MX2019004348A - Articulos cataliticos. - Google Patents
Articulos cataliticos.Info
- Publication number
- MX2019004348A MX2019004348A MX2019004348A MX2019004348A MX2019004348A MX 2019004348 A MX2019004348 A MX 2019004348A MX 2019004348 A MX2019004348 A MX 2019004348A MX 2019004348 A MX2019004348 A MX 2019004348A MX 2019004348 A MX2019004348 A MX 2019004348A
- Authority
- MX
- Mexico
- Prior art keywords
- particles
- catalytic
- scale
- mixture
- substrate
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/63—Platinum group metals with rare earths or actinides
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/944—Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/44—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
- B01J37/0219—Coating the coating containing organic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/038—Precipitation; Co-precipitation to form slurries or suspensions, e.g. a washcoat
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/04—Mixing
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1021—Platinum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
- B01D2255/1023—Palladium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2065—Cerium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20715—Zirconium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2092—Aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/908—O2-storage component incorporated in the catalyst
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9202—Linear dimensions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/92—Dimensions
- B01D2255/9205—Porosity
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/01—Engine exhaust gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0027—Powdering
- B01J37/0036—Grinding
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES
- F01N2370/00—Selection of materials for exhaust purification
- F01N2370/02—Selection of materials for exhaust purification used in catalytic reactors
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Toxicology (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Catalysts (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
Artículos catalíticos que comprenden un sustrato que tiene un recubrimiento catalítico sobre este, en donde el recubrimiento catalítico comprende una capa catalítica; en donde la capa catalítica comprende un componente de metal noble sobre partículas de soporte, y en donde las partículas de soporte tienen una distribución bimodal del tamaño de partículas que comprende partículas a escala micrométrica y partículas a escala nanométrica, que son altamente eficaces para tratar los flujos de escape de motores de combustión interna. Los artículos se preparan mediante un método que comprende proporcionar una primera mezcla que comprende partículas de soporte a escala micrométrica; proporcionar una segunda mezcla que comprende partículas de soporte a escala nanométrica y un componente de metal noble que tiene un pH inicial; mezclar la primera y segunda mezclas; aplicar la mezcla a un sustrato para formar una capa catalítica y calcinar el sustrato.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/101900 WO2018068229A1 (en) | 2016-10-12 | 2016-10-12 | Catalytic articles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2019004348A true MX2019004348A (es) | 2019-09-19 |
Family
ID=61905054
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2019004348A MX2019004348A (es) | 2016-10-12 | 2016-10-12 | Articulos cataliticos. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20210283582A1 (es) |
| EP (1) | EP3525927A4 (es) |
| JP (1) | JP2020500097A (es) |
| KR (1) | KR20190072560A (es) |
| CN (1) | CN110022975A (es) |
| BR (1) | BR112019006473A2 (es) |
| CA (1) | CA3039392A1 (es) |
| MX (1) | MX2019004348A (es) |
| RU (1) | RU2731562C1 (es) |
| WO (1) | WO2018068229A1 (es) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102743542B1 (ko) * | 2019-04-12 | 2024-12-16 | 더블유. 엘. 고어 앤드 어소시에이트스, 인코포레이티드 | 고성능 대형 입자 촉매 테이프 |
