AR079616A1 - Proceso para modificar aceites vegetales y plastificante primario para polimeros de vinilo - Google Patents
Proceso para modificar aceites vegetales y plastificante primario para polimeros de viniloInfo
- Publication number
- AR079616A1 AR079616A1 ARP100104634A ARP100104634A AR079616A1 AR 079616 A1 AR079616 A1 AR 079616A1 AR P100104634 A ARP100104634 A AR P100104634A AR P100104634 A ARP100104634 A AR P100104634A AR 079616 A1 AR079616 A1 AR 079616A1
- Authority
- AR
- Argentina
- Prior art keywords
- alcohol
- reaction
- plastificant
- primary
- vegetable oils
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 235000015112 vegetable and seed oil Nutrition 0.000 title abstract 3
- 239000008158 vegetable oil Substances 0.000 title abstract 3
- 229920002554 vinyl polymer Polymers 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000005809 transesterification reaction Methods 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000004703 alkoxides Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 235000011187 glycerol Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 150000005846 sugar alcohols Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/006—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by oxidation
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/06—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils with glycerol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Fats And Perfumes (AREA)
Abstract
Reivindicacion 1: Proceso para modificar aceite vegetal, caracterizado porque comprende la transesterificacion de al menos un aceite vegetal con al menos un alcohol monohídrico, con un tamano de cadena de más de 3 átomos de carbono, y/o con al menos un alcohol polihídrico de cualquier tipo, siendo catalizado por un alcoxido generado a través de la reaccion de dicho alcohol (o alcoholes) con un metal alcalino. Reivindicacion 30: Proceso, de acuerdo con una de las reivindicaciones 1 a 29, caracterizado porque abarca una etapa de purificacion en la cual, al final de la reaccion de transesterificacion, la glicerina formada es decantada y separada, luego de lo cual la mezcla de reaccion es neutralizada con ácido, lavada y depurada (proceso de eliminacion de alcohol) con vapor de agua y bajo un discreto vacío (de hasta aproximadamente 600 mmHg), a temperaturas que varían desde 120 a 220°C.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/BR2009/000428 WO2011072346A1 (en) | 2009-12-17 | 2009-12-17 | Process for modifying vegetable oils and primary plasticizer for vinyl polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR079616A1 true AR079616A1 (es) | 2012-02-08 |
Family
ID=44166655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP100104634A AR079616A1 (es) | 2009-12-17 | 2010-12-14 | Proceso para modificar aceites vegetales y plastificante primario para polimeros de vinilo |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8802877B2 (es) |
| EP (1) | EP2513276A4 (es) |
| CN (1) | CN102762707B (es) |
| AR (1) | AR079616A1 (es) |
| BR (1) | BR112012014253B1 (es) |
| UY (1) | UY33065A (es) |
| WO (1) | WO2011072346A1 (es) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102010033035A1 (de) * | 2010-08-02 | 2012-02-02 | Emery Oleochemicals Gmbh | Gleitmittelkombination für die Verarbeitung von thermoplastischen Kunststoffen |
| EP2768818B1 (en) * | 2011-10-19 | 2018-12-19 | Archer Daniels Midland Co. | Making epoxidized esters from epoxidized natural fats and oils |
| KR101288437B1 (ko) * | 2011-11-29 | 2013-07-26 | 동구산업(주) | 식물성 기름을 사용하여 제조된 친환경 가소제 및 이의 제조방법 |
| US9499681B2 (en) * | 2012-11-12 | 2016-11-22 | Dow Global Technologies Llc | Epoxidized fatty acid alkyl ester plasticizers and methods for making epoxidized fatty acid alkyl ester plasticizers |
| DE102013203973A1 (de) * | 2013-03-08 | 2014-09-11 | Evonik Industries Ag | Isononylester auf Basis von Fettsäuregemischen aus pflanzlichen Ölen |
| DE102013203972A1 (de) * | 2013-03-08 | 2014-09-11 | Evonik Industries Ag | Isononylester auf Basis von Fettsäuren oder Fettsäuregemischen aus Tallöl oder Leinöl |
| US10113051B2 (en) | 2013-06-03 | 2018-10-30 | Regents Of The University Of Minnesota | Epoxy estolide fatty acid alkyl esters useful as biorenewable plasticizers |
| EP2990470A1 (de) | 2014-08-26 | 2016-03-02 | Evonik Degussa GmbH | Gemische epoxidierter Fettsäureester |
