AR024267A1 - Procedimiento para realizar reacciones cataliticas multifase, en particular, vinilaciones de acidos carboxilicos - Google Patents
Procedimiento para realizar reacciones cataliticas multifase, en particular, vinilaciones de acidos carboxilicosInfo
- Publication number
- AR024267A1 AR024267A1 ARP000102743A ARP000102743A AR024267A1 AR 024267 A1 AR024267 A1 AR 024267A1 AR P000102743 A ARP000102743 A AR P000102743A AR P000102743 A ARP000102743 A AR P000102743A AR 024267 A1 AR024267 A1 AR 024267A1
- Authority
- AR
- Argentina
- Prior art keywords
- procedure
- carboxyl acid
- catalytic reactions
- multiphase catalytic
- acid links
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- -1 CARBOXYL Chemical class 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 238000006555 catalytic reaction Methods 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229920001567 vinyl ester resin Polymers 0.000 abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- 150000001735 carboxylic acids Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/007—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
- C07C67/055—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation in the presence of platinum group metals or their compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00103—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor in a heat exchanger separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00105—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling
- B01J2219/0011—Controlling the temperature by indirect heating or cooling employing heat exchange fluids part or all of the reactants being heated or cooled outside the reactor while recycling involving reactant liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00243—Mathematical modelling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Un procedimiento catalítico para llevar a acabo reacciones multifase en un reactor tubular, en donde el catalizador se encuentra presente en la fasecontinua y al menos un material de partida se encuentra presente en la fase dispersa, y el factor dec arga B del reactor tubular es igual a o mayor que 0,8. Elprocedimiento es particularmente adecuado para la preparacion de ésteres vinílicos por reaccion de los ácidos carboxílicos con acetileno. Los ésteres vinílicosobtenidos se usan para lapreparac ion de homopolímeros o copolímeros.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19925385A DE19925385A1 (de) | 1999-06-02 | 1999-06-02 | Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Vinylierungen von Carbonsäuren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR024267A1 true AR024267A1 (es) | 2002-09-25 |
Family
ID=7910095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP000102743A AR024267A1 (es) | 1999-06-02 | 2000-06-02 | Procedimiento para realizar reacciones cataliticas multifase, en particular, vinilaciones de acidos carboxilicos |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US6500979B1 (es) |
| EP (1) | EP1057525B1 (es) |
| JP (1) | JP2001019660A (es) |
| KR (1) | KR100648848B1 (es) |
| CN (1) | CN1183093C (es) |
| AR (1) | AR024267A1 (es) |
| AT (1) | ATE387955T1 (es) |
| BR (1) | BR0002555A (es) |
| CA (1) | CA2310512A1 (es) |
| DE (2) | DE19925385A1 (es) |
| ES (1) | ES2301459T3 (es) |
| MX (1) | MXPA00005432A (es) |
| MY (1) | MY123679A (es) |
| PL (1) | PL200925B1 (es) |
| SG (1) | SG85706A1 (es) |
| TW (1) | TW523423B (es) |
| ZA (1) | ZA200002739B (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19957522A1 (de) * | 1999-11-30 | 2001-05-31 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Durchführung von Aldolkondensationen mittels Mehrphasenreaktion |
| DE10106186A1 (de) | 2001-02-10 | 2002-08-14 | Oxeno Olefinchemie Gmbh | Verfahren zur Kondensation von Aldehyden mit Ketonen mittels Mehrphasenreaktion |
| US20040000474A1 (en) * | 2002-02-22 | 2004-01-01 | Catalytic Distillation Technologies | Liquid-continuous column distillation |
| DE102004011081A1 (de) * | 2004-03-06 | 2005-09-22 | Oxeno Olefinchemie Gmbh | Verfahren zur Herstellung von tertiären Carbonsäuren |
| US8173830B2 (en) * | 2009-05-07 | 2012-05-08 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing homogeneous catalyst |
| US7982065B2 (en) * | 2009-05-07 | 2011-07-19 | Celanese International Corporation | Vinyl ester production from acetylene and carboxylic acid utilizing heterogeneous catalyst |
| WO2012174729A1 (en) * | 2011-06-24 | 2012-12-27 | The Southwest Research & Design Institute Of Chemical Industry | Process for preparing vinyl esters of tertiary carboxylic acids |
