AR032061A1 - Un procedimiento para la preparacion de acidos carboxilicos mediante carbonilacion con paladio - Google Patents
Un procedimiento para la preparacion de acidos carboxilicos mediante carbonilacion con paladioInfo
- Publication number
- AR032061A1 AR032061A1 ARP010106048A ARP010106048A AR032061A1 AR 032061 A1 AR032061 A1 AR 032061A1 AR P010106048 A ARP010106048 A AR P010106048A AR P010106048 A ARP010106048 A AR P010106048A AR 032061 A1 AR032061 A1 AR 032061A1
- Authority
- AR
- Argentina
- Prior art keywords
- palladium
- preparation
- paladio
- carbonilation
- procedure
- Prior art date
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title abstract 8
- 238000000034 method Methods 0.000 title abstract 2
- -1 CARBOXYL ACIDS Chemical class 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 229910052763 palladium Inorganic materials 0.000 abstract 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 230000003647 oxidation Effects 0.000 abstract 2
- 238000007254 oxidation reaction Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- YIYBQIKDCADOSF-UHFFFAOYSA-N pentenoic acid group Chemical class C(C=CCC)(=O)O YIYBQIKDCADOSF-UHFFFAOYSA-N 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Un procedimiento para la preparacion de ácidos carboxílicos Beta- o gamma-insaturados o saturados. Se refiere más particularmente a la hidroxicarbonilacion de un compuesto orgánico que comprende una insaturacion conjugada, tal como butadieno, por la accion de monoxido de carbono y agua en presencia de un catalizador basado en paladio. Los ácidos carboxílicos así obtenidos son preferentemente ácidos pentenoicos. De acuerdo con la presente, el medio de reaccion después de la etapa de hidroxicarbonilacion es tratado con hidrogeno para reducir el paladio presente en el estado de oxidacion 2+ a paladio en el estado de oxidacion cero y se recupera el paladio precipitado.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0017101A FR2818638B1 (fr) | 2000-12-27 | 2000-12-27 | Procede de preparation d'acides carboxyliques par carbonylation au palladium |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR032061A1 true AR032061A1 (es) | 2003-10-22 |
Family
ID=8858258
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP010106048A AR032061A1 (es) | 2000-12-27 | 2001-12-27 | Un procedimiento para la preparacion de acidos carboxilicos mediante carbonilacion con paladio |
Country Status (20)
| Country | Link |
|---|---|
| US (1) | US6946574B2 (es) |
| EP (1) | EP1345880B1 (es) |
| JP (1) | JP3906154B2 (es) |
| KR (1) | KR100523721B1 (es) |
| CN (1) | CN1220668C (es) |
| AR (1) | AR032061A1 (es) |
| AT (1) | ATE289288T1 (es) |
| BR (1) | BR0116755A (es) |
| CA (1) | CA2433300A1 (es) |
| DE (1) | DE60108979T2 (es) |
| ES (1) | ES2233715T3 (es) |
| FR (1) | FR2818638B1 (es) |
| HU (1) | HUP0600058A3 (es) |
| IL (1) | IL156598A0 (es) |
| MX (1) | MXPA03005794A (es) |
| PL (1) | PL363484A1 (es) |
| RU (1) | RU2240306C1 (es) |
| TW (1) | TWI227230B (es) |
| UA (1) | UA73622C2 (es) |
| WO (1) | WO2002051783A1 (es) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060252938A1 (en) * | 2003-04-28 | 2006-11-09 | Basf Aktiengesellschaft | Process for the separation of palladium catalyst from crude reaction mixtures of aryl acetic acids obtained by carbonylation |
| US20080194870A1 (en) * | 2005-02-11 | 2008-08-14 | Eit Drent | Process for the Preparation of a Dicarboxylic Acid |
| US20080269459A1 (en) * | 2005-02-11 | 2008-10-30 | Eit Drent | Process for the Preparation of a Dicarboxylic Acid |
| WO2006084893A1 (en) * | 2005-02-11 | 2006-08-17 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of a conjugated diene to a dicarboxylic acid |
| US20080269433A1 (en) * | 2005-02-11 | 2008-10-30 | Eit Drent | Process for the Carbonylation of a Conjugated Diene |
| JP5240750B2 (ja) * | 2007-04-11 | 2013-07-17 | 東ソー有機化学株式会社 | パラジウムの除去方法 |
| HK1208197A1 (en) * | 2012-05-15 | 2016-02-26 | Archer-Daniels-Midland Company | Reduction catalysts |
