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AR079400A1 - CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT - Google Patents

CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT

Info

Publication number
AR079400A1
AR079400A1 ARP100102498A AR079400A1 AR 079400 A1 AR079400 A1 AR 079400A1 AR P100102498 A ARP100102498 A AR P100102498A AR 079400 A1 AR079400 A1 AR 079400A1
Authority
AR
Argentina
Prior art keywords
alkyl
haloalkyl
groups
alkynyl
cycloalkyl
Prior art date
Application number
Other languages
Spanish (es)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR079400A1 publication Critical patent/AR079400A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/41—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by carboxyl groups, other than cyano groups
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/34—Nitriles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/26—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings
    • A01N43/28—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3
    • A01N43/30—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms five-membered rings with two hetero atoms in positions 1,3 with two oxygen atoms in positions 1,3, condensed with a carbocyclic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
    • C07C255/57—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Dentistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

Reivindicacion 1: Cianobutiratos caracterizados porque tienen la formula (1), donde las variables tienen los siguientes significados: R es halogeno, ciano, nitro, alquilo C1-4, haloalquilo C1-4, alquenilo C2-6, alquinilo C2-6, Z-(tri-alquil C1-4)sililo; R1 es hidrogeno, Z-CN, alquilo C1-8, Z-cicloalquilo C3-6, haloalquilo C1-8, alquenilo C3-8, Z-cicloalquenilo C3-6, alquinilo C3-8, Z(tri-alquil C1-4)sililo, Z-C(=O)Ra, Z-P(=O)(Ra)2, Z-fenilo, heterociclo saturado, no saturado o aromático, monocíclico de 3 a 7 miembros o bicíclico de 9 o 10 miembros, ligado por medio de C o N, que contiene 1, 2, 3 o 4 heteroátomos seleccionados entre O, N y S, que puede estar parcial o completamente sustituido por grupos Ra y/o Rb; Ra es hidrogeno, OH, alquilo C1-8, haloalquilo C1-4, Z-cicloalquilo C3-6, alquenilo C2-8, Z-cicloalquenilo C5-6, alquinilo C2-8, Z-alcoxi C1-6, Z-haloalcoxi C1-4, Z-alqueniloxi C3-8, Z-alquiniloxi C3-8, NRiRii, alquilsulfonilo C1-6, Z-(tri-alquil C1-4)sililo, Z-fenilo, Z-fenoxi, Z-fenilamino y heterociclo monocíclico de 5 o 6 miembros o bicíclico de 9 o 10 miembros, que contiene 1, 2, 3 o 4 heteroátomos seleccionados entre O, N y S, estando los grupos cíclicos no sustituidos o sustituidos por 1, 2, 3 o 4 grupos Rb; Ri, Rii significan, independientemente entre si, hidrogeno, alquilo C1-8, haloalquilo C1-4, alquenilo C3-8, alquinilo C3-8, Z-cicloalquilo C3-6, Z-alcoxi C1-8, Z-haloalcoxi C1-8, Z-C(=O)-RA, donde RA es OH o alcoxi C1-8; Ri y Rii también pueden formar conjuntamente con el átomo de N al que están ligados, un heterociclo monocíclico de 5 o 6 miembros o bicíclico de 9 o 10 miembros, que contiene 1, 2, 3 o 4 heteroátomos seleccionados entre O, N y S; Rb significan, independientemente entre si, Z-CN, Z-OH, Z-NO2, Z-halogeno, alquilo C1-8, haloalquilo C1-4, alquenilo C2-8, alquinilo C2-8, Z-alcoxi C1-8, Z-haloalcoxi C1-8, Z-cicloalquilo C3-10, O-Z-cicloalquilo C3-10, Z-C(=O)-Ra, NRiRii, Z-(tri-alquil C1-4)sililo, Z-fenilo y S(O)mRbb, donde Rbb es alquilo C1-8 y haloalquilo C1-6; m es 0, 1 o 2; Rb también puede formar conjuntamente con el grupo enlazado con el átomo de C vecino Rb un anillo saturado, parcialmente o completamente insaturado de cinco o seis miembros, que puede contener además de átomos de carbono 1, 2 o 3 heteroátomos seleccionados entre O, N y S; Z es un enlace covalente o alquileno C1-8; n es 0, 1, 2, 3, 4 o 5; R2, R3 significan, independientemente entre si, halogeno, ciano, nitro, alquilo C1-4, alcoxi C1-4, S(O)mRbb, NRiRii, halogenoalquilo C1-4, halogenoalcoxi C1-4; R2 y R3 también pueden formar juntos un anillo mono o bicíclico, parcial o completamente insaturado, de cinco o seis miembros, que además de átomos de carbono puede contener 1, 2 o 3 heteroátomos seleccionados de entre O, N y S, y que puede estar sustituido por grupos Rb; pudiendo los grupos R y R1 y sus sub-sustituyentes las cadenas de carbono y/o los grupos cíclicos estar parcial o completamente sustituidos por grupos Ra y/o Rb, siendo preciso que los dos radicales R2 y R3 no signifiquen ambos cloro cuando R es hidrogeno y R1 etilo o alilo; así como sus N-oxidos y sales apropiadas en la agricultura.Claim 1: Cyanobutyrates characterized in that they have the formula (1), wherein the variables have the following meanings: R is halogen, cyano, nitro, C1-4 alkyl, C1-4 haloalkyl, C2-6 alkenyl, C2-6 alkynyl, Z - (tri-C 1-4 alkyl) silyl; R1 is hydrogen, Z-CN, C1-8 alkyl, Z3-6 cycloalkyl, C1-8 haloalkyl, C3-8 alkenyl, Z3-6 cycloalkenyl, C3-8 alkynyl, Z (C1-4 tri-alkyl ) silyl, ZC (= O) Ra, ZP (= O) (Ra) 2, Z-phenyl, saturated, unsaturated or aromatic heterocycle, 3-7 membered monocyclic or 9 or 10 membered bicyclic, linked by C or N, which contains 1, 2, 3 or 4 heteroatoms selected from O, N and S, which may be partially or completely substituted by Ra and / or Rb groups; Ra is hydrogen, OH, C1-8 alkyl, C1-4 haloalkyl, Z3-6 cycloalkyl, C2-8 alkenyl, C5-6 Z-cycloalkenyl, C2-8 alkynyl, Z- C1-6 alkoxy, Z-haloalkoxy C1-4, Z3-8 alkenyloxy, C3-8 alkynyloxy, NRiRii, C1-6 alkylsulfonyl, Z- (tri-C1-4 alkyl) silyl, Z-phenyl, Z-phenoxy, Z-phenylamino and heterocycle monocyclic of 5 or 6 members or bicyclic of 9 or 10 members, containing 1, 2, 3 or 4 heteroatoms selected from O, N and S, the cyclic groups being unsubstituted or substituted by 1, 2, 3 or 4 Rb groups ; Ri, Rii means, independently of each other, hydrogen, C1-8 alkyl, C1-4 haloalkyl, C3-8 alkenyl, C3-8 alkynyl, Z3-6 cycloalkyl, Z- C1-8 alkoxy, Z-haloalkoxy C1- 8, ZC (= O) -RA, where RA is OH or C1-8 alkoxy; Ri and Rii can also form together with the N atom to which they are linked, a 5 or 6 membered monocyclic heterocyclic or 9 or 10 membered bicyclic heterocycle, containing 1, 2, 3 or 4 heteroatoms selected from O, N and S ; Rb means, independently of each other, Z-CN, Z-OH, Z-NO2, Z-halogen, C1-8 alkyl, C1-4 haloalkyl, C2-8 alkenyl, C2-8 alkynyl, Z- C1-8 alkoxy, Z-haloalkoxy C1-8, Z-cycloalkyl C3-10, OZ-cycloalkyl C3-10, ZC (= O) -Ra, NRiRii, Z- (tri-alkyl C1-4) silyl, Z-phenyl and S (O ) mRbb, where Rbb is C1-8 alkyl and C1-6 haloalkyl; m is 0, 1 or 2; Rb may also form together with the group linked to the neighboring C atom Rb a saturated ring, partially or completely unsaturated of five or six members, which may contain in addition to carbon atoms 1, 2 or 3 heteroatoms selected from O, N and S; Z is a covalent bond or C1-8 alkylene; n is 0, 1, 2, 3, 4 or 5; R2, R3 means, independently of each other, halogen, cyano, nitro, C1-4 alkyl, C1-4 alkoxy, S (O) mRbb, NRiRii, C1-4 halogenoalkyl, C1-4 halogenoalkoxy; R2 and R3 can also together form a mono or bicyclic ring, partially or completely unsaturated, of five or six members, which in addition to carbon atoms can contain 1, 2 or 3 heteroatoms selected from O, N and S, and which can be substituted by Rb groups; the R and R1 groups and their substituents may be the carbon chains and / or the cyclic groups being partially or completely substituted by Ra and / or Rb groups, it being necessary that the two radicals R2 and R3 do not mean both chlorine when R is hydrogen and R1 ethyl or allyl; as well as its appropriate N-oxides and salts in agriculture.

ARP100102498 2009-07-09 2010-07-08 CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT AR079400A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09165071 2009-07-09
EP09180018 2009-12-18

Publications (1)

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AR079400A1 true AR079400A1 (en) 2012-01-25

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ARP100102499 AR079401A1 (en) 2009-07-09 2010-07-08 REPLACED CYANOBUTIRATES WITH HERBICITY ACTION
ARP100102498 AR079400A1 (en) 2009-07-09 2010-07-08 CYANOBUTIRATES REPLACED WITH HERBICIDE EFFECT

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AR (2) AR079401A1 (en)
TW (2) TW201105235A (en)
UY (2) UY32779A (en)
WO (1) WO2011003776A2 (en)

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CA2407396C (en) 2000-04-28 2013-12-31 Basf Aktiengesellschaft Use of the maize x112 mutant ahas 2 gene and imidazolinone herbicides for selection of transgenic monocots
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WO2002015701A2 (en) 2000-08-25 2002-02-28 Syngenta Participations Ag Bacillus thuringiensis crystal protein hybrids
WO2003014356A1 (en) 2001-08-09 2003-02-20 University Of Saskatchewan Wheat plants having increased resistance to imidazolinone herbicides
AR036336A1 (en) 2001-08-09 2004-09-01 Univ Saskatchewan A WHEAT PLANT THAT INCLUDES NUCLEIC ACIDS, A PLANT PART, A PLANT CELL., A SEED PRODUCED BY THE PLANT, AN IMI ISOLATED NUCLEIC ACID, A METHOD FOR CONTROLLING THE WEEDS, A METHOD TO MODIFY THE TOLERANCE AND PLASTERS A METHOD TO PRODUCE A TRANSGE PLANT
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US7230167B2 (en) 2001-08-31 2007-06-12 Syngenta Participations Ag Modified Cry3A toxins and nucleic acid sequences coding therefor
WO2003052073A2 (en) 2001-12-17 2003-06-26 Syngenta Participations Ag Novel corn event
EP1551218B1 (en) 2002-07-10 2017-05-17 The Department of Agriculture, Western Australia Wheat plants having increased resistance to imidazolinone herbicides
US9382526B2 (en) 2003-05-28 2016-07-05 Basf Aktiengesellschaft Wheat plants having increased tolerance to imidazolinone herbicides
UY38692A (en) 2003-08-29 2020-06-30 Instituto Nac De Tecnologia Agropecuaria METHOD TO CONTROL WEEDS IN RICE PLANTS WITH INCREASED TOLERANCE FOR THE HERBICIDE IMIDAZOLINONE AND SULFONYLURÉA
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UY32779A (en) 2011-01-31
TW201105235A (en) 2011-02-16
WO2011003776A2 (en) 2011-01-13

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