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NO802492L - Hair conditioner. - Google Patents

Hair conditioner.

Info

Publication number
NO802492L
NO802492L NO802492A NO802492A NO802492L NO 802492 L NO802492 L NO 802492L NO 802492 A NO802492 A NO 802492A NO 802492 A NO802492 A NO 802492A NO 802492 L NO802492 L NO 802492L
Authority
NO
Norway
Prior art keywords
molecular weight
agent according
agent
polymer
cationic polymer
Prior art date
Application number
NO802492A
Other languages
Norwegian (no)
Inventor
Richard Demarco
Joseph Varco
Leszek J Wolfram
Michael Wong
Original Assignee
Bristol Myers Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bristol Myers Co filed Critical Bristol Myers Co
Publication of NO802492L publication Critical patent/NO802492L/en

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54Polymers characterized by specific structures/properties
    • A61K2800/542Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426Polymers characterized by specific structures/properties characterized by the charge cationic
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/594Mixtures of polymers

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Description

Den foreliggende oppfinnelse vedrører et middel som er an-vendbart ved kondisjonering av hår, samt en fremgangsmåte til kondisjonering av hår hvor preparatet anvendes. The present invention relates to an agent which can be used for conditioning hair, as well as a method for conditioning hair in which the preparation is used.

Det er kjent å behandle hår med visse kvaternære ammonium-f orbindelser, med det formål å kondisjonere håret, dvs. å bedre dets friserbarhet og medgjørlighet og å gi det blødt grep, glansfullt utseende etc. Selv om slike kjente midler har vist seg effektive i varierende grad, har en av hovedmanglende vært virkningens forbigående karakter, dvs. at den ikke overlever gjentatte hårvaskinger. Noe forbedring av kondisjoneringens stabilitet overfor hårvask kan oppnås med visse klasser av silikonpolymerer. Et eksempel på slike polymerer er amodimetiokon, hvis strukturformel er: It is known to treat hair with certain quaternary ammonium compounds, with the aim of conditioning the hair, i.e. to improve its combability and malleability and to give it a soft grip, glossy appearance, etc. Although such known agents have proven effective in varying degrees, one of the main shortcomings has been the transitory nature of the effect, i.e. that it does not survive repeated hair washings. Some improvement in conditioner stability to hair washing can be achieved with certain classes of silicone polymers. An example of such polymers is amodimethiocone, whose structural formula is:

hvor x og y er molekylvektavhengige kardinaltall og den vektmidlere molekylvekt er omtrentlig mellom 5.000 og 100.000. Men selv anvendelsen av slike silikonpolymerer oppfyller ikke alle ønsker. where x and y are molecular weight dependent cardinal numbers and the weight average molecular weight is approximately between 5,000 and 100,000. But even the application of such silicone polymers does not fulfill all wishes.

Det har nå vist seg at både slike silikonpolymerers kon-dis joneringsef f ektivitet og kondisjoneringsvirkningens holdbarhet kanøkes sterkt ved å inkorporere én eller flere kationiske polymerer i kondisjoneringsmidlet. De polymerer som er nyttige for formålet ned oppfinnelsen kan variere over et bredt område. Kationiske polymerer, som har vist seg særlig nyttige i denne forbindelse, er slike som selges under varemerkene "Merquat" It has now been shown that both the conditioning effectiveness of such silicone polymers and the durability of the conditioning effect can be greatly increased by incorporating one or more cationic polymers into the conditioning agent. The polymers useful for the purpose of the invention can vary over a wide range. Cationic polymers which have proved particularly useful in this connection are those sold under the trademarks "Merquat"

(f.eks. "Merquat 100" og "Merquat 550"), "Onamer" (f.eks. "Onamer M") samt kvaterniserte polyvinylpyridiner. (e.g. "Merquat 100" and "Merquat 550"), "Onamer" (e.g. "Onamer M") as well as quaternized polyvinylpyridines.

