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AR012220A1 - Polimero de etileno y alfa olefina, film que comprende al polimero y un procedimiento en fase continua de gas para la polimerizacion. - Google Patents

Polimero de etileno y alfa olefina, film que comprende al polimero y un procedimiento en fase continua de gas para la polimerizacion.

Info

Publication number
AR012220A1
AR012220A1 ARP980101483A ARP980101483A AR012220A1 AR 012220 A1 AR012220 A1 AR 012220A1 AR P980101483 A ARP980101483 A AR P980101483A AR P980101483 A ARP980101483 A AR P980101483A AR 012220 A1 AR012220 A1 AR 012220A1
Authority
AR
Argentina
Prior art keywords
polymer
ethylene
polymerization
film
continuous phase
Prior art date
Application number
ARP980101483A
Other languages
English (en)
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of AR012220A1 publication Critical patent/AR012220A1/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/08—Copolymers of ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)
  • Laminated Bodies (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

Un polímero de etileno y de por lo menos una alfa olefina que tiene por lo menos 5 átomos, obtenible mediante polimerizacion en fase contínua de gas,usando un catalizador soportador de un catalizador discreto molecularmente activado, tal comou n metaloceno en ausencia de un depurador a base de alquilaluminio, cuyo polímero tiene un indice de fusion (IF) tal como el definido aquí desde 0,1 a 15; un indice de Amplitud de Distribucion Composicional(CDBI) tal como el definido aquí de por lo menos 70%, una densidad de desde 0,910 a 930 g/ml; un valor de turbidez tal como el definido aquí menos de 20%;una relacion del Indice de Fusion (RIF) tal como la definida aquí de desde 35 a 80; un Modulo promediado (M) tal como el definido aqu íde 20.000 a 60.000 psi(libras por pulgada cuadrada)(13790 a 41369 N/cm2) y una relacion entre M y la Resistencia al Impacto mediante Dardo en g/mil (DIS) de acuerdo con la formula:DIS < o = 0,8 X[100 + exp (11,71-0,000268Xm + 2,183X10-9Xm2)], película que comprende por lo menos una capa del polímero y procedimiento en fase de gaspara la polimerizacion del polímero de etileno.
ARP980101483A 1997-04-01 1998-04-01 Polimero de etileno y alfa olefina, film que comprende al polimero y un procedimiento en fase continua de gas para la polimerizacion. AR012220A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US4231097P 1997-04-01 1997-04-01

Publications (1)

Publication Number Publication Date
AR012220A1 true AR012220A1 (es) 2000-09-27

Family

ID=21921169

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP980101483A AR012220A1 (es) 1997-04-01 1998-04-01 Polimero de etileno y alfa olefina, film que comprende al polimero y un procedimiento en fase continua de gas para la polimerizacion.

Country Status (14)

Country Link
US (2) US6255426B1 (es)
EP (1) EP0973814B1 (es)
JP (1) JP4982003B2 (es)
KR (1) KR100529425B1 (es)
CN (1) CN1111550C (es)
AR (1) AR012220A1 (es)
AU (1) AU733306B2 (es)
BR (1) BR9807852A (es)
CA (1) CA2283246C (es)
DE (1) DE69819314T2 (es)
EA (1) EA002321B1 (es)
TW (1) TW422853B (es)
WO (1) WO1998044011A1 (es)
ZA (1) ZA982690B (es)

