AR003552A1 - Metodo para fabricar elastomeros de poliuretano compacto o celular y prepolimeros de isocianato apropiados para ello. - Google Patents
Metodo para fabricar elastomeros de poliuretano compacto o celular y prepolimeros de isocianato apropiados para ello.Info
- Publication number
- AR003552A1 AR003552A1 ARP960104305A AR10430596A AR003552A1 AR 003552 A1 AR003552 A1 AR 003552A1 AR P960104305 A ARP960104305 A AR P960104305A AR 10430596 A AR10430596 A AR 10430596A AR 003552 A1 AR003552 A1 AR 003552A1
- Authority
- AR
- Argentina
- Prior art keywords
- diisocyanate
- polyurethane elastomers
- cellular polyurethane
- isocianate
- manufacturing compact
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7678—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing condensed aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/721—Two or more polyisocyanates not provided for in one single group C08G18/73 - C08G18/80
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2350/00—Acoustic or vibration damping material
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
El objeto de la presente invención es un método para fabricar elastómeros de poliuretano compactos y preferentemente celulares por conversión de: a)compuestos polihidroxilo de alto peso molecular y, en caso necesario, b)medios prolongadores decad ena y/o reticulantes de bajo peso molecular con c) 1,5-naftilen diisocianato y por lo menos un diisocianato aromático adicional, seleccionado del grupo formado por diisocianato de toluileno, de difenilmetano,de 3,3-dimetil-difenilo, de1,2-dife niletano y de fenileno y/o diisocianato alifático con 4 a 12 átomos de carbono y/o diisocianato cicloalifático con 6 a18 átomos de carbono, donde los componentes constitutivos (a), (c) y en caso necesario (b) se hacen reaccionarpreferentemente de acuerdo con el método delos prepolímeros en presencia o ausencia de: d) catalizadores, e) expansores, f) aditivos, y prepolímeros de isocianato apropiados para ello.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19534163A DE19534163A1 (de) | 1995-09-15 | 1995-09-15 | Verfahren zur Herstellung von kompakten oder zelligen Polyurethan-Elastomeren und hierfür geeignete Isocyanatpräpolymere |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR003552A1 true AR003552A1 (es) | 1998-08-05 |
Family
ID=7772208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP960104305A AR003552A1 (es) | 1995-09-15 | 1996-09-11 | Metodo para fabricar elastomeros de poliuretano compacto o celular y prepolimeros de isocianato apropiados para ello. |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6310114B1 (es) |
| EP (1) | EP0850260B1 (es) |
| JP (1) | JP3973232B2 (es) |
| KR (1) | KR100426299B1 (es) |
| CN (1) | CN1154679C (es) |
| AR (1) | AR003552A1 (es) |
| AT (1) | ATE212043T1 (es) |
| AU (1) | AU709325B2 (es) |
| BR (1) | BR9610179A (es) |
| CA (1) | CA2230171A1 (es) |
| CZ (1) | CZ67598A3 (es) |
| DE (2) | DE19534163A1 (es) |
| EA (1) | EA001028B1 (es) |
| ES (1) | ES2171720T3 (es) |
| HU (1) | HUP9900656A3 (es) |
| MX (1) | MX9801915A (es) |
| PL (1) | PL325634A1 (es) |
| PT (1) | PT850260E (es) |
| TR (1) | TR199800465T1 (es) |
| WO (1) | WO1997010278A1 (es) |
| ZA (1) | ZA967731B (es) |
Families Citing this family (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19548771A1 (de) * | 1995-12-23 | 1997-06-26 | Basf Ag | Mikrozelluläres, harnstoffgruppenhaltiges Polyurethanelastomer |
