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AR065807A1 - Procedimiento para preparar acido formico - Google Patents

Procedimiento para preparar acido formico

Info

Publication number
AR065807A1
AR065807A1 ARP080101174A ARP080101174A AR065807A1 AR 065807 A1 AR065807 A1 AR 065807A1 AR P080101174 A ARP080101174 A AR P080101174A AR P080101174 A ARP080101174 A AR P080101174A AR 065807 A1 AR065807 A1 AR 065807A1
Authority
AR
Argentina
Prior art keywords
formic acid
moieties
ammonium formate
primary
carbon atoms
Prior art date
Application number
ARP080101174A
Other languages
English (en)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR065807A1 publication Critical patent/AR065807A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/60—Reduction reactions, e.g. hydrogenation
    • B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
    • B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0202—Alcohols or phenols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0237—Amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0271—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds also containing elements or functional groups covered by B01J31/0201 - B01J31/0231
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Un procedimiento para preparar ácido formico, en el que la hidrogenacion catalítica de dioxido de carbono con hidrogeno en un catalizador que comprende un metal de los grupos 8 a 10 de la tabla periodica, en presencia de aminas primarias,secundarias y/o terciarias genera el formiato de amonio correspondiente y el formiato de amonio se desdobla por calentamiento para formar acido formico y la amina, que comprende seleccionar la amina primaria, secundaria o terciaria de entre aminasde formula 1 o mezclas de estas en la que R1 a R3 son iguales o diferentes y representan cada uno hidrogeno, restos alquilo lineales o ramificados que tienen de 1 a 18 átomos de carbono, restos cicloalifáticos que tienen de 5 a 7 átomos de carbono,restos arilo y/o restos arilalquilo, y por lo menos uno de los restos R1 a R3 porta un grupo hidroxilo, y llevar a cabo la hidrogenacion en un disolvente que tiene un punto de ebullicion >= 105°C a presion normal, y obtener el acido formico en lamezcla de reaccion que comprende el disolvente de alto punto de ebullicion mediante desdoblamiento térmico del formiato de amonio y separacion por destilacion del ácido formico.
ARP080101174A 2007-03-23 2008-03-19 Procedimiento para preparar acido formico AR065807A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP07104745 2007-03-23

Publications (1)

Publication Number Publication Date
AR065807A1 true AR065807A1 (es) 2009-07-01

Family

ID=39469940

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP080101174A AR065807A1 (es) 2007-03-23 2008-03-19 Procedimiento para preparar acido formico

Country Status (10)

Country Link
US (1) US20100063320A1 (es)
EP (1) EP2139837A1 (es)
JP (1) JP2010521533A (es)
KR (1) KR20090123972A (es)
CN (1) CN101663259A (es)
AR (1) AR065807A1 (es)
BR (1) BRPI0809156A2 (es)
CA (1) CA2681508A1 (es)
NO (1) NO20093037L (es)
WO (1) WO2008116799A1 (es)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20120047239A (ko) * 2009-06-26 2012-05-11 바스프 에스이 포름산의 제조 방법
UA104324C2 (ru) * 2009-06-26 2014-01-27 Басф Се Способ получения муравьиной кислоты
US8877965B2 (en) 2010-06-29 2014-11-04 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
US8901350B2 (en) 2010-06-29 2014-12-02 Basf Se Process for the preparation of formic acid
JP2013533869A (ja) 2010-06-29 2013-08-29 ビーエーエスエフ ソシエタス・ヨーロピア ギ酸の製造方法
US8791297B2 (en) 2010-06-29 2014-07-29 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
SG186045A1 (en) 2010-06-29 2013-01-30 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
CA2802927A1 (en) * 2010-06-29 2012-01-05 Basf Se Process for preparing formic acid by reaction of carbon dioxide with hydrogen
WO2012034991A1 (de) * 2010-09-17 2012-03-22 Basf Se Verfahren zur herstellung von formamiden
EP2655310B1 (de) * 2010-12-21 2014-11-05 Basf Se Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff
DE102011000077A1 (de) * 2011-01-11 2012-07-12 Rheinisch-Westfälische Technische Hochschule Aachen CO2-Hydrierungsverfahren zu Ameisensäure
WO2012168905A1 (en) * 2011-06-09 2012-12-13 Basf Se Process for preparing formic acid
EP2718256A1 (en) * 2011-06-09 2014-04-16 Basf Se Process for preparing formic acid
JP2014522823A (ja) * 2011-07-07 2014-09-08 ビーエーエスエフ ソシエタス・ヨーロピア 二酸化炭素と水素との反応によるギ酸の製造方法
SG11201400997TA (en) * 2011-10-07 2014-09-26 Basf Se Method for producing formic acid by reacting carbon dioxide with hydrogen
EP2776448A1 (de) * 2011-11-10 2014-09-17 Basf Se Verfahren zur herstellung von ameisensäure durch umsetzung von kohlendioxid mit wasserstoff
US8889905B2 (en) 2011-12-20 2014-11-18 Basf Se Process for preparing formic acid
US8835683B2 (en) 2011-12-20 2014-09-16 Basf Se Process for preparing formic acid
EP2794539B1 (de) 2011-12-20 2015-05-27 Basf Se Verfahren zur herstellung von ameisensäure
SG11201402587UA (en) * 2011-12-20 2014-09-26 Basf Se Process for preparing formic acid
DE102013201246A1 (de) 2013-01-25 2014-07-31 Technische Universität Bergakademie Freiberg Verfahren zur in-situ Umsetzung von chemisch fixiertem Kohlendioxid in niedermolekulare Kohlenwasserstoffe
JP6289310B2 (ja) * 2014-08-27 2018-03-07 一般財団法人電力中央研究所 触媒又はその前駆体並びにこれらを利用した二酸化炭素の水素化方法及びギ酸塩の製造方法
CN105367404B (zh) * 2015-10-13 2018-04-10 大连理工大学 一种二氧化碳催化加氢制备甲酸盐的方法
CN108424359B (zh) * 2018-03-21 2020-11-13 大连理工大学 一种水相中钌配合物催化co2加氢还原制备甲酸盐/甲酸的方法
US20220177402A1 (en) * 2019-03-08 2022-06-09 Nitto Denko Corporation Method for producing formic acid
JP7405594B2 (ja) * 2019-03-08 2023-12-26 日東電工株式会社 ギ酸の製造方法
CN115279723A (zh) * 2020-03-17 2022-11-01 日东电工株式会社 甲酸盐的制造方法及甲酸盐制造系统

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4474959A (en) * 1982-05-22 1984-10-02 Bp Chemicals Limited Production of formate salts from carbon dioxide, hydrogen and amines
EP0357243B1 (en) * 1988-08-20 1995-02-01 BP Chemicals Limited The production of formate salts of nitrogenous bases
DE4211141A1 (de) * 1992-04-03 1993-10-07 Basf Ag Verfahren zur Herstellung von Ameisensäure durch thermische Spaltung von quartären Ammoniumformiaten

Also Published As

Publication number Publication date
WO2008116799A1 (de) 2008-10-02
EP2139837A1 (de) 2010-01-06
CA2681508A1 (en) 2008-10-02
NO20093037L (no) 2009-10-19
CN101663259A (zh) 2010-03-03
BRPI0809156A2 (pt) 2014-09-16
US20100063320A1 (en) 2010-03-11
JP2010521533A (ja) 2010-06-24
KR20090123972A (ko) 2009-12-02

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