Families Citing this family (149)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7153909B2 (en) * 1994-11-17 2006-12-26 Dow Global Technologies Inc. High density ethylene homopolymers and blend compositions
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
US5998558A (en) * 1997-12-29 1999-12-07 Union Carbide Chemicals & Plastics Technology Corporation Ethylene polymers having enhanced processing ease
WO1999046302A1 (en) 1998-03-12 1999-09-16 Bp Chemicals Limited Polymerisation catalysts
ES2232125T5 (es) * 1998-04-06 2016-12-09 Borealis Technology Oy Composiciones de polietileno de alta densidad, un proceso para la fabricación de las mismas y películas preparadas a partir de las mismas
EP1204685B1 (de) 1999-08-13 2004-10-13 Basell Polyolefine GmbH Copolymere von ethylen mit c3-c9 alpha-olefinen
GB9928679D0 (en) * 1999-12-03 2000-02-02 Bp Chem Int Ltd Polymerisation process
US20080281063A9 (en) * 1999-12-30 2008-11-13 Sukhadia Ashish M Ethylene polymers and copolymers with high optical opacity and methods of making the same
EP1138702A1 (en) * 2000-03-30 2001-10-04 Fina Research S.A. Metallocene-produced polyethylene for glossy plastic containers
US6936675B2 (en) * 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
AU2003259234A1 (en) * 2002-07-31 2004-02-25 Exxonmobil Chemical Patents Inc. Silane crosslinkable polyethylene
EP1537175B1 (en) * 2002-09-05 2008-05-14 ExxonMobil Chemical Patents Inc. Shrink film
ATE494321T1 (de) * 2002-09-05 2011-01-15 Exxonmobil Chem Patents Inc Stretchfoliewickelverfahren
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
ATE399056T1 (de) 2002-12-20 2008-07-15 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe
CN101372521B (zh) 2002-12-20 2011-09-07 巴塞尔聚烯烃有限公司 乙烯和α-烯烃的共聚物
EP1589044A3 (en) 2003-08-11 2006-02-15 ExxonMobil Chemical Patents Inc. Polymers of ethylene and, optionally, copolymerizable esters, films using such polymers and stretch hood packaging processes using such films
US7422786B2 (en) * 2003-09-24 2008-09-09 Exxonmobil Chemical Patents Inc. Collation shrink
US6870010B1 (en) 2003-12-01 2005-03-22 Univation Technologies, Llc Low haze high strength polyethylene compositions
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
US7011335B2 (en) * 2004-01-29 2006-03-14 Deven Faye Kight Adjustable, bi-directional, removable baby stroller handle
US7094857B2 (en) * 2004-03-10 2006-08-22 Chevron Phillips Chemical Company, L.P. Ethylene polymers and copolymers with high optical opacity
US7588706B2 (en) 2004-12-16 2009-09-15 Exxonmobil Chemical Patents Inc. Multi-layer films with improved properties
US20060188678A1 (en) * 2005-02-21 2006-08-24 Ohlsson Stefan B Multi-layer polyethylene films
DE102005019395A1 (de) * 2005-04-25 2006-10-26 Basell Polyolefine Gmbh Formmasse aus Polyethylen zur Folienherstellung und Verfahren zum Herstellen der Formmasse in Gegenwart eines Mischkatalysators
EP1888659B1 (en) * 2005-05-10 2010-12-22 Ineos Europe Limited Novel copolymers
US7951873B2 (en) * 2006-05-05 2011-05-31 Exxonmobil Chemical Patents Inc. Linear low density polymer blends and articles made therefrom
GB0611331D0 (en) 2006-06-09 2006-07-19 Exxonmobil Chem Patents Inc Transparent coextruded films and processes for making such films
US20100093953A1 (en) * 2007-05-04 2010-04-15 Basell Polyolefine Gmbh Polyethylene, process and catalyst composition for the preparation thereof
CN101878237B (zh) * 2007-11-30 2013-04-24 住友化学株式会社 乙烯-α-烯烃共聚物和成型体
GB2458160A (en) * 2008-03-07 2009-09-09 Exxonmobil Chem Patents Inc High MIR linear polyethylene, in co-extruded films
US8283428B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Polymacromonomer and process for production thereof
US8802797B2 (en) 2008-06-20 2014-08-12 Exxonmobil Chemical Patents Inc. Vinyl-terminated macromonomer oligomerization
FR2934599B1 (fr) * 2008-07-29 2012-12-21 Arkema France Fabrication de polyethylene a partir de matieres renouvelables, polyethylene obtenu et utilisations
KR101003250B1 (ko) 2008-08-21 2010-12-21 삼성토탈 주식회사 우수한 투명성과 높은 충격강도를 갖는 선형 저밀도 폴리에틸렌 수지
KR101038592B1 (ko) 2008-08-27 2011-06-03 삼성토탈 주식회사 고수축성 선형 저밀도 폴리에틸렌 수지