| WO2022258961A1 (en) * | 2021-06-10 | 2022-12-15 | Johnson Matthey Public Limited Company | Improved twc activity using rhodium/platinum and tannic acid as a complexing and reducing agent |
| KR102621234B1 (ko) * | 2021-08-13 | 2024-01-09 | 현대자동차 주식회사 | 알루미나 상에 담지된 나노-세리아의 구조 변형을 통한 황 피독 저항성 개선방법 |
| EP4166230A1 (en) * | 2021-10-12 | 2023-04-19 | Johnson Matthey Public Limited Company | Catalyst article for exhaust system of natural gas engine |
| WO2024008077A1 (en) * | 2022-07-05 | 2024-01-11 | Basf Corporation | Catalytic article comprising ammonia oxidation catalyst |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4244712C2 (de) * | 1992-02-14 | 1996-09-05 | Degussa | Beschichtungsdispersion zur Herstellung von kalysefördernden Überzügen auf einem inerten, strukturverstärkenden Körper |
| WO2000062923A1 (en) * | 1999-04-19 | 2000-10-26 | Engelhard Corporation | Catalyst composition comprising ceria and a platinum group metal |
| JP2001286759A (ja) * | 2000-04-07 | 2001-10-16 | Honda Motor Co Ltd | 排気ガス浄化用触媒 |
| US6956007B2 (en) * | 2003-08-25 | 2005-10-18 | General Motors Corporation | Noble metal catalyst |
| CN101400441B (zh) * | 2005-11-01 | 2014-12-31 | 日产自动车株式会社 | 废气净化用催化剂及其制造方法 |
| US8119075B2 (en) * | 2005-11-10 | 2012-02-21 | Basf Corporation | Diesel particulate filters having ultra-thin catalyzed oxidation coatings |
| SG183687A1 (en) * | 2007-08-03 | 2012-09-27 | Errcive Inc | Porous bodies and methods |
| JP5014086B2 (ja) * | 2007-11-26 | 2012-08-29 | 株式会社キャタラー | 排ガス浄化用触媒 |
| US9126191B2 (en) * | 2009-12-15 | 2015-09-08 | SDCmaterials, Inc. | Advanced catalysts for automotive applications |
| JP5376261B2 (ja) * | 2011-03-10 | 2013-12-25 | トヨタ自動車株式会社 | 排ガス浄化用触媒 |
| KR101336595B1 (ko) * | 2011-09-27 | 2013-12-05 | 희성촉매 주식회사 | 이봉 분포 입자크기 지지체들을 가지는 배기가스 정화용 촉매 |
| US9358533B2 (en) * | 2012-12-20 | 2016-06-07 | Basf Corporation | Hollow microsphere catalyst support and methods of making same |
| KR20150131017A (ko) * | 2013-03-14 | 2015-11-24 | 바스프 코포레이션 | 분리된 워시코트를 갖는 촉매 물품 및 이의 제조 방법 |
| CN105592921A (zh) * | 2013-07-25 | 2016-05-18 | Sdc材料公司 | 用于催化转化器的洗涂层和经涂覆基底及其制造和使用方法 |
| EP3060335A4 (en) * | 2013-10-22 | 2017-07-19 | SDCMaterials, Inc. | Catalyst design for heavy-duty diesel combustion engines |
| US20160038874A1 (en) * | 2014-07-29 | 2016-02-11 | SDCmaterials, Inc. | Three way catalytic converter using hybrid catalytic particles |
| WO2016019067A1 (en) * | 2014-07-29 | 2016-02-04 | SDCmaterials, Inc. | Zone coated catalytic substrates with passive nox adsorption zones |
| RU2730496C2 (ru) * | 2015-01-29 | 2020-08-24 | Басф Корпорейшн | Содержащие родий катализаторы для обработки автомобильных выхлопов |
-
2016
- 2016-10-12 BR BR112019006473A patent/BR112019006473A2/pt not_active Application Discontinuation
- 2016-10-12 WO PCT/CN2016/101900 patent/WO2018068229A1/en not_active Ceased
- 2016-10-12 US US16/340,748 patent/US20210283582A1/en not_active Abandoned
- 2016-10-12 CN CN201680090030.3A patent/CN110022975A/zh active Pending
- 2016-10-12 EP EP16918477.7A patent/EP3525927A4/en not_active Withdrawn
- 2016-10-12 MX MX2019004348A patent/MX2019004348A/es unknown
- 2016-10-12 JP JP2019520022A patent/JP2020500097A/ja active Pending
- 2016-10-12 RU RU2019113942A patent/RU2731562C1/ru active
- 2016-10-12 KR KR1020197013112A patent/KR20190072560A/ko not_active Ceased
- 2016-10-12 CA CA3039392A patent/CA3039392A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR20190072560A (ko) | 2019-06-25 |
| CN110022975A (zh) | 2019-07-16 |
| US20210283582A1 (en) | 2021-09-16 |
| RU2731562C1 (ru) | 2020-09-04 |
| EP3525927A1 (en) | 2019-08-21 |
| JP2020500097A (ja) | 2020-01-09 |
| WO2018068229A1 (en) | 2018-04-19 |
| EP3525927A4 (en) | 2020-05-27 |
| CA3039392A1 (en) | 2018-04-19 |
| BR112019006473A2 (pt) | 2019-06-25 |
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