AR038656A1 - Un procedimiento para la preparacion de una espuma microcelular flexible de poliuretano, una espuma microcelular flexible de poliuretano preparada por el mismo, y un componente de suela de calzado que la comprende. - Google Patents
Un procedimiento para la preparacion de una espuma microcelular flexible de poliuretano, una espuma microcelular flexible de poliuretano preparada por el mismo, y un componente de suela de calzado que la comprende.Info
- Publication number
- AR038656A1 AR038656A1 ARP020100189A ARP020100189A AR038656A1 AR 038656 A1 AR038656 A1 AR 038656A1 AR P020100189 A ARP020100189 A AR P020100189A AR P020100189 A ARP020100189 A AR P020100189A AR 038656 A1 AR038656 A1 AR 038656A1
- Authority
- AR
- Argentina
- Prior art keywords
- foams
- microcellular
- polyurethane
- water
- flexible
- Prior art date
Links
- 239000006260 foam Substances 0.000 title abstract 9
- 229920002635 polyurethane Polymers 0.000 title abstract 5
- 239000004814 polyurethane Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 2
- 239000002689 soil Substances 0.000 title 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 abstract 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 6
- 229910002092 carbon dioxide Inorganic materials 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 4
- 229920005830 Polyurethane Foam Polymers 0.000 abstract 3
- 238000009472 formulation Methods 0.000 abstract 3
- 239000012948 isocyanate Substances 0.000 abstract 3
- 150000002513 isocyanates Chemical class 0.000 abstract 3
- 239000011496 polyurethane foam Substances 0.000 abstract 3
- 239000001569 carbon dioxide Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 229920001971 elastomer Polymers 0.000 abstract 2
- 239000000806 elastomer Substances 0.000 abstract 2
- 230000000704 physical effect Effects 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000004970 Chain extender Substances 0.000 abstract 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 abstract 1
- 210000003850 cellular structure Anatomy 0.000 abstract 1
- 239000003431 cross linking reagent Substances 0.000 abstract 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- COPLXRFZXQINJM-UHFFFAOYSA-N isocyanic acid;hydrate Chemical compound O.N=C=O COPLXRFZXQINJM-UHFFFAOYSA-N 0.000 abstract 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract 1
- 229920005862 polyol Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/08—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4072—Mixtures of compounds of group C08G18/63 with other macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6552—Compounds of group C08G18/63
- C08G18/6558—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6564—Compounds of group C08G18/63 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2410/00—Soles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/06—Flexible foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Polyurethanes Or Polyureas (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