| DE102012002274A1 (de) | 2012-02-06 | 2013-08-08 | Oxea Gmbh | Verfahren zur Koppelproduktion von Vinylestern und Essigsäurefolgeprodukten oder Propionsäurefolgeprodukten |
| DE102012002282A1 (de) | 2012-02-06 | 2013-08-08 | Oxea Gmbh | Verfahren zur Herstellung von Vinylestern |
| CN102617344B (zh) * | 2012-03-09 | 2014-04-16 | 天津市沃克玛特科技有限公司 | 羧酸乙烯酯的制备方法 |
| US20140005352A1 (en) * | 2012-06-29 | 2014-01-02 | Invista North America S.A R.L. | Gas scrubber and related processes |
| DE102012105874A1 (de) | 2012-07-02 | 2014-01-02 | Oxea Gmbh | Verfahren zur Herstellung von Isononansäurevinylestern |
| DE102012013969B4 (de) | 2012-07-13 | 2017-09-14 | Oxea Gmbh | Verfahren zur Herstellung eines Gemisches stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol |
| DE102012014396B4 (de) * | 2012-07-13 | 2018-01-11 | Oxea Gmbh | Verfahren zur Herstellung eines Vinylestergemisches aus einem Gemisch stellungsisomerer aliphatischer Isononansäuren ausgehend von 2-Ethylhexanol |
| CN102847492A (zh) * | 2012-10-16 | 2013-01-02 | 四川国光农化股份有限公司 | 一种适用于气液反应的制备装置 |
| CN118405735B (zh) * | 2024-04-17 | 2024-12-24 | 金沂蒙集团有限公司 | 一种乙醛废水的处理装置 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1237557B (de) | 1962-07-10 | 1967-03-30 | Shell Int Research | Verfahren zur Herstellung von Vinylestern gesaettigter aliphatischer Monocarbonsaeuren |
| DE1210810B (de) * | 1963-08-05 | 1966-02-17 | Wacker Chemie Gmbh | Verfahren zur kontinuierlichen Herstellung von Vinylestern |
| DE1238010B (de) * | 1964-03-09 | 1967-04-06 | Wacker Chemie Gmbh | Verfahren zur kontinuierlichen Herstellung von Vinylestern |
| GB1125055A (en) * | 1967-04-27 | 1968-08-28 | Shell Int Research | Improvements in or relating to the preparation of vinyl esters |
| DE4313922A1 (de) | 1993-04-28 | 1994-11-03 | Basf Ag | Verfahren zur Herstellung von Carbonsäurevinylestern |
| US5430179A (en) * | 1994-07-28 | 1995-07-04 | Union Carbide Chemicals & Plastics Technology | Homogeneous process for the ruthenium catalyzed addition of carboxylic acids to alkynes |
| DE69609616T2 (de) * | 1995-08-11 | 2001-04-12 | Minnesota Mining And Mfg. Co., Saint Paul | Initiatorsystem und daraus hergestellte klebstoffzusammensetzung |
| ZA979132B (en) * | 1996-10-15 | 1998-07-17 | Shell Int Research | A process for the preparation of vinylesters |
| DE19925384A1 (de) * | 1999-06-02 | 2000-12-07 | Oxeno Olefinchemie Gmbh | Verfahren zur katalytischen Durchführung von Mehrphasenreaktionen, insbesondere Hydroformylierungen |
-
1999
- 1999-06-02 DE DE19925385A patent/DE19925385A1/de not_active Withdrawn
-
2000
- 2000-05-09 AT AT00109784T patent/ATE387955T1/de not_active IP Right Cessation
- 2000-05-09 EP EP00109784A patent/EP1057525B1/de not_active Expired - Lifetime
- 2000-05-09 DE DE50015006T patent/DE50015006D1/de not_active Expired - Lifetime
- 2000-05-09 ES ES00109784T patent/ES2301459T3/es not_active Expired - Lifetime
- 2000-05-30 JP JP2000160521A patent/JP2001019660A/ja active Pending
- 2000-05-31 CA CA002310512A patent/CA2310512A1/en not_active Abandoned
- 2000-05-31 US US09/583,776 patent/US6500979B1/en not_active Expired - Lifetime
- 2000-05-31 SG SG200002944A patent/SG85706A1/en unknown
- 2000-06-01 CN CNB001317415A patent/CN1183093C/zh not_active Expired - Fee Related
- 2000-06-01 MY MYPI20002475A patent/MY123679A/en unknown
- 2000-06-01 MX MXPA00005432A patent/MXPA00005432A/es unknown
- 2000-06-01 KR KR1020000029966A patent/KR100648848B1/ko not_active Expired - Fee Related
- 2000-06-01 ZA ZA200002739A patent/ZA200002739B/xx unknown
- 2000-06-01 PL PL340447A patent/PL200925B1/pl unknown
- 2000-06-01 TW TW089110686A patent/TW523423B/zh not_active IP Right Cessation
- 2000-06-01 BR BR0002555-0A patent/BR0002555A/pt not_active Application Discontinuation
- 2000-06-02 AR ARP000102743A patent/AR024267A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CN1290684A (zh) | 2001-04-11 |
| CN1183093C (zh) | 2005-01-05 |
| US6500979B1 (en) | 2002-12-31 |
| SG85706A1 (en) | 2002-01-15 |
| HK1036051A1 (en) | 2001-12-21 |
| KR100648848B1 (ko) | 2006-11-24 |
| PL200925B1 (pl) | 2009-02-27 |
| EP1057525A3 (de) | 2002-04-17 |
| PL340447A1 (en) | 2000-12-04 |
| EP1057525B1 (de) | 2008-03-05 |
| CA2310512A1 (en) | 2000-12-02 |
| TW523423B (en) | 2003-03-11 |
| KR20010049468A (ko) | 2001-06-15 |
| EP1057525A2 (de) | 2000-12-06 |
| BR0002555A (pt) | 2001-01-02 |
| ATE387955T1 (de) | 2008-03-15 |
| ES2301459T3 (es) | 2008-07-01 |
| MY123679A (en) | 2006-05-31 |
| MXPA00005432A (es) | 2002-06-04 |
| DE50015006D1 (de) | 2008-04-17 |
| ZA200002739B (en) | 2000-12-11 |
| DE19925385A1 (de) | 2000-12-07 |
| JP2001019660A (ja) | 2001-01-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration | ||
| FG | Grant, registration |