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AR079401A1 - REPLACED CYANOBUTIRATES WITH HERBICITY ACTION - Google Patents

REPLACED CYANOBUTIRATES WITH HERBICITY ACTION

Info

Publication number
AR079401A1
AR079401A1 ARP100102499A AR079401A1 AR 079401 A1 AR079401 A1 AR 079401A1 AR P100102499 A ARP100102499 A AR P100102499A AR 079401 A1 AR079401 A1 AR 079401A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
alkoxy
groups
haloalkoxy
Prior art date
Application number
Other languages
Spanish (es)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR079401A1 publication Critical patent/AR079401A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/41—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by carboxyl groups, other than cyano groups
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/57—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Reivindicacion 1: Un compuesto de cianobutirato caracterizado porque tiene la formula (1), en donde las variables tienen el siguiente significado: R es halogeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alquenilo C2-6, alquinilo C2-6, alcoxi C1-4, haloalcoxi C1-4, S(O)xRaa, Z-tri(alquil C1-4)sililo; x es 0, 1 o 2; Raa es alquilo C1-4, haloalquilo C1-4, alquenilo C2-6, alquinilo C2-6; R1 es haloalquilo C1-8, bencilo, fenilo, en donde los grupos aromáticos pueden ser no sustituidos o parcial o totalmente sustituidos con los grupos Ra y/o Rb, Ra es OH, alquilo C1-8, haloalquilo C1-4, Z-cicloalquilo C3-6, alquenilo C2-8, Z-cicloalquenilo C5-6, alquinilo C2-8, Z-alcoxi C1-6, Z-haloalcoxi C1-4, Z-alqueniloxi C3-8, Z-alquiniloxi C3-8, NRiRii, alquilsulfonilo C1-6, Z-(tri-alquil C1-4)sililo, Z-fenilo, Z-fenoxi, Z-fenilamino o un heterociclo monocíclico de 5 o 6 miembros o bicíclico de 9 o 10 miembros, que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S, en donde los grupos cíclicos son no sustituidos o sustituidos con 1, 2, 3 o 4 grupos Rb; Ri, Rii independientemente entre sí, son hidrogeno, alquilo C1-8, haloalquilo C1-4, alquenilo C3-8, alquinilo C3-8, Z-cicloalquilo C3-6, Z-alcoxi C1-8, Z-haloalcoxi C1-8, Z-C(=O)-RA, en donde RA es OH o alcoxi C1-4; Ri y Rii, junto con el átomo de nitrogeno al que están unidos, también pueden formar un heterociclo monocíclico de 5 o 6 miembros o bicíclico de 9 o 10 miembros, que contiene 1, 2, 3 o 4 heteroátomos seleccionados del grupo que consiste en O, N y S; Rb independientemente entre sí, son Z-CN, Z-OH, Z-NO2, Z-halogeno, alquilo C1-8, haloalquilo C1-4, alquenilo C2-8, alquinilo C2-8, Z-alcoxi C1-8, Z-haloalcoxi C1-8, Z-cicloalquilo C3-10, O-Z-cicloalquilo C3-10, Z-C(=O)-Ra, NRiRii, Z-(tri-alquil C1-4)sililo, Z-fenilo y S(O)xRbb, en donde Rbb es alquilo C1-8 o haloalquilo C1-6; Rb, junto con el grupo Rb unido al átomo de carbono adyacente, también puede formar un anillo saturado o parcial o totalmente insaturado de 5 o 6 miembros que, además de átomos de carbono, puede contener 1, 2 o 3 heteroátomos seleccionados del grupo que consiste en O, N y S; Z es un enlace covalente o alquileno C1-8; R2 es halogeno, ciano, nitro, alquilo C1-4, alcoxi C1-4, S(O)xRbb, NRiRii, haloalquilo C1-4, haloalcoxi C1-4; m, n independientemente entre sí, son 0, 1, 2, 3, 4 o 5; en donde en los grupos R, R1 y R2 y sus subsustituyentes, las cadenas de carbono y/o los grupos cíclicos pueden ser parcial o totalmente sustituidos con grupos Ra y/o Rb, siempre que R1 no sea bencilo no sustituido, si Rn es 4-F y (R2)m es 3-F; o un N-oxido o una sal de aquél adecuados en la agricultura.Claim 1: A cyanobutyrate compound characterized in that it has the formula (1), wherein the variables have the following meaning: R is halogen, cyano, nitro, C1-4 alkyl, C1-4 haloalkyl, C2-6 alkenyl, C2 alkynyl -6, C1-4 alkoxy, C1-4 haloalkoxy, S (O) xRaa, Z-tri (C1-4 alkyl) silyl; x is 0, 1 or 2; Raa is C1-4 alkyl, C1-4 haloalkyl, C2-6 alkenyl, C2-6 alkynyl; R1 is C1-8 haloalkyl, benzyl, phenyl, wherein the aromatic groups may be unsubstituted or partially or totally substituted with the groups Ra and / or Rb, Ra is OH, C1-8 alkyl, C1-4 haloalkyl, Z- C3-6 cycloalkyl, C2-8 alkenyl, Z5-6 cycloalkenyl, C2-8 alkynyl, Z-6-6 alkoxy, Z4-4 haloalkoxy, Z3-8 alkenyloxy, C3-8 alkyloxy, NRiRii, C 1-6 alkylsulfonyl, Z- (tri-C 1-4 alkyl) silyl, Z-phenyl, Z-phenoxy, Z-phenylamino or a 5- or 6-membered monocyclic heterocycle or 9 or 10-membered bicyclic, containing 1 , 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S, where the cyclic groups are unsubstituted or substituted with 1, 2, 3 or 4 Rb groups; Ri, Rii independently of each other, are hydrogen, C1-8 alkyl, C1-4 haloalkyl, C3-8 alkenyl, C3-8 alkynyl, Z3-6 cycloalkyl, Z- C1-8 alkoxy, C1-8 haloalkoxy , ZC (= O) -RA, where RA is OH or C1-4 alkoxy; Ri and Rii, together with the nitrogen atom to which they are attached, can also form a 5- or 6-membered monocyclic heterocyclic or 9 or 10-membered bicyclic heterocycle, containing 1, 2, 3 or 4 heteroatoms selected from the group consisting of O, N and S; Rb independently of each other, are Z-CN, Z-OH, Z-NO2, Z-halogen, C1-8 alkyl, C1-4 haloalkyl, C2-8 alkenyl, C2-8 alkynyl, Z- C1-8 alkoxy, Z C1-8 haloalkoxy, C3-10 Z-cycloalkyl, OZ C3-10 cycloalkyl, ZC (= O) -Ra, NRiRii, Z- (tri-C 1-4 alkyl) silyl, Z-phenyl and S (O) xRbb, wherein Rbb is C1-8 alkyl or C1-6 haloalkyl; Rb, together with the group Rb attached to the adjacent carbon atom, can also form a saturated or partially or totally unsaturated ring of 5 or 6 members which, in addition to carbon atoms, can contain 1, 2 or 3 heteroatoms selected from the group that consists of O, N and S; Z is a covalent bond or C1-8 alkylene; R2 is halogen, cyano, nitro, C1-4 alkyl, C1-4 alkoxy, S (O) xRbb, NRiRii, C1-4 haloalkyl, C1-4 haloalkoxy; m, n independently of each other, are 0, 1, 2, 3, 4 or 5; wherein in the R, R1 and R2 groups and their substituents, the carbon chains and / or the cyclic groups may be partially or totally substituted with Ra and / or Rb groups, provided that R1 is not unsubstituted benzyl, if Rn is 4-F and (R2) m is 3-F; or an N-oxide or a salt thereof suitable in agriculture.

