AR059434A1 - Piridil sulfoximinas multisustiudas y su uso como insecticidas - Google Patents
Piridil sulfoximinas multisustiudas y su uso como insecticidasInfo
- Publication number
- AR059434A1 AR059434A1 ARP070100565A ARP070100565A AR059434A1 AR 059434 A1 AR059434 A1 AR 059434A1 AR P070100565 A ARP070100565 A AR P070100565A AR P070100565 A ARP070100565 A AR P070100565A AR 059434 A1 AR059434 A1 AR 059434A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- haloalkyl
- alkoxy
- insecticides
- halogen
- Prior art date
Links
- 239000002917 insecticide Substances 0.000 title abstract 2
- WGNUNYPERJMVRM-UHFFFAOYSA-N 3-pyridylacetic acid Chemical compound OC(=O)CC1=CC=CN=C1 WGNUNYPERJMVRM-UHFFFAOYSA-N 0.000 title 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 6
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 5
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000001072 heteroaryl group Chemical group 0.000 abstract 2
- 125000004446 heteroarylalkyl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 150000002431 hydrogen Chemical class 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 101100134922 Gallus gallus COR5 gene Proteins 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000262 haloalkenyl group Chemical group 0.000 abstract 1
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 1
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
- A61P33/14—Ectoparasiticides, e.g. scabicides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/65—One oxygen atom attached in position 3 or 5
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/70—Sulfur atoms
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Animal Behavior & Ethology (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Tropical Medicine & Parasitology (AREA)
- Pharmacology & Pharmacy (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Pyridine Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Las piridilsulfoximinas multisustituidas son utiles como insecticidas. Reivindicacion 1: Un compuesto de formula (1) donde X representa CN, NO2, o COOR4, CONR5R6 o COR5, Y representa halogeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, CN, NO2, R1S, R1SO-, R1SO2-, COOR4 o CONR5R6, Z representa halogeno, azido, alquilo C1-4, alcoxi C1-4, haloalquilo C1-4, haloalcoxi C1-4, arilo o. heteroarilo; m representa un numero entero de 1-3; L representa un unico enlace o R1, S y L tomados juntos representan un anillo de 4, 5 o 6 miembros; R1 representa, alquilo C1-4, haloalquilo C1-4, arilalquilo, heteroarilalquilo, alquenilo C3-6, haloalquenilo C3-6, o alquinilo C3-6, o -CH2- en los casos que R1, S y L juntos representan un anillo de 4, 5, o 6 miembros; R2 y R3 representan de manera independiente hidrogeno, halogeno, alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, alcoxi C1-4-alquilo C1-4, arilalquilo, o heteroarilalquilo, o R2, C y R3 tomados juntos forman un anillo de 3, 4, 5 o 6 miembros que contiene opcionalmente un átomo de O o N; n representa un numero entero de 0-3; y R4, R5 y R6 representan cada uno hidrogeno, alquilo C1-4, haloalquilo C1-4, arilo, o heteroarilo.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US85761106P | 2006-11-08 | 2006-11-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR059434A1 true AR059434A1 (es) | 2008-04-09 |
