AR040799A1 - Procedimiento y dispositivo para la obtencion de formiato de acido formico y su uso - Google Patents
Procedimiento y dispositivo para la obtencion de formiato de acido formico y su usoInfo
- Publication number
- AR040799A1 AR040799A1 AR20030102816A ARP030102816A AR040799A1 AR 040799 A1 AR040799 A1 AR 040799A1 AR 20030102816 A AR20030102816 A AR 20030102816A AR P030102816 A ARP030102816 A AR P030102816A AR 040799 A1 AR040799 A1 AR 040799A1
- Authority
- AR
- Argentina
- Prior art keywords
- formic acid
- water
- stream containing
- process step
- methyl ester
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 6
- XVVLAOSRANDVDB-UHFFFAOYSA-N formic acid Chemical compound OC=O.OC=O XVVLAOSRANDVDB-UHFFFAOYSA-N 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 7
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 6
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 abstract 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 3
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 abstract 3
- 235000019253 formic acid Nutrition 0.000 abstract 3
- 241000196324 Embryophyta Species 0.000 abstract 2
- 239000010796 biological waste Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 244000025254 Cannabis sativa Species 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 235000019728 animal nutrition Nutrition 0.000 abstract 1
- 230000000845 anti-microbial effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 150000007514 bases Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010494 dissociation reaction Methods 0.000 abstract 1
- 230000005593 dissociations Effects 0.000 abstract 1
- 235000013372 meat Nutrition 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P3/00—Drugs for disorders of the metabolism
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/02—Formic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/02—Formic acid
- C07C53/06—Salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Hematology (AREA)
- Diabetes (AREA)
- Pharmacology & Pharmacy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Obesity (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fodder In General (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Procedimiento para la obtención de formiatos de ácido fórmico, en donde: a) se hidroliza éster metílico de ácido fórmico parcialmente con agua; b) se destila de la mezcla de reacción obtenida en la etapa de procedimiento a) el éster metílico de ácido fórmico y metanol, formándose una corriente que contiene ácido fórmico y agua; c) se transforma la corriente que contiene éster metílico de ácido fórmico y eventualmente metanol de la etapa de procedimiento b) por: (i) reacción con un compuesto básico con un valor pK, del ácido correspondiente de la respectiva etapa de disociación de > = 3, medido a 25° C en solución acuosa, en presencia de agua, y (ii) separación destilativa del metanol en una corriente que contiene formiato y agua; y d) se reúne la corriente que contiene el ácido fórmico y agua de la etapa de procedimiento b) y la corriente que contiene formiato y agua de la etapa de procedimiento c), formándose una mezcla que contiene el formiato de ácido fórmico y agua. Uso de estos compuestos para la conservación y / o acidulación de sustancias vegetales y / o animales para el tratamiento de desperdicios biológicos, un dispositivos para su obtención y el uso de los mismos. Los formiatos de ácido fórmico poseen una acción antimicrobiana y se usan, por ejemplo para la conservación y acidulación de sustancias vegetales y animales, por ejemplo, de pasto, productos agrícolas o carnes, para el tratamiento de desperdicios biológicos o como aditivo en la nutrición animal.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10237379A DE10237379A1 (de) | 2002-08-12 | 2002-08-12 | Verfahren und Vorrichtung zur Herstellung von ameisensauren Formiaten und deren Verwendung |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR040799A1 true AR040799A1 (es) | 2005-04-20 |
