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MX2022000006A - Materiales de aerogel hidrofobos mejorados. - Google Patents

Materiales de aerogel hidrofobos mejorados.

Info

Publication number
MX2022000006A
MX2022000006A MX2022000006A MX2022000006A MX2022000006A MX 2022000006 A MX2022000006 A MX 2022000006A MX 2022000006 A MX2022000006 A MX 2022000006A MX 2022000006 A MX2022000006 A MX 2022000006A MX 2022000006 A MX2022000006 A MX 2022000006A
Authority
MX
Mexico
Prior art keywords
favorable
combustion
aerogel composition
hydrophobic aerogel
aerogel materials
Prior art date
Application number
MX2022000006A
Other languages
English (en)
Inventor
Irene Melnikova
Owen Evans
Kathryn Dekraft
Nicholas Zafiropoulos
Wenting Dong
David Mihalcik
George Gould
Original Assignee
Aspen Aerogels Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=54352496&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=MX2022000006(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Aspen Aerogels Inc filed Critical Aspen Aerogels Inc
Publication of MX2022000006A publication Critical patent/MX2022000006A/es

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/157After-treatment of gels
    • C01B33/158Purification; Drying; Dehydrating
    • C01B33/1585Dehydration into aerogels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/0091Preparation of aerogels, e.g. xerogels
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00Silicon; Compounds thereof
    • C01B33/113Silicon oxides; Hydrates thereof
    • C01B33/12Silica; Hydrates thereof, e.g. lepidoic silicic acid
    • C01B33/14Colloidal silica, e.g. dispersions, gels, sols
    • C01B33/157After-treatment of gels
    • C01B33/159Coating or hydrophobisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/06Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by burning-out added substances by burning natural expanding materials or by sublimating or melting out added substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085Use of fibrous compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00Foams characterised by the foaming process
    • C08J2201/04Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
    • C08J2201/05Elimination by evaporation or heat degradation of a liquid phase
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00Foams characterised by their properties
    • C08J2205/02Foams characterised by their properties the finished foam itself being a gel or a gel being temporarily formed when processing the foamable composition
    • C08J2205/026Aerogel, i.e. a supercritically dried gel
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/02Polysilicates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/28Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2262Oxides; Hydroxides of metals of manganese

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Silicon Compounds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Silicon Polymers (AREA)

Abstract

La presente descripción proporciona una composición de aerogel que es durable y fácil de manejar, tiene un funcionamiento favorable en ambientes acuosos, y que también tiene propiedades de combustión y auto-calentamiento favorables. También se proporciona un método para preparar una composición de aerogel que es durable y fácil de manejar, que tiene un funcionamiento favorable en ambientes acuosos, y que tiene propiedades de combustión y auto-calentamiento favorables. Además, se proporciona un método para mejorar la hidrofobicidad, la absorción de agua líquida, el calor de combustión, o la temperatura del inicio de la descomposición térmica de una composición de aerogel.
MX2022000006A 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados. MX2022000006A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462059555P 2014-10-03 2014-10-03
US201562118864P 2015-02-20 2015-02-20
US201562232945P 2015-09-25 2015-09-25

Publications (1)

Publication Number Publication Date
MX2022000006A true MX2022000006A (es) 2022-02-25

Family

ID=54352496

Family Applications (6)

Application Number Title Priority Date Filing Date
MX2017003836A MX2017003836A (es) 2014-10-03 2015-10-02 Materiales de aerogel hidrofobos mejorados.
MX2022000019A MX2022000019A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.
MX2022000011A MX2022000011A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.
MX2022000022A MX2022000022A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.
MX2022000006A MX2022000006A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.
MX2022000017A MX2022000017A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.

Family Applications Before (4)

Application Number Title Priority Date Filing Date
MX2017003836A MX2017003836A (es) 2014-10-03 2015-10-02 Materiales de aerogel hidrofobos mejorados.
MX2022000019A MX2022000019A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.
MX2022000011A MX2022000011A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.
MX2022000022A MX2022000022A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.

