NL8001928A - Werkwijze voor het maken van polymeerdispersies. - Google Patents
Werkwijze voor het maken van polymeerdispersies. Download PDFInfo
- Publication number
- NL8001928A NL8001928A NL8001928A NL8001928A NL8001928A NL 8001928 A NL8001928 A NL 8001928A NL 8001928 A NL8001928 A NL 8001928A NL 8001928 A NL8001928 A NL 8001928A NL 8001928 A NL8001928 A NL 8001928A
- Authority
- NL
- Netherlands
- Prior art keywords
- weight
- emulsifier
- copolymerizable
- monomers
- parts
- Prior art date
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- 239000006185 dispersion Substances 0.000 title claims abstract description 37
- 238000000034 method Methods 0.000 title claims abstract description 19
- 229920000642 polymer Polymers 0.000 title claims description 32
- -1 polyoxyethylene chain Polymers 0.000 claims abstract description 49
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 48
- 239000000178 monomer Substances 0.000 claims abstract description 37
- 239000003973 paint Substances 0.000 claims abstract description 26
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- 125000006353 oxyethylene group Chemical group 0.000 claims abstract description 18
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 9
- 125000002843 carboxylic acid group Chemical group 0.000 claims abstract description 5
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 4
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 17
- 239000010452 phosphate Substances 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 229920001223 polyethylene glycol Polymers 0.000 claims description 11
- 125000000129 anionic group Chemical group 0.000 claims description 10
- 239000012874 anionic emulsifier Substances 0.000 claims description 9
- 229920003176 water-insoluble polymer Polymers 0.000 claims description 9
- 239000012875 nonionic emulsifier Substances 0.000 claims description 7
- 229920005682 EO-PO block copolymer Polymers 0.000 claims description 6
- RVGRUAULSDPKGF-UHFFFAOYSA-N Poloxamer Chemical compound C1CO1.CC1CO1 RVGRUAULSDPKGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000011230 binding agent Substances 0.000 claims description 6
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 6
- 150000007942 carboxylates Chemical class 0.000 claims description 5
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000012644 addition polymerization Methods 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 150000002989 phenols Chemical class 0.000 claims 2
- 239000000839 emulsion Substances 0.000 abstract description 8
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- 150000002334 glycols Chemical class 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 34
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 34
- 235000021317 phosphate Nutrition 0.000 description 15
- 238000006116 polymerization reaction Methods 0.000 description 11
- 238000000576 coating method Methods 0.000 description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 9
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 8
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 8
- 239000003381 stabilizer Substances 0.000 description 8
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 7
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 6
- GJYCVCVHRSWLNY-UHFFFAOYSA-N ortho-butylphenol Natural products CCCCC1=CC=CC=C1O GJYCVCVHRSWLNY-UHFFFAOYSA-N 0.000 description 6
- 239000011521 glass Substances 0.000 description 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 5
- NWMMSYALOCZIED-UHFFFAOYSA-N P(=O)(O)(O)O.OCCC=C(C(=O)OCCCCCCCCCCCC)C Chemical compound P(=O)(O)(O)O.OCCC=C(C(=O)OCCCCCCCCCCCC)C NWMMSYALOCZIED-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 150000001735 carboxylic acids Chemical class 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 239000000084 colloidal system Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- ZRIMDWRLVGDUBW-UHFFFAOYSA-N 5-hydroxy-2-methylpent-2-enoic acid phosphoric acid Chemical compound P(=O)(O)(O)O.OCCC=C(C(=O)O)C ZRIMDWRLVGDUBW-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 239000001530 fumaric acid Substances 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 230000000087 stabilizing effect Effects 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229960002887 deanol Drugs 0.000 description 2
