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AR041182A1 - Derivados de fenoxipropenilfenilo y su uso como herbicidas - Google Patents

Derivados de fenoxipropenilfenilo y su uso como herbicidas

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Publication number
AR041182A1
AR041182A1 ARP030102332A AR041182A1 AR 041182 A1 AR041182 A1 AR 041182A1 AR P030102332 A ARP030102332 A AR P030102332A AR 041182 A1 AR041182 A1 AR 041182A1
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Argentina
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alkyl
substituted
halogen
twice
once
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Syngenta Participations Ag
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    • C07C255/54—Carboxylic acid nitriles having cyano groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton containing cyano groups and etherified hydroxy groups bound to the carbon skeleton
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
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    • C07C205/38—Compounds containing nitro groups bound to a carbon skeleton the carbon skeleton being further substituted by etherified hydroxy groups having nitro groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton to carbon atoms of the same non-condensed six-membered aromatic ring or to carbon atoms of six-membered aromatic rings being part of the same condensed ring system the oxygen atom of at least one of the etherified hydroxy groups being further bound to a carbon atom of a six-membered aromatic ring, e.g. nitrodiphenyl ethers
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    • C07C217/80—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings
    • C07C217/82—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring
    • C07C217/84—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of six-membered aromatic rings of the same carbon skeleton having amino groups and etherified hydroxy groups bound to carbon atoms of non-condensed six-membered aromatic rings of the same non-condensed six-membered aromatic ring the oxygen atom of at least one of the etherified hydroxy groups being further bound to an acyclic carbon atom
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    • C07C225/04—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being saturated
    • C07C225/08—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being saturated and containing rings
    • C07C225/10—Compounds containing amino groups and doubly—bound oxygen atoms bound to the same carbon skeleton, at least one of the doubly—bound oxygen atoms not being part of a —CHO group, e.g. amino ketones having amino groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being saturated and containing rings with doubly-bound oxygen atoms bound to carbon atoms not being part of rings
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    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/24—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • C07C233/25—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a hydrogen atom or to a carbon atom of an acyclic saturated carbon skeleton
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    • C07C235/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/44—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C235/46—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
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    • C07C251/32—Oximes
    • C07C251/34—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals
    • C07C251/48—Oximes with oxygen atoms of oxyimino groups bound to hydrogen atoms or to carbon atoms of unsubstituted hydrocarbon radicals with the carbon atom of at least one of the oxyimino groups bound to a carbon atom of a six-membered aromatic ring
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    • C07C255/32—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring
    • C07C255/37—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms having cyano groups bound to acyclic carbon atoms of a carbon skeleton containing at least one six-membered aromatic ring the carbon skeleton being further substituted by etherified hydroxy groups
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    • C07C39/18—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with unsaturation outside the aromatic ring
    • C07C39/19—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with unsaturation outside the aromatic ring containing carbon-to-carbon double bonds but no carbon-to-carbon triple bonds