Family Applications After (1)

Application Number Title Priority Date Filing Date
MX2022000017A MX2022000017A (es) 2014-10-03 2017-03-23 Materiales de aerogel hidrofobos mejorados.

Country Status (18)

Country Link
US (11) US9868843B2 (es)
EP (5) EP4234619A3 (es)
JP (5) JP6487542B2 (es)
KR (9) KR102164554B1 (es)
CN (6) CN114804125A (es)
AU (5) AU2015327930C1 (es)
BR (1) BR112017006480B1 (es)
CA (2) CA3041713C (es)
CL (1) CL2017000797A1 (es)
CO (1) CO2017003835A2 (es)
IL (2) IL287217B2 (es)
MX (6) MX2017003836A (es)
MY (1) MY179571A (es)
RU (1) RU2668657C1 (es)
SG (2) SG11201702138XA (es)
TW (1) TWI588209B (es)
WO (1) WO2016054524A2 (es)
ZA (2) ZA201702245B (es)

Families Citing this family (58)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11380953B2 (en) 2014-06-23 2022-07-05 Aspen Aerogels, Inc. Thin aerogel materials
CA3041713C (en) * 2014-10-03 2025-05-06 Aspen Aerogels, Inc. IMPROVED HYDROPHOBIC AEROGEEL MATERIALS
WO2017074751A1 (en) 2015-10-30 2017-05-04 Blueshift International Materials, Inc. Highly branched non-crosslinked aerogel, methods of making, and uses thereof
CA3002361A1 (en) 2015-11-03 2017-05-11 Blueshift Materials, Inc. Internally reinforced aerogel and uses thereof
FR3050013B1 (fr) * 2016-04-11 2019-08-02 Saint-Gobain Isover Fours et produits d'isolation pour fours
CN108699277B (zh) 2016-06-08 2022-12-02 蓝移材料有限公司 具有改善的机械性能和热性能的聚合物气凝胶
KR20180116363A (ko) 2016-07-27 2018-10-24 와커 헤미 아게 개질된 침전 실리카의 제조 방법 및 이를 함유하는 조성물
JP6672524B2 (ja) * 2016-08-09 2020-03-25 エルジー・ケム・リミテッド エアロゲル前駆体、その製造方法、これにより製造されたエアロゲルおよびこれを用いたエアロゲルの製造方法
US10072213B2 (en) * 2016-10-20 2018-09-11 Jean-Hong CHEN Fireproof material incorporating aerogel with organic foam material and method for making the same
US10256861B2 (en) * 2017-01-23 2019-04-09 Nicole Elizabeth Burns Floatable cell phone case
KR101913507B1 (ko) * 2017-07-19 2018-10-30 한양대학교 산학협력단 실리카 에어로겔 파우더 제조 방법 및 그에 의해 제조된 실리카 에어로겔 파우더
UA115857C2 (uk) * 2017-08-30 2017-12-26 Олександр Михайлович Мартиненко Спосіб одержання гідрогелю метилкремнієвої кислоти з властивостями супрамолекулярних структур і гідрогель, одержаний цим способом
JP7000753B2 (ja) 2017-09-08 2022-01-19 富士フイルムビジネスイノベーション株式会社 酸化チタンエアロゲル粒子、酸化チタンエアロゲル粒子の製造方法、光触媒形成用組成物、光触媒、及び構造体