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 2
- 229940043264 dodecyl sulfate Drugs 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- NJFXSOYZTRWIJA-IHWYPQMZSA-N (Z)-4-oxo-4-(2-sulfopropoxy)but-2-enoic acid Chemical compound OS(=O)(=O)C(C)COC(=O)\C=C/C(O)=O NJFXSOYZTRWIJA-IHWYPQMZSA-N 0.000 description 1
- OGTWEKWZKLWFNN-UHFFFAOYSA-N 1-[3-(2-sulfopropoxycarbonyl)but-3-enoyloxy]propane-2-sulfonic acid Chemical compound OS(=O)(=O)C(C)COC(=O)CC(=C)C(=O)OCC(C)S(O)(=O)=O OGTWEKWZKLWFNN-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 1
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical compound CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- ABMULKFGWTYIIK-UHFFFAOYSA-N 2-hexylphenol Chemical compound CCCCCCC1=CC=CC=C1O ABMULKFGWTYIIK-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- IRORLSOGUSRERU-UHFFFAOYSA-N 3-(2-sulfopropoxycarbonyl)but-3-enoic acid Chemical compound OS(=O)(=O)C(C)COC(=O)C(=C)CC(O)=O IRORLSOGUSRERU-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- IEEGFBHLLWBJJH-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)butane-1-sulfonic acid Chemical compound CC(=C)C(=O)OCCCCS(O)(=O)=O IEEGFBHLLWBJJH-UHFFFAOYSA-N 0.000 description 1
- KFDVPJUYSDEJTH-UHFFFAOYSA-N 4-ethenylpyridine Chemical compound C=CC1=CC=NC=C1 KFDVPJUYSDEJTH-UHFFFAOYSA-N 0.000 description 1
- RTTAGBVNSDJDTE-UHFFFAOYSA-N 4-ethoxy-2-methylidene-4-oxobutanoic acid Chemical compound CCOC(=O)CC(=C)C(O)=O RTTAGBVNSDJDTE-UHFFFAOYSA-N 0.000 description 1
- IFMAXSPUGLIHME-UHFFFAOYSA-N 5-hydroxy-2-methylhex-2-enoic acid phosphoric acid Chemical compound P(=O)(O)(O)O.OC(CC=C(C(=O)O)C)C IFMAXSPUGLIHME-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 101001053401 Arabidopsis thaliana Acid beta-fructofuranosidase 3, vacuolar Proteins 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 229920002043 Pluronic® L 35 Polymers 0.000 description 1
- 229920002066 Pluronic® P 65 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-M benzenesulfonate Chemical compound [O-]S(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-M 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- BRXCDHOLJPJLLT-UHFFFAOYSA-N butane-2-sulfonic acid Chemical compound CCC(C)S(O)(=O)=O BRXCDHOLJPJLLT-UHFFFAOYSA-N 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229940125773 compound 10 Drugs 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- WDRSIEGNABPGRZ-UHFFFAOYSA-N dodecyl 4-hydroxy-2-methylidenebutanoate phosphoric acid Chemical compound P(=O)(O)(O)O.OCCC(C(=O)OCCCCCCCCCCCC)=C WDRSIEGNABPGRZ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- ZLVXBBHTMQJRSX-VMGNSXQWSA-N jdtic Chemical compound C1([C@]2(C)CCN(C[C@@H]2C)C[C@H](C(C)C)NC(=O)[C@@H]2NCC3=CC(O)=CC=C3C2)=CC=CC(O)=C1 ZLVXBBHTMQJRSX-VMGNSXQWSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920001993 poloxamer 188 Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Paints Or Removers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Heat Treatment Of Steel (AREA)
- Bulkheads Adapted To Foundation Construction (AREA)
- Colloid Chemistry (AREA)
Priority Applications (14)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8001928A NL8001928A (nl) | 1980-04-02 | 1980-04-02 | Werkwijze voor het maken van polymeerdispersies. |
| AU68298/81A AU542047B2 (en) | 1980-04-02 | 1981-03-12 | Preparation of aqueous polymer dispersion |
| AT81200330T ATE14738T1 (de) | 1980-04-02 | 1981-03-25 | Verfahren zur herstellung von polymerdispersionen. |
| DE8181200330T DE3171656D1 (en) | 1980-04-02 | 1981-03-25 | Process for the preparation of polymer dispersions |
| EP81200330A EP0037150B2 (en) | 1980-04-02 | 1981-03-25 | Process for the preparation of polymer dispersions |
| ES500847A ES500847A0 (es) | 1980-04-02 | 1981-03-30 | Un procedimiento de preparacion de una dispersion acuosa de un polimero insoluble en agua |
| PT72777A PT72777B (en) | 1980-04-02 | 1981-03-31 | Process for the preparation of polymer dispersions |
| NO811101A NO159387C (no) | 1980-04-02 | 1981-03-31 | Fremgangsmaate ved fremstilling av polymerdispersjoner og anvendelse av dispersjonene som bindemiddel i maling. |
| FI811004A FI68846C (fi) | 1980-04-02 | 1981-04-01 | Foerfarande foer framstaellning av polymerdispersion och dess anvaendning som bindemedel i faerger |
| BR8101975A BR8101975A (pt) | 1980-04-02 | 1981-04-01 | Processo para a preparacao de uma dispersao aquosa de um polimero insoluvel em agua,processo para preparacao de uma dispersao aquosa polimera com escoamento aumentado,e tinta contendo a ultima dispersao |
| CA000374396A CA1201835A (en) | 1980-04-02 | 1981-04-01 | Process for the preparation of polymer dispersions |
| MX819389U MX7264E (es) | 1980-04-02 | 1981-04-01 | Procedimiento mejorado para la obtencion de una dispersion acuosa de un polimero insoluble en agua |
| JP4998881A JPS56155212A (en) | 1980-04-02 | 1981-04-02 | Manufacture of polymer dispersion |
| US06/461,493 US4477623A (en) | 1980-04-02 | 1983-01-27 | Process for the preparation of polymer dispersions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8001928 | 1980-04-02 | ||
| NL8001928A NL8001928A (nl) | 1980-04-02 | 1980-04-02 | Werkwijze voor het maken van polymeerdispersies. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NL8001928A true NL8001928A (nl) | 1981-11-02 |
Family
ID=19835099
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NL8001928A NL8001928A (nl) | 1980-04-02 | 1980-04-02 | Werkwijze voor het maken van polymeerdispersies. |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4477623A (es) |
| EP (1) | EP0037150B2 (es) |
| JP (1) | JPS56155212A (es) |
| AT (1) | ATE14738T1 (es) |
| AU (1) | AU542047B2 (es) |
| BR (1) | BR8101975A (es) |
| CA (1) | CA1201835A (es) |
| DE (1) | DE3171656D1 (es) |
| ES (1) | ES500847A0 (es) |
| FI (1) | FI68846C (es) |
| MX (1) | MX7264E (es) |
| NL (1) | NL8001928A (es) |
| NO (1) | NO159387C (es) |
| PT (1) | PT72777B (es) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59155413A (ja) * | 1983-02-24 | 1984-09-04 | Dainippon Ink & Chem Inc | 樹脂分散液およびその製法 |
| US4604414A (en) * | 1983-03-31 | 1986-08-05 | Sumitomo Chemical Company, Limited | Antistatic acrylic resin composition and method for the production thereof |
| DE3402447A1 (de) | 1984-01-25 | 1985-07-25 | Henkel KGaA, 4000 Düsseldorf | Acrylathydrosole |
| DE3518671A1 (de) * | 1985-05-24 | 1986-11-27 | Basf Ag, 6700 Ludwigshafen | Anstrichfarben mit einem zusatz an einer grobteiligen polystyrol-dispersion |
| DE3620679A1 (de) * | 1986-06-20 | 1987-12-23 | Henkel Kgaa | Mittel zur ausruestung von textilien |
| DE3728992A1 (de) * | 1987-08-29 | 1989-03-09 | Basf Ag | Phosphatgruppen enthaltende waessrige sekundaerdispersionen fuer anstrichmittel |
| US5191029A (en) * | 1988-12-29 | 1993-03-02 | Deldonno Theodore A | Phosphorus-containing polymer compositions containing water-soluble polyvalent metal compounds |
| US5258451A (en) * | 1990-06-07 | 1993-11-02 | Shin-Etsu Chemical Co., Ltd. | Method for the preparation of an aqueous emulsion of organopolysiloxane |
| US5191009A (en) * | 1990-09-20 | 1993-03-02 | The Goodyear Tire & Rubber Company | Process for producing stable latex |
| US6080802A (en) * | 1991-12-03 | 2000-06-27 | Rohm And Haas Company | Process for preparing an aqueous dispersion of composite particles including polymeric latex adsorbed to titanium dioxide |
| US5663224A (en) * | 1991-12-03 | 1997-09-02 | Rohm And Haas Company | Process for preparing an aqueous dispersion |
| US5232838A (en) * | 1991-12-09 | 1993-08-03 | Minnesota Mining And Manufacturing Company | Culture media device and method of use |
| DE4141942A1 (de) * | 1991-12-19 | 1993-06-24 | Huels Chemische Werke Ag | Verfahren zur herstellung grossteiliger, waessriger kunststoffdispersionen |
| EP0661302B1 (en) * | 1993-12-23 | 1999-09-01 | Nitto Denko Corporation | Process for producing aqueous Dispersion-Type Acrylic Polymer, the acrylic polymer obtained thereby, and pressure-sensitive adhesive comprising the acrylic polymer |
| US5962580A (en) * | 1995-06-07 | 1999-10-05 | Rohm And Haas Company | Method for providing a waterborne coating composition with improved color acceptance |
| US5731368A (en) * | 1995-09-01 | 1998-03-24 | Union Carbide Chemicals & Plastics Technology Corporation | Aoueous vinyl polymer dispersions |
| US5782972A (en) * | 1997-03-21 | 1998-07-21 | W.R. Grace & Co.-Conn. | Additive for production of highly workable mortar cement |
