NL8004710A - AQUEOUS COMPOSITION FOR CONDITIONING HAIR CONTAINING A SILICONE POLYMER AND A CATIONIC POLYMER; METHOD FOR CONDITIONING HAIR - Google Patents
AQUEOUS COMPOSITION FOR CONDITIONING HAIR CONTAINING A SILICONE POLYMER AND A CATIONIC POLYMER; METHOD FOR CONDITIONING HAIR Download PDFInfo
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- 239000000203 mixture Substances 0.000 title claims description 43
- 230000003750 conditioning effect Effects 0.000 title claims description 22
- 229920006317 cationic polymer Polymers 0.000 title claims description 15
- 229920005573 silicon-containing polymer Polymers 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 8
- 229920000642 polymer Polymers 0.000 claims description 12
- 230000001419 dependent effect Effects 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920002717 polyvinylpyridine Polymers 0.000 claims description 4
- 150000001450 anions Chemical group 0.000 claims description 3
- 239000008365 aqueous carrier Substances 0.000 claims description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 239000000178 monomer Substances 0.000 claims 4
- 229920001519 homopolymer Polymers 0.000 claims 3
- QIZYPLYXKKJCPO-UHFFFAOYSA-N but-1-enyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCC=C[NH+](C)C QIZYPLYXKKJCPO-UHFFFAOYSA-N 0.000 claims 1
- 229920003118 cationic copolymer Polymers 0.000 claims 1
- 238000011282 treatment Methods 0.000 description 13
- 239000002453 shampoo Substances 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000004615 ingredient Substances 0.000 description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 4
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 4
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- -1 amine compounds Chemical class 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 230000003766 combability Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- CXIISRLRZRAKST-UHFFFAOYSA-N 29‐(4‐nonylphenoxy)‐3,6,9,12,15,18,21,24,27‐ nonaoxanonacosan‐1‐ol Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 CXIISRLRZRAKST-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000008266 hair spray Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229940073555 nonoxynol-10 Drugs 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- HHLJUSLZGFYWKW-UHFFFAOYSA-N triethanolamine hydrochloride Chemical class Cl.OCCN(CCO)CCO HHLJUSLZGFYWKW-UHFFFAOYSA-N 0.000 description 1
- KZMWNMQETCHSTH-UHFFFAOYSA-N trimethylazanium dichloride Chemical compound [Cl-].C[NH+](C)C.[Cl-].C[NH+](C)C KZMWNMQETCHSTH-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/594—Mixtures of polymers
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
i VO 818 !i VO 818!
Waterige samenstelling voor het conditioneren van haar, welke een siliconenpolymeer èn een kationisch polymeer bevat; werkwijze voor het conditioneren van haar.Aqueous hair conditioning composition containing a silicone polymer and a cationic polymer; method of conditioning hair.
De uitvinding heeft betrekking op samenstellingen, die gebruikt kunnen worden voor het conditioneren van haar alsmede op werkwijzen voor het conditioneren van haar, waarbij van dergelijke samenstellingen gebruik wordt gemaakt.The invention relates to compositions which can be used for hair conditioning as well as methods of hair conditioning using such compositions.
5 Het is bekend om haar te behandelen met bepaalde quaternaire amineverbindingen teneinde haar te conditioneren, d.w.z. de kambaar-heid en hanteerbaarheid te verbeteren, te zorgen dat het zacht aanvoelt,. een glanzend voorkomen te geven enz. Hoewel dergelijke bekende samenstellingen in verschillende maten doelmatig zijn gebleken 10 is een van de belangrijkste nadelen gebleken dat het effect van voorbijgaande aard is, d.w.z. een herhaalde behandeling met shampoo niet overleeft. Enige verbetering in de conditioneringsstabiliteit tegen behandeling met shampoo kan worden verkregen met bepaalde klassen van siliconenpolymeren. Voorbeelden van dergelijke polymeren 15 zijn amodimethiconen met de op het formuleblad weergegeven struc- tuurformule 1, waarin x en y van het molecuulgewicht afhangende hoofdtelwoorden zijn en waarvan het gewichtsgemiddelde molecuulgewicht ongeveer 5.000 - 100.000 bedraagt. Zelfs het gebruik van der--gelijke siliconenpolymeren laat echter nog te wensen over.It is known to treat hair with certain quaternary amine compounds to condition hair, i.e. improve combability and manageability, to leave it feeling soft. give a glossy appearance, etc. While such known compositions have been found to be effective in various sizes, one of the major disadvantages has been found to be transient, i.e., does not survive repeated shampooing. Some improvement in conditioning stability against shampooing can be achieved with certain classes of silicone polymers. Examples of such polymers are amodimethicones having the structural formula 1 shown on the formula sheet, wherein x and y are molecular weight dependent cardinal numbers and the weight average molecular weight of which is about 5,000-100,000. However, even the use of such silicone polymers leaves much to be desired.