US8957158B2 (en) * 2008-09-25 2015-02-17 Basell Polyolefine Gmbh Impact resistant LLDPE composition and films made thereof
BR112012013675A2 (pt) 2009-12-07 2016-04-19 Univation Tech Llc métodos para a produção de carga estática de um catalisador e métodos para o uso do catalisador para produzir poliolefinas
JP5471629B2 (ja) * 2010-03-10 2014-04-16 株式会社島津製作所 液体クロマトグラフ用分析システム及び該分析システムの制御プログラム
US8722804B2 (en) 2010-04-13 2014-05-13 Univation Technologies, Llc Polymer blends and films made therefrom
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012009216A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring particle accumulation on reactor surfaces
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
MX337727B (es) 2010-12-17 2016-03-16 Univation Tech Llc Sistemas y metodos para recuperar hidrocarburos a partir de un producto de gas de purga de poliolefinas.
WO2012112259A2 (en) 2011-02-15 2012-08-23 Exxonmobil Chemical Patents Inc. Thermoplastic polyolefin blends
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8785562B2 (en) 2011-03-25 2014-07-22 Exxonmobil Chemical Patents Inc. Amphiphilic block polymers prepared by alkene metathesis
US8318998B2 (en) 2011-03-25 2012-11-27 Exxonmobil Chemical Patents Inc. Enhanced catalyst performance for production of vinyl terminated propylene and ethylene/propylene macromers
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
US8501894B2 (en) 2011-03-25 2013-08-06 Exxonmobil Chemical Patents Inc. Hydrosilyation of vinyl macromers with metallocenes
US8455597B2 (en) 2011-03-25 2013-06-04 Exxonmobil Chemical Patents Inc. Catalysts and methods of use thereof to produce vinyl terminated polymers
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
US8669330B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Olefin triblock polymers via ring-opening metathesis polymerization
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8426659B2 (en) 2011-03-25 2013-04-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8669326B2 (en) 2011-03-25 2014-03-11 Exxonmobil Chemical Patents Inc. Amine functionalized polyolefin and methods for preparation thereof
CN103946022B (zh) 2011-12-02 2016-10-12 埃克森美孚化学专利公司 多层薄膜及其制造方法
CA2863694C (en) 2012-03-05 2020-11-03 Univation Technologies, Llc Methods for making catalyst compositions and polymer products produced therefrom
US9284415B2 (en) 2012-03-15 2016-03-15 Exxonmobil Chemical Patents Inc. Oxygen tailoring of polyethylene
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
US9115233B2 (en) 2012-06-21 2015-08-25 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CA2798855C (en) 2012-06-21 2021-01-26 Nova Chemicals Corporation Ethylene copolymers having reverse comonomer incorporation
US20140051771A1 (en) * 2012-08-20 2014-02-20 Ticona Llc Biomedical Devices Comprising Molded Polyethylene Components
KR20150038416A (ko) * 2012-09-14 2015-04-08 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌계 중합체 및 이로부터 제조된 물품
US9902822B2 (en) 2012-10-31 2018-02-27 Exxonmobil Chemical Patents Inc. Articles comprising broad molecular weight distribution polypropylene resins
WO2014070384A1 (en) 2012-10-31 2014-05-08 Exxonmobil Chemical Patents Inc. Articles comprising broad molecular weight distribution polypropylene resins
US9453093B2 (en) 2012-10-31 2016-09-27 Exxonmobil Chemical Patents Inc. Broad molecular weight distribution polypropylene resins
CN104837630B (zh) 2012-12-05 2017-02-22 埃克森美孚化学专利公司 基于乙烯的聚合物和由其制成的制品
WO2014088827A1 (en) 2012-12-05 2014-06-12 Exxonmobil Chemical Patents Inc. Hdpe modified polyethylene blown film compositions having excellent bubble stability
WO2014089671A1 (en) 2012-12-14 2014-06-19 Nova Chemicals (International) S.A. Ethylene copolymer compositions, film and polymerization processes
CN104903100B (zh) 2012-12-18 2017-11-14 埃克森美孚化学专利公司 聚乙烯膜及其制造方法
EP2746320A1 (en) 2012-12-20 2014-06-25 Basell Polyolefine GmbH Polyethylene composition having high mechanical properties
CA2800056A1 (en) 2012-12-24 2014-06-24 Nova Chemicals Corporation Polyethylene blend compositions