"Merquat 100" er en polymer av dimetyldiallylammoniumklorid og er sannsynligvis blandinger av forbindelser med følgende formler: "Merquat 100" is a polymer of dimethyldiallylammonium chloride and is likely to be mixtures of compounds with the following formulas:

Disse varierer i molekylvekt og n er et kardinaltall som er avhengig av molekylvekten. Vanligvis vil de polymerer i denne klasse som anvendes imidlertid ha en molekylvekt i intervallet fra 4.000 til 550.000, og fortrinnsvis i intervallet fra 20.000 til 100.000. "Merquat 550" er en kopolymer av dimetyldiallylammoniumklorid og akrylamid. Den menes å ha formelen og en molekylvekt i intervallet fra 5.000 til 550.000, og n og m er kardinaltall, som avhenger av molekylvekten. These vary in molecular weight and n is a cardinal number that depends on the molecular weight. Generally, however, the polymers of this class that are used will have a molecular weight in the range from 4,000 to 550,000, and preferably in the range from 20,000 to 100,000. "Merquat 550" is a copolymer of dimethyldiallylammonium chloride and acrylamide. It is believed to have the formula and a molecular weight in the range of 5,000 to 550,000, and n and m are cardinal numbers, which depend on the molecular weight.

De polymerer av "Onamer"-type, som er nyttige for formålet ifølge oppfinnelsen, er poly(dimetylbutenylammoniumklorid)-a,w-bis(trietanolammoniumklorid)-forbindelser, som kan beskrives med den generelle formel: The polymers of the "Onamer" type, which are useful for the purpose of the invention, are poly(dimethylbutenylammonium chloride)-a,w-bis(triethanolammonium chloride) compounds, which can be described by the general formula:

hvor n er et kardinaltall som er molekylvektavhengig. Molekyl-vektene til disse polymerer som kan anvendes, vil være i intervallet fra 800 til 5.000, fortrinnsvis i intervallet fra 1.000 til 3.000. where n is a cardinal number which is molecular weight dependent. The molecular weights of these polymers which can be used will be in the range from 800 to 5,000, preferably in the range from 1,000 to 3,000.

En tredje variant av kåtioniske materialer, som har vist seg særlig nyttige, er polymerer og kopolymerer av kvaternisert polyvinylpyridin. Disse beskrives med den generelle formel: A third variety of cationic materials, which have proved particularly useful, are polymers and copolymers of quaternized polyvinylpyridine. These are described with the general formula:

hvor R er et alkylradikal og X er en anion, såsom et halogenid, sulfat eller.-karboksylat, og n er et kardinaltall som er avhengig av molekylvekten. Disse vil også ha en molekylvekt i intervallet fra 5.000 til 100.000. where R is an alkyl radical and X is an anion, such as a halide, sulfate or β-carboxylate, and n is a cardinal number that depends on the molecular weight. These will also have a molecular weight in the range from 5,000 to 100,000.

Som eksempel på en kationisk polymer i denne gruppe kan nevnes følgende: The following can be mentioned as an example of a cationic polymer in this group:

polyvinylmetylpyridinjodid med en midlere molekylvekt på 50.000. polyvinylmethylpyridine iodide with an average molecular weight of 50,000.

Mengden kationisk polymer i formuleringen vil avhenge avThe amount of cationic polymer in the formulation will depend on

de spesielle resultater som ønskes. Den vil vanligvis utgjøre mellom 0,01 og 10 vekts%, basert på den totale vekt av det vandige preparat, med et optimalt intervall mellom 0,05 og 3% på samme vektbasis. the particular results desired. It will usually amount to between 0.01 and 10% by weight, based on the total weight of the aqueous preparation, with an optimum range between 0.05 and 3% on the same weight basis.

Mengden silikonpolymer i hårkondisjonerlngsmidlet ifølge oppfinnelsen kan også variere noe. Vanligvis vil den imidlertid utgjøre fra 0,2 til 10 vekts%, basert på midlets totale vekt, fortrinnsvis fra 1 til 4%. The amount of silicone polymer in the hair conditioner according to the invention can also vary somewhat. Usually, however, it will amount to from 0.2 to 10% by weight, based on the total weight of the agent, preferably from 1 to 4%.

Selv om de ovennévnte kationiske polymerer og silikonpoly-merene er de vesentlige bestanddeler i midlet ifølge oppfinnelsen, kan dette også inneholde andre bestanddeler som kan tjene til", Although the above-mentioned cationic polymers and silicone polymers are the essential constituents of the agent according to the invention, this may also contain other constituents which can serve to

å bedre produktets organoleptiske karakter eller lettheten hvor-med det anvendes. Det er således innenfor rammen av oppfinnelsen å inkorporere slike stoffer som luktstoffer, fortykningsmidler, opacitetsmidler etc. i midlet ifølge oppfinnelsen. to improve the product's organoleptic character or the ease with which it is used. It is thus within the scope of the invention to incorporate substances such as odorants, thickeners, opacifiers etc. in the agent according to the invention.