Family
ID=38457800
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP070100565A AR059434A1 (es) | 2006-11-08 | 2007-02-09 | Piridil sulfoximinas multisustiudas y su uso como insecticidas |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7709649B2 (es) |
| EP (1) | EP2079697B1 (es) |
| JP (2) | JP5210319B2 (es) |
| KR (1) | KR101364355B1 (es) |
| CN (2) | CN102870796A (es) |
| AR (1) | AR059434A1 (es) |
| AU (1) | AU2007318244B2 (es) |
| BR (1) | BRPI0718712B1 (es) |
| ES (1) | ES2414983T3 (es) |
| MX (1) | MX2009004883A (es) |
| TW (1) | TWI383970B (es) |
| WO (1) | WO2008057129A1 (es) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MXPA06011589A (es) * | 2004-04-08 | 2006-12-20 | Dow Agrosciences Llc | Sulfoximinas n-sustituidas insecticidas. |
| TWI398433B (zh) | 2006-02-10 | 2013-06-11 | Dow Agrosciences Llc | 殺蟲性之n-取代(6-鹵烷基吡啶-3-基)烷基磺醯亞胺 |
| TWI381811B (zh) * | 2006-06-23 | 2013-01-11 | Dow Agrosciences Llc | 用以防治可抵抗一般殺蟲劑之昆蟲的方法 |
| TWI383973B (zh) * | 2006-08-07 | 2013-02-01 | Dow Agrosciences Llc | 用於製備2-取代-5-(1-烷硫基)烷基吡啶之方法 |
| TWI409256B (zh) * | 2006-09-01 | 2013-09-21 | Dow Agrosciences Llc | 殺蟲性之n-取代(雜芳基)環烷基磺醯亞胺 |
| EP2338883A1 (en) * | 2006-09-01 | 2011-06-29 | Dow AgroSciences LLC | Insecticidal N-substituted (2-substituted-1,3-thiazol) alkyl sulfoximines |
| TWI387585B (zh) * | 2006-09-01 | 2013-03-01 | Dow Agrosciences Llc | 殺蟲性之n-取代(雜芳基)烷基烴基硫亞胺 |
| TWI383970B (zh) | 2006-11-08 | 2013-02-01 | Dow Agrosciences Llc | 多取代的吡啶基磺醯亞胺及其作為殺蟲劑之用途 |
| TWI395736B (zh) * | 2006-11-08 | 2013-05-11 | Dow Agrosciences Llc | 作為殺蟲劑之雜芳基(取代的)烷基n-取代的磺醯亞胺(二) |
| CN102702082B (zh) * | 2006-11-30 | 2014-12-17 | 陶氏益农公司 | 2-取代的-5-((1-烷硫基)烷基)吡啶的制备方法 |
| US7709648B2 (en) * | 2007-02-09 | 2010-05-04 | Dow Agrosciences Llc | Process for the preparation of 2-substituted-5-(1-alkylthio)alkylpyridines |
| AR066366A1 (es) | 2007-05-01 | 2009-08-12 | Dow Agrosciences Llc | Mezclas sinergicas plaguicidas |
| KR101512528B1 (ko) * | 2007-07-20 | 2015-04-15 | 다우 아그로사이언시즈 엘엘씨 | 식물 생장력의 증가 |
| EP2338334A1 (en) | 2007-07-27 | 2011-06-29 | Dow AgroSciences LLC | Pesticides and uses thereof |
| AU2009222174B2 (en) | 2008-03-03 | 2013-02-28 | Corteva Agriscience Llc | Pesticides |
| BRPI0914565A2 (pt) * | 2008-06-23 | 2019-09-24 | Basf Se | compostos, composição agrícola ou veterinária, métodos para combate ou controle de insetos, aracnídeos ou nematóides, e para proteção de plantas em crescimento, para a proteção de sementes, semente, uso de compostos, método para o tratamento, controle, prevenção ou proteção de animais, e, processo para preparar uma composição. |
| MX2011000196A (es) * | 2008-07-01 | 2011-03-24 | Dow Agrosciences Llc | Proceso mejorado para la preparacion de alquilpiridinas 2-trifluorometil-5-(1-sustituidas). |
