloalifáticos antes mencionados no están sustituidos o están sustituidos con uno
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