US10538434B2 (en) * 2017-09-08 2020-01-21 Fuji Xerox Co., Ltd. Titanium oxide aerogel particle, photocatalyst forming composition, and photocatalyst
KR102190889B1 (ko) * 2017-11-21 2020-12-14 주식회사 엘지화학 고단열 및 고강도 실리카 에어로겔 블랭킷 제조방법
EP3720903B1 (en) 2017-12-05 2024-02-07 Blueshift Materials, Inc. Thermally treated polyamic amide aerogel
WO2019129607A1 (en) * 2017-12-27 2019-07-04 Rhodia Operations Precipitated silica and process for its manufacture
WO2019232087A1 (en) * 2018-05-31 2019-12-05 Aspen Aerogels, Inc. Fire-class reinforced aerogel compositions
JP7293583B2 (ja) * 2018-07-11 2023-06-20 株式会社レゾナック エアロゲルブロック
CN109019611B (zh) * 2018-08-17 2020-06-02 中南大学 一种块体透明二氧化硅气凝胶及其快速制备方法和应用
CN112119036B (zh) 2018-11-27 2023-09-12 株式会社Lg化学 气凝胶毡的制造方法
RU2696638C1 (ru) * 2019-01-17 2019-08-05 Общество с ограниченной ответственностью "Ниагара" Способ получения теплоизоляционного материала на основе аэрогеля
FR3094975B1 (fr) * 2019-04-10 2022-11-18 Keey Aerogel Procédé de synthèse d’un aérogel de silice hydrophobique de type « one pot » à partir d’un précurseur de silice
JP7426553B2 (ja) * 2019-05-29 2024-02-02 パナソニックIpマネジメント株式会社 断熱シートおよびその製造方法、ならびに電子機器および電池ユニット
US12139410B2 (en) 2019-09-03 2024-11-12 Lg Chem, Ltd. Aerogel blanket
KR102555087B1 (ko) * 2019-09-03 2023-07-17 주식회사 엘지화학 에어로겔 블랭킷
WO2021045484A1 (ko) * 2019-09-03 2021-03-11 주식회사 엘지화학 에어로겔 블랭킷
KR102581268B1 (ko) 2019-09-03 2023-09-22 주식회사 엘지화학 에어로겔 블랭킷 제조방법
EP3882214B1 (en) 2019-09-03 2023-11-08 LG Chem, Ltd. Apparatus and method for manufacturing aerogel blanket
CN113382962B (zh) * 2019-09-30 2024-01-30 株式会社Lg化学 二氧化硅溶胶、使用它制造的二氧化硅气凝胶毡和制造二氧化硅气凝胶毡的方法
EP4041435A4 (en) 2019-10-11 2023-11-15 Aerogel Technologies, LLC HYDROPHOBIC POLYIMIDE AIRGELS
WO2021072323A1 (en) 2019-10-11 2021-04-15 Aerogel Technologies, Llc Polymer-aerogel/fiber and polymer-aerogel/textile composites and related systems and methods
KR102245945B1 (ko) * 2019-10-30 2021-04-29 연세대학교 산학협력단 에어로겔
CN117569467A (zh) * 2019-11-22 2024-02-20 亚斯朋空气凝胶公司 用于建筑物隔热的包含至少一种气凝胶复合材料的绝热板
EP4069509A1 (en) 2019-12-02 2022-10-12 Aspen Aerogels Inc. Aerogel-based components and systems for electric vehicle thermal management