| WO2000031174A1 (en) | 1998-11-23 | 2000-06-02 | W.R. Grace & Co.-Conn. | Improved workability and board life in masonry mortar and method for obtaining same |
| DE19939327A1 (de) * | 1999-08-19 | 2001-02-22 | Basf Ag | Bindemittelzubereitungen auf der Basis wässriger Polymerdispersionen |
| KR100401114B1 (ko) * | 1999-11-24 | 2003-10-10 | 엄정철 | 수성페인트조성물 |
| US6541590B1 (en) | 1999-12-14 | 2003-04-01 | Rohm And Haas Company | Polymeric binders from copolymers of unsaturated carboxylic acids and surfactant monomers |
| US6638998B2 (en) | 2001-04-18 | 2003-10-28 | Basf Ag | Use of surfactants for improving the compatibility of inorganic pigments in aqueous coating compositions |
| DE10332621A1 (de) † | 2003-07-17 | 2005-02-03 | Wacker Polymer Systems Gmbh & Co. Kg | Verfahren zur Herstellung von Polyvinylalkohol-freien, wässrigen Polymerdispersionen |
| US9102848B2 (en) | 2011-02-28 | 2015-08-11 | Basf Se | Environmentally friendly, polymer dispersion-based coating formulations and methods of preparing and using same |
| DE102012019789A1 (de) | 2012-10-09 | 2014-04-10 | Clariant International Limited | Phosphorgruppenhaltige Polyalkylenglykol-Blockcopolymere und deren Verwendung als Emulgatoren für die Emulsionspolymerisation |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3202638A (en) * | 1961-06-01 | 1965-08-24 | Shell Oil Co | Freeze-thaw mechanically stable latex of a terpolymer of styrene, alkyl acrylate and an alpha-beta vinylidene carboxylic acid |
| CH425237A (de) * | 1963-12-12 | 1966-11-30 | Ciba Geigy | Verfahren zur Emulsionspolymerisation von ungesättigten polymerisierbaren Verbindungen |
| FR1520906A (fr) * | 1966-04-02 | 1968-04-12 | Basf Ag | Procédé de préparation de suspensions de copolymères styrène-butadiène |
| US3536682A (en) * | 1968-03-04 | 1970-10-27 | Gulf Research Development Co | Self-emulsifiable ethylene polymer compositions |
| US3516975A (en) * | 1968-10-25 | 1970-06-23 | Gen Tire & Rubber Co | Ethylene-vinyl acetate polymers prepared with polyoxyalkylene compounds |
| JPS4932787B2 (es) * | 1971-08-07 | 1974-09-03 | ||
| DE2452585B2 (de) * | 1974-11-06 | 1981-07-30 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung scherstabiler wäßriger Copolymerisat-Dispersionen |
| DE2604630C2 (de) * | 1976-02-06 | 1982-06-24 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von Acrylnitril-Vinylchlorid-Copolymerisaten mit erhöhter Viskositätzszahl |
-
1980
- 1980-04-02 NL NL8001928A patent/NL8001928A/nl not_active Application Discontinuation
-
1981
- 1981-03-12 AU AU68298/81A patent/AU542047B2/en not_active Ceased
- 1981-03-25 AT AT81200330T patent/ATE14738T1/de not_active IP Right Cessation
- 1981-03-25 DE DE8181200330T patent/DE3171656D1/de not_active Expired
- 1981-03-25 EP EP81200330A patent/EP0037150B2/en not_active Expired
- 1981-03-30 ES ES500847A patent/ES500847A0/es active Granted
- 1981-03-31 NO NO811101A patent/NO159387C/no unknown
- 1981-03-31 PT PT72777A patent/PT72777B/pt not_active IP Right Cessation
- 1981-04-01 MX MX819389U patent/MX7264E/es unknown
- 1981-04-01 CA CA000374396A patent/CA1201835A/en not_active Expired
- 1981-04-01 BR BR8101975A patent/BR8101975A/pt unknown
- 1981-04-01 FI FI811004A patent/FI68846C/fi not_active IP Right Cessation
- 1981-04-02 JP JP4998881A patent/JPS56155212A/ja active Pending
-
1983
- 1983-01-27 US US06/461,493 patent/US4477623A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0037150B1 (en) | 1985-08-07 |
| EP0037150A3 (en) | 1982-02-17 |
| FI68846C (fi) | 1985-11-11 |
| AU6829881A (en) | 1981-10-08 |
| FI811004L (fi) | 1981-10-03 |
| EP0037150A2 (en) | 1981-10-07 |
| NO159387B (no) | 1988-09-12 |
| PT72777B (en) | 1982-03-23 |
| BR8101975A (pt) | 1981-10-06 |
| ES8205423A1 (es) | 1982-06-01 |
| AU542047B2 (en) | 1985-02-07 |
| FI68846B (fi) | 1985-07-31 |
| EP0037150B2 (en) | 1989-10-18 |
| NO159387C (no) | 1988-12-21 |
| NO811101L (no) | 1981-10-05 |
| ATE14738T1 (de) | 1985-08-15 |
| PT72777A (en) | 1981-04-01 |
| JPS56155212A (en) | 1981-12-01 |
| US4477623A (en) | 1984-10-16 |
| CA1201835A (en) | 1986-03-11 |
| ES500847A0 (es) | 1982-06-01 |
| MX7264E (es) | 1988-03-11 |
| DE3171656D1 (en) | 1985-09-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| BV | The patent application has lapsed |