| AU2009288336B2 (en) * | 2008-08-27 | 2012-03-08 | Dow Agrosciences Llc | Pesticidal compositions |
| US8507532B2 (en) | 2008-12-26 | 2013-08-13 | Dow Agrosciences, Llc. | Stable insecticide compositions and methods for producing same |
| UA106363C2 (ru) * | 2008-12-26 | 2014-08-26 | ДАУ АГРОСАЙЕНСИЗ, ЭлЭлСи | Стабильные инсектицидные композиции на основе сульфоксимина |
| EP2223602A1 (de) | 2009-02-23 | 2010-09-01 | Bayer CropScience AG | Verfahren zur verbesserten Nutzung des Produktionspotentials genetisch modifizierter Pflanzen |
| WO2010075966A1 (de) * | 2008-12-29 | 2010-07-08 | Bayer Cropscience Ag | Verfahren zur verbesserten nutzung des produktionspotentials genetisch modifizierter pflanzen |
| AU2012219254B2 (en) | 2011-02-18 | 2016-08-11 | Libertas Bio, Inc. | Aminoindane compounds and use thereof in treating pain |
| UA116628C2 (uk) | 2012-02-16 | 2018-04-25 | ДАУ АГРОСАЙЄНСІЗ ЕлЕлСі | Спосіб отримання сульфілімінових сполук |
| TWI603957B (zh) | 2012-08-15 | 2017-11-01 | 阿沙納生物科學有限責任公司 | 胺基氫茚化合物用於治療膀胱過動症及間質性膀胱炎之用途 |
| CN115336501B (zh) * | 2022-09-21 | 2023-09-15 | 常德良群农业发展有限公司 | 一种富硒葡萄的栽培方法 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3609158A (en) * | 1969-03-17 | 1971-09-28 | Dow Chemical Co | Certain substituted (pyridyl)-oxy acetic acid derivatives |
| GB1307271A (en) * | 1970-06-25 | 1973-02-14 | Shell Int Research | Sulphoximine derivatives and their use in herbicidal compositions |
| US4053622A (en) * | 1977-01-14 | 1977-10-11 | Shell Oil Company | Phenyl esters of 3-methyl-2-(1-nitro-2-oxo-2-phenoxyethylidene)-1-imidazolidinecarboxylic acids |
| JPH066585B2 (ja) * | 1985-02-04 | 1994-01-26 | 日本バイエルアグロケム株式会社 | ニトロメチレン誘導体、その製法及び殺虫剤 |
| GB8700838D0 (en) | 1987-01-15 | 1987-02-18 | Shell Int Research | Termiticides |
| EP0306696B1 (de) * | 1987-08-04 | 1994-02-16 | Ciba-Geigy Ag | Substituierte Guanidine |
| IL115499A (en) * | 1994-10-18 | 1999-12-22 | Rohm & Haas | Preparation of 2,6-disubstituted benzensulfonate and certain derivatives thereof |
| IL118481A (en) * | 1995-06-05 | 2000-08-31 | Rhone Poulenc Agrochimie | Sulfur compounds pesticidal compositions containing them and method of their application |
| US6060502A (en) * | 1995-06-05 | 2000-05-09 | Rhone-Poulenc Agrochimie | Pesticidal sulfur compounds |
| MXPA02009313A (es) * | 2000-03-22 | 2005-04-19 | Bayer Cropscience Gmbh | Acilsulfimidas heterociclicas, un metodo para su produccion, agentes que contienen las mismas y su uso como plaguicidas. |
| JP4513284B2 (ja) * | 2002-07-17 | 2010-07-28 | 住友化学株式会社 | マロノニトリル化合物及びその用途 |
| MXPA06011589A (es) * | 2004-04-08 | 2006-12-20 | Dow Agrosciences Llc | Sulfoximinas n-sustituidas insecticidas. |
| TWI398433B (zh) * | 2006-02-10 | 2013-06-11 | Dow Agrosciences Llc | 殺蟲性之n-取代(6-鹵烷基吡啶-3-基)烷基磺醯亞胺 |
| TWI381811B (zh) * | 2006-06-23 | 2013-01-11 | Dow Agrosciences Llc | 用以防治可抵抗一般殺蟲劑之昆蟲的方法 |
| TWI383973B (zh) * | 2006-08-07 | 2013-02-01 | Dow Agrosciences Llc | 用於製備2-取代-5-(1-烷硫基)烷基吡啶之方法 |
| TWI409256B (zh) * | 2006-09-01 | 2013-09-21 | Dow Agrosciences Llc | 殺蟲性之n-取代(雜芳基)環烷基磺醯亞胺 |