BR112022010804A2 (pt) 2019-12-02 2022-08-23 Aspen Aerogels Inc Componentes e sistemas para gerenciar problemas de fuga térmica em baterias de veículos elétricos.
CN115279583B (zh) 2020-01-07 2025-01-14 亚斯朋空气凝胶公司 电池热管理构件
TWI726638B (zh) 2020-03-02 2021-05-01 趙國昇 二氧化矽氣凝膠之製備方法
EP3896035A1 (en) * 2020-04-15 2021-10-20 EMPA Eidgenössische Materialprüfungs- und Forschungsanstalt Silica aerogels and silica aerogel blankets
WO2021204815A1 (en) * 2020-04-06 2021-10-14 Empa Eidgenössische Materialprüfungs- Und Forschungsanstalt Silica aerogels
US11912579B2 (en) * 2020-04-06 2024-02-27 Aspen Aerogels, Inc. Aerogel compositions and methods
US20210332270A1 (en) * 2020-04-27 2021-10-28 Taiwan Aerogel Technology Material Co., Ltd. Method for producing a high temperature resistant, heat insulating, and fireproof composite glue composed of an aerogel and an inorganic fiber and the application of the related product
JP7070863B2 (ja) * 2020-04-28 2022-05-18 台湾気凝膠科技材料開発股▲分▼有限公司 高温耐性、断熱性、耐火性を備えたエアロゲル及び無機繊維複合ゲル材料の製造方法、並びにその製品の使用
JP7090294B2 (ja) * 2020-04-28 2022-06-24 台湾気凝膠科技材料開発股▲分▼有限公司 耐寒性と断熱性を有する疎水性エアロゲル複合ゲル状物質を製造する方法及びその関連製品
KR102730293B1 (ko) * 2020-07-24 2024-11-15 주식회사 엘지화학 실리카 에어로겔 제조방법
CN112897534A (zh) * 2021-01-27 2021-06-04 西南大学 苯基增强柔性二氧化硅气凝胶及制备方法和应用
WO2022160174A1 (zh) * 2021-01-28 2022-08-04 华豹(天津)新材料科技发展股份有限公司 一种绝热气凝胶真空复合板及其制备工艺
TWI864435B (zh) * 2021-09-06 2024-12-01 台灣氣凝膠科技材料開發股份有限公司 低介電氣凝膠/高分子複合膜製備方法
CN114133209B (zh) * 2021-12-06 2022-10-04 中国科学院工程热物理研究所 疏水性纤维复合硅气凝胶材料的制备方法
JP7719299B2 (ja) 2021-12-17 2025-08-05 アスペン エアロゲルズ,インコーポレイティド 圧縮永久ひずみが低いエアロゲル及びエアロゲル複合材、ならびに作製方法
KR102842651B1 (ko) * 2022-01-27 2025-08-05 주식회사 익스톨 내화성이 부여된 단열 탄소섬유 복합체 제조방법
JP2025519308A (ja) 2022-06-10 2025-06-26 アスペン エアロゲルズ,インコーポレイティド アルミノケイ酸塩エアロゲル
EP4590422A1 (en) * 2022-10-13 2025-07-30 Aspen Aerogels, Inc. Compressed aerogel composite and method of making
JP2025534655A (ja) 2022-10-14 2025-10-17 アスペン エアロゲルズ,インコーポレイティド 単一容器内での湿潤ゲルのエージング及び抽出
CN115819973B (zh) * 2022-11-04 2023-10-20 航天特种材料及工艺技术研究所 一种大尺寸连续气凝胶卷材快速复合制备方法
EP4570758A1 (en) * 2023-04-19 2025-06-18 Lg Chem, Ltd. Aerogel blanket
CN121263564A (zh) 2023-06-05 2026-01-02 卡博特公司 柔性隔绝构件
WO2025178929A1 (en) 2024-02-20 2025-08-28 Aspen Aerogels, Inc. Resilient silica aerogels with reduced processing

