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AR045226A1 - Proceso para producir 1-octeno a partir de butadieno - Google Patents

Proceso para producir 1-octeno a partir de butadieno

Info

Publication number
AR045226A1
AR045226A1 ARP040102841A ARP040102841A AR045226A1 AR 045226 A1 AR045226 A1 AR 045226A1 AR P040102841 A ARP040102841 A AR P040102841A AR P040102841 A ARP040102841 A AR P040102841A AR 045226 A1 AR045226 A1 AR 045226A1
Authority
AR
Argentina
Prior art keywords
alkoxy
dimerization
product
produce
conditions
Prior art date
Application number
ARP040102841A
Other languages
English (en)
Inventor
Charles Lee Edwards
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of AR045226A1 publication Critical patent/AR045226A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/22—Carbides
    • C07C2527/224—Silicon carbide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

Se describe un método para producir 1-octeno a partir de butadieno por dimerización y alcoxilación de butadieno en presencia de uno o más ligandos fosfina sustituidos con alcoxilo bajo condiciones de alcoxidimerización con un catalizador de alcoxidimerización, las condiciones de alcoxidimerización son efectivas como para producir un producto de alcoxidimerización con uno o más octadienos sustituidos con alcoxilo que incluyen principalmente octadienos sustituidos con 1-alcoxilo; hidrogenar el producto de alcoxidimerización bajo condicione de hidrogenación efectivas como para producir un producto de hidrogenación que es principalmente sustituido con 1-alcoxilo; eliminar el grupo alcoxilo del producto de hidrogenación bajo condiciones de eliminación que sean efectivas para producir un producto de eliminación que es principalmente 1-octeno y un primer alcanol que tiene de aproximadamente 1 a aproximadamente 3 átomos carbono; y separar el 1-octeno de dicho producto de eliminación.
ARP040102841A 2003-08-11 2004-08-09 Proceso para producir 1-octeno a partir de butadieno AR045226A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US49421203P 2003-08-11 2003-08-11

Publications (1)

Publication Number Publication Date
AR045226A1 true AR045226A1 (es) 2005-10-19

Family

ID=34215862

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP040102841A AR045226A1 (es) 2003-08-11 2004-08-09 Proceso para producir 1-octeno a partir de butadieno

Country Status (3)

Country Link
US (1) US7425658B2 (es)
AR (1) AR045226A1 (es)
WO (1) WO2005019139A2 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008002347A1 (de) 2008-06-11 2009-12-17 Evonik Oxeno Gmbh Katalysator und Verfahren zur Herstellung von gesättigten Ethern durch Hydrierung ungesättigter Ether
ES2617320T3 (es) * 2008-08-12 2017-06-16 Dow Global Technologies Llc Un proceso mejorado para la telomerización de butadieno
WO2010130846A2 (es) 2009-05-14 2010-11-18 Dow Global Technologies Inc. Complejos de paladio-fosfina para la telomerización de butadieno
EP2519347B1 (en) 2009-12-29 2016-03-30 Dow Global Technologies LLC Method for producing alpha-olefins by catalytic cleaving of methyl-octyl ether precursor
JP2013519519A (ja) 2010-02-17 2013-05-30 ダウ グローバル テクノロジーズ エルエルシー ブタジエンの短鎖重合に有用なホスフィンに基づく新規触媒
CA2818033A1 (en) 2010-12-21 2012-06-28 Dow Global Technologies Llc Process for telomerization of butadiene using a mono-orthoalkoxy substituted catalyst
CN112898109A (zh) * 2019-12-03 2021-06-04 中国科学院大连化学物理研究所 一种α-高碳醇脱水制α-高碳烯烃的方法
CN116174049A (zh) * 2023-03-17 2023-05-30 太原大成环能化工技术有限公司 一种乙烯选择性四聚钯催化剂及其应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4687876A (en) * 1978-03-27 1987-08-18 Shell Oil Company Production of 1,7-octadiene from butadiene
US4180694A (en) * 1978-07-24 1979-12-25 Shell Oil Company Production of 1,7-octadiene from butadiene
US4229606A (en) * 1978-12-13 1980-10-21 Shell Oil Company 1,7-Octadiene process
US4229605A (en) * 1978-12-13 1980-10-21 Shell Oil Company 1,7-Octadiene process
GB2114974B (en) 1981-10-12 1985-10-16 Ici Plc Octadienyl' hydroxyalky ethers and surfactants
DE3667166D1 (de) 1985-09-09 1990-01-04 Quantum Chem Corp Organo-oxyalkadiene durch telomerisation von konjugierten alkadienen.
DE3889936T2 (de) 1987-02-09 1995-01-26 Mitsubishi Chem Ind Alkoholgemisch für Plastifiziermittel.
US5030792A (en) * 1987-06-22 1991-07-09 Shell Oil Company Process for preparing 1-octene
ES2053192T3 (es) 1989-05-03 1994-07-16 Henkel Research Corp Eteres octadienilicos y un proceso para elaborar eteres octadienilicos.
WO1992010450A1 (en) 1990-12-13 1992-06-25 Dow Benelux N.V. Process for producing 1-octene
US5198598A (en) 1991-07-19 1993-03-30 Henkel Kommanditgesellschaft Auf Aktien Telomerization process of a conjugated alkadiene with a polyol
TW251302B (es) 1992-12-28 1995-07-11 Kao Corp
US5412137A (en) * 1993-06-07 1995-05-02 Sandoz Ltd. Process for preparing phosphinyloxy propanaminium inner salt derivatives
EP1178029A1 (en) 2000-07-31 2002-02-06 Oxeno Olefinchemie GmbH Process for preparing di-iso-butanes, di-iso-butenes, and di-n-butenes from field butanes
DE10105751B4 (de) 2001-02-08 2005-09-29 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von 1-Octen
US20040001797A1 (en) 2002-06-21 2004-01-01 Abel Saud Antimicrobial compositions, products and methods employing same

Also Published As

Publication number Publication date
US20050038305A1 (en) 2005-02-17
US7425658B2 (en) 2008-09-16
WO2005019139A3 (en) 2005-05-06
WO2005019139A2 (en) 2005-03-03

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