Bæreren for overlevering av midlet ifølge oppfinnelsen vil vanligvis være vandig bærermedium. Dette kan ha en vilkårlig av mange forskjellige former, f.eks. oppløsninger, vandige emul-sjoner, vandige geler etc. Slik betegnelsen vandig bærer anvendes her skal den omfatte både de tilfeller hvor vann stort sett er det eneste materiale som utgjør bæremediet, og de tilfeller hvor vannet er blandet med betydelige mengder av andre bestanddeler, f.eks. løsningsmidler, fortykningsmidler, emulgatorer, geldan-nelsesmidler etc. The carrier for delivery of the agent according to the invention will usually be an aqueous carrier medium. This can take any of many different forms, e.g. solutions, aqueous emulsions, aqueous gels, etc. As the term aqueous carrier is used here, it shall include both cases where water is mostly the only material that makes up the carrier medium, and cases where the water is mixed with significant amounts of other components, e.g. .ex. solvents, thickeners, emulsifiers, gelling agents etc.

Kondisjoneringsmidlet ifølge oppfinnelsen kan anbringesThe conditioner according to the invention can be applied

på hår på en vilkårlig egnet måte. En typisk fremgangsmåte omfatter at kondisjoneringsmidlet slik som beskrevet i eksempel, 1 nedenfor anbringes på nyvasket hår, hvorved det innarbeides lett i hårmassen, hvoretter man lar midlet bli i håret i 1-5 minutter on hair in any suitable manner. A typical method involves applying the conditioning agent as described in example 1 below to freshly washed hair, whereby it is lightly incorporated into the hair mass, after which the agent is left in the hair for 1-5 minutes

og skyller håret omhyggelig med vann før frisering. Den mengde kondisjoneringsmiddel som anbringes på håret kan variere, men bør vanligvis ikke være mindre enn 1% av hårets vekt og ikke overstige 20% av hårets vekt. and rinses the hair carefully with water before styling. The amount of conditioner applied to the hair can vary, but should generally not be less than 1% of the hair's weight and not exceed 20% of the hair's weight.

Oppfinnelsen vil bli nærmere illustrert i de etterfølgende eksempler. The invention will be further illustrated in the following examples.

Eksempel 1Example 1

Eksempel 2 Example 2

Eksempel 3 Example 3

Eksempel 4 Eksempel 5 Example 4 Example 5

Kondisjoneringseffektiviteten og holdbarheten hvor det som forsøksunderlag ble anvendt normalt hår fra en av den hvite rase. The conditioning efficiency and durability where normal hair from one of the white race was used as test material.

Hårbunter av intakt hår fra en av den hvite rase ble vasket med "Herbal Essence Shampoo" i overensstemmelse med instruksjonene på etiketten. Forholdet mellom shampoomengden og hårvekten samt mengden av vann som ble anvendt til skylling etter vask, ble alle holdt slik at man simulerte betingelsene på hodet. Etter skylling ble kondisjoneringsmidlet ifølge eksempel 1 ovenfor anbrakt på hår (0,1 g av hvert produkt pr. 1 g hår). Det ble innarbeidet i 30 sekunder, og man lot det bli på håret i ytter-ligere 1 minutt, hvoretter håret ble skyllet og frisert. Fri-seringsmålingene ble gjennomført ved den i artikkelen av Garcia og Diaz, beskrevne fremgangsmåte (J. Soc. Cosmetic. Chem., vol. 27, 1976, p. 379) . Prøven innebærer stort sett at en hårlokk føres gjennom en kam festet til en deformasjonsmåler som på sin side er forbundet med en registreringsanordning. Det må utøves kraft for å utføre denne passasje av hårlokken gjennom kammen, og den maksimale kraft avlest av registreringsanordningen er det objektive mål for friseringslettheten. Hair bundles of intact hair from one of the white race were washed with "Herbal Essence Shampoo" in accordance with the instructions on the label. The ratio between the amount of shampoo and the weight of the hair, as well as the amount of water used for rinsing after washing, were all kept so as to simulate the conditions on the head. After rinsing, the conditioner according to example 1 above was applied to hair (0.1 g of each product per 1 g of hair). It was incorporated for 30 seconds, and it was left on the hair for a further 1 minute, after which the hair was rinsed and styled. The release measurements were carried out by the method described in the article by Garcia and Diaz (J. Soc. Cosmetic. Chem., vol. 27, 1976, p. 379). The test generally involves a lock of hair being passed through a comb attached to a deformation gauge which is in turn connected to a recording device. Force must be exerted to effect this passage of the lock of hair through the comb, and the maximum force read by the recording device is the objective measure of styling ease.