| CN104877170A (zh) * | 2015-04-29 | 2015-09-02 | 苏州乔布注塑工业有限公司 | 一种pvc内润滑剂 |
| CN105085982A (zh) * | 2015-09-07 | 2015-11-25 | 四川大学 | 一种环保耐迁移的环氧脂肪酸环己酯增塑剂及其制备方法 |
| US10144812B2 (en) | 2015-10-05 | 2018-12-04 | Regents Of The University Of Minnesota | Multi-functional fatty acid ester derivatives useful as biorenewable plasticizers |
| CN106519081B (zh) * | 2016-09-22 | 2018-06-26 | 深圳立山环保材料有限公司 | 一种环氧类增塑剂及其制备方法 |
| BE1025186B1 (nl) | 2017-09-27 | 2018-11-26 | Proviron Holding N.V. | Weekmaker samenstelling |
| BE1026295B9 (nl) | 2018-05-22 | 2020-01-14 | Proviron Holding N V | Gebruik van een geëpoxideerde vetzuurester als weekmaker in gehalogeneerde harsen |
| CN109369574A (zh) * | 2018-09-14 | 2019-02-22 | 许昌鑫瑞德化工科技有限公司 | 一种改性动植物油的加工方法 |
| CN110128755A (zh) * | 2019-05-24 | 2019-08-16 | 烟台鑫汇包装有限公司 | 一种气雾剂阀门系统用三元乙丙橡胶密封垫片 |
| KR102669652B1 (ko) | 2019-09-19 | 2024-05-28 | 주식회사 엘지화학 | 에스터화 생성물의 중화/수분리 장치 및 에스터화 생성물의 중화/수분리 방법 |
| KR102614264B1 (ko) | 2019-09-19 | 2023-12-18 | 주식회사 엘지화학 | 에스터화 생성물의 중화/수분리조 및 에스터화 생성물의 중화/수분리 방법 |
| CN110804029B (zh) * | 2019-11-08 | 2022-04-29 | 浙江工业大学 | 一种环氧类增塑剂及其制备方法 |
| CN113817226B (zh) * | 2021-10-12 | 2022-05-10 | 南京工业大学 | 一种高分子复合材料添加剂及其应用 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2559177A (en) | 1950-05-01 | 1951-07-03 | Gen Mills Inc | Plasticized polyvinyl resin compositions |
| US2895966A (en) * | 1954-04-12 | 1959-07-21 | Waldo C Ault | Monoglyceride diacetates |
| US2835966A (en) | 1956-10-01 | 1958-05-27 | Combustion Eng | Method of welding |
| US3070608A (en) | 1958-07-07 | 1962-12-25 | Swift & Co | Selective alcoholysis of epoxy fatty acid esters |
| GB934689A (en) | 1959-04-22 | 1963-08-21 | Swift & Co | Epoxy fatty acid esters and polyvinyl resin compositions containing them |
| US3275584A (en) | 1962-03-22 | 1966-09-27 | Tenneco Chem | Polyvinyl chloride plasticized with the addition products of alpha, beta-unsaturateddicarboxylic esters with epoxidized fatty esters |
| DE2009047C2 (de) | 1970-02-26 | 1982-04-08 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von Epoxystearinsäureestern |
| US5324846A (en) | 1992-01-30 | 1994-06-28 | Elf Atochem North America, Inc. | Partial esters of epoxy containing compounds |
| DE4304468A1 (de) | 1993-02-15 | 1994-08-18 | Henkel Kgaa | Verfahren zur Herstellung hellfarbiger Polyolester |
| DK1183362T3 (da) | 1999-05-25 | 2007-05-07 | Immunex Corp | IL-1- ETA-DNA og -polypeptider |
| CA2273570A1 (en) | 1999-05-31 | 2000-11-30 | Jfs Envirohealth Ltd. | Concentration and purification of polyunsaturated fatty acid esters by distillation-enzymatic transesterification coupling |
| MXPA00011394A (es) * | 2000-11-21 | 2003-03-12 | Resinas Y Materiales S A De C | Proceso mejorado para la obtencion de polioles oleoquimicos. |
| AU778808B2 (en) | 2001-05-31 | 2004-12-23 | Biodiesel Australia Ltd | Method for production of alkyl esters |
| KR20050068297A (ko) | 2003-12-30 | 2005-07-05 | 엘지전자 주식회사 | 원격제어시스템 및 그 제어방법 |
| KR20050088297A (ko) * | 2005-05-27 | 2005-09-05 | 바이오디젤 오스트레일리아 리미티드. | 알킬 에스테르 제조방법 |
| MY144354A (en) * | 2005-11-08 | 2011-09-15 | Malaysian Palm Oil Board Mpob | A process for the production of a polyol monomer |
| EP2574397B1 (en) | 2008-01-24 | 2016-04-13 | PolyOne Corporation | Epoxidized 1,3-propanediol disoyate |
-
2009
- 2009-12-17 BR BR112012014253-4A patent/BR112012014253B1/pt active IP Right Grant
- 2009-12-17 CN CN200980162941.2A patent/CN102762707B/zh not_active Expired - Fee Related
- 2009-12-17 EP EP09852146.1A patent/EP2513276A4/en not_active Withdrawn
- 2009-12-17 WO PCT/BR2009/000428 patent/WO2011072346A1/en not_active Ceased
- 2009-12-17 US US13/516,410 patent/US8802877B2/en active Active
-
2010
- 2010-11-29 UY UY0001033065A patent/UY33065A/es not_active Application Discontinuation
- 2010-12-14 AR ARP100104634A patent/AR079616A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20120289727A1 (en) | 2012-11-15 |
| UY33065A (es) | 2011-07-29 |
| CN102762707B (zh) | 2014-09-24 |
| EP2513276A4 (en) | 2016-09-07 |
| US8802877B2 (en) | 2014-08-12 |
| BR112012014253A2 (pt) | 2017-07-25 |
| EP2513276A1 (en) | 2012-10-24 |
| WO2011072346A1 (en) | 2011-06-23 |
| BR112012014253B1 (pt) | 2019-11-19 |
| CN102762707A (zh) | 2012-10-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |