MX2019009974A - Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc. - Google Patents
Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc.Info
- Publication number
- MX2019009974A MX2019009974A MX2019009974A MX2019009974A MX2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A MX 2019009974 A MX2019009974 A MX 2019009974A
- Authority
- MX
- Mexico
- Prior art keywords
- range
- zinc catalyst
- preparing poly
- trimethylene furandicarboxylate
- propanediol
- Prior art date
Links
- -1 poly(trimethylene furandicarboxylate) Polymers 0.000 title abstract 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000011701 zinc Substances 0.000 title 1
- 229910052725 zinc Inorganic materials 0.000 title 1
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 abstract 2
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- DNXDYHALMANNEJ-UHFFFAOYSA-N furan-2,3-dicarboxylic acid Chemical compound OC(=O)C=1C=COC=1C(O)=O DNXDYHALMANNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229920000166 polytrimethylene carbonate Polymers 0.000 abstract 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 abstract 1
- 150000002009 diols Chemical class 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003752 zinc compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/672—Dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/88—Post-polymerisation treatment
- C08G63/90—Purification; Drying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
- C08K5/08—Quinones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
En la presente se describe un proceso que comprende los pasos de: a) poner en contacto una mezcla que comprende éster dialquílico del ácido furanodicarboxílico, 1,3-propanodiol, un compuesto de zinc y opcionalmente un poli(éter alquilénico)diol, a una temperatura comprendida en el intervalo de aproximadamente 120 °C a aproximadamente 220 °C para formar un prepolímero, donde la relación molar del éster dialquílico del ácido furanodicarboxílico respecto al 1,3-propanodiol está comprendida en el intervalo de 1:1.3 a 1:2.2; y b) calentar el prepolímero a presión reducida hasta una temperatura comprendida en el intervalo de aproximadamente 220 °C a aproximadamente 260 °C para formar el polímero. La mezcla del paso a) puede comprender además un compuesto de tipo antraquinona.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762462948P | 2017-02-24 | 2017-02-24 | |
| PCT/US2018/019363 WO2018156859A1 (en) | 2017-02-24 | 2018-02-23 | Process for preparing poly(trimethylene furandicarboxylate) using zinc catalyst |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019009974A true MX2019009974A (es) | 2020-01-27 |
Family
ID=61563558
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019009974A MX2019009974A (es) | 2017-02-24 | 2018-02-23 | Proceso para preparar poli (furanodicarboxilato de trimetileno) usando un catalizador de zinc. |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US20200017634A1 (es) |
| EP (2) | EP3585827B1 (es) |
| JP (2) | JP7204687B2 (es) |
| KR (2) | KR20230067711A (es) |
| CN (2) | CN110520459B (es) |
| AU (2) | AU2018225205A1 (es) |
| CA (1) | CA3054371A1 (es) |
| ES (1) | ES2880324T3 (es) |
| MX (1) | MX2019009974A (es) |
| WO (1) | WO2018156859A1 (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111116880B (zh) * | 2020-01-17 | 2021-11-30 | 沈阳化工大学 | 一种基于呋喃环的全生物基热塑性聚酯弹性体及其制备方法 |
| CN117986551A (zh) * | 2024-02-28 | 2024-05-07 | 华东理工大学 | 一种基于生物质基2,5-呋喃二甲酸的含支链的长碳链聚酯弹性体及其制备方法 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4843668B1 (es) * | 1968-12-03 | 1973-12-20 | ||
| EP0861279A1 (en) | 1995-11-13 | 1998-09-02 | Eastman Chemical Company | Thermally stable polyesters formed utilizing antimony compounds as catalysts |