US9493591B2 (en) 2013-05-14 2016-11-15 Exxonmobil Chemical Patents Inc. Ethylene based polymers and articles made therefrom
WO2015012948A1 (en) 2013-07-23 2015-01-29 Exxonmobil Chemical Patents Inc. Polymer compositions, methods of making the same, and articles made therefrom
EP3060399A1 (en) 2013-10-16 2016-08-31 ExxonMobil Chemical Patents Inc. Enhanced stretched cling performance polyolefin films
MX2016006655A (es) * 2013-11-22 2016-12-16 Paragon Films Inc Películas de estiramiento mecánico moldeadas de alto rendimiento con propiedades mejoradas de aplicación y uso final.
US20160362510A1 (en) 2014-02-11 2016-12-15 Univation Technologies, Llc Method to prepare ethylene copolymers
EP3031831B1 (en) 2014-09-05 2019-06-19 LG Chem, Ltd. Supported hybrid catalyst and method for preparing olefin-based polymer using same
EP3261839B1 (en) 2015-03-17 2021-08-04 ExxonMobil Chemical Patents Inc. Multilayer films and methods thereof
US10618989B2 (en) 2015-04-20 2020-04-14 Exxonmobil Chemical Patents Inc. Polyethylene composition
WO2016177621A1 (en) 2015-05-04 2016-11-10 Exxonmobil Chemical Patents Inc. Processes for collation shrink packaging with a thermally insulating film
US10308736B2 (en) 2015-09-17 2019-06-04 Exxonmobil Chemical Patents Inc. Polyethylene polymers and articles made therefrom
EP3414280A1 (en) 2016-02-10 2018-12-19 ExxonMobil Chemical Patents Inc. Polyethylene shrink films and processes for making the same
EP3411428B1 (en) * 2016-02-10 2022-02-09 ExxonMobil Chemical Patents Inc. Polyethylene films and processes for making them
CN109071844A (zh) 2016-04-22 2018-12-21 埃克森美孚化学专利公司 聚乙烯片材
WO2018017180A1 (en) 2016-07-21 2018-01-25 Exxonmobil Chemical Patents Inc. Rotomolded compositions, articles, and processes for making the same
US10975183B2 (en) 2016-09-09 2021-04-13 Exxonmobil Chemical Patents Inc. Pilot plant scale semi-condensing operation
WO2018064048A1 (en) 2016-09-27 2018-04-05 Univation Technologies, Llc Method for long chain branching control in polyethylene production
US10882932B2 (en) 2016-10-05 2021-01-05 Exxonmobil Chemical Patents Inc. Sterically hindered metallocenes, synthesis and use
WO2018102091A1 (en) 2016-12-02 2018-06-07 Exxonmobil Chemical Patents Inc. Polyethylene films
WO2018106480A1 (en) 2016-12-06 2018-06-14 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
KR102087340B1 (ko) * 2016-12-20 2020-03-10 주식회사 엘지화학 폴리올레핀계 필름
KR102139364B1 (ko) * 2016-12-20 2020-07-29 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
CN110637049B (zh) 2017-04-06 2022-04-05 埃克森美孚化学专利公司 流延膜及其制造方法
WO2018194740A1 (en) 2017-04-19 2018-10-25 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2018226311A1 (en) 2017-06-08 2018-12-13 Exxonmobil Chemical Patents Inc. Polyethylene blends and extrudates and methods of making the same
WO2019022801A1 (en) 2017-07-24 2019-01-31 Exxonmobil Chemical Patents Inc. POLYETHYLENE FILMS AND METHODS OF PRODUCING THE SAME
WO2019027524A1 (en) 2017-08-02 2019-02-07 Exxonmobil Chemical Patents Inc. MULTILAYER FILMS AND METHODS OF MANUFACTURE
CN111183160B (zh) 2017-10-06 2022-06-10 埃克森美孚化学专利公司 聚乙烯挤出物及其制备方法
US11479624B2 (en) 2017-11-17 2022-10-25 Exxonmobil Chemical Patents Inc. PE-RT pipes and processes for making the same
US11691398B2 (en) 2017-11-28 2023-07-04 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
US11952480B2 (en) 2018-02-05 2024-04-09 Exxonmobil Chemical Patents Inc. Enhanced processability of LLDPE by addition of ultra-high molecular weight density polyethylene
SG11202008315TA (en) 2018-03-26 2020-10-29 Dow Global Technologies Llc Spray-dried zirconocene catalyst system
US11441023B2 (en) 2018-04-27 2022-09-13 Exxonmobil Chemical Patents Inc. Polyethylene films and methods of making the same
US11459408B2 (en) 2018-05-02 2022-10-04 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
WO2019213227A1 (en) 2018-05-02 2019-11-07 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
EP3797132A1 (en) 2018-05-22 2021-03-31 ExxonMobil Chemical Patents Inc. Methods for forming films and their related computing devices
WO2020068497A1 (en) 2018-09-25 2020-04-02 Exxonmobil Chemical Patents Inc. Multilayer films and methods of making the same