Etter å ha bestemt hårets friseringsegenskaper etter vask og kondisjoneringsbehandlinger, ble hårbuntene vasket fem ganger og igjen prøvet på friserbarhet. Resultatene av friserbarhets-prøvene er sammenstilt i tabell I nedenfor. I denne tabell er den maksimale friseringskraft uttrykt i gram kraftenheter (G). Jo høyere verdiene er, desto vanskeligere var det å frisere håret. After determining the styling properties of the hair after washing and conditioning treatments, the hair bundles were washed five times and again tested for styling. The results of the combability tests are compiled in table I below. In this table, the maximum styling force is expressed in gram force units (G). The higher the values, the more difficult it was to style the hair.

Med kondisjoneringsmidlet ifølge eksempel 4 ble det opp-nådd enda bedre holdbarhet av kondisjoneringsegenskaper. Også i dette tilfelle ble det anvendt lokker av nyvasket brunt hår fra en av den europeiske rase til forsøket. Resultatene er anført i tabell II nedenfor. With the conditioner according to example 4, even better durability of conditioning properties was achieved. In this case too, locks of freshly washed brown hair from one of the European race were used for the experiment. The results are listed in Table II below.

Claims (13)

1. Vandig middel som er nyttig til kondisjonering av hår, karakterisert ved at det på vektbasis og basert på midlets totale vekt inneholder: a) fra 0,2 til 10% av en silikonpolymer, b) fra 0,01 til 10% av'minst én kationisk polymer, samt c) en vandig bærer.1. Aqueous agent which is useful for conditioning hair, characterized in that it contains, by weight and based on the total weight of the agent: a) from 0.2 to 10% of a silicone polymer, b) from 0.01 to 10% of at least one cationic polymer, as well as c) an aqueous carrier. 2. Middel i samsvar med krav 1, karakterisert ved at silikonpolymeren utgjør fra 1 til 4 vekts% av midlet, og at den kationiske polymer utgjør fra 0,05 til 3 vekt,s%.2. Agent according to claim 1, characterized in that the silicone polymer constitutes from 1 to 4% by weight of the agent, and that the cationic polymer constitutes from 0.05 to 3% by weight. 3. Middel i samsvar med krav 1 eller 2, karakterisert ved at silikonpolymeren er i form av en vandig emulsjon av en polymer som er sammensatt av følgende strukturelle enheter: 3. Agent according to claim 1 or 2, characterized in that the silicone polymer is in the form of an aqueous emulsion of a polymer which is composed of the following structural units: hvor x og y er kardinaltall som avhenger av molekylvekten, og at polymerens vektmidlere molekylvekt er mellom 5.000 og 100.000.where x and y are cardinal numbers that depend on the molecular weight, and that the polymer's weight average molecular weight is between 5,000 and 100,000. 4. Middel i samsvar med et av kravene 1-3, karakterisert ved at den kationiske polymer i det minste delvis er en homopolymer av dimetyldiallylammoniumklorid.4. Agent according to one of claims 1-3, characterized in that the cationic polymer is at least partly a homopolymer of dimethyldiallylammonium chloride. 5. Middel i samsvar med krav 4, karakterisert ved at den kationiske homopolymer omfatter monomerenheter med formelen: 5. Agent in accordance with claim 4, characterized in that the cationic homopolymer comprises monomer units with the formula: eller blandinger av disse.or mixtures thereof. 6. Middel i samsvar med krav 4 eller 5, karakterisert ved at homopolymerene har en molekylvekt i intervallet fra 4.000 til 550.000.6. Agent according to claim 4 or 5, characterized in that the homopolymers have a molecular weight in the range from 4,000 to 550,000. 7. Middel i samsvar med et av kravene 1-3, karakterisert ved at den kationiske polymer er en kopolymer av dimetyldiallylammoniumklorid og akrylamid.7. Agent according to one of claims 1-3, characterized in that the cationic polymer is a copolymer of dimethyldiallylammonium chloride and acrylamide. 