| DE19860205A1 (de) * | 1998-12-24 | 2000-06-29 | Basf Ag | Verbundelemente enthaltend (i) thermoplastische Polyurethane und (ii) mikrozellige Polyurethanelastomere |
| EP1171515B1 (de) * | 1999-04-15 | 2002-10-30 | Basf Aktiengesellschaft | Zellige polyisocyanat-polyadditionsprodukte |
| DE10060473A1 (de) * | 2000-12-06 | 2002-06-13 | Bayer Ag | Polyurethan-Prepolymer und Polyurethan-Elastomere auf Basis von 1,4-Naphthalindiisocyanat |
| RU2197505C2 (ru) * | 2001-04-05 | 2003-01-27 | Халяпов Руслан Ренатович | Способ получения эластичного пеноматериала |
| RU2003132545A (ru) * | 2001-04-06 | 2005-04-20 | Басф Акциенгезелльшафт (De) | Ячеистые продукты полиприсоединения полиизоцианата |
| US20030092848A1 (en) * | 2001-09-11 | 2003-05-15 | Ashok Sengupta | Sprayable liner for supporting the rock surface of a mine |
| US20060183882A1 (en) * | 2001-12-21 | 2006-08-17 | Dexheimer Edward M | Continuous process for preparation of polyether polyols |
| US20060281894A1 (en) * | 2005-06-13 | 2006-12-14 | Basf Corporation. | Method of forming polyetherols in the presence of aluminum phosphate catalysts |
| US6919486B2 (en) * | 2001-12-21 | 2005-07-19 | Basf Corporation | Polyetherols produced using aluminium phosphonate catalysts |
| US6706844B2 (en) | 2001-12-21 | 2004-03-16 | Basf Corporation | Polyurethane products produced from aluminum phosphonate catalyzed polyetherols |
| US6777533B2 (en) * | 2001-12-21 | 2004-08-17 | Basf Corporation | Production of polyetherols using aluminum phosphonate catalysts |
| US7226988B1 (en) | 2001-12-21 | 2007-06-05 | Basf Corporation | Method of forming polyetherols in the presence of carboxy-modified aluminum-based catalysts |
| WO2004065449A1 (ja) * | 2003-01-17 | 2004-08-05 | Bridgestone Corporation | 微細セル軟質ポリウレタンフォーム |
| US7118438B2 (en) | 2003-01-27 | 2006-10-10 | 3M Innovative Properties Company | Methods of making phosphor based light sources having an interference reflector |
| US7312560B2 (en) | 2003-01-27 | 2007-12-25 | 3M Innovative Properties | Phosphor based light sources having a non-planar long pass reflector and method of making |
| US20040145289A1 (en) | 2003-01-27 | 2004-07-29 | 3M Innovative Properties Company | Phosphor based light sources having a non-planar short pass reflector and method of making |
| US7091653B2 (en) | 2003-01-27 | 2006-08-15 | 3M Innovative Properties Company | Phosphor based light sources having a non-planar long pass reflector |
| US7245072B2 (en) | 2003-01-27 | 2007-07-17 | 3M Innovative Properties Company | Phosphor based light sources having a polymeric long pass reflector |
| KR20050103200A (ko) | 2003-01-27 | 2005-10-27 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 인광계 광원 요소와 제조 방법 |
| US20040159900A1 (en) | 2003-01-27 | 2004-08-19 | 3M Innovative Properties Company | Phosphor based light sources having front illumination |
| US7091661B2 (en) | 2003-01-27 | 2006-08-15 | 3M Innovative Properties Company | Phosphor based light sources having a reflective polarizer |
| US7763336B2 (en) * | 2004-05-20 | 2010-07-27 | The Gates Corporation | Flexible coupling sleeve and a flexible shaft coupling incorporating same |
| US20060134374A1 (en) * | 2004-12-16 | 2006-06-22 | Mohawk Carpet Corporation | Vinyl polymer adhesives with post-consumer recycled glass powder filler |