Se describen elastómeros microcelulares flexibles de baja densidad. Los polímeros de poliuretano generalmente exhiben propiedades físicas que son superiores a las de los polímeros de etilenvinilacetatos pero muestran numerosas dificultades cuando se intenta moldear espumas microcelulares de poliuretano a bajas densidades. Las espumas microcelulares de poliuretano flexibles adecuadas para usar como componentes de suelas de calzado ligeros se preparan disolviendo dióxido de carbono en uno o ambos lados iso o resina de una formulación de espuma microcelular de poliuretano basada en un prepolímero de isocianato. Las espumas resultantes poseen una estructura celular mas uniforme y propiedades físicas realzadas en comparación con todas las espumas expandidas con agua de la misma formulación y densidad básica. La dureza de las espumas es más adecuada para suelas de calzado, en particular para aplicaciones de mediasuelas, que la de las espumas expandidas con agua a pesar del menor contenido de segmento duro de urea de las espumas expandidas con CO2. Las espumas microcelulares de poliuretano flexibles que tienen menos de 0,75 g/cm3, se preparan por un procedimiento que comprende: A) disponer una mezcla reactiva que comprende 1) un componente isocianato-funcional; 2) un componente reactivo frente a isocianato que comprende 2S) al menos un poliol hidroxi-funcional con una funcionalidad teórica entre 2 y 4; 2b) opcionalmente un alargador de cadena con un peso molecular inferior a 300 Da; 2c) opcionalmente un agente de entrecruzamiento con un peso molecular inferior a 300 Da; 3) un catalizador promotor de uretano y opcionalmente, si también hay agua presente, un catalizador para la reacción de expansión isocianato-agua; 4) un tensioactivo eficaz para formar células estables con un diámetro medio inferior a 200 microm; y B) una cantidad de agente de expansión adecuada para formar una espuma microcelular de poliuretano con una densidad entre 0,1 g/cm3 y 0,75 g/cm3, en el que dicho agente de expansión comprende dióxido de carbono que ha sido disuelto en dicho componente isocianato-funcional A, dicho componente reactivo frente a isocianato B, o en ambos, componente A y componente B, y opcionalmente una cantidad minoritaria de agua que es inferior al 50% en peso de la cantidad de agua requerida para preparar un elastómero microcelular expandido totalmente con agua de la misma densidad a partir de la misma formulación sin contenido de CO2 disuelto.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/764,682 US6458861B1 (en) | 2001-01-18 | 2001-01-18 | Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR038656A1 true AR038656A1 (es) | 2005-01-26 |
Family
ID=25071444
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP020100189A AR038656A1 (es) | 2001-01-18 | 2002-01-18 | Un procedimiento para la preparacion de una espuma microcelular flexible de poliuretano, una espuma microcelular flexible de poliuretano preparada por el mismo, y un componente de suela de calzado que la comprende. |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6458861B1 (es) |
| EP (1) | EP1225199B1 (es) |
| JP (1) | JP2002241462A (es) |
| KR (1) | KR100803856B1 (es) |
| AR (1) | AR038656A1 (es) |
| AT (1) | ATE289329T1 (es) |
| AU (1) | AU1021802A (es) |
| BR (1) | BR0200091A (es) |
| CA (1) | CA2367077C (es) |
| DE (1) | DE60202975T2 (es) |
| HU (1) | HUP0200183A3 (es) |
| MX (1) | MXPA02000493A (es) |
| PL (1) | PL351735A1 (es) |
| RU (1) | RU2002100702A (es) |
| SK (1) | SK422002A3 (es) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2489547C (en) * | 2002-06-21 | 2011-08-02 | Recticel | Micro-cellular or non-cellular light-stable polyurethane material and method for the production thereof |
| DE10319393A1 (de) * | 2003-04-30 | 2004-11-18 | Bayer Materialscience Ag | Flexible Formteile aus geschäumten Polyurethan und ihre Verwendung |
| FR2858622B1 (fr) * | 2003-08-08 | 2007-03-30 | Rhodia Polyamide Intermediates | Mousses polyurethane, polyester-polyols pour l'obtention des mousses et utilisation de ces mousses |