20 Thans is gevonden dat zowel de doeltreffendheid van de con ditionering als de duurzaamheid van het conditioneringseffect van dergelijke siliconenpolymeren aanzienlijk versterkt kan worden door in het conditioneringspreparaat een of meerdere kationische polymeren cp te nemen. De polymeren die voor de doeleinden van de uitvin-25 ding bruikbaar zijn, kunnen over een ruim gebied variëren. Bijzon der nuttig gebleken kationische polymeren zijn die, welke in de handel verkrijgbaar zijn onder de merkaanduiding Merquat Cb.v.It has now been found that both the effectiveness of the conditioning and the durability of the conditioning effect of such silicone polymers can be greatly enhanced by incorporating one or more cationic polymers in the conditioning composition. The polymers useful for the purposes of the invention can vary over a wide range. Particularly useful cationic polymers have been found to be commercially available under the trade designation Merquat Cb.v.
Merquat 100 en Merquat 5503, Onamer Cb.v. Onamer M3 en gequaterni- 8 0 0 4 7 10 - 2 - seerde polyvinylpyridinen.Merquat 100 and Merquat 5503, Onamer Cb.v. Onamer M3 and quaternized polyvinylpyridines.
Merquat 100 is een polymeer van dimethyldiallylammoniumchlo-ride en bestaat waarschijnlijk uit mengsels van verbindingen met de formules 8 en 9. Ze variëren in molecuulgewicht en n is een van 5 het molecuulgewicht afhankelijk hoofdtelwoord. Gewoonlijk hebben echter de polymeren van deze klasse die gebruikt worden een molecuulgewicht in het gebied van ongeveer 4.000 - 550.000, bij voorkeur in het gebied van ongeveer 20.000 - 100.000. Merquat 550 is een copoly-meer van dimethyldiallylammoniumchloride en acrylamide met waar-10 schijnlijk formule 4 en een molecuulgewicht in het gebied van onge veer 5.000 - 550.000, waarbij n en m van het molecuulgewicht afhankelijke hoofdtelwoorden zijn.Merquat 100 is a polymer of dimethyldiallylammonium chloride and probably consists of mixtures of compounds of formulas 8 and 9. They vary in molecular weight and n is a molecular number dependent 5. Usually, however, the polymers of this class used have a molecular weight in the range of about 4,000-550,000, preferably in the range of about 20,000-100,000. Merquat 550 is a copolymer of dimethyldiallylammonium chloride and acrylamide of probably formula 4 and a molecular weight in the range of about 5,000-550,000, wherein n and m are molecular weight dependent headwords.
De Onamer-type polymeren die volgens de uitvinding kunnen worden toegepast, zijn polyCdimethylbutenylammoniumchloride]-<* .CO -15 bis(triëthanolammoniumchloride)verbindingen die met formule 5 kunnerr worden beschreven, waarin n een van het molecuulgewicht afhankelijk hoofdtelwoord is. De molecuulgewichten van deze polymeren die gebruikt kunnen worden, zullen liggen in een gebied van ongeveer 800 - 5.000 bij voorkeur ongeveer 1.000 - 3.000.The Onamer-type polymers that can be used according to the invention are poly [dimethylbutenyl ammonium chloride] - <15> CO -15 bis (triethanolammonium chloride) compounds which can be described by formula 5, wherein n is a molecular weight dependent numeral. The molecular weights of these polymers that can be used will range from about 800-5,000, preferably about 1,000-3,000.
