AR081025A1 - Procedimiento para preparar acidos dicarboxilicos - Google Patents
Procedimiento para preparar acidos dicarboxilicosInfo
- Publication number
- AR081025A1 AR081025A1 ARP110101592A ARP110101592A AR081025A1 AR 081025 A1 AR081025 A1 AR 081025A1 AR P110101592 A ARP110101592 A AR P110101592A AR P110101592 A ARP110101592 A AR P110101592A AR 081025 A1 AR081025 A1 AR 081025A1
- Authority
- AR
- Argentina
- Prior art keywords
- reaction mixture
- formula
- acid
- prepare
- procedure
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 abstract 6
- 239000011541 reaction mixture Substances 0.000 abstract 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910017604 nitric acid Inorganic materials 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000003997 cyclic ketones Chemical class 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- YVSCCMNRWFOKDU-UHFFFAOYSA-N hexanedioic acid Chemical compound OC(=O)CCCCC(O)=O.OC(=O)CCCCC(O)=O YVSCCMNRWFOKDU-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/316—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with oxides of nitrogen or nitrogen-containing mineral acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/13—Dicarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento para reparar ácidos dicarboxílicos, más particularmente, ácido adípico (ácido 1,6-hexanodioico), mediante la accion de ácido nítrico, partiendo de cetonas cíclicas o alcoholes que son los compuestos correspondientes desde el punto de vista del numero de átomos de carbono, en presencia de uno o más oxidos de nitrogeno en una concentracion molar en la mezcla de reaccion superior a 2,5 mmol por kg de mezcla de reaccion. Reivindicacion 1: Procedimiento para preparar un ácido dicarboxílico de formula (1), caracterizado porque n representa un entero que oscila entre 1 y 9, en una unica etapa, por accion de ácido nítrico, en presencia de uno o más oxidos de nitrogeno, en una concentracion molar en la mezcla de reaccion de más de 2,5 mmol por kg de mezcla de reaccion, en los compuestos de formula (2) o (3), en los cuales n representa el mismo numero entero que en la formula (1).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR1053628A FR2959741B1 (fr) | 2010-05-10 | 2010-05-10 | Procede de preparation de diacides carboxyliques |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR081025A1 true AR081025A1 (es) | 2012-05-30 |
Family
ID=43242624
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110101592A AR081025A1 (es) | 2010-05-10 | 2011-05-09 | Procedimiento para preparar acidos dicarboxilicos |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8846975B2 (es) |
| EP (1) | EP2569272B1 (es) |
| KR (1) | KR101494953B1 (es) |
| CN (1) | CN102892741B (es) |
| AR (1) | AR081025A1 (es) |
| BR (1) | BR112012028718B1 (es) |
| ES (1) | ES2605007T3 (es) |
| FR (1) | FR2959741B1 (es) |
| PL (1) | PL2569272T3 (es) |
| TW (1) | TW201204698A (es) |
| WO (1) | WO2011141404A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102688386B1 (ko) * | 2017-10-16 | 2024-07-24 | 바스프 에스이 | 암모니아 첨가에 의한 니트로 화합물의 연속 수소화에서의 촉매 선택도 증가 |
| WO2019112992A1 (en) * | 2017-12-05 | 2019-06-13 | Ascend Performance Materials Operations Llc | Process for preparation of nitrogen oxides and nitric acid from nitrous oxide |
| CN115160127B (zh) * | 2022-07-29 | 2024-06-11 | 中国天辰工程有限公司 | 一种共氧化反应制备长碳链二元酸的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE68897C (de) | H. JOLY in Wittenberg, Provinz Sachsen | Zerlegbarer Gitterträger | ||
| DD68897A (es) * | ||||
| US2298387A (en) * | 1939-08-25 | 1942-10-13 | Eastman Kodak Co | Oxidation process |
| DE767840C (de) * | 1940-02-11 | 1954-08-02 | Ig Farbenindustrie Ag | Verfahren zur Herstellung von Adipinsaeure |
| US3076026A (en) * | 1960-04-01 | 1963-01-29 | Du Pont | Process for the simultaneous production of hydroxylamine and adipic acid |
| US3444194A (en) * | 1962-09-25 | 1969-05-13 | Montedison Spa | Process for the preparation of adipic acid |
| BE627356A (es) * | 1963-01-21 | |||
| FR2043012A5 (es) * | 1969-04-16 | 1971-02-12 | Huels Chemische Werke Ag | |
| GB1555781A (en) * | 1975-08-27 | 1979-11-14 | Pollution Preventing Res | Methods for producing dibasic fatty acid |
| CN1231449C (zh) * | 2003-12-31 | 2005-12-14 | 北京工业大学 | 仿生催化氧气氧化环己烷制备己二酸的方法 |
-
2010
- 2010-05-10 FR FR1053628A patent/FR2959741B1/fr not_active Expired - Fee Related
-
2011
- 2011-05-09 BR BR112012028718-4A patent/BR112012028718B1/pt not_active IP Right Cessation
- 2011-05-09 AR ARP110101592A patent/AR081025A1/es unknown
- 2011-05-09 PL PL11720429T patent/PL2569272T3/pl unknown
- 2011-05-09 CN CN201180023492.0A patent/CN102892741B/zh not_active Expired - Fee Related
- 2011-05-09 ES ES11720429.7T patent/ES2605007T3/es active Active
- 2011-05-09 EP EP11720429.7A patent/EP2569272B1/fr active Active
- 2011-05-09 US US13/697,189 patent/US8846975B2/en active Active
- 2011-05-09 KR KR1020127031986A patent/KR101494953B1/ko active Active
- 2011-05-09 TW TW100116212A patent/TW201204698A/zh unknown
- 2011-05-09 WO PCT/EP2011/057381 patent/WO2011141404A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN102892741B (zh) | 2014-10-08 |
| KR101494953B1 (ko) | 2015-02-23 |
| BR112012028718A2 (pt) | 2016-07-19 |
| US20130109886A1 (en) | 2013-05-02 |
| EP2569272A1 (fr) | 2013-03-20 |
| US8846975B2 (en) | 2014-09-30 |
| EP2569272B1 (fr) | 2016-08-24 |
| WO2011141404A1 (fr) | 2011-11-17 |
| PL2569272T3 (pl) | 2017-05-31 |
| KR20130004600A (ko) | 2013-01-11 |
| CN102892741A (zh) | 2013-01-23 |
| TW201204698A (en) | 2012-02-01 |
| FR2959741A1 (fr) | 2011-11-11 |
| ES2605007T3 (es) | 2017-03-10 |
| BR112012028718B1 (pt) | 2019-01-29 |
| FR2959741B1 (fr) | 2014-11-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |