AR076841A1 - Derivados de triazol-sustituidos, procesos para su preparacion y metodos de uso en el control de plagas - Google Patents
Derivados de triazol-sustituidos, procesos para su preparacion y metodos de uso en el control de plagasInfo
- Publication number
- AR076841A1 AR076841A1 ARP100101525A ARP100101525A AR076841A1 AR 076841 A1 AR076841 A1 AR 076841A1 AR P100101525 A ARP100101525 A AR P100101525A AR P100101525 A ARP100101525 A AR P100101525A AR 076841 A1 AR076841 A1 AR 076841A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- phenyl
- nonafluorbut
- alkoxy
- triazol
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 4
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 abstract 2
- -1 2-ethyl-6-methyl-4- (nonafluorbut-2-yl) phenyl Chemical group 0.000 abstract 2
- 125000004453 alkoxycarbonyl group Chemical group 0.000 abstract 2
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 1
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241000237852 Mollusca Species 0.000 abstract 1
- 150000001204 N-oxides Chemical class 0.000 abstract 1
- 241000244206 Nematoda Species 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 241000607479 Yersinia pestis Species 0.000 abstract 1
- 230000000895 acaricidal effect Effects 0.000 abstract 1
- 125000003668 acetyloxy group Chemical group [H]C([H])([H])C(=O)O[*] 0.000 abstract 1
- 125000004414 alkyl thio group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 230000000749 insecticidal effect Effects 0.000 abstract 1
- 239000000543 intermediate Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000002013 molluscicidal effect Effects 0.000 abstract 1
- 125000002911 monocyclic heterocycle group Chemical group 0.000 abstract 1
- 230000001069 nematicidal effect Effects 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Chemical group 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C237/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups
- C07C237/28—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton
- C07C237/44—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by amino groups having the carbon atom of at least one of the carboxamide groups bound to a carbon atom of a non-condensed six-membered aromatic ring of the carbon skeleton having carbon atoms of carboxamide groups, amino groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
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- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
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- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/82—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with three ring hetero atoms
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/49—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
- C07C255/57—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and carboxyl groups, other than cyano groups, bound to the carbon skeleton
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
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- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C317/00—Sulfones; Sulfoxides
- C07C317/44—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton
- C07C317/46—Sulfones; Sulfoxides having sulfone or sulfoxide groups and carboxyl groups bound to the same carbon skeleton the carbon skeleton being further substituted by singly-bound oxygen atoms
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- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
- C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
- C07C323/62—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atom of at least one of the thio groups bound to a carbon atom of a six-membered aromatic ring of the carbon skeleton
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
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- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
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Abstract
La presente se refiere derivados triazol-sustituidos, a procedimientos e intermediarios para prepararlos, a métodos de uso de los mismos para el control de plagas de insectos, ácaros, nematodos y moluscos, y a composiciones insecticidas, acaricidas, nematicidas y moluscicidas que los comprenden. Reivindicacion 1: Un compuesto de la formula (1) en la cual Q1 es arilo o heterociclilo, cada uno de los cuales está opcionalmente sustituido con uno a cinco sustituyentes R3, que pueden ser iguales o diferentes; Q2 se selecciona entre 2-etil-6-metil-4-(nonafluorbut-2-il)fenilo, 2-bromo-6-cloro-4-(nonafluorbut-2-iI)fenilo, 2,6-dicloro-4-(nonafluor-but-2-iI)fenilo, 2,6-dimetil-4-(nonafluor-but-2-iI)fenilo, 2-cloro-6-metoximetil-4-(nonafluorbut-2-il)fenilo, y 2-bromo-6-metoximetil-4-(nonafluorbut-2-iI)fenilo; R1 se selecciona entre hidrogeno, alquilo C1-8, alquilcarbonilo C1-8, alcoxicarbonilo C1-8 y alquil C1-4-C(O)NH2; R2 se selecciona entre hidrogeno, alquilo C1-8, alquilcarbonilo C1-8, alcoxicarbonilo C1-8 y alquil C1-4-C(O)NH2; y R3 se selecciona entre ciano, nitro, halogeno, hidroxilo, acetoxi, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alquiltio C1-4, alcoxi C1-4-alquilo C1-4, alcoxi C1-4-alcoxi C1-4, CN-alquilo C1-4, alquil C1-4-C(O)O, alquil C1-4-S(O)2, NH2, alquil C1-4NH, (alquil C1-4)2N, (alquil C1-4O)2P(O)O, fenilo y un heterociclo monocíclico de cinco a seis miembros que contiene de 1 a 3 heteroátomos seleccionados independientemente entre nitrogeno, oxígeno y azufre; o una sal agroquímicamente aceptable o los N-oxidos del mismo.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0907824A GB0907824D0 (en) | 2009-05-06 | 2009-05-06 | Insecticidal compounds |
| EP10150814 | 2010-01-15 |
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| Publication Number | Publication Date |
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| AR076841A1 true AR076841A1 (es) | 2011-07-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| ARP100101525A AR076841A1 (es) | 2009-05-06 | 2010-05-05 | Derivados de triazol-sustituidos, procesos para su preparacion y metodos de uso en el control de plagas |
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| Country | Link |
|---|---|
| US (1) | US20120295907A1 (es) |
| EP (2) | EP2427426B1 (es) |
| JP (2) | JP5823951B2 (es) |
| KR (1) | KR20120007070A (es) |
| CN (2) | CN102414170B (es) |
| AR (1) | AR076841A1 (es) |
| AU (2) | AU2010244581B2 (es) |
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| SA (2) | SA114350251B1 (es) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2012320779B8 (en) | 2011-10-03 | 2015-10-29 | Syngenta Participations Ag | Insecticidal 2-methoxybenzamide derivatives |
| WO2013092942A1 (en) | 2011-12-21 | 2013-06-27 | Syngenta Participations Ag | Use of aminobenzamide derivatives for controlling animal parasites |
| WO2013191041A1 (ja) * | 2012-06-22 | 2013-12-27 | 住友化学株式会社 | アミド化合物及びその有害生物防除用途 |
| WO2014067838A1 (en) | 2012-10-31 | 2014-05-08 | Syngenta Participations Ag | Insecticidal compounds |
| JP6352389B2 (ja) * | 2013-04-02 | 2018-07-04 | シンジェンタ パーティシペーションズ アーゲー | パーハロアルキル基を含有するヒンダードアニリンからのアミドの製造方法 |
| EP2981523B1 (en) * | 2013-04-02 | 2021-05-19 | Syngenta Participations AG | Insecticidal compounds |
| CN105102433B (zh) | 2013-04-02 | 2017-12-15 | 先正达参股股份有限公司 | 杀虫化合物 |
| EP3087052B1 (en) * | 2013-12-23 | 2019-11-20 | Syngenta Participations AG | Insecticidal compounds |
| WO2016168059A1 (en) * | 2015-04-17 | 2016-10-20 | Dow Agrosciences Llc | Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto |
| CA3007468C (en) * | 2015-12-18 | 2020-04-14 | Mitsui Chemicals Agro, Inc. | Method of producing aromatic amide derivative |
| ES2977285T3 (es) * | 2016-10-12 | 2024-08-21 | Corteva Agriscience Llc | Composición que comprende una molécula con utilidad plaguicida |
| CN112105599B (zh) * | 2018-05-11 | 2023-05-12 | 广西思钺生物科技有限责任公司 | 一种苯甲酰胺类化合物及其应用 |
| WO2020200290A1 (zh) * | 2019-04-02 | 2020-10-08 | 沈阳化工大学 | 一种间二酰胺类化合物及其应用 |
| US20250185649A1 (en) * | 2022-02-14 | 2025-06-12 | Exxonmobil Chemical Patents Inc. | Agricultural chemical formulation |
Family Cites Families (13)
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| AU731777B2 (en) | 1998-11-30 | 2001-04-05 | Nihon Nohyaku Co., Ltd. | Aniline derivative and process for producing the same |
| CN100554249C (zh) * | 2003-08-29 | 2009-10-28 | 三井化学株式会社 | 农园艺用杀虫剂及其使用方法 |
| CA2554437C (en) | 2004-01-28 | 2011-06-21 | Mitsui Chemicals, Inc. | Amide derivatives, process for preparation thereof and use thereof as insecticide |
| JP2006306771A (ja) | 2005-04-28 | 2006-11-09 | Mitsui Chemicals Inc | 農園芸用殺虫剤 |
| JP5149003B2 (ja) | 2005-06-21 | 2013-02-20 | 三井化学アグロ株式会社 | アミド誘導体ならびに該化合物を含有する殺虫剤 |
| TW200740370A (en) | 2005-06-23 | 2007-11-01 | Mitsui Chemicals Inc | Amide derivative, pesticide containing such compound and use thereof |
| JP4580836B2 (ja) * | 2005-07-25 | 2010-11-17 | 三井化学アグロ株式会社 | 殺虫殺菌組成物 |
| JP2007031395A (ja) | 2005-07-29 | 2007-02-08 | Bayer Cropscience Ag | 殺虫性3−アシルアミノベンズアニリド類 |
| GB0612713D0 (en) * | 2006-06-27 | 2006-08-09 | Syngenta Participations Ag | Insecticidal compounds |
| EA016685B1 (ru) | 2006-12-21 | 2012-06-29 | Синджента Партисипейшнс Аг | Инсектицидные соединения |
| GB0720320D0 (en) | 2007-10-17 | 2007-11-28 | Syngenta Participations Ag | Insecticidal compounds |
| EP2072501A1 (en) * | 2007-12-21 | 2009-06-24 | Bayer CropScience AG | Aminobenzamide derivatives as useful agents for controlling animal parasites |
| WO2010018714A1 (ja) * | 2008-08-13 | 2010-02-18 | 三井化学アグロ株式会社 | アミド誘導体、該アミド誘導体を含有する有害生物防除剤およびその使用方法 |
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- 2010-04-14 EP EP10713464.5A patent/EP2427426B1/en not_active Not-in-force
- 2010-04-14 EP EP18155187.0A patent/EP3339286A1/en not_active Withdrawn
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- 2010-04-14 US US13/318,978 patent/US20120295907A1/en not_active Abandoned
- 2010-04-14 CN CN201080019742.9A patent/CN102414170B/zh not_active Expired - Fee Related
- 2010-04-14 EA EA201101588A patent/EA020296B1/ru not_active IP Right Cessation
- 2010-04-14 MA MA34400A patent/MA33328B1/fr unknown
- 2010-04-14 BR BRPI1013941A patent/BRPI1013941B1/pt not_active IP Right Cessation
- 2010-04-14 CN CN201710079573.1A patent/CN106749129A/zh active Pending
- 2010-04-14 MX MX2011011394A patent/MX2011011394A/es active IP Right Grant
- 2010-04-14 KR KR1020117028706A patent/KR20120007070A/ko not_active Ceased
- 2010-05-03 SA SA114350251A patent/SA114350251B1/ar unknown
- 2010-05-03 SA SA110310347A patent/SA110310347B1/ar unknown
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- 2010-05-05 AR ARP100101525A patent/AR076841A1/es unknown
- 2010-05-06 UY UY0001032614A patent/UY32614A/es not_active Application Discontinuation
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| CR20110572A (es) | 2011-11-07 |
| BRPI1013941A2 (pt) | 2016-04-05 |
| MX2011011394A (es) | 2011-11-18 |
| EA201101588A1 (ru) | 2012-05-30 |
| EP3339286A1 (en) | 2018-06-27 |
| CN102414170B (zh) | 2017-03-22 |
| JP6080917B2 (ja) | 2017-02-15 |
| JP2016026143A (ja) | 2016-02-12 |
| SA114350251B1 (ar) | 2015-08-26 |
| AU2015238928B2 (en) | 2017-03-16 |
| TW201105234A (en) | 2011-02-16 |
| CN106749129A (zh) | 2017-05-31 |
| UY32614A (es) | 2010-12-31 |
| BRPI1013941B1 (pt) | 2018-11-13 |
| EP2427426A1 (en) | 2012-03-14 |
| CL2011002738A1 (es) | 2012-04-27 |
| AU2010244581A1 (en) | 2011-11-03 |
| CN102414170A (zh) | 2012-04-11 |
| AU2015238928A1 (en) | 2015-10-29 |
| AU2010244581B2 (en) | 2015-09-17 |
| EP2427426B1 (en) | 2018-02-07 |
| JP2012526066A (ja) | 2012-10-25 |
| JP5823951B2 (ja) | 2015-11-25 |
| EA020296B1 (ru) | 2014-10-30 |
| US20120295907A1 (en) | 2012-11-22 |
| WO2010127928A1 (en) | 2010-11-11 |
| SA110310347B1 (ar) | 2015-04-15 |
| CO6450638A2 (es) | 2012-05-31 |
| MA33328B1 (fr) | 2012-06-01 |
| CA2759592A1 (en) | 2010-11-11 |
| KR20120007070A (ko) | 2012-01-19 |
| ZA201107522B (en) | 2012-06-27 |
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