Family Cites Families (113)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2188007A (en) 1937-07-03 1940-01-23 Samuel S Kistler Inorganic aerogel compositions
BE556585A (es) * 1956-04-11
FR1568817A (es) 1967-11-30 1969-05-30
US4022152A (en) 1969-03-29 1977-05-10 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Apparatus for making particulate materials, particularly oxides, hydrophobic
US4007050A (en) 1969-03-29 1977-02-08 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Hydrophobic oxides of metals and for metalloids
US3920865A (en) 1969-03-29 1975-11-18 Degussa Process of hydrophorizing highly dispersed metal or metalloid oxides
US4036933A (en) 1974-01-18 1977-07-19 Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler Highly-active, finely divided super-dry silicon dioxide
DE2942180C2 (de) 1979-10-18 1985-02-21 Grünzweig + Hartmann und Glasfaser AG, 6700 Ludwigshafen Verfahren zur Herstellung eines Wärmeisolierkörpers
US4402927A (en) 1980-04-22 1983-09-06 Dardel Guy Von Silica aerogel
DE3108816A1 (de) 1981-03-09 1982-09-30 Grünzweig + Hartmann und Glasfaser AG, 6700 Ludwigshafen Waermedaemmender pressstoff auf der basis von aus der flammenhydrolyse gewonnenem mikroporoesem oxidaerogel, sowie verfahren zu seiner herstellung, eine daraus hergestellte folie und ein damit hergestelltes kaschiertes waermedaemmelement
FR2507171A1 (fr) 1981-06-04 1982-12-10 Zarzycki Jerzy Aerogels de silice monolithiques, leur preparation et leur utilisation pour la preparation d'articles en verre de silice et de materiaux thermiquement isolants
US4717708A (en) 1983-12-27 1988-01-05 Stauffer Chemical Company Inorganic oxide aerogels and their preparation
DE3429671A1 (de) 1984-08-11 1986-02-20 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von aerogelen
US4619908A (en) 1984-12-24 1986-10-28 Stauffer Chemical Company Non-aged inorganic oxide-containing aerogels and their preparation
US4610863A (en) 1985-09-04 1986-09-09 The United States Of America As Represented By The United States Department Of Energy Process for forming transparent aerogel insulating arrays
JPS6345418A (ja) 1986-08-13 1988-02-26 Kubota Ltd 排気タ−ビン過給機付エンジンの軽負荷時過給休止装置
GB2210036B (en) 1987-03-26 1992-01-29 Matsushita Electric Works Ltd Method for manufacturing fine porous member
SU1680623A1 (ru) * 1989-05-27 1991-09-30 Институт катализа СО АН СССР Способ получени блоков аэрогел оксида кремни
US5037859A (en) 1989-06-20 1991-08-06 The United States Of America As Represented By The United States Department Of Energy Composite foams
US4966919A (en) 1989-06-20 1990-10-30 The United States Of America As Represented By The United States Department Of Energy Composite foams
DE69128073T2 (de) 1990-08-23 1998-02-26 Univ California As Represented Verfahren zur herstellung von metalloxidaerogelen mit dichte weniger als 0,02 g/cm3
US5306555A (en) 1991-09-18 1994-04-26 Battelle Memorial Institute Aerogel matrix composites
WO1993016125A1 (en) 1992-02-18 1993-08-19 Matsushita Electric Works, Ltd. Process for producing hydrophobic aerogel
US5565142A (en) 1992-04-01 1996-10-15 Deshpande; Ravindra Preparation of high porosity xerogels by chemical surface modification.
DE4300598A1 (de) * 1993-01-13 1994-07-14 Basf Ag Kohlenstoff-Partikel enthaltende SiO¶2¶-Aerogele und Verfahren zu ihrer Herstellung
