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AR011387A1 - Una composicion catalitica y un procedimiento para la polimerizacion de una olefina - Google Patents

Una composicion catalitica y un procedimiento para la polimerizacion de una olefina

Info

Publication number
AR011387A1
AR011387A1 ARP980100100A ARP980100100A AR011387A1 AR 011387 A1 AR011387 A1 AR 011387A1 AR P980100100 A ARP980100100 A AR P980100100A AR P980100100 A ARP980100100 A AR P980100100A AR 011387 A1 AR011387 A1 AR 011387A1
Authority
AR
Argentina
Prior art keywords
carbon atoms
group
catalytic composition
polymerization
radical
Prior art date
Application number
ARP980100100A
Other languages
English (en)
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of AR011387A1 publication Critical patent/AR011387A1/es

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Una composicion catalítica que comprende el producto de reaccion de: a) precursor catalítico monocicloalcadienilo de la formula LMXx donde: M es unmetal de los grupos IIIB a VIII o un metal de tierra rara de la tabla periodica; L es unligando cicloalcadienilo, cada X independientemente eshidrogeno, un radical arilo, alquilo, alquenilo, alquil arilo, o arilalquilo que tiene 1-20 átomos de carbono, un radical hidrocarboxi que tiene 1-20 átomosde carbono, un haluro, un radicalque contiene nitrogeno con 1-20 átomos de carbono, o Q2YZ, donde cada Q es seleccionado independientemente entre el grupoque comprende -O-, -NR-, CR2- y -S-, Y es C o S; Z se selecciona entre el grupo que comprende -OR, -NR2, -CR3, -SR, -SiR3, -PR2, -H, y grupos arilo sustituidoso no, con la condicion de que cuando Q es -NR- entonces Z se seleciciona entre el grupo que comprende -OR, -NR2, -SR, -SiR3, -PR2, -H; y x es 2, 3 o 4dependiendo de la valencia de M; b) un cicloalcadieno deincremento de actividad; y c) un cocatalizador activador. Un procedimiento para lapolimerizacion de una olefina que comprende contactar al menos un monomero de olefina en condiciones de polimerizacion, con la composicion catalítica.
ARP980100100A 1997-01-10 1998-01-09 Una composicion catalitica y un procedimiento para la polimerizacion de una olefina AR011387A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US08/782,504 US5747406A (en) 1997-01-10 1997-01-10 Catalyst composition for the production of olefin polymers

Publications (1)

Publication Number Publication Date
AR011387A1 true AR011387A1 (es) 2000-08-16

Family

ID=25126264

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP980100100A AR011387A1 (es) 1997-01-10 1998-01-09 Una composicion catalitica y un procedimiento para la polimerizacion de una olefina

Country Status (14)

Country Link
US (2) US5747406A (es)
EP (1) EP0952994B1 (es)
JP (1) JP2001509827A (es)
AR (1) AR011387A1 (es)
AU (1) AU736451B2 (es)
BR (1) BR9806251A (es)
CA (1) CA2277057C (es)
DE (1) DE69812889D1 (es)
EG (1) EG21245A (es)
ES (1) ES2196529T3 (es)
ID (1) ID20933A (es)
MY (1) MY132847A (es)
TW (1) TW588061B (es)
WO (1) WO1998030607A1 (es)

