AR001504A1 - Procedimiento para preparar acido carboxilico mediante la oxidación de un hidrocarburo, un alcohol ouna cetona, en fase líquida, por medio de oxigeno molecular y en presencia de un catalizador hetero geneo. - Google Patents
Procedimiento para preparar acido carboxilico mediante la oxidación de un hidrocarburo, un alcohol ouna cetona, en fase líquida, por medio de oxigeno molecular y en presencia de un catalizador hetero geneo.Info
- Publication number
- AR001504A1 AR001504A1 AR33602496A AR33602496A AR001504A1 AR 001504 A1 AR001504 A1 AR 001504A1 AR 33602496 A AR33602496 A AR 33602496A AR 33602496 A AR33602496 A AR 33602496A AR 001504 A1 AR001504 A1 AR 001504A1
- Authority
- AR
- Argentina
- Prior art keywords
- liquid phase
- oxidation
- carboxylic acid
- heterogeneous catalyst
- ketone
- Prior art date
Links
- 239000004215 Carbon black (E152) Substances 0.000 title 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 title 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 title 1
- 229910001882 dioxygen Inorganic materials 0.000 title 1
- 239000002638 heterogeneous catalyst Substances 0.000 title 1
- 229930195733 hydrocarbon Natural products 0.000 title 1
- 150000002430 hydrocarbons Chemical class 0.000 title 1
- 150000002576 ketones Chemical class 0.000 title 1
- 239000007791 liquid phase Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 230000003647 oxidation Effects 0.000 title 1
- 238000007254 oxidation reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/31—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting
- C07C51/313—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation of cyclic compounds with ring-splitting with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/245—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of keto groups or secondary alcohol groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C55/00—Saturated compounds having more than one carboxyl group bound to acyclic carbon atoms
- C07C55/02—Dicarboxylic acids
- C07C55/14—Adipic acid
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente invención se refiere a la oxidación de hidrocarburos, de alcoholes o de cetonas, en fase líquida y en presencia de un catalizadorheterogéneo. Se trata más precisamente de la oxidación en ácido carboxílico, por el oxígeno molecular o un gas que lo contiene, de un hidrocarburo, de unalcohol o de una cetona, en fase líquida, en un solvente por lo menos parcial del ácido carboxílico mencionado, en presencia de un catalizador heterogéneoque comprende por lo menos átomos de manganeso incorporados en la matriz cristalina de un tamiz molecular. La fase líquida comprende un solventeelegido generalmente entre los solventes próticos polares y los solventes apróticos polares, más particularmente entre los ácidos carboxílicos y susésteres.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9504428A FR2732678B1 (fr) | 1995-04-07 | 1995-04-07 | Procede d'oxydation d'hydrocarbures, d'alcools ou de cetones par catalyse heterogene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR001504A1 true AR001504A1 (es) | 1997-10-22 |
Family
ID=9478065
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AR33602496A AR001504A1 (es) | 1995-04-07 | 1996-04-03 | Procedimiento para preparar acido carboxilico mediante la oxidación de un hidrocarburo, un alcohol ouna cetona, en fase líquida, por medio de oxigeno molecular y en presencia de un catalizador hetero geneo. |
Country Status (14)
| Country | Link |
|---|---|
| EP (1) | EP0819110A1 (es) |
| JP (1) | JPH10505867A (es) |
| KR (1) | KR19980703703A (es) |
| CN (1) | CN1183760A (es) |
| AR (1) | AR001504A1 (es) |
| BR (1) | BR9604863A (es) |
| CA (1) | CA2215472A1 (es) |
| CZ (1) | CZ313797A3 (es) |
| FR (1) | FR2732678B1 (es) |