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    • C07C59/40—Unsaturated compounds
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    • C07C69/92—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring with etherified hydroxyl groups

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  • Chemical & Material Sciences (AREA)
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Abstract

Reivindicación 1: Compuestos de la fórmula (1) en la cual R01 representa hidrógeno, alquilo C1-8, alquenilo C3-8 o alquinilo C3-8; o R01 representa fenilo o fenil-alquilo C1-6, pudiendo por su parte los anillos fenilo estar substituidos de una a cinco veces con halógeno, y/o una, dos o tres veces con alquilo C1-4, halo-alquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-8, alquilsulfinilo C1-8 o alquilsulfonilo C1-8; o R01 representa alquilo C1-8 substituido de una a cinco veces con halógeno o substituido una, dos o tres veces con -CN, alquilamino C1-6, di(alquil C1-6)amino o alcoxi C1-4; n representa 0, 1, 2, 3 o 4; cada uno de los R1 independientemente de los demás, representa halógeno, -CN, -SCN, -SF5, -NO2, -NH2, -CO2R7, -CONR8R9, -C(S)NH2, -C(R10)=NOR11, -COR12, -OR13, -SR14, -SOR15, -SO2R16, -OSO2R17, alquilo C1-8, alquenilo C2-8, alquinilo C2-8 o cicloalquilo C3-6; o representa alquilo C1-8, alquenilo C2-8 o alquinilo C2-8 substituidos de una a cinco veces con halógeno o substituidos una, dos o tres veces con -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C(R24)=NOR25, -C(S)NR26R27, -C(alquiltio C1-4)=NR28, -OR29, -SR30, -SOR31, -SO2R32 o cicloalquilo C3-6; y/o cada uno de los R1 independientemente de los demás, representa cicloalquilo C3-6 substituido de una a cinco veces con halógeno o substituido una, dos o tres veces con -CN, -NO2, -NR18R19, -CO2R20, -CONR21R22, -COR23, -C(R24)=NOR25, -C(S)NR26R27, -C(alquiltio C1-4)=NR28, -SR30, -SOR31, -SO2R32 o cicloalquilo C3-6; y/o cada uno de los R1 independientemente de los demás, representa fenilo, que por su parte puede estar substituido de una a cinco veces halógeno o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; y/o dos R1 adyacentes juntos forman un puente alquileno C1-7, que puede estar interrumpido por 1 a 3 heteroátomos seleccionados entre oxígeno, nitrógeno y azufre y que puede estar substituido de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-6 o alcoxi C1-6, siendo la cantidad total de átomos de anillo por lo menos de 5 y a lo sumo de 9; y/o dos R1 adyacentes juntos forman un puente alquenileno C2-7, que puede estar interrumpido por 1 a 3 heteroátomos seleccionados entre oxígeno, nitrógeno y azufre y que puede estar substituido de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-6 o alcoxi C1-6, siendo la cantidad total de átomos de anillo por lo menos de 5 y a lo sumo de 9; R3 y R4 independientemente entre sí, representan hidrógeno, halógeno, -CN, alquilo C1-4 o alcoxi C1-4; o R3 y R4 juntos forman alquileno C2-5; R7 representa hidrógeno, alquilo C1-8, alquenilo C3-8 o alquinilo C3-8, o alquilo C1-8, alquenilo C3-8 o alquinilo C3-8 substituidos de una a cinco veces con halógeno, y/o una, dos o tres veces con alcoxi C1-4 o fenilo, pudiendo fenilo a su vez estar substituido de una a cinco veces con halógeno, y/o una, dos o tres veces con alquilo C1-6, haloalquilo C1-4, alcoxi C1-6, -CN, -NO2, alquiltio C1-6, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; R8 representa hidrógeno o alquilo C1-8; R9 representa hidrógeno o alquilo C1-8, o es alquilo C1-8 substituido una, dos o tres veces con -COOH, alcoxicarbonilo C1-8 o -CN, o R9 representa alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; o R8 y R9 conjuntamente representan alquileno C2-5; R10 representa hidrógeno, alquilo C1-4, haloalquilo C1-4 o cicloalquilo C3-6; R11 representa hidrógeno, alquilo C1-8, alquenilo C3-8, alquinilo C3-8, haloalquilo C1-4, o haloalquenilo C3-6; R12 representa hidrógeno, alquilo C1-4, haloalquilo C1-4 o cicloalquilo C3-6; R13 representa hidrógeno, alquilo C1-8, alquenilo C3-8 o alquinilo C3-8; o R13 representa fenilo o fenil-alquilo C1-6, pudiendo por su parte los anillos fenilo, estar substituidos de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-4, halo-alquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-8, alquilsulfinilo C1-8 o alquilsulfonilo C1-8, o R13 representa alquilo C1-8 substituido de una a cinco veces con halógeno o una, dos o tres veces con -CN, alquilamino C1-6, di(alquil C1-6)amino o alcoxi C1-4; R14 representa hidrógeno, alquilo C1-8, alquenilo C3-8 o alquinilo C3-8, o alquilo C1-8 substituido