| JP4548220B2 (ja) * | 2005-05-25 | 2010-09-22 | 旭硝子株式会社 | 軟質ポリウレタンフォームおよびその製造方法、該軟質ポリウレタンフォームを用いた自動車用シート |
| US20060281892A1 (en) * | 2005-06-14 | 2006-12-14 | Basf Corporation | Polyurethane products including aluminum phosphates |
| JP5211452B2 (ja) * | 2006-08-29 | 2013-06-12 | Nok株式会社 | 発泡ポリウレタンエラストマーの製造方法 |
| US8110704B2 (en) * | 2006-11-02 | 2012-02-07 | Bayer Materialscience Llc | Process for the production of stable polymers |
| DE102007023963B4 (de) * | 2007-05-23 | 2014-01-02 | Abi Anlagentechnik-Baumaschinen-Industriebedarf Maschinenfabrik Und Vertriebsgesellschaft Mbh | Vorrichtung für einen Schwingungserreger |
| DE102007031546A1 (de) * | 2007-06-01 | 2008-12-04 | Bayer Materialscience Ag | Verfahren zur Herstellung von thermoplastischen Polyurethanen auf Basis 1,5-Naphthalindiisocyanat |
| EP1997841A3 (de) * | 2007-06-01 | 2010-01-20 | Bayer MaterialScience AG | Verfahren zur Herstellung von thermoplastischen Polyurethanen auf Basis von 1,5-Naphthalindiisocyanat |
| DE102007054983A1 (de) * | 2007-11-17 | 2009-05-20 | Bayer Materialscience Ag | Verfahren zur Herstellung von zelligen Polyurethan(PUR)-Gießelastomeren aus lagerstabilen 1,5-Naphthalindiisocyanat(NDI)-Prepolymeren |
| CN102105505B (zh) | 2008-07-25 | 2013-12-04 | 巴斯夫欧洲公司 | 在高温下具有较小蠕变趋势的多孔弹性体 |
| WO2012098145A1 (de) * | 2011-01-21 | 2012-07-26 | Basf Se | Mikrozelluläre schäume mit verbesserten mechanischen eigenschaften |
| US20130072588A1 (en) * | 2011-09-21 | 2013-03-21 | Bayer Materialscience Llc | Medium density foams having good impact resistance and a process for their production |
| KR101351432B1 (ko) | 2011-12-27 | 2014-01-15 | 에스케이씨 주식회사 | 초미세 발포 폴리우레탄 탄성체의 제조방법 |
| CN103788332B (zh) * | 2012-11-02 | 2016-03-30 | 上海凯众材料科技股份有限公司 | Ndi改性mdi基聚氨酯微孔弹性体的制备方法 |
| DE102013017571A1 (de) * | 2013-10-24 | 2015-04-30 | Carl Freudenberg Kg | Elastomerer Körper zur Schwingungsdämpfung |
| CN104098753A (zh) * | 2014-07-17 | 2014-10-15 | 苏州井上高分子新材料有限公司 | 复合聚酯 |
| CN104327242A (zh) * | 2014-10-11 | 2015-02-04 | 江苏捷欣新材料科技有限公司 | 油砂输送用耐低温耐油聚氨酯复合材料的制备方法及应用 |
| KR102747810B1 (ko) * | 2015-09-23 | 2024-12-27 | 바스프 에스이 | 개선된 절연 특성 및 기계적 특성을 지닌 경질 폴리우레탄 폼 |
| CN105820310A (zh) * | 2016-04-07 | 2016-08-03 | 苏州绿朗新材料科技有限公司 | 一种nco预聚物及其制备方法和用途 |
| CN109762136B (zh) * | 2019-01-25 | 2021-05-25 | 海信容声(广东)冰箱有限公司 | 一种聚氨酯发泡组合物、聚氨酯泡沫及其制备方法和应用 |
| EP4263187A1 (de) | 2020-12-18 | 2023-10-25 | BASF Polyurethanes GmbH | ENTKOPPLUNGSBUCHSE AUF DER BASIS EINES GIEßELASTOMERS |
| EP4265407A1 (en) | 2022-04-20 | 2023-10-25 | Basf Se | Thermal insulation composite |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4191818A (en) | 1975-10-25 | 1980-03-04 | Basf Wyandotte Corporation | Process for preparing heat-resistant polyurethane elastomers having no secondary softening range |
| DE2940856A1 (de) | 1979-10-09 | 1981-04-23 | Elastogran GmbH, 2844 Lemförde | Verfahren zur herstellung von gegebenenfalls zellhaltigen polyurethan-elastomeren |
| DE3329775A1 (de) * | 1983-08-18 | 1985-02-28 | Bayer Ag, 5090 Leverkusen | Thermoplastische polyurethane hoher waermestandfestigkeit auf basis von naphthylendiisocyanat, verfahren zu ihrer herstellung und ihre verwendung |
| JPS61250019A (ja) | 1985-04-27 | 1986-11-07 | Bridgestone Corp | 微小気泡質状ポリウレタンエラストマ−の製造方法 |