US5395805A (en) 1993-03-25 1995-03-07 Regents Of The University Of California Method for making monolithic metal oxide aerogels
US5420168A (en) 1993-04-01 1995-05-30 The Regents Of The University Of California Method of low pressure and/or evaporative drying of aerogel
WO1995017347A1 (en) 1993-12-23 1995-06-29 Ppg Industries, Inc. Silica aerogel produced under subcritical conditions
DE4404701A1 (de) 1994-02-15 1995-08-17 Hoechst Ag Verbundschaumstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung
JPH0834678A (ja) * 1994-07-27 1996-02-06 Matsushita Electric Works Ltd エアロゲルパネル
US5569513A (en) 1994-08-10 1996-10-29 Armstrong World Industries, Inc. Aerogel-in-foam thermal insulation and its preparation
DE4430669A1 (de) 1994-08-29 1996-03-07 Hoechst Ag Verfahren zur Herstellung von faserverstärkten Xerogelen, sowie ihre Verwendung
DE4430642A1 (de) 1994-08-29 1996-03-07 Hoechst Ag Aerogel- und Xerogelverbundstoffe, Verfahren zu ihrer Herstellung sowie ihre Verwendung
DE4437424A1 (de) * 1994-10-20 1996-04-25 Hoechst Ag Aerogelhaltige Zusammensetzung, Verfahren zu ihrer Herstellung sowie ihre Verwendung
US6083619A (en) 1994-11-23 2000-07-04 Hoechst Aktiengesellschaft Composite material containing aerogel, process for its preparation, and its use
DE4441567A1 (de) 1994-11-23 1996-05-30 Hoechst Ag Aerogelhaltiges Verbundmaterial, Verfahren zu seiner Herstellung sowie seine Verwendung
ES2146795T3 (es) 1994-12-21 2000-08-16 Cabot Corp Fibras de dos componentes que contienen materiales de vellon de fibra, de aerogel y compuestos, procedimiento para su elaboracion, asi como modo de utilizacion.
DE19507732A1 (de) * 1995-03-07 1996-09-12 Hoechst Ag Transparentes Bauelement, enthaltend mindestens eine faserverstärkte Aerogelplatte und/oder -matte
JP3520601B2 (ja) * 1995-04-28 2004-04-19 松下電工株式会社 エアロゲルの製法
US6887563B2 (en) 1995-09-11 2005-05-03 Cabot Corporation Composite aerogel material that contains fibres
DE19541279A1 (de) 1995-11-06 1997-05-07 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen unter Verwendung von Alkoholen
WO1997017308A1 (en) 1995-11-09 1997-05-15 Aspen Systems, Inc. Flexible aerogel superinsulation and its manufacture
EP0775669B1 (en) * 1995-11-16 2001-05-02 Texas Instruments Incorporated Low volatility solvent-based precursors for nanoporous aerogels
FR2741420B1 (fr) * 1995-11-16 1997-12-26 Elf Aquitaine Systeme d'isolation thermique et/ou acoustique d'un conduit
DE19548128A1 (de) 1995-12-21 1997-06-26 Hoechst Ag Faservlies-Aerogel-Verbundmaterial enthaltend mindestens ein thermoplastisches Fasermaterial, Verfahren zu seiner Herstellung, sowie seine Verwendung
JPH10147664A (ja) * 1996-11-20 1998-06-02 C I Kasei Co Ltd エアロゲル断熱パネルおよびその製造方法
DE19648798C2 (de) * 1996-11-26 1998-11-19 Hoechst Ag Verfahren zur Herstellung von organisch modifizierten Aerogelen durch Oberflächenmodifikation des wäßrigen Gels (ohne vorherigen Lösungsmitteltausch) und anschließender Trocknung
US5972254A (en) 1996-12-06 1999-10-26 Sander; Matthew T. Ultra-thin prestressed fiber reinforced aerogel honeycomb catalyst monoliths
US6197270B1 (en) 1996-12-20 2001-03-06 Matsushita Electric Works, Ltd. Process for producing aerogel
JP3339394B2 (ja) * 1996-12-24 2002-10-28 松下電工株式会社 疎水性エアロゲルの製法
US5691392A (en) 1997-02-05 1997-11-25 Ppg Industries, Inc. Stable particulate dispersions
US6315971B1 (en) 1997-04-09 2001-11-13 Cabot Corporation Process for producing low density gel compositions
