AR016811A1 - 4-benzoil-pirazoles, procedimiento para su obtencion, los compuestos intermediarios en dicho procedimiento de sintesis, las composiciones herbicidas quecontienen dichos pirazoles, el procedimiento de obtencion de dichas composiciones, el procedimiento para controlar el crecimiento de plantas indesea - Google Patents
4-benzoil-pirazoles, procedimiento para su obtencion, los compuestos intermediarios en dicho procedimiento de sintesis, las composiciones herbicidas quecontienen dichos pirazoles, el procedimiento de obtencion de dichas composiciones, el procedimiento para controlar el crecimiento de plantas indeseaInfo
- Publication number
- AR016811A1 AR016811A1 ARP980103924A ARP980103924A AR016811A1 AR 016811 A1 AR016811 A1 AR 016811A1 AR P980103924 A ARP980103924 A AR P980103924A AR P980103924 A ARP980103924 A AR P980103924A AR 016811 A1 AR016811 A1 AR 016811A1
- Authority
- AR
- Argentina
- Prior art keywords
- procedure
- alkyl
- obtaining
- halogenoalkyl
- compounds
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 9
- 239000000203 mixture Substances 0.000 title abstract 5
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 239000004009 herbicide Substances 0.000 title abstract 4
- 230000002363 herbicidal effect Effects 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 4
- 241000196324 Embryophyta Species 0.000 abstract 3
- 125000001188 haloalkyl group Chemical group 0.000 abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 3
- 239000001257 hydrogen Substances 0.000 abstract 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 3
- 125000000882 C2-C6 alkenyl group Chemical group 0.000 abstract 2
- 125000004093 cyano group Chemical group *C#N 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- -1 hydroxy, mercapto, amino Chemical group 0.000 abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 2
- NJYFRQQXXXRJHK-UHFFFAOYSA-N (4-aminophenyl) thiocyanate Chemical compound NC1=CC=C(SC#N)C=C1 NJYFRQQXXXRJHK-UHFFFAOYSA-N 0.000 abstract 1
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 abstract 1
- MZAGXDHQGXUDDX-JSRXJHBZSA-N (e,2z)-4-ethyl-2-hydroxyimino-5-nitrohex-3-enamide Chemical compound [O-][N+](=O)C(C)C(/CC)=C/C(=N/O)/C(N)=O MZAGXDHQGXUDDX-JSRXJHBZSA-N 0.000 abstract 1
- NPRXQXFTKCBAAY-UHFFFAOYSA-N 4-benzoylpyrazole Chemical class C=1C=CC=CC=1C(=O)C=1C=NNC=1 NPRXQXFTKCBAAY-UHFFFAOYSA-N 0.000 abstract 1
- 125000003601 C2-C6 alkynyl group Chemical group 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 abstract 1
- 244000068988 Glycine max Species 0.000 abstract 1
- 235000010469 Glycine max Nutrition 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 abstract 1
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 235000007164 Oryza sativa Nutrition 0.000 abstract 1
- 241000209504 Poaceae Species 0.000 abstract 1
- 241000209140 Triticum Species 0.000 abstract 1
- 235000021307 Triticum Nutrition 0.000 abstract 1
- 240000008042 Zea mays Species 0.000 abstract 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 abstract 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 abstract 1
- 125000000033 alkoxyamino group Chemical group 0.000 abstract 1
- 125000004448 alkyl carbonyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 abstract 1
- 235000005822 corn Nutrition 0.000 abstract 1
- 244000038559 crop plants Species 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000001072 heteroaryl group Chemical group 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- 125000005844 heterocyclyloxy group Chemical group 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 150000003217 pyrazoles Chemical class 0.000 abstract 1