20 Een derde soort kationische materialen die bijzonder nuttig zijn gebleken, zijn polymeren en copolymeren van gequaterniseerd polyvinylpyridine. Deze worden beschreven met formule 6 of 7, waarin R een alkylgroep met 1-20 koolstofatomén voorstelt an X een anion voorstelt zoals een halogenide, sulfaat of carboxylaat, en 25 n een van het molecuulgewicht afhankelijk hoofdtelwoord is. Deze verbindingen zullen eveneens een molecuulgewicht in een gebied van ongeveer 5.000 - 100.000 hebben.A third type of cationic materials that have proved particularly useful are polymers and copolymers of quaternized polyvinylpyridine. These are described in formula 6 or 7, in which R represents an alkyl group having 1-20 carbon atoms and X represents an anion such as a halide, sulfate or carboxylate, and 25n is a molecular number dependent principal. These compounds will also have a molecular weight in the range of about 5,000-100,000.
Als voorbeeld van een kationisch polymeer uit deze groep kan het polymeer met formule 10 worden genoemd, polyvinylmethylpyridini-30 umjodide genaamd, met een gemiddeld molecuulgewicht van 50.000.As an example of a cationic polymer from this group, the polymer of formula 10 can be mentioned, called polyvinylmethylpyridini-30 µm iodide, with an average molecular weight of 50,000.
De in het preparaat aanwezige hoeveelheid kationisch polymeer hangt af van de resultaten welke men wenst. Gewoonlijk zal deze hoe-• veelheid tussen ongeveer 0,01 en ongeveer 10 gew.%, gebaseerd op het totale gewicht van de waterige samenstellingen bedragen, waarbij de 35 optimale hoeveelheid tussen ongeveer 0,05 en ongeveer 3 gew.% op de- 8004710 j* *1 - 3 - zelfde gewichtsbasis bedraagt.The amount of cationic polymer present in the composition depends on the results desired. Usually, this amount will be between about 0.01 and about 10% by weight based on the total weight of the aqueous compositions, with the optimum amount being between about 0.05 and about 3% by weight on the 8004710 j * * 1 - 3 - is the same weight basis.
De in de samenstelling voor het conditioneren van haar volgens de uitvinding op te nemen hoeveelheid siliconenpolymeer Kan eveneens enigszins variëren. Gewoonlijk echter zal deze ongeveer 5 0,2 tot ongeveer 10 gew.%, gebaseerd op het totale gewicht van de samenstelling bedragen, bij voorkeur ongeveer 1 tot ongeveer 4 gew.%.The amount of silicone polymer to be included in the hair conditioning composition of the invention may also vary slightly. Usually, however, it will be about 0.2 to about 10 wt% based on the total weight of the composition, preferably about 1 to about 4 wt%.
Hoewel de bovenstaand vermelde kationische polymeren en siliconenpolymeren de essentiële actieve componenten van de samenstellingen volgens de uitvinding vormen, kunnen deze samenstellingen 10 eveneens andere ingrediënten bevatten, die voor het verbeteren van het organoleptische karakter van het produkt of het gemak van aanbrengen kunnen dienen. Het valt derhalve binnen de beschermings-omvang van de uitvinding om dergelijke materialen zoals geurstoffen, verdikkingsmiddelen, opaak makende middelen, enz., in de samenstel-15 lingen volgens de uitvinding op te nemen.While the above cationic polymers and silicone polymers are the essential active components of the compositions of the invention, these compositions may also contain other ingredients which may serve to improve the organoleptic character of the product or ease of application. It is therefore within the scope of the invention to include such materials as fragrances, thickeners, opacifying agents, etc., in the compositions of the invention.
De drager voor de samenstellingen volgens de uitvinding zal in het algemeen een waterige drager zijn. Deze kan velerlei soorten vormen hebben, b.v. de vorm van oplossingen, waterige emulsies, waterige gels enz. De hier gebruikte term "waterige drager" omvat 20 ook de gevallen waarin water in wezen het enige materiaal is dat de drager vormt, alsmede de gevallen waarin het water gemengd wordt met aanzienlijke hoeveelheden andere ingrediënten zoals oplosmiddelen, verdikkingsmiddelen, emulgeringsmiddelen, geleringsmiddelen, enz.The carrier for the compositions of the invention will generally be an aqueous carrier. It can take many kinds of shapes, e.g. the form of solutions, aqueous emulsions, aqueous gels, etc. The term "aqueous carrier" used herein also includes the cases where water is essentially the only material constituting the carrier, as well as the cases where the water is mixed with significant amounts of other ingredients such as solvents, thickeners, emulsifying agents, gelling agents, etc.