Family
ID=30469745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AR20030102816A AR040799A1 (es) | 2002-08-12 | 2003-08-06 | Procedimiento y dispositivo para la obtencion de formiato de acido formico y su uso |
Country Status (18)
| Country | Link |
|---|---|
| US (1) | US7351860B2 (es) |
| EP (1) | EP1530559B1 (es) |
| JP (1) | JP2005535724A (es) |
| KR (1) | KR20050069982A (es) |
| CN (1) | CN1315770C (es) |
| AR (1) | AR040799A1 (es) |
| AU (1) | AU2003253356A1 (es) |
| BR (1) | BR0313245A (es) |
| CA (1) | CA2495340A1 (es) |
| DE (2) | DE10237379A1 (es) |
| MX (1) | MXPA05001090A (es) |
| MY (1) | MY158855A (es) |
| NO (1) | NO20050538L (es) |
| PL (1) | PL375582A1 (es) |
| RU (1) | RU2005106992A (es) |
| TW (1) | TW200413307A (es) |
| WO (1) | WO2004020382A1 (es) |
| ZA (1) | ZA200502075B (es) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10321733A1 (de) * | 2003-05-14 | 2004-12-02 | Basf Ag | Verfahren zur Herstellung von ameisensauren Formiaten |
| TW200523246A (en) * | 2003-11-06 | 2005-07-16 | Basf Ag | Preparation of acid formates |
| MY158458A (en) * | 2005-04-13 | 2016-10-14 | Basf Ag | Sodium diformate production and use |
| DE102005020890A1 (de) * | 2005-05-04 | 2006-11-09 | Basf Ag | Herstellung von Natriumformiat |
| WO2007061550A1 (en) * | 2005-11-16 | 2007-05-31 | Dow Corning Corporation | Organosilanes and their preparation and use in elastomer compositions |
| DE102005062931A1 (de) * | 2005-12-29 | 2007-07-05 | Basf Ag | Herstellung von Natriumdiformiat |
| DE102005063109A1 (de) * | 2005-12-30 | 2007-07-05 | Basf Ag | Herstellung von sauren Propionaten |
| US20110237830A1 (en) | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
| US9957624B2 (en) | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
| US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
| US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
| US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
| US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
| US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
| US8329455B2 (en) | 2011-07-08 | 2012-12-11 | Aikan North America, Inc. | Systems and methods for digestion of solid waste |
| CN104822861B (zh) | 2012-09-24 | 2017-03-08 | 二氧化碳材料公司 | 用于将二氧化碳转化为有用燃料和化学品的装置和方法 |
| US10647652B2 (en) | 2013-02-24 | 2020-05-12 | Dioxide Materials, Inc. | Process for the sustainable production of acrylic acid |
| US10774431B2 (en) | 2014-10-21 | 2020-09-15 | Dioxide Materials, Inc. | Ion-conducting membranes |
| US10975480B2 (en) | 2015-02-03 | 2021-04-13 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| CN108707062A (zh) * | 2018-06-08 | 2018-10-26 | 聊城市鲁西化工工程设计有限责任公司 | 一种用于钾盐回收处理的工艺 |
| CN110559681B (zh) * | 2019-09-02 | 2022-05-13 | 湘潭大学 | 制备高纯对甲酚的装置及制备高纯对甲酚的方法 |
| CN112409163B (zh) * | 2020-12-18 | 2022-12-20 | 贵州天福化工有限责任公司 | 一种甲醇羰基化制甲酸甲酯工艺中副产物的分离方法 |
| CN113651686B (zh) * | 2021-07-30 | 2024-11-01 | 中盐安徽红四方股份有限公司 | 煤制乙二醇mf废液综合利用生产甲酸钠的方法 |
| CN113999102A (zh) * | 2021-11-03 | 2022-02-01 | 武汉联德化学品有限公司 | 一种制备甲酸的方法 |
| CN116282112B (zh) * | 2022-10-22 | 2025-05-06 | 新疆天业（集团）有限公司 | 一种过程低品位甲酸钙精制及基于甲酸钙的高纯钙基化合物制备工艺方法 |
| CN117534559B (zh) * | 2024-01-09 | 2024-04-23 | 江苏中丹化工技术有限公司 | 一种微通道反应器制备酸式甲酸盐的方法及其应用 |
| CN117623909A (zh) * | 2024-01-26 | 2024-03-01 | 江苏中丹化工技术有限公司 | 一种基于液滴微流控技术制备甲酸盐的方法及甲酸盐微球 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2545889A (en) * | 1948-11-19 | 1951-03-20 | Celanese Corp | Recovery of oxygenated compounds |
| NL7501253A (nl) * | 1974-02-15 | 1975-08-19 | Basf Ag | Werkwijze voor het winnen van mierezuur. |
| NL185703C (nl) | 1975-11-27 | 1990-07-02 | Bp Chem Int Ltd | Werkwijze voor het conserveren van diervoeder of landbouwprodukten. |
| DE2744313A1 (de) * | 1977-10-01 | 1979-04-12 | Basf Ag | Verfahren zur herstellung von ameisensaeure |