| TWI387585B (zh) * | 2006-09-01 | 2013-03-01 | Dow Agrosciences Llc | 殺蟲性之n-取代(雜芳基)烷基烴基硫亞胺 |
| TW200820902A (en) * | 2006-11-08 | 2008-05-16 | Dow Agrosciences Llc | Use of N-substituted sulfoximines for control of invertebrate pests |
| TWI395736B (zh) * | 2006-11-08 | 2013-05-11 | Dow Agrosciences Llc | 作為殺蟲劑之雜芳基(取代的)烷基n-取代的磺醯亞胺(二) |
| TWI383970B (zh) * | 2006-11-08 | 2013-02-01 | Dow Agrosciences Llc | 多取代的吡啶基磺醯亞胺及其作為殺蟲劑之用途 |
| CN102702082B (zh) * | 2006-11-30 | 2014-12-17 | 陶氏益农公司 | 2-取代的-5-((1-烷硫基)烷基)吡啶的制备方法 |
| US7511149B2 (en) * | 2007-02-09 | 2009-03-31 | Dow Agrosciences Llc | Process for the oxidation of certain substituted sulfilimines to insecticidal sulfoximines |
| US7709648B2 (en) * | 2007-02-09 | 2010-05-04 | Dow Agrosciences Llc | Process for the preparation of 2-substituted-5-(1-alkylthio)alkylpyridines |
| KR101512528B1 (ko) * | 2007-07-20 | 2015-04-15 | 다우 아그로사이언시즈 엘엘씨 | 식물 생장력의 증가 |
-
2007
- 2007-02-08 TW TW096104620A patent/TWI383970B/zh not_active IP Right Cessation
- 2007-02-09 AU AU2007318244A patent/AU2007318244B2/en not_active Ceased
- 2007-02-09 MX MX2009004883A patent/MX2009004883A/es active IP Right Grant
- 2007-02-09 CN CN2012103325059A patent/CN102870796A/zh active Pending
- 2007-02-09 ES ES07750607T patent/ES2414983T3/es active Active
- 2007-02-09 CN CN2007800416797A patent/CN101535263B/zh active Active
- 2007-02-09 KR KR1020097009458A patent/KR101364355B1/ko not_active Expired - Fee Related
- 2007-02-09 JP JP2009536216A patent/JP5210319B2/ja not_active Expired - Fee Related
- 2007-02-09 WO PCT/US2007/003780 patent/WO2008057129A1/en not_active Ceased
- 2007-02-09 US US11/704,820 patent/US7709649B2/en active Active
- 2007-02-09 EP EP07750607.9A patent/EP2079697B1/en not_active Not-in-force
- 2007-02-09 AR ARP070100565A patent/AR059434A1/es not_active Application Discontinuation
- 2007-02-09 BR BRPI0718712A patent/BRPI0718712B1/pt not_active IP Right Cessation
-
2010
- 2010-03-18 US US12/726,360 patent/US8178565B2/en active Active
-
2013
- 2013-01-21 JP JP2013008259A patent/JP2013100328A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007318244A1 (en) | 2008-05-15 |
| TWI383970B (zh) | 2013-02-01 |
| CN102870796A (zh) | 2013-01-16 |
| ES2414983T3 (es) | 2013-07-23 |
| MX2009004883A (es) | 2009-05-21 |
| KR20090086988A (ko) | 2009-08-14 |
| TW200821280A (en) | 2008-05-16 |
| US20100179197A1 (en) | 2010-07-15 |
| HK1135983A1 (en) | 2010-06-18 |
| JP2013100328A (ja) | 2013-05-23 |
| BRPI0718712B1 (pt) | 2016-05-10 |
| BRPI0718712A2 (pt) | 2012-12-25 |
| CN101535263B (zh) | 2012-10-31 |
| JP2010509323A (ja) | 2010-03-25 |
| WO2008057129A1 (en) | 2008-05-15 |
| CN101535263A (zh) | 2009-09-16 |
| US20080108667A1 (en) | 2008-05-08 |
| JP5210319B2 (ja) | 2013-06-12 |
| EP2079697A1 (en) | 2009-07-22 |
| KR101364355B1 (ko) | 2014-02-21 |
| US8178565B2 (en) | 2012-05-15 |
| US7709649B2 (en) | 2010-05-04 |
| AU2007318244B2 (en) | 2012-05-31 |
| EP2079697B1 (en) | 2013-06-05 |
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