De samenstellingen volgens de uitvinding kunnen op elke ge-25 schikte wijze op haar worden aangebracht. Een typische werkwijze om vat het aanbrengen van de conditioneringssamenstelling, zoals beschreven in voorbeeld I, op pas met shampoo behandeld haar, het kalm in de haarmassa inwerken, het op het haar laten van de samenstelling gedurende 1-5 minuten en het grondig spoelen van het haar met wa-30 ter alvorens het baar te kammen. De op het haar aangebrachte hoeveel heid van de conditioneringssamenstelling kan variëren maar is in het algemeen liever niet minder dan 1% van het gewicht van het haar en liever niet meer dan 20% van het gewicht van het haar.The compositions of the invention can be applied to hair in any suitable manner. A typical method includes applying the conditioning composition, as described in Example I, to newly shampooed hair, gently working it into the hair mass, leaving the composition on the hair for 1-5 minutes and rinsing it thoroughly. hair with water before combing it. The amount of the conditioning composition applied to the hair may vary, but generally it is preferred not to be less than 1% of the weight of the hair and more preferably not more than 20% of the weight of the hair.
De uitvinding wordt aan de hand van de voorbeelden nader toe-35 gelicht.The invention is further elucidated by means of the examples.
80 0 4 7 1 0 - 4 -80 0 4 7 1 0 - 4 -
Voorbeeld-IExample I
Ingrediënt gew.%Ingredient wt%
XX
siliconenpolymeer (Amodimethicon} als emulsie 1,6 ' 5 Merquat 100 ** 1,6 hydroxyethylcellulose 1,5 citroenzuur 0,5 water aanvullend tot 100,0 * CTFA naam (RD-nummer 977069-10-53. Het handelsprodukt is Dow-10 Corning Cationic Emulsion 929, een mengsel van het geëmulgeerde polymeer en 1,9% talktrimethylammoniumdichloride, en 1,7% nonoxy-nol-10, een alkylfenoxypolyoxyethyleenethanol met 10 mol ethyleen-oxyde.silicone polymer (Amodimethicone} as emulsion 1.6 '5 Merquat 100 ** 1.6 hydroxyethyl cellulose 1.5 citric acid 0.5 water additionally up to 100.0 * CTFA name (RD number 977069-10-53. The commercial product is Dow- Corning Cationic Emulsion 929, a mixture of the emulsified polymer and 1.9% tallow trimethyl ammonium dichloride, and 1.7% nonoxy-nol-10, an alkylphenoxy polyoxyethylene ethanol with 10 moles of ethylene oxide.
XXXX
CTFA-naam Quaternium M-40 CRD-nummer 977066-02-63.CTFA name Quaternium M-40 CRD number 977066-02-63.
15 Voorbeeld ΙΓ15 Example ΙΓ
Ingrediënt gew.%Ingredient wt%
Amodimethicon 1,6 polyvinylallylpyridiniumsulfaat 1,6 hydroxyethylcellulose 1,5 20 citroenzuur 0,5 water aanvallend tot 100,0Amodimethicone 1.6 polyvinyl allyl pyridinium sulfate 1.6 hydroxyethyl cellulose 1.5 20 citric acid 0.5 water offensive to 100.0
Voorbeeld IIIExample III
Ingrediënt gew.%Ingredient wt%
Amodimethicon 1,6 25 Merquat 550 0,6 polyvinylmethylpyridiniumjodide 0,8 hydroxyethylcellulose 1,5 citroenzuur . 0,5 water aanvullend tot 100,0Amodimethicone 1.6 25 Merquat 550 0.6 polyvinylmethylpyridinium iodide 0.8 hydroxyethyl cellulose 1.5 citric acid. 0.5 water additionally up to 100.0
30 Voorbeeld IVExample IV
Ingrediënt gew.%Ingredient wt%
Siliconenpolymeer [Amodimethicon3 als emulsie· (Dow Corning Cationic Emulsion 9293 2,0Silicone polymer [Amodimethicone3 as emulsion · (Dow Corning Cationic Emulsion 9293 2.0
XXXXXX
35 Onamer M 1,5 80 04 7 1 0 - 5 - hydroxyethylcellulose 1,2 water aanvullend tot 100,035 Onamer M 1.5 80 04 7 1 0 - 5 - hydroxyethyl cellulose 1.2 water additionally up to 100.0
polyCdimethylbutenylammoniumchloride]--bisitriethanolammo-niumchloride) gemiddeld molecuulgewicht ongeveer 1.000 - 2.000 5 Voorbeeld VpolyCdimethylbutenylammonium chloride] - bisitriethanol ammonium chloride) average molecular weight about 1,000 - 2,000 Example V
Ingredient gew.%Ingredient wt%