| FR2858623B1 (fr) * | 2003-08-08 | 2006-01-13 | Rhodia Polyamide Intermediates | Mousses polyurethannes, procede de fabrication et utilisation de ces mousses |
| DE102004010809A1 (de) * | 2004-03-05 | 2005-09-22 | Bayer Materialscience Ag | Flexible Formteile aus geschäumtem Polyurethan und ihre Verwendung |
| AU2005293571A1 (en) * | 2004-10-15 | 2006-04-20 | Danisco A/S | A foamed isocyanate-based polymer, a mix and process for production thereof |
| US7465757B2 (en) * | 2004-10-15 | 2008-12-16 | Danisco A/S | Foamed isocyanate-based polymer, a mix and process for production thereof |
| US7670501B2 (en) * | 2005-05-27 | 2010-03-02 | Bayer Materialscience Llc | Carbon dioxide blown low density, flexible microcellular polyurethane elastomers |
| ITMI20052257A1 (it) | 2005-11-25 | 2007-05-26 | Basf Ag | Suole intermedie per scarpe dio sicurezza da espanso poliuretano di bassa densita' |
| US20080058468A1 (en) * | 2006-08-31 | 2008-03-06 | Bayer Materialscience Llc | Low density rigid reinforced polyurethanes and a process for their production |
| DE102006042338A1 (de) * | 2006-09-08 | 2008-03-27 | Evonik Goldschmidt Gmbh | Verwendung von Urethan- oder Harnstoffgruppen enthaltenden Polyethern zur Stabilisierung von Polyurethanschäumen |
| WO2009047149A1 (de) * | 2007-10-02 | 2009-04-16 | Basf Se | Niederdichte polyurethanschaumstoffe und deren verwendung in schuhsohlen |
| DE102007050100A1 (de) * | 2007-10-19 | 2009-04-23 | Entwicklungsgesellschaft für Akustik (EfA) mit beschränkter Haftung | Schallisolierung mit CO2-beladener Kompakt-Polyurethan-Schaumstoff (RIM)-Schicht |
| US8642670B2 (en) * | 2008-03-14 | 2014-02-04 | Basf Se | Coarse-cell polyurethane elastomers |
| CN101486788B (zh) * | 2008-12-30 | 2011-09-14 | 浙江华峰新材料股份有限公司 | 一种低密度高硬度聚氨酯微孔弹性体及其制备方法 |
| TWI404739B (zh) * | 2009-04-02 | 2013-08-11 | Chung Hsien Tu | 軟質聚氨酯低回彈發泡體及其製備方法 |
| JP5597380B2 (ja) * | 2009-10-09 | 2014-10-01 | 株式会社ダイフレックス | 手塗り施工用塗工剤 |
| ITMI20110062A1 (it) * | 2011-01-24 | 2012-07-25 | Dow Chemical Co | Poliuretani polieteri con migliore resistenza allo scivolo in condizioni umide |
| US9023910B2 (en) | 2012-01-18 | 2015-05-05 | Basf Se | Low-density polyurethane shoe soles or sole parts with high rebound resilience and low compression set |
| CN104066763A (zh) | 2012-01-18 | 2014-09-24 | 巴斯夫欧洲公司 | 具有高回弹性和低压缩形变的低密度聚氨酯鞋底或鞋底部分 |
| US9695266B2 (en) * | 2013-03-06 | 2017-07-04 | Foamtec International Co., Ltd. | Wettable, high strength foam especially for ink holders |
| CN103419371B (zh) * | 2013-08-01 | 2015-06-03 | 四川大学 | 一种具有开孔结构的橡胶泡沫材料的制备方法 |
| CN103627310B (zh) * | 2013-11-01 | 2016-01-06 | 华南理工大学 | 一种环保型聚氨酯塑胶跑道的喷涂面层的制备方法 |
| CN107383322B (zh) * | 2017-08-30 | 2020-12-18 | 中车青岛四方车辆研究所有限公司 | 城轨用低动静刚度比聚氨酯微孔弹性体组合料及制备方法 |
| MX2020003218A (es) * | 2017-09-21 | 2020-07-29 | Basf Se | Composicion y metodo para producir sistemas de espuma de poliuretano microcelular. |
| KR101939205B1 (ko) * | 2018-02-22 | 2019-01-17 | 정순구 | 미드솔로 이루어진 기능성 신발 밑창 |
| WO2019178154A1 (en) * | 2018-03-12 | 2019-09-19 | Nike Innovate C.V. | A method for making a thermoplastic foam article |
| US11447615B2 (en) * | 2019-09-12 | 2022-09-20 | Nike, Inc. | Foam compositions and uses thereof |
| GB2600855B (en) | 2019-09-12 | 2024-05-29 | Nike Innovate Cv | A cushioning element for an article of footwear |
| US20230250220A1 (en) * | 2020-07-10 | 2023-08-10 | Basf Se | Process for preparing a crosslinked thermoplastic polyurethane and articles thereof |