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69428990T2 (de) * 1993-03-31 2002-04-04 Idemitsu Kosan Co. Ltd., Tokio/Tokyo Katalysator zur herstellung von vinylpolymer und verfahren zur herstellung von vinylaromatischem polymer
WO1996013529A1 (en) * 1994-10-31 1996-05-09 Dsm N.V. Catalyst composition and process for the polymerization of an olefin
US6054405A (en) * 1997-12-29 2000-04-25 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for the polymerization of olefins
US6552137B1 (en) 2000-11-16 2003-04-22 Univation Technologies, Llc Catalyst system and its use in olefin polymerization
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
WO2002040549A2 (en) * 2000-11-17 2002-05-23 Univation Technologies, Llc A method for preparing a catalyst composition and its use in a polymerization process
WO2005108442A1 (en) 2002-10-15 2005-11-17 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
DE10257185B3 (de) * 2002-12-06 2004-02-05 Infineon Technologies Ag Phasenregelschleife mit Sigma-Delta-Modulator
US7365039B2 (en) * 2003-03-21 2008-04-29 Dow Global Technologies Inc. Morphology controlled olefin polymerization process
US7087301B2 (en) * 2003-08-06 2006-08-08 Fina Technology, Inc. Bicomponent fibers of syndiotactic polypropylene
US7244795B2 (en) * 2003-12-08 2007-07-17 Univation Technologies, Llc Polymerization process using metallocene catalyst systems
US7410926B2 (en) * 2003-12-30 2008-08-12 Univation Technologies, Llc Polymerization process using a supported, treated catalyst system
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20050182210A1 (en) 2004-02-17 2005-08-18 Natarajan Muruganandam De-foaming spray dried catalyst slurries
TW200631965A (en) * 2004-12-07 2006-09-16 Fina Technology Random copolymers and formulations useful for thermoforming and blow molding applications
US7241850B2 (en) * 2004-12-15 2007-07-10 Fina Technology, Inc. Polypropylene having improved clarity and articles prepared therefrom
US20070202285A1 (en) * 2004-12-15 2007-08-30 Fina Technology, Inc. Articles having improved clarity, prepared from propylene-ethylene copolymers
US7220806B2 (en) * 2005-04-29 2007-05-22 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7645834B2 (en) * 2005-04-29 2010-01-12 Fina Technologies, Inc. Catalyst system for production of polyolefins
US7081285B1 (en) 2005-04-29 2006-07-25 Fina Technology, Inc. Polyethylene useful for blown films and blow molding
US20060247394A1 (en) * 2005-04-29 2006-11-02 Fina Technology, Inc. Process for increasing ethylene incorporation into random copolymers
US7138474B1 (en) 2005-05-03 2006-11-21 Fina Technology, Inc. End use articles derived from polypropylene homopolymers and random copolymers
US7282546B2 (en) * 2005-06-22 2007-10-16 Fina Technology, Inc. Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
US7683002B2 (en) 2006-04-04 2010-03-23 Fina Technology, Inc. Transition metal catalyst and formation thereof
US20070299222A1 (en) 2006-04-04 2007-12-27 Fina Technology, Inc. Transition metal catalysts and formation thereof
US9061450B2 (en) * 2007-02-12 2015-06-23 Cree, Inc. Methods of forming packaged semiconductor light emitting devices having front contacts by compression molding
EP2112175A1 (en) 2008-04-16 2009-10-28 ExxonMobil Chemical Patents Inc. Activator for metallocenes comprising one or more halogen substituted heterocyclic heteroatom containing ligand coordinated to an alumoxane
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
US9334342B2 (en) 2008-10-01 2016-05-10 Fina Technology, Inc. Polypropylene for reduced plate out in polymer article production processes
JP5269756B2 (ja) * 2009-12-24 2013-08-21 日本ポリエチレン株式会社 オレフィン重合体の製造方法
CN102803308B (zh) 2010-02-18 2015-04-01 尤尼威蒂恩技术有限公司 用于操作聚合反应器的方法
MY157091A (en) 2010-04-13 2016-04-29 Univation Tech Llc Polymer blends and films made therefrom
US8278403B2 (en) 2010-07-08 2012-10-02 Fina Technology, Inc. Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers
EP2593217B1 (en) 2010-07-16 2014-07-02 Univation Technologies, LLC Systems and methods for measuring particle accumulation on reactor surfaces
WO2012009215A1 (en) 2010-07-16 2012-01-19 Univation Technologies, Llc Systems and methods for measuring static charge on particulates
WO2012015898A1 (en) 2010-07-28 2012-02-02 Univation Technologies, Llc Systems and methods for measuring velocity of a particle/fluid mixture
US8841393B2 (en) 2010-11-30 2014-09-23 Univation Technologies, Llc Catalyst composition having improved flow characteristics and methods of making and using the same
CN103298842B (zh) 2010-12-17 2016-08-31 尤尼威蒂恩技术有限责任公司 从聚烯烃吹扫气体产物回收烃的系统以及方法
US9637567B2 (en) 2011-05-13 2017-05-02 Univation Technologies, Llc Spray-dried catalyst compositions and polymerization processes employing the same
CN103917292B (zh) 2011-11-08 2016-11-23 尤尼威蒂恩技术有限责任公司 制备催化剂体系的方法
WO2013158225A1 (en) 2012-04-18 2013-10-24 Exxonmobil Chemical Patents Inc. Polyolefin compositions and methods of production thereof
ES2987855T3 (es) 2012-09-07 2024-11-18 Univation Tech Llc Un método para determinar la temperatura de adherencia de una resina
EP2951211B1 (en) 2013-01-30 2019-11-13 Univation Technologies, LLC Processes for making catalyst compositions having improved flow
BR112016022780B1 (pt) 2014-04-02 2021-08-17 Univation Technologies, Llc Composição de continuidade
WO2016085945A1 (en) 2014-11-25 2016-06-02 Univation Technologies, Llc Methods of monitoring and controlling the melt index of a polyolefin product during production
RU2696875C2 (ru) 2014-11-25 2019-08-07 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Способы изменения скорости производства полиолефинов с применением композиции индуцированных конденсирующих агентов
EP3224288A1 (en) 2014-11-25 2017-10-04 Univation Technologies, LLC Methods of changing polyolefin production conditions to mitigate small gels in a polyolefin article
PT3224287T (pt) 2014-11-25 2019-06-11 Univation Tech Llc Métodos de controle do índice de derretimento da poliolefina
WO2016145179A1 (en) 2015-03-10 2016-09-15 Univation Technologies, Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
ES2719407T3 (es) 2015-04-08 2019-07-10 Univation Tech Llc Transiciones en reactor cerrado entre catalizadores de metaloceno
WO2016176135A1 (en) 2015-04-27 2016-11-03 Univation Technologies, Llc Supported catalyst compositions having improved flow properties and preparation thereof
EP3749707A1 (en) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
US12152095B2 (en) 2019-03-21 2024-11-26 Exxonmobil Chemical Patents Inc. Methods for improving production in gas phase polymerization
EP3941949B1 (en) 2019-03-21 2025-10-22 ExxonMobil Chemical Patents Inc. Methods for improving gas phase polymerization
CN117098785A (zh) 2021-04-30 2023-11-21 埃克森美孚化学专利公司 用于聚合反应器中不同聚合催化剂之间的转变的方法
WO2025117117A1 (en) 2023-11-28 2025-06-05 ExxonMobil Technology and Engineering Company Quantifying entrainment in a fluidized bed reactor
WO2025136637A1 (en) 2023-12-20 2025-06-26 ExxonMobil Technology and Engineering Company Recovery method for polyolefin synthesis
WO2025136609A1 (en) 2023-12-20 2025-06-26 ExxonMobil Technology and Engineering Company Finishing systems and methods thereof
WO2025250307A1 (en) 2024-05-30 2025-12-04 ExxonMobil Technology and Engineering Company Methods for improving gas phase polymerization