Siliconenpolymeer·(Amodimethicon) als emulsie CDow Corning Cationic Emulsion 929) 1,75 10 stearylalcohol 1,6 glycerylmonostearaat 1,.5 minerale olie 0,8Silicone polymer (Amodimethicone) as emulsion CDow Corning Cationic Emulsion 929) 1.75 10 stearyl alcohol 1.6 glyceryl monostearate 1.5 oil mineral 0.8
Merquat 550 **** 0,4 propylparaben 0,5 15 water aanvullend tot 100,0 **** CTFA naam Quatemium M-41 (RD-nummer 977066-03-7) 0e doeltreffendheid van de conditionering alsmede de duurzaamheid daarvan wordt geïllustreerd in de volgende proef, waarbij het. normale kaukasische haar als testsubstraat is gebruikt.Merquat 550 **** 0.4 propyl paraben 0.5 15 water additionally up to 100.0 **** CTFA name Quatemium M-41 (RD number 977066-03-7) The effectiveness of the conditioning as well as its durability is illustrated in the following experiment, where the. normal Caucasian hair has been used as a test substrate.
20 Monsters van intact kaukasisch haar werden met kruidenshampoo (Herbal Essence Shampoo) behandeld volgens de op het etiket gegeven instructies. De verhouding van de hoeveelheid shampoo ten opzichte van het gewicht van het haar en de voor het spoelen na de shampoo-behandeling gebruikte hoeveelheid water werden gehouden op waarden, 25 waarmede de omstandigheden op het hoofd werden nagebootst. Na spoe len werd het in voorbeeld I beschreven conditioneringsmateriaal op het haar aangebracht (0,1 g van elk produkt per g haar). Het werd gedurende 30 seconden ingewerkt en gedurende nog eens 1 minuut op het haar gelaten waarna het haar gespoeld en gekamd werd. De kamme-30 tingen werden uitgevoerd . volgens de werkwijze, beschreven in het artikel van Carcia en Oiaz (j. Soc. Cosmetic Cheem, 27, 379 (1976)). Volgens deze proef wordt in wezen een haarlak door een kam geleid, die verbonden is met een spanningsmeter die op zijn beurt verbonden is met een optekeninstrument. Er wordt een kracht uitgeoefend om de 35 lok door de kam te laten passeren en de maximum kracht wordt afgele- 8004710 - 6 - zen- van het optekeninstrument als een objectieve maat voor het kam-gemak.Samples of intact Caucasian hair were treated with herbal shampoo (Herbal Essence Shampoo) according to the instructions on the label. The ratio of the amount of shampoo to the weight of the hair and the amount of water used for rinsing after the shampoo treatment were maintained at values simulating the conditions on the head. After rinsing, the conditioning material described in Example I was applied to the hair (0.1 g of each product per g of hair). It was soaked in for 30 seconds and left on the hair for an additional 1 minute after which the hair was rinsed and combed. Comb measurements were performed. according to the method described in the article by Carcia and Oiaz (J. Soc. Cosmetic Cheem, 27, 379 (1976)). According to this test, essentially a hairspray is passed through a comb which is connected to a strain gauge which in turn is connected to a recording instrument. A force is applied to allow the lock to pass through the comb and the maximum force is read from the recording instrument as an objective measure of combing convenience.
Nadat de kameigenschappen van haar na shampoobehandeling en conditioneerbehandelingen waren bepaald, werden de monsters vijfmaal 5 met shampoo behandeld en opnieuw aan de kamtest onderworpen. De re sultaten van de kambaarheidstesten staan in tabel A. Hierin is de maximum kamkracht uitgedrukt in eenheden G (Gram Force). Hoe hoger de waarde, des te moeilijker was het om het haar te kammen.After the combing properties of hair after shampooing and conditioning treatments were determined, the samples were shampooed five times and subjected to combing again. The results of the combability tests are shown in Table A. Here, the maximum combing force is expressed in units of G (Gram Force). The higher the value, the more difficult it was to comb the hair.