DE19718741A1 (de) 1997-05-02 1998-11-05 Hoechst Ag Verfahren zur Kompaktierung von Aerogelen
US5962539A (en) 1997-05-09 1999-10-05 Separex S.A. Process and equipment for drying a polymeric aerogel in the presence of a supercritical fluid
US6316050B1 (en) 1997-12-22 2001-11-13 Degussa Method of producing hydrophobic pyrogenically produced oxides
US5973015A (en) 1998-02-02 1999-10-26 The Regents Of The University Of California Flexible aerogel composite for mechanical stability and process of fabrication
JP2960927B1 (ja) 1998-07-21 1999-10-12 株式会社日本吸収体技術研究所 シート状高吸水性複合体の製造法
DE19834265A1 (de) 1998-07-30 2000-02-17 Thomas Gesner Verfahren zur Herstellung von Aerogelen und Anlage zur Herstellung von Aerogelschichten auf Substraten oder aus Aerogelen bestehenden Produkten
US6187250B1 (en) 1998-08-19 2001-02-13 James Champagne Continuous gel casting method and apparatus
HK1049295A1 (zh) 1999-10-21 2003-05-09 阿斯彭系统公司 气凝胶的快速生产方法
TWI250968B (en) * 2000-04-04 2006-03-11 Asahi Kasei Corp Coating composition for use in producing a silica insulating thin film and method for producing a silica insulating thin film
US20020000290A1 (en) 2000-06-29 2002-01-03 Crump Larry Scott Curing of a gel coat on a mold
IT1318617B1 (it) 2000-07-10 2003-08-27 Novara Technology Srl Processo sol-gel per la produzione di geli secchi di grandidimensioni e vetri derivati.
CN1306993C (zh) 2000-12-22 2007-03-28 思攀气凝胶公司 带有纤维胎的气凝胶复合材料
RU2004126237A (ru) 2002-01-29 2005-05-27 Кабот Корпорейшн (US) Термостойкий аэрогельный изолирующий композиционный материал и способ его получения: аэрогельная связующая композиция и способ ее получения
US6770584B2 (en) 2002-08-16 2004-08-03 The Boeing Company Hybrid aerogel rigid ceramic fiber insulation and method of producing same
PL3120983T5 (pl) 2003-06-24 2024-04-22 Aspen Aerogels, Inc. Ciągły arkusz materiału żelowego oraz ciągły arkusz materiału aerożelowego
JP2007524739A (ja) 2004-01-06 2007-08-30 アスペン エアロゲルズ,インコーポレイティド ケイ素結合線状ポリマーを含有するオルモシルエーロゲル
CN101014535A (zh) * 2004-01-06 2007-08-08 白杨气凝胶股份有限公司 含有键合硅的聚甲基丙烯酸酯的有机改性的二氧化硅气凝胶
EP1770063A1 (en) 2004-05-14 2007-04-04 Dynax Corporation Process for producing silica aerogel
ES2392644T3 (es) 2004-06-29 2012-12-12 Aspen Aerogels Inc. Cerramientos para edificios energéticamente eficientes y provistos de aislamiento
US20070238008A1 (en) 2004-08-24 2007-10-11 Hogan Edward J Aerogel-based vehicle thermal management systems and methods
WO2007001354A2 (en) * 2004-09-01 2007-01-04 Aspen Aerogels, Inc. High performance vacuum-sealed insulations
WO2007086819A2 (en) 2004-11-24 2007-08-02 Aspen Aerogels, Inc. High strength aerogel panels
DE102004061981A1 (de) * 2004-12-23 2006-07-06 Rehau Ag + Co. Materialzusammensetzung zur UV-Vernetzung
US20060178496A1 (en) 2005-02-07 2006-08-10 Industrial Technology Research Institute Silica aerogels with high-temperature hydrophobation synthesized by using co-precursor solutions
WO2007011750A2 (en) * 2005-07-15 2007-01-25 Aspen Aerogels, Inc. Secured aerogel composites and method of manufacture thereof
WO2007079244A2 (en) * 2005-12-29 2007-07-12 Aspen Aerogels, Inc. Improved gel production via multi-stream mixing
US20070259979A1 (en) * 2006-05-03 2007-11-08 Aspen Aerogels, Inc. Organic aerogels reinforced with inorganic aerogel fillers