- 235000009566 rice Nutrition 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/30—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D261/00—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings
- C07D261/02—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings
- C07D261/06—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members
- C07D261/08—Heterocyclic compounds containing 1,2-oxazole or hydrogenated 1,2-oxazole rings not condensed with other rings having two or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/58—One oxygen atom, e.g. butenolide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/10—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/10—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D413/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms
- C07D413/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings
- C07D413/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and oxygen atoms as the only ring hetero atoms containing two hetero rings linked by a carbon chain containing aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
Abstract
Se revelan 4-benzoil-pirazoles sustituídos de la formula (I). También se describe el procedimiento para su obtencion, los compuestos intermediarios endicho procedimiento de síntesis, las composiciones herbicidas que contienen dichos pirazoles, el procedimiento de obtencion de dichas composiciones, elprocedimiento para controlar el crecimiento de plantas indeseadas con dichos compuestos y el uso de los mismos como herbicidas. Los compuestos (I) y sus salesutiles para la agricultura son apropiadas, (tanto en forma de mezclas isomeras, como también en forma de los isomeros puros) como herbicidas. Los productosherbicidas que contienen (I) son apropiados para combatir el crecimiento de plantas indeseadas en áreas no destinadas al cultivo, especialmente en altascantidades de aplicacion. En cultivos, tales como trigo, arroz, maíz, soja y algodon son activos contra hierbas malas y gramíneas nocivas, sin causar danosdignos de mencionar en las plantas de cultivo. Este efecto se presenta sobre todo con bajas cantidades de aplicacion. En la formula (I) los sustituyentestienen los siguientes significados: R1 y R2 son hidrogeno, mercapto, nitro, halogeno, ciano, rodano, alquilo C1-6, halogenoalquilo C1-6, alcoxi C1-6, alqueniloC2-6, alquinilo C2-6, -OR3, -OCOR3, -OSO2R3, -S(O)nR3, -SO2OR3, -SO2N(R3)2, -NR3SO2R3 o -NR3COR3; R3 es hidrogeno, alquilo C1-6, halogenoalquilo C1-6,alquenilo C2-6, alquinilo C2-6, fenil o fenil C1-6 alquil; pudiendo los radicales alquilo mencionados estar parcial ocompletamente halogenados y/o llevar unoa tres de los grupos siguientes: hidroxi, mercapto, amino, ciano, R3, -OR3, -SR3, -N(R3)2, =NOR3, -OCOR3, -SCOR3, -NR3COR3, -CO2R3, -COSR3, -CON(R3)2,alquiliminooxi C1-4, alcoxiamino C1-4, alquilcarbonilo C1-4, alcoxi C1-4-alcoxicarbonilo C2-6, alquilsulfonilo C1-4, heterocíclilo, heterocicliloxi, fenilo,bencilo, hetarilo, fenoxi, benciloxi y hetariloxi, pudiendo los 8 ultimos radicales mencionados estar a su vez sustituidos; n es 0, 1 o 2; Q es un pirazolenlazado en la posicion 4 de la formula (II), donde R4 significa hidrogeno, alquilo C1-6 o halogenoalquilo C1-6; R5 significa alquilo C1-6, halogenoalquilo
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19734186 | 1997-08-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR016811A1 true AR016811A1 (es) | 2001-08-01 |
Family
ID=7838255