Tabel ATable A
10 Effect van conditionering op het kamgemak10 Effect of conditioning on combing ease
Procedure Behandeling Maximum kam-Procedure Treatment Maximum comb
No- kracht CG) 1 shampoobehandeling 30 2 proc.(l) gevolgd door behandeling met 15 bekend conditioneringspreparaat 42 3 proc.(2) gevolgd door 5 shampoos 97 4 proc.(l) gevolgd door behandeling met sa menstelling volgens voorbeeld I zonder Merquat 29 20 5 ~ Proc.(4) gevolgd door 5 shampoos 60 6 Proc.(l) gevolgd door behandeling met samenstelling volgens voorbeeld I 12 7 Proc.(6) gevolgd door 5 shampoos 18No-force CG) 1 shampoo treatment 30 2 proc. (1) followed by treatment with 15 known conditioning preparation 42 3 proc. (2) followed by 5 shampoos 97 4 proc. (1) followed by treatment with composition according to example I without Merquat 29 20 5 ~ Proc. (4) followed by 5 shampoos 60 6 Proc. (1) followed by treatment with composition according to example I 12 7 Proc. (6) followed by 5 shampoos 18
Nog· betere duurzaamheicf van de conditioneringseigenschappen 25 werd verkregen met samenstellingen volgens voorbeeld IV. Wederom werden pas met shampoo behandelde, bruine kaukasische haarlokken in het experiment gebruikt. De resultaten staan in tabel B.Even better durability of the conditioning properties was obtained with compositions according to example IV. Again, newly shampooed brown Caucasian locks of hair were used in the experiment. The results are shown in Table B.
Tabel BTable B
Effect van conditionering op kamgemak 30 Procedure Behandeling Maximum kam-Effect of conditioning on ease of combing 30 Procedure Treatment Maximum combing
No. kracht (G) 1 Shampoobehandeling 92 2 Proc.(l) gevolgd door behandeling met de samenstelling volgens voorbeeld IV zonder 35 Qnamer 19 8004710 - 7 - 3 Proc.(2) gevolgd door 10 opeenvolgende shampoobehandelingen 79 4 Proc.Cl] gevolgd door behandeling met de samenstelling volgens voorbeeld IV 11 5 5 Proc.(4] gevolgd door 10 opeenvolgende shampoobehandelingen 16No. potency (G) 1 Shampoo treatment 92 2 Proc. (1) followed by treatment with the composition of Example IV without 35 Qnamer 19 8004710 - 7 - 3 Proc. (2) followed by 10 consecutive shampoo treatments 79 4 Proc.Cl] followed by treatment with the composition according to example IV 11 5 5 Proc. (4] followed by 10 consecutive shampoo treatments 16
Hoewel de uitvinding beschreven is onder toelichting aan de hand van specifieke vormen daarvan, zal duidelijk zijn dat vele veranderingen en modificaties kunnen worden aangebracht zonder dat daar-lü mede de idee van de uitvinding wordt verlaten.While the invention has been described with reference to specific forms thereof, it will be appreciated that many changes and modifications can be made without departing from the idea of the invention.