WO2020167929A1 (en) 2019-02-13 2020-08-20 Exxonmobil Chemical Patents Inc. Methods for making films and films made thereby
US12036716B2 (en) 2019-02-13 2024-07-16 Exxonmobil Chemical Patents Inc. Oriented multilayer polyethylene films and laminates thereof
WO2020190507A1 (en) 2019-03-19 2020-09-24 Exxonmobil Chemical Patents Inc. Multilayer oriented films
US20220145024A1 (en) 2019-05-01 2022-05-12 Exxonmobil Chemical Patents Inc. Heat-Shrinkable Polyethylene Films
CN113993977B (zh) 2019-05-24 2024-09-13 伊士曼化工公司 进入气体裂化器中加工的液体流中混入少量热解油
US12497467B2 (en) 2019-05-24 2025-12-16 Exxon Mobil Product Solutions Company Recycle content cellulose ester
WO2020247192A1 (en) 2019-05-24 2020-12-10 Eastman Chemical Company Recycle content cracked effluent
WO2021021847A1 (en) 2019-07-29 2021-02-04 Eastman Chemical Company Recycle content (c4)alkanal
CN114174375B (zh) 2019-07-29 2025-01-28 伊士曼化工公司 回收成分环丁二醇聚酯
KR20220091549A (ko) 2019-10-31 2022-06-30 이스트만 케미칼 컴파니 재활용된 폐기물을 위한 열분해 방법 및 시스템
US11945998B2 (en) 2019-10-31 2024-04-02 Eastman Chemical Company Processes and systems for making recycle content hydrocarbons
US12104121B2 (en) 2019-11-07 2024-10-01 Eastman Chemical Company Recycle content mixed esters and solvents
US11939534B2 (en) 2019-11-07 2024-03-26 Eastman Chemical Company Recycle content alpha olefins and fatty alcohols
CN119080582A (zh) 2019-11-07 2024-12-06 伊士曼化工公司 回收成分羰基合成醇和羰基合成增塑剂
WO2021092309A1 (en) 2019-11-07 2021-05-14 Eastman Chemical Company Recycle content propanol
WO2021118715A1 (en) * 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Low aromatic polyolefins
WO2021154442A1 (en) 2020-01-31 2021-08-05 Exxonmobil Research And Engineering Company Polyethylene films having high tear strength
WO2021167739A1 (en) 2020-02-18 2021-08-26 Exxonmobil Chemical Patents Inc. High tenacity handwrap stretch film for improved pallet stability
WO2021188256A1 (en) 2020-03-18 2021-09-23 Exxonmobil Chemical Patents Inc. Extrusion blow molded articles and processes for making same
CA3174931A1 (en) 2020-04-13 2021-10-21 Bruce Roger Debruin Recycle content polyethylene
WO2021221904A1 (en) 2020-04-28 2021-11-04 Exxonmobil Chemical Patents Inc. Density and chemical composition control for polymer with good stress crack properties
WO2021236322A1 (en) 2020-05-19 2021-11-25 Exxonmobil Chemical Patents Inc. Extrusion blow molded containers and processes for making same
US12195674B2 (en) 2021-09-21 2025-01-14 Eastman Chemical Company Using spent caustic solution from pygas treatment to neutralize halogens from liquified waste plastic
EP4499716A1 (en) 2022-03-31 2025-02-05 ExxonMobil Chemical Patents Inc. Linear low density polyethylenes, polymerizations thereof, and films thereof
US20250340682A1 (en) 2022-05-18 2025-11-06 Exxonmobil Chemical Patents Inc. Polyethylene compositions and processes for their production
CN119365499A (zh) 2022-06-15 2025-01-24 埃克森美孚化学专利公司 基于乙烯的聚合物、由其制成的制品和制备其的方法
WO2024044423A1 (en) 2022-08-22 2024-02-29 Exxonmobil Chemical Patents, Inc. Polyethylene compositions and films made therefrom
EP4584306A1 (en) 2022-09-07 2025-07-16 ExxonMobil Chemical Patents Inc. Polyethylenes and articles thereof
EP4594397A1 (en) * 2022-09-30 2025-08-06 TotalEnergies OneTech Asymmetric machine-direction oriented polyethylene film formed by cast extrusion with sealing properties and laminate comprising such a film
WO2024242933A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
WO2024242936A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Catalysts and polymerizations for improved polyolefins
WO2024242932A1 (en) 2023-05-23 2024-11-28 ExxonMobil Technology and Engineering Company Polethylenes, catalysts for their polymerization, and films thereof
CN121464161A (zh) 2023-05-23 2026-02-03 埃克森美孚技术与工程公司 具有改进的加工性的聚乙烯及其膜
WO2025221361A1 (en) 2024-04-19 2025-10-23 ExxonMobil Technology and Engineering Company Setting reactor operator parameters based on polymer properties and/or polymer film properties
WO2026024387A1 (en) 2024-07-22 2026-01-29 ExxonMobil Technology and Engineering Company Polyethylene sealing layer resins