| EP4308620A1 (en) * | 2021-03-15 | 2024-01-24 | Toscana Gomma S.p.A. | Process for making a polyurethane gel |
| CN114395105A (zh) * | 2021-12-31 | 2022-04-26 | 广东粤港澳大湾区黄埔材料研究院 | 一种聚氨酯微孔弹性体及应用该弹性体的鞋底材料、减震材料 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4906672A (en) * | 1988-07-29 | 1990-03-06 | Pmc, Inc. | Blowing agents for polyurethane foam |
| US5120770A (en) | 1989-11-29 | 1992-06-09 | Doyle Earl N | Use of liquid carbon dioxide as a blowing agent in the production of open-cell polyurethane foam |
| US5403088A (en) * | 1993-06-18 | 1995-04-04 | The Dow Chemical Company | Apparatus and method for the dispersion of minute bubbles in liquid materials for the production of polymer foams |
| US5500450A (en) * | 1995-04-05 | 1996-03-19 | The United States Of America As Represented By The Department Of Energy | Ultra-low density microcellular polymer foam and method |
| DE19622742C1 (de) | 1996-06-07 | 1998-03-12 | Hennecke Gmbh | Verfahren zur Schaumherstellung mittels unter Druck gelöstem Kohlendioxid |
| US6022903A (en) * | 1998-07-09 | 2000-02-08 | Arco Chemical Technology L.P. | Permanent gas blown microcellular polyurethane elastomers |
| US6100310A (en) * | 1998-09-25 | 2000-08-08 | Bayer Antwerp N.V. | Process for making microcellular polyurethane elastomers |
| AU3283400A (en) * | 1999-02-26 | 2000-09-14 | Bayer Antwerpen N.V. | Process for making microcellular polyurethane elastomers with improved processability |
-
2001
- 2001-01-18 US US09/764,682 patent/US6458861B1/en not_active Expired - Fee Related
-
2002
- 2002-01-10 CA CA2367077A patent/CA2367077C/en not_active Expired - Fee Related
- 2002-01-11 SK SK42-2002A patent/SK422002A3/sk unknown
- 2002-01-14 MX MXPA02000493A patent/MXPA02000493A/es active IP Right Grant
- 2002-01-15 AT AT02000254T patent/ATE289329T1/de not_active IP Right Cessation
- 2002-01-15 EP EP02000254A patent/EP1225199B1/en not_active Expired - Lifetime
- 2002-01-15 DE DE60202975T patent/DE60202975T2/de not_active Expired - Lifetime
- 2002-01-16 PL PL02351735A patent/PL351735A1/xx not_active Application Discontinuation
- 2002-01-17 RU RU2002100702/12A patent/RU2002100702A/ru not_active Application Discontinuation
- 2002-01-17 HU HU0200183A patent/HUP0200183A3/hu unknown
- 2002-01-17 KR KR1020020002643A patent/KR100803856B1/ko not_active Expired - Fee Related
- 2002-01-17 BR BR0200091-1A patent/BR0200091A/pt not_active Application Discontinuation
- 2002-01-18 AR ARP020100189A patent/AR038656A1/es unknown
- 2002-01-18 AU AU10218/02A patent/AU1021802A/en not_active Abandoned
- 2002-01-18 JP JP2002009870A patent/JP2002241462A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU1021802A (en) | 2002-07-25 |
| KR100803856B1 (ko) | 2008-02-14 |
| CA2367077C (en) | 2011-03-22 |
| KR20020062180A (ko) | 2002-07-25 |
| MXPA02000493A (es) | 2004-05-21 |
| HUP0200183A2 (hu) | 2002-11-28 |
| DE60202975D1 (de) | 2005-03-24 |
| US6458861B1 (en) | 2002-10-01 |
| EP1225199A1 (en) | 2002-07-24 |
| JP2002241462A (ja) | 2002-08-28 |
| HUP0200183A3 (en) | 2003-12-29 |
| HU0200183D0 (en) | 2002-03-28 |
| ATE289329T1 (de) | 2005-03-15 |
| RU2002100702A (ru) | 2003-07-20 |
| BR0200091A (pt) | 2002-10-22 |
| CA2367077A1 (en) | 2002-07-18 |
| PL351735A1 (en) | 2002-07-29 |
| SK422002A3 (en) | 2003-07-01 |
| EP1225199B1 (en) | 2005-02-16 |
| DE60202975T2 (de) | 2006-04-13 |
| US20020132870A1 (en) | 2002-09-19 |
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