| NZ192046A (en) * | 1978-11-15 | 1981-02-11 | Bp Chemicals Co | Cementitious composition comprising an acid formate of ammonium, sodium or potassium as an accelerator |
| DE2914671A1 (de) * | 1979-04-11 | 1980-10-23 | Basf Ag | Verfahren zur gewinnung von wasserfreier oder weitgehend wasserfreier ameisensaeure |
| NO300912B1 (no) | 1995-05-12 | 1997-08-18 | Norsk Hydro As | Additiv for dyrefôr og fôr inneholdende slike additiv |
| NO300038B1 (no) | 1995-05-12 | 1997-03-24 | Norsk Hydro As | Fremgangsmåte for fremstilling av produkter inneholdende dobbelsalter av maursyre |
| NO300192B1 (no) | 1995-08-07 | 1997-04-28 | Sildolje & Sildemelind Forsk | Fremgangsmate for kjoling og konservering av fisk samt produkt fra fisk behandlet ifolge fremgangsmaten |
| NO308210B1 (no) * | 1996-11-08 | 2000-08-14 | Norsk Hydro As | FremgangsmÕte til behandling av vÕtorganisk avfall samt anvendelse av løsning for behandling av organisk avfall |
| NO305301B1 (no) | 1997-09-11 | 1999-05-10 | Norsk Hydro As | Vandig konserveringsmiddel |
| NO307591B1 (no) | 1998-08-14 | 2000-05-02 | Norsk Hydro As | Vandig konserveringsmiddel |
| NO310091B1 (no) | 1999-09-15 | 2001-05-21 | Norsk Hydro As | Vandig konserveringsmiddel/surgjöringsmiddel |
| DE10210730A1 (de) | 2002-03-12 | 2003-09-25 | Basf Ag | Verfahren zur Herstellung von ameisensauren Formiaten |
| DE10154757A1 (de) | 2001-11-09 | 2003-05-22 | Basf Ag | Verfahren zur Herstellung von Metallformiat-Ameisensäure-Mischungen |
-
2002
- 2002-08-12 DE DE10237379A patent/DE10237379A1/de not_active Withdrawn
-
2003
- 2003-07-30 CN CNB038195097A patent/CN1315770C/zh not_active Expired - Fee Related
- 2003-07-30 BR BR0313245-5A patent/BR0313245A/pt not_active IP Right Cessation
- 2003-07-30 PL PL03375582A patent/PL375582A1/xx not_active Application Discontinuation
- 2003-07-30 JP JP2004531833A patent/JP2005535724A/ja not_active Withdrawn
- 2003-07-30 EP EP03790832A patent/EP1530559B1/de not_active Expired - Lifetime
- 2003-07-30 WO PCT/EP2003/008399 patent/WO2004020382A1/de not_active Ceased
- 2003-07-30 CA CA002495340A patent/CA2495340A1/en not_active Abandoned
- 2003-07-30 RU RU2005106992/04A patent/RU2005106992A/ru not_active Application Discontinuation
- 2003-07-30 DE DE50308660T patent/DE50308660D1/de not_active Expired - Fee Related
- 2003-07-30 KR KR1020057002310A patent/KR20050069982A/ko not_active Withdrawn
- 2003-07-30 AU AU2003253356A patent/AU2003253356A1/en not_active Abandoned
- 2003-07-30 MX MXPA05001090A patent/MXPA05001090A/es unknown
- 2003-07-30 US US10/524,268 patent/US7351860B2/en not_active Expired - Fee Related
- 2003-08-06 AR AR20030102816A patent/AR040799A1/es not_active Application Discontinuation
- 2003-08-06 MY MYPI20032970A patent/MY158855A/en unknown
- 2003-08-08 TW TW092121838A patent/TW200413307A/zh unknown
-
2005
- 2005-01-31 NO NO20050538A patent/NO20050538L/no not_active Application Discontinuation
- 2005-03-11 ZA ZA200502075A patent/ZA200502075B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA200502075B (en) | 2006-05-31 |
| JP2005535724A (ja) | 2005-11-24 |
| CN1675159A (zh) | 2005-09-28 |
| DE50308660D1 (de) | 2008-01-03 |
| EP1530559A1 (de) | 2005-05-18 |
| CN1315770C (zh) | 2007-05-16 |
| RU2005106992A (ru) | 2005-07-20 |
| NO20050538L (no) | 2005-02-28 |
| MY158855A (en) | 2016-11-15 |
| US7351860B2 (en) | 2008-04-01 |
| BR0313245A (pt) | 2005-06-14 |
| US20050245765A1 (en) | 2005-11-03 |
| MXPA05001090A (es) | 2005-04-28 |
| AU2003253356A1 (en) | 2004-03-19 |
| WO2004020382A1 (de) | 2004-03-11 |
| EP1530559B1 (de) | 2007-11-21 |
| PL375582A1 (en) | 2005-11-28 |
| DE10237379A1 (de) | 2004-02-19 |
| TW200413307A (en) | 2004-08-01 |
| KR20050069982A (ko) | 2005-07-05 |
| CA2495340A1 (en) | 2004-03-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA | Abandonment or withdrawal |