| DE3613650A1 (de) | 1986-04-23 | 1987-10-29 | Basf Ag | Verfahren zur herstellung von elastischen, kompakten oder zelligen polyurethan- oder polyurethan-polyharnstoff-formkoerpern |
| DE4102174A1 (de) | 1991-01-25 | 1992-07-30 | Basf Ag | Verfahren zur herstellung von zelligen polyurethan-elastomeren unter verwendung von polyethercarbonatdiolen als ausgangskomponente |
| CA2143389C (en) * | 1994-03-17 | 1999-05-18 | Tohoru Nagashima | Microcellular polyurethane elastomer and process for producing the same |
| DE4412329A1 (de) * | 1994-04-11 | 1995-10-12 | Bayer Ag | Verfahren zur thermoplastischen Verarbeitung von Polyurethanen und/oder Polyurethanharnstoffen unter Zugabe von Polyisocyanaten |
-
1995
- 1995-09-15 DE DE19534163A patent/DE19534163A1/de not_active Withdrawn
-
1996
- 1996-09-09 TR TR1998/00465T patent/TR199800465T1/xx unknown
- 1996-09-09 CZ CZ98675A patent/CZ67598A3/cs unknown
- 1996-09-09 DE DE59608602T patent/DE59608602D1/de not_active Expired - Lifetime
- 1996-09-09 US US09/043,280 patent/US6310114B1/en not_active Expired - Lifetime
- 1996-09-09 BR BR9610179A patent/BR9610179A/pt not_active IP Right Cessation
- 1996-09-09 JP JP51164397A patent/JP3973232B2/ja not_active Expired - Lifetime
- 1996-09-09 ES ES96932483T patent/ES2171720T3/es not_active Expired - Lifetime
- 1996-09-09 EA EA199800294A patent/EA001028B1/ru not_active IP Right Cessation
- 1996-09-09 CN CNB961969482A patent/CN1154679C/zh not_active Expired - Lifetime
- 1996-09-09 KR KR10-1998-0701935A patent/KR100426299B1/ko not_active Expired - Lifetime
- 1996-09-09 WO PCT/EP1996/003946 patent/WO1997010278A1/de not_active Ceased
- 1996-09-09 HU HU9900656A patent/HUP9900656A3/hu unknown
- 1996-09-09 PT PT96932483T patent/PT850260E/pt unknown
- 1996-09-09 AT AT96932483T patent/ATE212043T1/de not_active IP Right Cessation
- 1996-09-09 PL PL96325634A patent/PL325634A1/xx unknown
- 1996-09-09 CA CA002230171A patent/CA2230171A1/en not_active Abandoned
- 1996-09-09 AU AU71268/96A patent/AU709325B2/en not_active Ceased
- 1996-09-09 MX MX9801915A patent/MX9801915A/es not_active IP Right Cessation
- 1996-09-09 EP EP96932483A patent/EP0850260B1/de not_active Expired - Lifetime
- 1996-09-11 AR ARP960104305A patent/AR003552A1/es unknown
- 1996-09-13 ZA ZA9607731A patent/ZA967731B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU709325B2 (en) | 1999-08-26 |
| MX9801915A (es) | 1998-05-31 |
| PT850260E (pt) | 2002-07-31 |
| ES2171720T3 (es) | 2002-09-16 |
| HUP9900656A2 (hu) | 1999-07-28 |
| HUP9900656A3 (en) | 1999-11-29 |
| KR19990044680A (ko) | 1999-06-25 |
| US6310114B1 (en) | 2001-10-30 |
| CN1154679C (zh) | 2004-06-23 |
| CZ67598A3 (cs) | 1998-10-14 |
| ZA967731B (en) | 1998-03-13 |
| EP0850260A1 (de) | 1998-07-01 |
| TR199800465T1 (xx) | 1998-05-21 |
| EA001028B1 (ru) | 2000-08-28 |
| JP3973232B2 (ja) | 2007-09-12 |
| EP0850260B1 (de) | 2002-01-16 |
| PL325634A1 (en) | 1998-08-03 |
| ATE212043T1 (de) | 2002-02-15 |
| JPH11512465A (ja) | 1999-10-26 |
| KR100426299B1 (ko) | 2004-05-17 |
| EA199800294A1 (ru) | 1998-12-24 |
| BR9610179A (pt) | 1998-08-11 |
| DE59608602D1 (de) | 2002-02-21 |
| DE19534163A1 (de) | 1997-03-20 |
| WO1997010278A1 (de) | 1997-03-20 |
| CN1196068A (zh) | 1998-10-14 |
| CA2230171A1 (en) | 1997-03-20 |
| AU7126896A (en) | 1997-04-01 |
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