80 04 7 1080 04 7 10
Claims (13)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6898679A | 1979-08-23 | 1979-08-23 | |
| US6898679 | 1979-08-23 | ||
| US16546880A | 1980-07-11 | 1980-07-11 | |
| US16546880 | 1980-07-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8004710A true NL8004710A (en) | 1981-02-25 |
Family
ID=26749571
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8004710A NL8004710A (en) | 1979-08-23 | 1980-08-20 | AQUEOUS COMPOSITION FOR CONDITIONING HAIR CONTAINING A SILICONE POLYMER AND A CATIONIC POLYMER; METHOD FOR CONDITIONING HAIR |
Country Status (11)
| Country | Link |
|---|---|
| AU (1) | AU6081680A (en) |
| DE (1) | DE3029306A1 (en) |
| DK (1) | DK360680A (en) |
| FI (1) | FI802631A7 (en) |
| FR (1) | FR2463612A1 (en) |
| GB (1) | GB2058103A (en) |
| GR (1) | GR69885B (en) |
| IT (1) | IT1145700B (en) |
| NL (1) | NL8004710A (en) |
| NO (1) | NO802492L (en) |
| SE (1) | SE8005886L (en) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5874602A (en) * | 1981-10-29 | 1983-05-06 | Toray Silicone Co Ltd | Hair conditioner |
| US4563347A (en) * | 1982-05-20 | 1986-01-07 | Dow Corning Corporation | Compositions used to condition hair |
| US4487883A (en) * | 1982-12-27 | 1984-12-11 | Dow Corning Corporation | One-part moisture cured aminosiloxanes |
| EP0117360A1 (en) * | 1982-12-27 | 1984-09-05 | Dow Corning Corporation | Aqueous compositions containing siloxane and a metallorganic additive |
| US4770873A (en) * | 1983-06-15 | 1988-09-13 | Clairol, Incorporated | Neutralizing composition and method for hair waving and straightening |
| LU84894A1 (en) * | 1983-07-01 | 1985-04-17 | Oreal | HAIR COMPOSITION AND METHOD FOR TREATING HAIR |
| GB8320603D0 (en) * | 1983-07-30 | 1983-09-01 | Dow Corning Ltd | Compositions for treating hair |
| US5213793A (en) * | 1984-01-13 | 1993-05-25 | The Gillette Company | Hair conditioning |
| US4801447A (en) * | 1984-02-22 | 1989-01-31 | Union Carbide Corporation | Water-in-volatile silicone emulsifier concentrates, water-in-volatile silicone emulsions that are useful in personal-care formulations and methods of making same |
| US4782095A (en) * | 1984-02-22 | 1988-11-01 | Union Carbide Corporation | Water-in-volatile silicone emulsifier concentrates |
| LU85303A1 (en) * | 1984-04-13 | 1985-11-27 | Oreal | HAIR COMPOSITION AND METHOD FOR TREATING HAIR |
| LU85549A1 (en) * | 1984-09-21 | 1986-04-03 | Oreal | COSMETIC COMPOSITIONS BASED ON CATIONIC SILICONE AND XANTHANE GUM |
| LU85589A1 (en) * | 1984-10-12 | 1986-06-11 | Oreal | DETERGENT COSMETIC COMPOSITIONS |
| US4820308A (en) * | 1984-10-12 | 1989-04-11 | L'oreal | Detergent cosmetic compositions containing a soap and cationic compound and direct dye |
| USRE34584E (en) | 1984-11-09 | 1994-04-12 | The Procter & Gamble Company | Shampoo compositions |
| US4764363A (en) * | 1986-04-04 | 1988-08-16 | The Procter & Gamble Company | Hair styling mousse |
| GB8821587D0 (en) * | 1988-09-15 | 1988-10-12 | Euro Celtique Sa | Method for controlling lice/their ova |
| JP2759486B2 (en) * | 1989-04-14 | 1998-05-28 | 花王株式会社 | Shampoo composition |
| US5211883A (en) * | 1989-04-14 | 1993-05-18 | Kao Corporation | Shampoo composition |
| US5049377A (en) * | 1990-03-02 | 1991-09-17 | Dow Corning Corporation | Hair-care composition and methods of treating hair |
| FR2677995B1 (en) * | 1991-06-21 | 1994-07-22 | Oreal | COMPOSITION FOR WASHING AND / OR CONDITIONING KERATINIC MATERIALS, CONTAINING A SILICONE AND AN AMPHOTERIC POLYMER DERIVED FROM DIALLYLDIALKYLAMMONIUM AND AN ANIONIC MONOMER. |
| FR2678633B1 (en) * | 1991-07-04 | 1993-10-22 | Oreal | COMPOSITION FOR WASHING AND / OR CONDITIONING KERATINIC MATERIALS BASED ON A SILICONE HAVING HYDROXYACYLAMINO FUNCTION AND SUBSTANTIVE POLYMERS. |