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198401A (en) * 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5451555A (en) * 1991-06-27 1995-09-19 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
US5387567A (en) * 1991-06-27 1995-02-07 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
EP0546690B1 (en) * 1991-11-12 1998-03-04 Nippon Oil Co. Ltd. Catalyst components for polymerization of olefins
CA2089591C (en) * 1992-02-21 1997-06-03 Kenji Nakacho Polyolefin resin and method for the preparation thereof
EP0587440A3 (en) * 1992-09-10 1995-03-08 Nippon Oil Co Ltd Catalytic component for the polymerization of olefins and polymerization process using the same.
DE4402829A1 (de) * 1993-01-29 1994-08-04 Nippon Oil Co Ltd Katalysatorbestandteil und Katalysator zur Polymerisation von Olefinen
US5470993A (en) * 1993-06-24 1995-11-28 The Dow Chemical Company Titanium(II) or zirconium(II) complexes and addition polymerization catalysts therefrom
JP3349277B2 (ja) * 1994-07-26 2002-11-20 新日本石油株式会社 ポリオレフィンの製造方法
JP3352555B2 (ja) * 1994-12-01 2002-12-03 日本ポリオレフィン株式会社 オレフィン類重合用触媒
US5527752A (en) * 1995-03-29 1996-06-18 Union Carbide Chemicals & Plastics Technology Corporation Catalysts for the production of polyolefins

Also Published As

Publication number Publication date
MY132847A (en) 2007-10-31
WO1998030607A1 (en) 1998-07-16
TW588061B (en) 2004-05-21
JP2001509827A (ja) 2001-07-24
ID20933A (id) 1999-04-01
AU736451B2 (en) 2001-07-26
BR9806251A (pt) 2000-01-25
CA2277057A1 (en) 1998-07-16
CA2277057C (en) 2005-01-04
DE69812889D1 (de) 2003-05-08
EP0952994A1 (en) 1999-11-03
EG21245A (en) 2001-04-01
EP0952994B1 (en) 2003-04-02
US6066703A (en) 2000-05-23
AU5820998A (en) 1998-08-03
US5747406A (en) 1998-05-05
ES2196529T3 (es) 2003-12-16

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