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP980103924A AR016811A1 (es) | 1997-08-07 | 1998-08-07 | 4-benzoil-pirazoles, procedimiento para su obtencion, los compuestos intermediarios en dicho procedimiento de sintesis, las composiciones herbicidas quecontienen dichos pirazoles, el procedimiento de obtencion de dichas composiciones, el procedimiento para controlar el crecimiento de plantas indesea |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6156702A (es) |
| EP (1) | EP1003736B1 (es) |
| JP (1) | JP2001512726A (es) |
| AR (1) | AR016811A1 (es) |
| AU (1) | AU9066598A (es) |
| CA (1) | CA2298589A1 (es) |
| DE (1) | DE59813487D1 (es) |
| WO (1) | WO1999007697A1 (es) |
| ZA (1) | ZA987055B (es) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19914140A1 (de) | 1999-03-27 | 2000-09-28 | Bayer Ag | Substituierte Benzoylpyrazole |
| DE19953136A1 (de) | 1999-11-04 | 2001-05-10 | Aventis Cropscience Gmbh | Benzoylcyclohexandione und Benzoylpyrazole, Verfahren zu ihrer Herstellung und ihre Verwendung als Herbizide und Pflanzenwachstumsregulatoren |
| DE10136449A1 (de) * | 2001-05-09 | 2002-11-14 | Bayer Ag | Substituierte Arylketone |
| CN1297543C (zh) * | 2001-05-09 | 2007-01-31 | 拜尔农作物科学股份公司 | 取代的芳基酮类化合物 |
| DE10138577A1 (de) * | 2001-05-21 | 2002-11-28 | Bayer Ag | Substituierte Benzoylpyrazole |
| DE10206792A1 (de) * | 2002-02-19 | 2003-08-28 | Bayer Cropscience Ag | Substituierte Arylketone |
| DE10209645A1 (de) * | 2002-03-05 | 2003-09-18 | Bayer Cropscience Ag | Substituierte Arylketone |
| JP5420169B2 (ja) * | 2006-12-27 | 2014-02-19 | 石原産業株式会社 | ベンゾイルピラゾール系化合物を含有する除草剤 |
| CN105503728B (zh) * | 2015-12-31 | 2017-03-22 | 青岛清原化合物有限公司 | 吡唑类化合物或其盐、制备方法、除草剂组合物及用途 |
| CN105399674B (zh) * | 2015-12-31 | 2017-02-15 | 青岛清原化合物有限公司 | 吡唑类化合物或其盐、制备方法、除草剂组合物及用途 |
| CN106946783B (zh) * | 2017-04-19 | 2019-04-19 | 青岛清原化合物有限公司 | 三唑磺草酮c晶型及其制备方法和用途 |
| CN107522676B (zh) * | 2017-08-18 | 2019-06-14 | 南通大学 | 含噁唑联苯硫基结构的氰基丙烯酸酯衍生物的制备和应用 |
| CN107522675B (zh) * | 2017-08-18 | 2019-07-26 | 南通大学 | 含噁唑联苄氧基结构的氰基丙烯酸酯化合物的制备和应用 |
| CN107629046B (zh) * | 2017-10-24 | 2021-07-06 | 青岛清原化合物有限公司 | 吡唑酮类化合物或其盐、除草剂组合物及用途 |
| CN111559965B (zh) * | 2019-02-14 | 2022-11-18 | 东莞市东阳光农药研发有限公司 | 取代的苯甲酰类化合物及其在农业中的应用 |
| CN113387942B (zh) * | 2020-03-13 | 2025-08-01 | 沈阳中化农药化工研发有限公司 | 一种吡唑羧酸酯类化合物及其应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3655693A (en) * | 1969-06-25 | 1972-04-11 | Merck & Co Inc | Anti-inflammatory salicyclic acid derivatives |
| NL7008622A (es) * | 1969-06-25 | 1970-12-29 | ||
| IL85659A (en) * | 1987-03-17 | 1992-03-29 | Nissan Chemical Ind Ltd | 4-benzoylpyrazole derivatives,method for their preparation and herbicidal compositions containing them |
| AU710172B2 (en) * | 1995-02-24 | 1999-09-16 | Basf Aktiengesellschaft | Pyrazolylbenzoyl derivatives |
-
1998
- 1998-07-20 US US09/485,232 patent/US6156702A/en not_active Expired - Fee Related
- 1998-07-20 AU AU90665/98A patent/AU9066598A/en not_active Abandoned
- 1998-07-20 JP JP2000506201A patent/JP2001512726A/ja not_active Withdrawn
- 1998-07-20 CA CA002298589A patent/CA2298589A1/en not_active Abandoned
- 1998-07-20 DE DE59813487T patent/DE59813487D1/de not_active Expired - Fee Related
- 1998-07-20 WO PCT/EP1998/004481 patent/WO1999007697A1/de not_active Ceased
- 1998-07-20 EP EP98942572A patent/EP1003736B1/de not_active Expired - Lifetime
- 1998-08-06 ZA ZA9807055A patent/ZA987055B/xx unknown
- 1998-08-07 AR ARP980103924A patent/AR016811A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1003736A1 (de) | 2000-05-31 |
| JP2001512726A (ja) | 2001-08-28 |
| US6156702A (en) | 2000-12-05 |
| WO1999007697A1 (de) | 1999-02-18 |
| CA2298589A1 (en) | 1999-02-18 |
| ZA987055B (en) | 2000-02-07 |
| AU9066598A (en) | 1999-03-01 |
| EP1003736B1 (de) | 2006-04-12 |
| DE59813487D1 (de) | 2006-05-24 |
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