AR007915A1 - Mezcla esencialmente libre de solvente de poliester de poliol de acido graso que comprende un catalizador de transferencia de fase, proceso parasintetizar dicho poliester y producto que la contiene. - Google Patents
Mezcla esencialmente libre de solvente de poliester de poliol de acido graso que comprende un catalizador de transferencia de fase, proceso parasintetizar dicho poliester y producto que la contiene.Info
- Publication number
- AR007915A1 AR007915A1 ARP970103227A ARP970103227A AR007915A1 AR 007915 A1 AR007915 A1 AR 007915A1 AR P970103227 A ARP970103227 A AR P970103227A AR P970103227 A ARP970103227 A AR P970103227A AR 007915 A1 AR007915 A1 AR 007915A1
- Authority
- AR
- Argentina
- Prior art keywords
- fatty acid
- polyol
- phase transfer
- polyester
- transfer catalyst
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title abstract 7
- -1 FATTY ACID POLYOL Chemical class 0.000 title abstract 6
- 235000014113 dietary fatty acids Nutrition 0.000 title abstract 6
- 229930195729 fatty acid Natural products 0.000 title abstract 6
- 239000000194 fatty acid Substances 0.000 title abstract 6
- 229920000728 polyester Polymers 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 239000003444 phase transfer catalyst Substances 0.000 title abstract 3
- 239000002904 solvent Substances 0.000 title abstract 2
- 239000002202 Polyethylene glycol Substances 0.000 abstract 3
- 229920001223 polyethylene glycol Polymers 0.000 abstract 3
- 239000006227 byproduct Substances 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- MIDXCONKKJTLDX-UHFFFAOYSA-N 3,5-dimethylcyclopentane-1,2-dione Chemical compound CC1CC(C)C(=O)C1=O MIDXCONKKJTLDX-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 235000013736 caramel Nutrition 0.000 abstract 1
- 238000001311 chemical methods and process Methods 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003153 chemical reaction reagent Substances 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 150000003983 crown ethers Chemical class 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000003408 phase transfer catalysis Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 abstract 1
- 238000003786 synthesis reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H13/00—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids
- C07H13/02—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids
- C07H13/04—Compounds containing saccharide radicals esterified by carbonic acid or derivatives thereof, or by organic acids, e.g. phosphonic acids by carboxylic acids having the esterifying carboxyl radicals attached to acyclic carbon atoms
- C07H13/06—Fatty acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Biotechnology (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Saccharide Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Es la síntesis de poliéster de poliol de ácidos grasos que usa catálisis de transferencia de fase, la cual es usada en una amplia variedad de procesosquímicos donde uno o más límites de fase existen y uno o más constituyentes deben cruzar un límite de fases. Se provee una mezcla de reacción para fabricarpoliesteres de poliol de ácidos grasos comprende un poliol, un éster alquílico inferior de ácidos grasos, un iniciador de base y un catalizador detransferencia de fase. El catalizador de transferencia de fase puede ser un compuesto de amonio cuaternario, un éter corona, un polietilenglicol, un éterde polietilenglicol, un éster de polietilenglicol o mezclas de éstos. El proceso para fabricar poliésteres de poliol de ácidos grasos se realiza a bajastemperaturas o esencialmente en ausencia de un disolvente o emulsionante. La corriente de producto de poliéster de poliol de ácidos grasos que se producemediante el proceso anterior y la mezcla de reacción tienen una concentración más baja de subproductos de reacción tales como quetonas di-grasas y beta-quetoésteres y de subproducto acaramelado que resulta de la descomposición del reactivo de poliol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/749,568 US5840703A (en) | 1996-11-15 | 1996-11-15 | Phase transfer catalyst for use in the synthesis of polyol fatty acid polyesters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR007915A1 true AR007915A1 (es) | 1999-11-24 |