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5580939A (en) 1983-06-06 1996-12-03 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5008204A (en) 1988-02-02 1991-04-16 Exxon Chemical Patents Inc. Method for determining the compositional distribution of a crystalline copolymer
CA2003882C (en) 1988-12-19 1997-01-07 Edwin Rogers Smith Heat shrinkable very low density polyethylene terpolymer film
US5639842A (en) 1988-12-26 1997-06-17 Mitsui Petrochemical Industries, Ltd. Ethylene random copolymers
DE68928696T2 (de) 1988-12-26 1998-12-03 Mitsui Chemicals, Inc., Tokio/Tokyo Olefin-kopolymer und verfahren zur herstellung
EP0955322A3 (en) 1988-12-26 1999-12-08 Mitsui Chemicals, Inc. Olefin copolymers and processes for preparing same
MY107639A (en) 1990-04-18 1996-05-30 Mitsui Chemicals Incorporated Process for the preparation of an ethylene copolymer and an olefin polymer, and catalyst for olefin polymeri -zation
CA2113627A1 (en) 1991-07-18 1993-02-18 Prasadarao Meka Heat sealed article
US5278272A (en) 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
ES2109473T3 (es) 1991-12-13 1998-01-16 Exxon Chemical Patents Inc Copolimeros de etileno/alfa-olefinas superiores.
JP2888639B2 (ja) 1992-04-20 1999-05-10 エクソン・ケミカル・パテンツ・インク エチレン／分枝鎖オレフィンのコポリマー
EP0675906B2 (en) 1992-12-28 2007-01-10 Exxonmobil Oil Corporation Linear low density polyethylene film
PT719289E (pt) 1993-09-17 2000-05-31 Dow Chemical Co Polimerizacao de olefinas em fase gasosa
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
ATE317858T1 (de) 1994-04-07 2006-03-15 Innovene Europ Ltd Polymerisationsverfahren und so enthaltende polyolefinen
US5763543A (en) 1994-09-14 1998-06-09 Exxon Chemical Patents Inc. Olefin polymerization process with little or no scavenger present
US5403014A (en) 1994-09-15 1995-04-04 Anema; Dale A. Game and method of play
US5929129A (en) 1994-09-19 1999-07-27 Sentinel Products Corp. Crosslinked foamable compositions of silane-grafted, essentially linear polyolefins blended with polypropylene
US6114477A (en) 1996-02-09 2000-09-05 Exxon Chemical Patents Inc. Polymerization process

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WO1998044011A1 (en) 1998-10-08
US6255426B1 (en) 2001-07-03
US6476171B1 (en) 2002-11-05
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EA002321B1 (ru) 2002-04-25
KR20010005690A (ko) 2001-01-15
KR100529425B1 (ko) 2005-11-17
EP0973814A1 (en) 2000-01-26
ZA982690B (en) 1999-03-16
DE69819314D1 (de) 2003-12-04
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