de una a cinco veces con halógeno o una, dos o tres veces con -CN o alcoxi C1-4; R15, R16 y R17 independientemente entre sí, representan alquilo C1-8, alquenilo C3-8 o alquinilo C3-8, o alquilo C1-8 substituido de una a cinco veces con halógeno, o substituido una, dos o tres veces con -CN o alcoxi C1-4; R18 representa hidrógeno o alquilo C1-8; R19 representa hidrógeno, alquilo C1-8, alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno o estar substituidos una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; o R18 y R19 representan conjuntamente una cadena alquileno C2-5, que puede estar interrumpida por un átomo de oxígeno o por un átomo de azufre; R20 representa hidrógeno, alquilo C1-8, alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno y/o substituido una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; R2 representa hidrógeno o alquilo C1-8; R22 representa hidrógeno o alquilo C1-8, o alquilo C1-8 substituido una, dos o tres veces con -COOH, alcoxicarbonilo C1-8 o -CN, o R22 representa alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; o R21 y R22 conjuntamente representan alquileno C2-5; R23 representa hidrógeno, alquilo C1-4, haloalquilo C1-4 o cicloalquilo C3-6; R24 representa hidrógeno, alquilo C1-4, haloalquilo C1-4 o cicloalquilo C3-6; R25 representa hidrógeno, alquilo C1-8, alquenilo C3-8, alquinilo C3-8, haloalquilo C1-4 o haloalquenilo C3-6; R26 representa hidrógeno o alquilo C1-8; R27 representa hidrógeno o alquilo C1-8, o alquilo C1-8 substituido una, dos o tres veces con -COOH, alcoxicarbonilo C1-8 o -CN, o R27 representa alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo por su parte estar substituidos de una a cinco veces con halógeno y/o substituidos una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; o R26 y R27 conjuntamente representan alquileno C2-5; R28 representa hidrógeno o alquilo C1-8; R29 y R30 independientemente entre sí, representan hidrógeno, alquilo C1-8, alquenilo C3-8 o alquinilo, o alquilo C1-8 substituido de una a cinco veces con halógeno, o substituidos una, dos o tres veces con -CN o alcoxi C1-4; R31 y R32 independientemente entre sí, representan alquilo C1-8, alquenilo C3-8 o alquinilo C3-8, o alquilo C1-8 substituido de una a cinco veces con halógeno, o una, dos o tres veces con -CN o alcoxi C1-4; m vale 1, 2, 3, 4 o 5; cada uno de los R2 independientemente de los demás, representa halógeno, -CN, -SCN, -OCN, -N3, -SF5, -NO2, -NR33R34, -CO2R35, -CONR36R37, -C(R38)=NOR39, -COR40, -OR41, -SR42, -SOR43, -SO2R44, -OSO2R45, -N([CO]pR46)COR47, -N(OR54)COR55, -N(R56)SO2R57, -N(SO2R58)SO2R59, -N=C(OR60)R61, -CR62(OR63)OR64, -OC(O)NR65R66, -SC(O)NR67R68, -OC(S)NR69R70 o -N-ftalimida; y/o R2 representa un sistema de anillo heterocíclico de 5 a 7 miembros que puede ser aromático, parcial o totalmente saturado y que puede contener de 1 a 4 heteroátomos seleccionados entre nitrógeno, oxígeno y azufre, pudiendo dicho sistema de anillo heterocíclico a su vez estar substituido de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, hidroxi-alquilo C1-4, alcoxi C1-4, haloalcoxi C1-4, alcoxi C1-4-alquilo C1-4, -CN, -NO2, alquiltio C1-6, alquilsulfinilo C1-6 o alquilsulfonilo C1-6; R33 representa hidrógeno o alquilo C1-8; y R34 representa hidrógeno, alquilo C1-8, alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo a su vez estar substituidos de una a cinco veces con halógeno, y/o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; o R33 y R34 conjuntamente representan una cadena alquileno C2-5, que puede estar interrumpida por un átomo de oxígeno o por un átomo de azufre; R35 representa hidrógeno, alquilo C1-8, alquenilo C3-8 o alquinilo C3-8, o alquilo C1-8, alquenilo C3-8 o alquinilo C3-8 substituidos de una a cinco veces con halógeno o una, dos o tres veces con alcoxi C1-4 o fenilo, pudiendo fenilo por su parte estar substituido de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; R36 representa hidrógeno o alquilo C1-8; R37 representa hidrógeno o alquilo C1-8, o representa alquilo C1-8 substituido una, dos o tres veces con -COOH, alcoxicarbonilo C1-8 o -CN, o R37 representa alquenilo C3-8, alquinilo C3-8, fenilo o bencilo, pudiendo fenilo y bencilo a su vez estar substituidos de una a cinco veces con halógeno y/o una, dos o tres veces con alquilo C1-4, haloalquilo C1-4, alcoxi C1-4, -CN, -NO2, alquiltio C1-4, alquilsulfinilo C1-4 o alquilsulfonilo C1-4; o R36 y R37 juntos representan alquileno C3-5; R38 representa hidrógeno, alquilo C1-4, haloalquilo C1-4 o cic
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