Family
ID=25014282
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP970103227A AR007915A1 (es) | 1996-11-15 | 1997-07-18 | Mezcla esencialmente libre de solvente de poliester de poliol de acido graso que comprende un catalizador de transferencia de fase, proceso parasintetizar dicho poliester y producto que la contiene. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5840703A (es) |
| EP (1) | EP0946577A1 (es) |
| JP (1) | JP3171858B2 (es) |
| CN (1) | CN1231669A (es) |
| AR (1) | AR007915A1 (es) |
| AU (1) | AU3723097A (es) |
| BR (1) | BR9713508A (es) |
| CA (1) | CA2260775C (es) |
| CO (1) | CO4900092A1 (es) |
| ID (1) | ID18905A (es) |
| PE (1) | PE36799A1 (es) |
| WO (1) | WO1998021219A1 (es) |
| ZA (1) | ZA976417B (es) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0881253A1 (en) * | 1997-05-27 | 1998-12-02 | Akcros Chemicals | B-ketoesters for use as polymer stabilisers |
| JP2003512343A (ja) | 1999-10-15 | 2003-04-02 | ダニスコ カルター アメリカ，インコーポレイテッド | 脂肪酸によるソルビトールの直接エステル化方法 |
| US8058482B2 (en) * | 2004-11-17 | 2011-11-15 | Piramal Critical Care, Inc. | Method for the preparation of sevoflurane |
| WO2007111604A1 (en) * | 2006-03-29 | 2007-10-04 | Ptc Organics, Inc. | Transesterification reaction of triglycerides and monohydric alcohols |
| CN102850413A (zh) * | 2012-05-29 | 2013-01-02 | 常州大学 | 一种制备蔗糖脂肪酸酯的方法 |
| CN102827213B (zh) * | 2012-08-31 | 2015-12-16 | 连云港正丰生物能源有限公司 | 一种通过废弃的动植物油脂制备蔗糖脂肪酸酯的方法 |
| CN106699702B (zh) * | 2016-12-16 | 2019-10-08 | 武汉桀升生物科技有限公司 | 一种司盘系列产品的制备方法 |
| CN117209745B (zh) * | 2023-10-30 | 2024-09-06 | 浙江恒翔新材料有限公司 | 一种低成本高转化率脂肪酸甲酯聚氧乙烯醚的合成方法 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3963699A (en) * | 1974-01-10 | 1976-06-15 | The Procter & Gamble Company | Synthesis of higher polyol fatty acid polyesters |
-
1996
- 1996-11-15 US US08/749,568 patent/US5840703A/en not_active Expired - Fee Related
-
1997
- 1997-07-16 JP JP52252598A patent/JP3171858B2/ja not_active Expired - Fee Related
- 1997-07-16 CN CN97198172A patent/CN1231669A/zh active Pending
- 1997-07-16 WO PCT/US1997/011986 patent/WO1998021219A1/en not_active Ceased
- 1997-07-16 AU AU37230/97A patent/AU3723097A/en not_active Abandoned
- 1997-07-16 BR BR9713508-9A patent/BR9713508A/pt not_active IP Right Cessation
- 1997-07-16 EP EP97934088A patent/EP0946577A1/en not_active Withdrawn
- 1997-07-16 CA CA002260775A patent/CA2260775C/en not_active Expired - Fee Related
- 1997-07-18 AR ARP970103227A patent/AR007915A1/es unknown
- 1997-07-18 CO CO97040896A patent/CO4900092A1/es unknown
- 1997-07-18 PE PE1997000638A patent/PE36799A1/es not_active Application Discontinuation
- 1997-07-21 ZA ZA9706417A patent/ZA976417B/xx unknown
- 1997-07-21 ID IDP972534A patent/ID18905A/id unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1231669A (zh) | 1999-10-13 |
| CA2260775A1 (en) | 1998-05-22 |
| WO1998021219A1 (en) | 1998-05-22 |
| ZA976417B (en) | 1998-02-04 |
| ID18905A (id) | 1998-05-20 |
| AU3723097A (en) | 1998-06-03 |
| US5840703A (en) | 1998-11-24 |
| PE36799A1 (es) | 1999-04-14 |
| JP2000503034A (ja) | 2000-03-14 |
| CA2260775C (en) | 2002-09-24 |
| BR9713508A (pt) | 2000-02-29 |
| JP3171858B2 (ja) | 2001-06-04 |
| EP0946577A1 (en) | 1999-10-06 |
| CO4900092A1 (es) | 2000-03-27 |
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