8. Middel i samsvar med krav 7, karakterisert ved at den kationiske polymer er oppbygget av monomerenheter med formelen: 8. Agent according to claim 7, characterized in that the cationic polymer is made up of monomer units with the formula: hvor n og m er molekylvektavhengige kardinaltall, og hvor kopolymeren har en molekylvekt i intervallet fra 5.000 til 550.000.where n and m are molecular weight-dependent cardinal numbers, and where the copolymer has a molecular weight in the range from 5,000 to 550,000. 9. Middel i samsvar med et av kravene 1-3, karakterisert ved at den kationiske polymer i det minste delvis er et poly (dimetylbutenylammoniumklorid) -a , co-bis(trietanolammoniumklorid) .9. Agent according to one of the claims 1-3, characterized in that the cationic polymer is at least partly a poly(dimethylbutenylammonium chloride)-a,co-bis(triethanolammonium chloride). 10. Middel i samsvar med krav 9, karakterisert ved at den kationiske polymer omfatter monomerenheter med formelen: 10. Agent according to claim 9, characterized in that the cationic polymer comprises monomer units with the formula: hvor n er et molekylvektavhengig kardinaltall og hvor den kationiske polymer har en molekylvekt i intervallet fra 800 til 5.000.where n is a molecular weight-dependent cardinal number and where the cationic polymer has a molecular weight in the range from 800 to 5,000. 11. Middel i samsvar med et av kravene 1-10, karakterisert vve d at den kationiske polymer i det minste delvis er en kvaternisert polyvinylpyridin.11. Agent according to one of claims 1-10, characterized in that the cationic polymer is at least partially a quaternized polyvinylpyridine. 12. Middel i samsvar med krav 11, karakterisert ved at polyvinylpyridinen omfatter monomere enheter med formelen: 12. Agent in accordance with claim 11, characterized in that the polyvinylpyridine comprises monomeric units with the formula: hvor R er et alkylradikal med 1-20 karbonatomer, X~ er en anion og n er et molekylvektavhengig kardinaltall, idet poly-meren har en vektmidlere molekylvekt i intervallet fra 5.000 til 100.000.where R is an alkyl radical with 1-20 carbon atoms, X~ is an anion and n is a molecular weight-dependent cardinal number, the polymer having a weight average molecular weight in the range from 5,000 to 100,000. 13. Middel i samsvar med krav 12, karakterisert ved at anionen er et sulfat, halogenid eller karboksylat.13. Agent according to claim 12, characterized in that the anion is a sulphate, halide or carboxylate.
NO802492A 1979-08-23 1980-08-22 Hair conditioner. NO802492L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US6898679A 1979-08-23 1979-08-23
US16546880A 1980-07-11 1980-07-11

Publications (1)

Publication Number Publication Date
NO802492L true NO802492L (en) 1981-02-24

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ID=26749571

Family Applications (1)

Application Number Title Priority Date Filing Date
NO802492A NO802492L (en) 1979-08-23 1980-08-22 Hair conditioner.

Country Status (11)

Country Link
AU (1) AU6081680A (en)
DE (1) DE3029306A1 (en)
DK (1) DK360680A (en)
FI (1) FI802631A7 (en)
FR (1) FR2463612A1 (en)
GB (1) GB2058103A (en)
GR (1) GR69885B (en)
IT (1) IT1145700B (en)
NL (1) NL8004710A (en)
NO (1) NO802492L (en)
SE (1) SE8005886L (en)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5874602A (en) * 1981-10-29 1983-05-06 Toray Silicone Co Ltd Hair conditioner
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US4487883A (en) * 1982-12-27 1984-12-11 Dow Corning Corporation One-part moisture cured aminosiloxanes
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GR69885B (en) 1982-07-20
FI802631A7 (en) 1981-01-01
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FR2463612A1 (en) 1981-02-27
GB2058103A (en) 1981-04-08
DE3029306A1 (en) 1981-03-12
AU6081680A (en) 1981-02-26
IT1145700B (en) 1986-11-05
NL8004710A (en) 1981-02-25
DK360680A (en) 1981-02-24

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