| US5326483A (en) * | 1993-02-19 | 1994-07-05 | Dow Corning Corporation | Method of making clear shampoo products |
| JP3273586B2 (en) * | 1995-03-01 | 2002-04-08 | 花王株式会社 | Hair cosmetics |
| FR2761599B1 (en) * | 1997-04-07 | 1999-12-03 | Oreal | COSMETIC COMPOSITIONS CONTAINING A LOW MOLECULAR MASS CATIONIC POLYMER AND THEIR USES |
| FR2831818B1 (en) | 2001-11-08 | 2004-07-16 | Oreal | OXIDIZING COMPOSITION FOR THE TREATMENT OF KERATINIC FIBERS COMPRISING A PARTICULAR AMINO SILICONE |
| FR2831815B1 (en) | 2001-11-08 | 2004-08-06 | Oreal | REDUCING COMPOSITION FOR THE TREATMENT OF KERATINIC FIBERS COMPRISING A PARTICULAR AMINO SILICONE |
| FR2831803B1 (en) | 2001-11-08 | 2004-07-30 | Oreal | COSMETIC COMPOSITIONS CONTAINING AN AMINO SILICONE AND A THICKENING AGENT AND THEIR USES |
| FR2831799B1 (en) * | 2001-11-08 | 2004-07-30 | Oreal | COSMETIC COMPOSITIONS CONTAINING AN AMINO SILICONE AND A SOLUBLE CONDITIONING AGENT AND USES THEREOF |
| AU2002301803B2 (en) | 2001-11-08 | 2004-09-09 | L'oreal | Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof |
| FR2831804B1 (en) | 2001-11-08 | 2004-07-30 | Oreal | PROCESS FOR PERMANENT DEFORMATION OF HAIR USING PARTICULAR AMINO SILICONES |
| FR2831814B1 (en) | 2001-11-08 | 2004-09-10 | Oreal | USES OF PARTICULAR AMINO SILICONES IN PRE- OR AFTER-TREATMENT OF KERATINIC FIBER DISCOLORATIONS |
| FR2926990B1 (en) * | 2008-01-31 | 2014-05-09 | Oreal | COSMETIC COMPOSITION COMPRISING VINYLFORMAMIDE / VINYLFORMAMINE COPOLYMER AND SILICONE, AND USE THEREOF FOR CAPILLARY TREATMENT |
| WO2016074142A1 (en) * | 2014-11-11 | 2016-05-19 | The Procter & Gamble Company | Detergent or cleaning compositions with improved sudsing profile |
| US20160310404A1 (en) * | 2015-04-21 | 2016-10-27 | Kao Usa, Inc. | Wash-out hair treatment composition |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE783231A (en) * | 1972-05-10 | 1972-09-01 | Gillette Co | Hair treatment before washing - with cationic polymer soln, to improve ease of combing and reduce static charges |
| DE2327066C3 (en) * | 1973-05-26 | 1975-11-20 | Hans Schwarzkopf Gmbh, 2000 Hamburg | Means and methods for setting hair |
| LU68901A1 (en) * | 1973-11-30 | 1975-08-20 | ||
| US3964500A (en) * | 1973-12-26 | 1976-06-22 | Lever Brothers Company | Lusterizing shampoo containing a polysiloxane and a hair-bodying agent |
| DE2631419A1 (en) * | 1975-07-16 | 1977-02-03 | Procter & Gamble Europ | COMPOSITIONS FOR TEXTILE TREATMENT |
-
1980
- 1980-07-25 GR GR62550A patent/GR69885B/el unknown
- 1980-07-25 AU AU60816/80A patent/AU6081680A/en not_active Abandoned
- 1980-07-31 FR FR8016909A patent/FR2463612A1/en not_active Withdrawn
- 1980-08-01 DE DE19803029306 patent/DE3029306A1/en not_active Withdrawn
- 1980-08-11 IT IT49463/80A patent/IT1145700B/en active
- 1980-08-20 NL NL8004710A patent/NL8004710A/en not_active Application Discontinuation
- 1980-08-20 FI FI802631A patent/FI802631A7/en not_active Application Discontinuation
- 1980-08-21 DK DK360680A patent/DK360680A/en unknown
- 1980-08-22 GB GB8027440A patent/GB2058103A/en not_active Withdrawn
- 1980-08-22 NO NO802492A patent/NO802492L/en unknown
- 1980-08-22 SE SE8005886A patent/SE8005886L/en not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| SE8005886L (en) | 1981-02-24 |
| GR69885B (en) | 1982-07-20 |
| DE3029306A1 (en) | 1981-03-12 |
| IT1145700B (en) | 1986-11-05 |
| DK360680A (en) | 1981-02-24 |
| GB2058103A (en) | 1981-04-08 |
| AU6081680A (en) | 1981-02-26 |
| IT8049463A0 (en) | 1980-08-11 |
| FR2463612A1 (en) | 1981-02-27 |
| FI802631A7 (en) | 1981-01-01 |
| NO802492L (en) | 1981-02-24 |
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