| US5608031A (en) * | 1995-11-30 | 1997-03-04 | Eastman Chemical Company | Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system |
| CN1552754A (zh) * | 2003-06-04 | 2004-12-08 | 中国石化集团天津石油化工公司 | 一种缩短聚酯生产中缩聚反应时间的方法 |
| JP4135581B2 (ja) * | 2003-07-02 | 2008-08-20 | 三菱化学株式会社 | 有機系調色剤含有ポリエステルの製造方法 |
| ATE382066T1 (de) * | 2004-05-05 | 2008-01-15 | Saudi Basic Ind Corp | Verfahren zur herstellung von copolyestern aus polyethylenterephthalat |
| JP2008239771A (ja) | 2007-03-27 | 2008-10-09 | Teijin Fibers Ltd | ポリエチレンテレフタレートの連続式製造方法 |
| JP5233390B2 (ja) | 2007-04-24 | 2013-07-10 | 三菱化学株式会社 | フラン構造を含むポリエステル樹脂の製造方法 |
| CN101899145B (zh) | 2010-07-28 | 2012-07-11 | 江南大学 | 一种2,5-呋喃二甲酸基聚酯的制备方法 |
| US9527954B2 (en) * | 2011-10-24 | 2016-12-27 | Furanix Technologies B.V. | Process for preparing a polymer product having a 2,5-furandicarboxylate moiety within the polymer backbone to be used in bottle, film or fibre applications |
| WO2013149157A1 (en) * | 2012-03-30 | 2013-10-03 | E. I. Du Pont De Nemours And Company | Polyesters and fibers made therefrom |
| KR101969004B1 (ko) * | 2012-06-05 | 2019-04-15 | 에스케이케미칼 주식회사 | 폴리에스테르 수지 및 이의 제조 방법 |
| CA3181003A1 (en) * | 2013-12-20 | 2015-06-25 | E. I. Du Pont De Nemours And Company | Nucleated crystallization of poly(trimethylene-2,5-furandicarboxylate) (ptf) and articles made therefrom |
| WO2015142181A1 (en) * | 2014-03-21 | 2015-09-24 | Furanix Technologies B.V. | Polyesters comprising 2,5-furandicarboxylate and saturated diol units having a high glass transition temperature |
| CN106432701A (zh) | 2016-09-14 | 2017-02-22 | 中国科学院宁波材料技术与工程研究所 | 一种生物基不饱和聚酯及其制备方法和应用 |
| ES2962764T3 (es) * | 2016-10-14 | 2024-03-21 | Covation Inc | Procedimiento para preparar poli(furandicarboxilato de trimetileno) |
-
2018
- 2018-02-23 EP EP18708880.2A patent/EP3585827B1/en active Active
- 2018-02-23 KR KR1020237015319A patent/KR20230067711A/ko not_active Ceased
- 2018-02-23 WO PCT/US2018/019363 patent/WO2018156859A1/en not_active Ceased
- 2018-02-23 ES ES18708880T patent/ES2880324T3/es active Active
- 2018-02-23 CN CN201880025372.6A patent/CN110520459B/zh active Active
- 2018-02-23 AU AU2018225205A patent/AU2018225205A1/en not_active Abandoned
- 2018-02-23 CA CA3054371A patent/CA3054371A1/en active Pending
- 2018-02-23 JP JP2019567502A patent/JP7204687B2/ja active Active
- 2018-02-23 MX MX2019009974A patent/MX2019009974A/es unknown
- 2018-02-23 KR KR1020197027760A patent/KR20190119112A/ko not_active Ceased
- 2018-02-23 CN CN202310079467.9A patent/CN116041675A/zh active Pending
- 2018-02-23 EP EP21155743.4A patent/EP3878886A1/en not_active Withdrawn
- 2018-02-23 US US16/485,940 patent/US20200017634A1/en not_active Abandoned
-
2021
- 2021-05-05 US US17/308,672 patent/US20210269589A1/en not_active Abandoned
-
2022
- 2022-12-27 JP JP2022209174A patent/JP2023036861A/ja active Pending
-
2023
- 2023-04-21 US US18/137,822 patent/US20230257520A1/en not_active Abandoned
- 2023-11-28 AU AU2023274099A patent/AU2023274099A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP3878886A1 (en) | 2021-09-15 |
| CA3054371A1 (en) | 2018-08-30 |
| WO2018156859A1 (en) | 2018-08-30 |
| JP7204687B2 (ja) | 2023-01-16 |
| US20230257520A1 (en) | 2023-08-17 |
| CN110520459B (zh) | 2022-12-02 |
| JP2020508390A (ja) | 2020-03-19 |
| CN116041675A (zh) | 2023-05-02 |
| KR20190119112A (ko) | 2019-10-21 |
| KR20230067711A (ko) | 2023-05-16 |
| ES2880324T3 (es) | 2021-11-24 |
| US20210269589A1 (en) | 2021-09-02 |
| EP3585827B1 (en) | 2021-04-21 |
| US20200017634A1 (en) | 2020-01-16 |
| EP3585827A1 (en) | 2020-01-01 |
| CN110520459A (zh) | 2019-11-29 |
| JP2023036861A (ja) | 2023-03-14 |
| AU2018225205A1 (en) | 2019-09-05 |
| AU2023274099A1 (en) | 2023-12-14 |
| BR112019017619A2 (pt) | 2020-03-24 |
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