| JP2018100221A (ja) * | 2015-04-17 | 2018-06-28 | アステラス製薬株式会社 | Ｐｄを実質的に含まない有機化合物の製造方法及び水素ガスを用いた有機化合物からＰｄを除去する新規な方法 |
| CN107337572A (zh) * | 2017-05-31 | 2017-11-10 | 中国科学技术大学 | 一种制备β,γ‑不饱和羧酸类化合物的方法 |
| EP4011893A1 (de) * | 2020-12-09 | 2022-06-15 | Evonik Operations GmbH | Platin-komplexe mit binaphthyl basiertem diphosphinliganden für die selektive katalyse der hydroxycarbonylierung ethylenisch ungesättigter verbindungen |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB655339A (en) * | 1948-10-27 | 1951-07-18 | Arthur William Charles Taylor | Improvements in and relating to the production of oxygencontaining compounds |
| US3509209A (en) | 1967-01-12 | 1970-04-28 | Union Oil Co | Hydrocarboxylation of certain conjugated diolefin compounds |
| DE2833469C2 (de) * | 1978-07-29 | 1986-10-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Aufarbeitung von Reaktionsgemischen, die bei der Hydroformylierung oder der Carbonylierung anfallen |
| FR2529885A1 (fr) | 1982-07-09 | 1984-01-13 | Rhone Poulenc Chim Base | Procede de preparation d'acides carboxyliques b,g-insatures |
| FR2711365B1 (fr) * | 1993-10-19 | 1995-12-15 | Rhone Poulenc Chimie | Procédé d'hydroxycarbonylation du butadiène. |
| US5981788A (en) * | 1997-11-03 | 1999-11-09 | General Electric Company | Method for recovering and recycling catalyst constituents |
-
2000
- 2000-12-27 FR FR0017101A patent/FR2818638B1/fr not_active Expired - Fee Related
-
2001
- 2001-12-21 PL PL01363484A patent/PL363484A1/xx unknown
- 2001-12-21 IL IL15659801A patent/IL156598A0/xx unknown
- 2001-12-21 CA CA002433300A patent/CA2433300A1/fr not_active Abandoned
- 2001-12-21 WO PCT/FR2001/004149 patent/WO2002051783A1/fr not_active Ceased
- 2001-12-21 JP JP2002552884A patent/JP3906154B2/ja not_active Expired - Fee Related
- 2001-12-21 CN CNB018221971A patent/CN1220668C/zh not_active Expired - Fee Related
- 2001-12-21 RU RU2003123117/04A patent/RU2240306C1/ru not_active IP Right Cessation
- 2001-12-21 BR BR0116755-3A patent/BR0116755A/pt active Search and Examination
- 2001-12-21 KR KR10-2003-7008766A patent/KR100523721B1/ko not_active Expired - Fee Related
- 2001-12-21 ES ES01995752T patent/ES2233715T3/es not_active Expired - Lifetime
- 2001-12-21 DE DE60108979T patent/DE60108979T2/de not_active Expired - Fee Related
- 2001-12-21 AT AT01995752T patent/ATE289288T1/de not_active IP Right Cessation
- 2001-12-21 UA UA2003065927A patent/UA73622C2/uk unknown
- 2001-12-21 EP EP01995752A patent/EP1345880B1/fr not_active Expired - Lifetime
- 2001-12-21 US US10/451,662 patent/US6946574B2/en not_active Expired - Fee Related
- 2001-12-21 HU HU0600058A patent/HUP0600058A3/hu unknown
- 2001-12-21 MX MXPA03005794A patent/MXPA03005794A/es not_active Application Discontinuation
- 2001-12-21 TW TW090131873A patent/TWI227230B/zh not_active IP Right Cessation
- 2001-12-27 AR ARP010106048A patent/AR032061A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1487913A (zh) | 2004-04-07 |
| FR2818638B1 (fr) | 2003-02-07 |
| UA73622C2 (en) | 2005-08-15 |
| ES2233715T3 (es) | 2005-06-16 |
| RU2240306C1 (ru) | 2004-11-20 |
| WO2002051783A1 (fr) | 2002-07-04 |
| US20040068142A1 (en) | 2004-04-08 |
| TWI227230B (en) | 2005-02-01 |
| PL363484A1 (en) | 2004-11-15 |
| MXPA03005794A (es) | 2003-09-10 |
| KR20030066776A (ko) | 2003-08-09 |
| BR0116755A (pt) | 2004-01-13 |
| HUP0600058A3 (en) | 2007-08-28 |
| EP1345880B1 (fr) | 2005-02-16 |
| FR2818638A1 (fr) | 2002-06-28 |
| ATE289288T1 (de) | 2005-03-15 |
| DE60108979D1 (de) | 2005-03-24 |
| CN1220668C (zh) | 2005-09-28 |
| JP3906154B2 (ja) | 2007-04-18 |
| EP1345880A1 (fr) | 2003-09-24 |
| HUP0600058A2 (en) | 2007-01-29 |
| US6946574B2 (en) | 2005-09-20 |
| RU2003123117A (ru) | 2005-02-20 |
| JP2004520322A (ja) | 2004-07-08 |
| DE60108979T2 (de) | 2005-07-14 |
| KR100523721B1 (ko) | 2005-10-26 |
| IL156598A0 (en) | 2004-01-04 |
| CA2433300A1 (fr) | 2002-07-04 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB | Suspension of granting procedure |