US7790787B2 (en) * 2006-05-03 2010-09-07 The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration Aerogel/polymer composite materials
WO2007140293A2 (en) 2006-05-25 2007-12-06 Aspen Aerogels, Inc. Aerogel compositions with enhanced performance
US20090029147A1 (en) 2006-06-12 2009-01-29 Aspen Aerogels, Inc. Aerogel-foam composites
DE102007024094A1 (de) 2007-05-22 2008-11-27 Evonik Degussa Gmbh Hydrophobe pyrogen hergestellte Kieselsäure und Silikonkautschukmassen, enthaltend die pyrogene Kieselsäure
DE102007055879A1 (de) 2007-12-19 2009-06-25 Wacker Chemie Ag Hydrophobierung von Kieselsäuren und oxidierenden Bedingungen
JP2010047710A (ja) * 2008-08-22 2010-03-04 National Institute Of Advanced Industrial Science & Technology 柔軟性、成形性を有する発泡ポリマー−シリカ複合体およびそれを用いた断熱材料
WO2010080237A2 (en) * 2008-12-18 2010-07-15 3M Innovative Properties Company Hydrophobic aerogels
WO2010080239A2 (en) * 2008-12-18 2010-07-15 3M Innovative Properties Company Methods of preparing hybrid aerogels
KR101042251B1 (ko) * 2008-12-23 2011-06-17 한국생산기술연구원 소수성을 갖는 에어로겔 과립 제조방법
CN105143141A (zh) * 2009-04-27 2015-12-09 罗克伍尔国际公司 气凝胶组合物及其制备方法和使用方法
KR101047965B1 (ko) * 2009-06-11 2011-07-12 한국에너지기술연구원 에어로겔 매트, 이의 제조방법 및 제조장치
CN101691227B (zh) * 2009-10-13 2011-10-12 厦门大学 二氧化硅气凝胶材料的制备方法
CN101698584B (zh) * 2009-11-13 2012-10-03 航天特种材料及工艺技术研究所 一种纤维增强二氧化硅气凝胶连续毡的制备方法
WO2012021499A1 (en) * 2010-08-10 2012-02-16 Massachusetts Institute Of Technology Silica aerogels and their preparation
CN101948297B (zh) * 2010-09-28 2013-02-20 航天特种材料及工艺技术研究所 一种自催化的气凝胶隔热复合材料及其制备方法
CN101948296B (zh) * 2010-09-28 2013-08-21 航天特种材料及工艺技术研究所 一种高性能隔热材料及其制备方法
CN101973752B (zh) * 2010-10-21 2013-01-23 厦门大学 玻璃纤维增强二氧化硅气凝胶复合材料及其制备方法
US8952119B2 (en) * 2010-11-18 2015-02-10 Aspen Aerogels, Inc. Organically modified hybrid aerogels
EP2481859A1 (en) 2011-01-17 2012-08-01 Aspen Aerogels Inc. Composite aerogel thermal insulation system
CN102225769A (zh) 2011-05-09 2011-10-26 北京化工大学 一种弹性二氧化硅气凝胶的制备方法
CN102351494B (zh) * 2011-07-20 2013-07-24 厦门大学 一种泡沫材料增强二氧化硅气凝胶复合材料的制备方法
CN103130231B (zh) * 2011-11-25 2015-09-02 航天特种材料及工艺技术研究所 一种二氧化硅气凝胶材料及其制备方法
US20130196137A1 (en) 2012-01-27 2013-08-01 Aspen Aerogels, Inc. Composite Aerogel Thermal Insulation System
JP2013231697A (ja) 2012-05-01 2013-11-14 Sumitomo Osaka Cement Co Ltd 混合土壌の混合精度判定方法
US11053369B2 (en) 2012-08-10 2021-07-06 Aspen Aerogels, Inc. Segmented flexible gel composites and rigid panels manufactured therefrom
CN103113043B (zh) 2013-02-04 2015-09-09 四川大学 无机微纳米粒子/聚合物复合建筑保温气凝胶材料及制备方法
CN105189104B (zh) 2013-03-08 2020-02-04 斯攀气凝胶公司 气凝胶绝缘面板及其制造
KR101786283B1 (ko) * 2013-03-15 2017-10-17 캐보트 코포레이션 에어로겔 블랭킷 및 그의 제조 방법
FR3007025B1 (fr) 2013-06-14 2015-06-19 Enersens Materiaux composites isolants comprenant un aerogel inorganique et une mousse de melamine
PT107101A (pt) * 2013-08-02 2015-02-02 Univ De Coimbra Painéis flexíveis de aerogel hidrofóbico reforçado com feltro de fibras
WO2015065557A1 (en) 2013-11-04 2015-05-07 Aspen Aerogels, Inc. Benzimidazole based aerogel materials
US20170154379A1 (en) 2014-07-08 2017-06-01 Inanlar Insaat Anonim Sirketi A novel system for the valuation and sales of immovable properties
CA3041713C (en) * 2014-10-03 2025-05-06 Aspen Aerogels, Inc. IMPROVED HYDROPHOBIC AEROGEEL MATERIALS
WO2019232087A1 (en) * 2018-05-31 2019-12-05 Aspen Aerogels, Inc. Fire-class reinforced aerogel compositions

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