ARP100102499 2009-07-09 2010-07-08 REPLACED CYANOBUTIRATES WITH HERBICITY ACTION AR079401A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09165071 2009-07-09
EP09180018 2009-12-18

Publications (1)

Publication Number Publication Date
AR079401A1 true AR079401A1 (en) 2012-01-25

Family

ID=43242373

Family Applications (2)

Application Number Title Priority Date Filing Date
ARP100102499 AR079401A1 (en) 2009-07-09 2010-07-08 REPLACED CYANOBUTIRATES WITH HERBICITY ACTION
ARP100102498 AR079400A1 (en) 2009-07-09 2010-07-08 CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT

Family Applications After (1)

Application Number Title Priority Date Filing Date
ARP100102498 AR079400A1 (en) 2009-07-09 2010-07-08 CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT

Country Status (4)

Country Link
AR (2) AR079401A1 (en)
TW (2) TW201105235A (en)
UY (2) UY32779A (en)
WO (1) WO2011003776A2 (en)

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RU2004106631A (en) 2001-08-09 2005-05-10 Нортвест Плант Бридинг Компани (Us) WHEAT PLANTS WITH HIGH RESISTANCE TO IMIDOSALINE HERBICIDES
US7230167B2 (en) 2001-08-31 2007-06-12 Syngenta Participations Ag Modified Cry3A toxins and nucleic acid sequences coding therefor
WO2003052073A2 (en) 2001-12-17 2003-06-26 Syngenta Participations Ag Novel corn event
EP1551218B1 (en) 2002-07-10 2017-05-17 The Department of Agriculture, Western Australia Wheat plants having increased resistance to imidazolinone herbicides
US9382526B2 (en) 2003-05-28 2016-07-05 Basf Aktiengesellschaft Wheat plants having increased tolerance to imidazolinone herbicides
UY38692A (en) 2003-08-29 2020-06-30 Instituto Nac De Tecnologia Agropecuaria METHOD TO CONTROL WEEDS IN RICE PLANTS WITH INCREASED TOLERANCE FOR THE HERBICIDE IMIDAZOLINONE AND SULFONYLURÉA
GB0625598D0 (en) 2006-12-21 2007-01-31 Syngenta Ltd Novel herbicides

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WO2011003776A2 (en) 2011-01-13

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