| MX (1) | MX9707721A (es) |
| PL (1) | PL322658A1 (es) |
| SK (1) | SK134097A3 (es) |
| TW (1) | TW338034B (es) |
| WO (1) | WO1996031455A1 (es) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69924151T2 (de) | 1998-12-22 | 2006-04-13 | Mitsubishi Chemical Corp. | Verfahren zur herstellung aliphatischer aldehydsäuren und/oder aliphatischer dicarbonsäuren |
| MXPA01007874A (es) * | 1999-02-04 | 2002-04-24 | Rpc Inc | Oxidacion de hidrocarburos a acidos en la presencia de fluorocompuestos. . |
| FR2791667B1 (fr) * | 1999-03-30 | 2002-05-24 | Rhone Poulenc Fibres | Procede d'oxydation d'hydrocarbures, d'alcools et/ou de cetones |
| FR2806079B1 (fr) | 2000-03-08 | 2003-03-14 | Rhodia Polyamide Intermediates | Procede d'oxydation d'hydrocarbures en acides |
| FR2806078B1 (fr) * | 2000-03-08 | 2004-01-30 | Rhodia Polyamide Intermediates | Procede d'oxydation d'hydrocarbures en acides |
| FR2828194B1 (fr) * | 2001-08-03 | 2004-03-19 | Rhodia Polyamide Intermediates | Procede d'oxydation d'hydrocarbures en acides |
| US7541489B2 (en) | 2004-06-30 | 2009-06-02 | Sabic Innovative Plastics Ip B.V. | Method of making halophthalic acids and halophthalic anhydrides |
| US7358401B2 (en) | 2005-03-31 | 2008-04-15 | Sumitomo Chemical Company, Limited | Method for manufacturing cycloalkanol and/or cycloalkanone |
| JP5136017B2 (ja) | 2007-11-21 | 2013-02-06 | 住友化学株式会社 | シクロアルカノール及び／又はシクロアルカノンの製造方法 |
| US8212099B2 (en) * | 2009-11-05 | 2012-07-03 | Chevron U.S.A. Inc. | N-paraffin selective hydroconversion process using borosilicate ZSM-48 molecular sieves |
| CN102452872B (zh) * | 2010-10-29 | 2014-08-20 | 中国石油化工股份有限公司 | 一种全硅分子筛催化环酮的反应方法 |
| DE102013204119A1 (de) | 2013-03-11 | 2014-09-11 | Ke-Min Lin | Fenster-Jalousien-Anordnung sowie dazugehörige Schnur-Führungseinrichtung |
| CN105646223B (zh) * | 2014-12-04 | 2017-12-26 | 中国科学院大连化学物理研究所 | 一种乙酰丙酸催化氧化酯化制备丁二酸二酯的方法 |
| CN108863758B (zh) * | 2018-08-06 | 2021-10-22 | 杭州紫乘生物科技有限公司 | 一种制备5-己烯酸的方法 |
| CN112961048B (zh) * | 2021-02-08 | 2022-10-18 | 中国石油大学(华东) | 一种一步法联产k.a.油和己二酸的工艺方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3529020A (en) * | 1965-08-16 | 1970-09-15 | Mobil Oil Corp | Oxidation processes employing aluminosilicate catalysts and an initiator |
-
1995
- 1995-04-07 FR FR9504428A patent/FR2732678B1/fr not_active Expired - Fee Related
-
1996
- 1996-04-03 AR AR33602496A patent/AR001504A1/es unknown
- 1996-04-04 BR BR9604863A patent/BR9604863A/pt not_active Application Discontinuation
- 1996-04-04 CA CA002215472A patent/CA2215472A1/fr not_active Abandoned
- 1996-04-04 EP EP96912067A patent/EP0819110A1/fr not_active Withdrawn
- 1996-04-04 MX MX9707721A patent/MX9707721A/es unknown
- 1996-04-04 KR KR1019970707103A patent/KR19980703703A/ko not_active Withdrawn
- 1996-04-04 WO PCT/FR1996/000515 patent/WO1996031455A1/fr not_active Ceased
- 1996-04-04 CZ CZ973137A patent/CZ313797A3/cs unknown
- 1996-04-04 CN CN96193786A patent/CN1183760A/zh active Pending
- 1996-04-04 SK SK1340-97A patent/SK134097A3/sk unknown
- 1996-04-04 JP JP8530042A patent/JPH10505867A/ja active Pending
- 1996-04-04 PL PL96322658A patent/PL322658A1/xx unknown
- 1996-04-16 TW TW085104533A patent/TW338034B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| FR2732678A1 (fr) | 1996-10-11 |
| TW338034B (en) | 1998-08-11 |
| MX9707721A (es) | 1997-12-31 |
| WO1996031455A1 (fr) | 1996-10-10 |
| EP0819110A1 (fr) | 1998-01-21 |
| FR2732678B1 (fr) | 1997-05-23 |
| BR9604863A (pt) | 1998-05-26 |
| PL322658A1 (en) | 1998-02-16 |
| JPH10505867A (ja) | 1998-06-09 |
| CN1183760A (zh) | 1998-06-03 |
| SK134097A3 (en) | 1998-02-04 |
| CA2215472A1 (fr) | 1996-10-10 |
| KR19980703703A (ko) | 1998-12-05 |
| CZ313797A3 (cs) | 1998-03-18 |
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